ADAMIJEE GOVT. SCIENCE COLLEGE KARACHI Off. Buisness Recorder Road, Garden East Karachi. PRELIMINARY EXAMINATION PAPER 2024 | Chemistry 1 -Atomic Mass: (Na=23 amu, H=1amu, P=3lamu, O=16amu, C=12amu, Cl=35.5 amu S=32amu, Ag=108amu, K=19amu, Mg=24 amu) SECTION ~ A (Multiple Choice Questions) (17 Marks) Note: This section consists of 17-part questions, and all are to be answered. Each question carries one mark. Ql @ (ii) ii) (iv) wv) co) (vii) (ix) @) (xi) (ii) iii) (xiv) (@) (xvi) (xvii) Which of the following samples of substances contains the same number of atoms as that of 20g Calcium: (a) l6gs 7 (b) 20g C (©) 192K (d) 24g Mg Line spectrum is used as a tool for the identification of: (a) Colors (b) Electrons (c) Elements (d) Molecules ‘The number of sigma and pi bonds in ethyne (CoH) molecule are respectively: (@)3 and 1 (b) 3 and 2 (c)2 and 2 (d) 4 and 2 The colour of universal indicator in basic medium (a) Red (b) Purple (c) Pink (d) Green In the Kelvin temperature of ideal gas is increase to double and pressure is reduce to one-half, the volume of gas pressure will: (a) Remains same (b) Double (c) Half (d) Four time Principal and azimuthal quantum number values for 3d orbital are: (@n=2,0=1 ()n=3,0=2 ()n=3,0=3 @)n=2,053 A liquid which showss maximum surface tension, is: : i (a) Water (0) Mereury (©) Ethyl alcohol (4) Gasoline Each unit cell of sodium chloride consists of: (a) Eight Na’ and eight CI’ ions (b) Two Na® and two CI ions (c) Four Na” and four CI’ ions (@ Four Na’ and six Cl ions If the radius of Zn’? ion is 0.74A° and S? ion is 1.84A°, the radius ratio of ZnS should be: (a) 0.74A° (b) 1.844° (©) 0.40A° (d) 2.48A° ‘Some reactions are nearly to completions in the forward direction and identified by their: (a) Very high value of Ke (b) Very low value of K, ‘ Very low value of AH (e) Very high value of AH @ Very 7 decomposition of H:Or is inhibited by: (a) 2% Ethanol (b) Glyceri (©) Mn0s @Vi0; Balmer series appears in the hydrogen spectrum if electron jumps from any appropriate high energy orbit ® 1* orbit, (b) 2" orbit (c) 3" orbit (a) 4 orbit smple of amphoteric oxide is: 7 he 7 (b) COr (©) CaO (@ AhOs (a ; ‘ik isan example of this type of colloid: te , meee (b) Aerosol (©) Emulsion (@ Foam (a) Ge’ i i 25°C and 1atm pressure are zero except of formation ofall ofthe following elements at 25°C and latm pres 1 — —_ (©) Crap (©) Oo (@N2 (a) Cieiamonty ing i sate function of a system? : ing is not a state y's which choad Following mg) Enthalpy (©) Intemal energy (@) Work done (a) Press! |vanic cell which is based on the reaction between: Fuel cell is a typical Gal (b) He & Or (©) CH: & O2 (@) He & SO; (a) Nz & OzADAMIJEE GOVT, SCIENCE COLLEGE KARACHI Off. Buisness Recorder Road, Garden East Karachi. HINARY LINATION PAPER 2024 Chemistry = 1 Atomic Mass: (Na=23.amu, H= tamu, P=3tamu, O= 16amu, C=12amu, Cl=35.5 amu 32amu, Ag SECTION ~ B (Short - Answer Questions) (36 Marks) Attempt any Nine (09) parts questions, Each question carries 04 marks. 1OSamu, K=19amu, Mg =24 amu) {What is limiting reactant? Sodium hydroxide (NaOH) reacts with phosphoric acid (HsPO:) to form sodium phosphate (NayPO.) and water by the reaction, 3NaOH + HyPO: ——® NasPOs + 3H:0 1F100g of NaOH and 100g of HsPOs are mixed for the reaction under specific conditions, determine the mass of sodium phosphate formed, ii, Give scientific reasons for any FOUR of the following: * Aqueous solution of NHiClis acidic in nature, * Powder zine is more reactive than the chunks of zinc. * Pressure cooker is used for rapid cooking. * Density of water is highest at 4°C. + Metallic solids conduct electricity and molecular solids possess low melting point. * Vapour pressure of solution is lowered by adding non-volatile solute. State Dalton’s law of partial pressure. Give its two ap} Calculate the molar mass of a given gas whose diffusion rate is 2.83 times the diffusion of methane (CH). Calculate the heat of formation from the following data: * 4NH3 + 50> —— 4N0+6HL0 AHr=? * V2N2+3/2H2 = ——> NH * V2N2+ 1/20: ——> NO * H+ 1/202 — > #0 v. The vapour pressure of a pure liquid ‘A’ is 37 mm Hg at 27°C, It is mixed into another liquid *B” to make a solution. The vapour pressure of “A’ in the solution is found to be 33 mm Hg. Calculate the mole fraction of *A’. (Assuming it obeys Raoult’s law) , vi. State and explain Law of Mass action. Apply this law to the following reversible reaction to obtain an expression of Ke. aN2 + DH —— wih OR Draw a molecular orbital diagram of 02 molecule and write down molecular orbital electronic configuration ~~ with determination of bond order. ; Silver sulphate (Ag:SO.) is used for medicinal purpose to fill wounds. Its solubility in water at 25°C is Wi 714310 mol/dm?. What will be its Ky? iii, What is corrosion? What causes it to form? What can be done to prevent its formation? vim. What is a Liquid crystal? Give its two properties and two uses. following terms: (Any Four) * Lattice energy * Osmotic pressure * Dipole moment * Common ion effect List the factors affecting on rate of reaction and how temperature can effect the rate of reaction, OB Determine the order of reaction. Also calculate the rate constant of the reaction from the fallowing data: x. ' INO} 103] dxdt aM mol / dm? mol / dm? mol / dm’. s O15 0.25 15 10" 0:30 0.25 60x10 | 0.15 0.75 43 X10"xiii. xiv. EF 2 B Q4 Io in 2 B ADAMJEE GOVT. SCIENCE COLLEGE KARACHI Off. Buisness Recorder Road, Garden East Karachi. Define pH and pOH ofa solution. Also show that pH + pOH = 14 A solution is made by dissolving 14,8g HCI in water at 25°C. If the volume of solution is 750 cm? and HCI is assumed to be completely ionized, calculate its pH. What is meant by Homogenous and Heterogeneous Catalysis? Give one example of each Explain all the four quantum numbers of two electrons of He-atom. Also write the electronic configuration of the following: * uP ~*9Cu * Ca” * aMo 150 cm? of Ha gas was collected over water at 800 mm Hg and 28°C. Calculate the mass in gram of Mz gas obtained. The pressure of water vapours at 28°C is 20 mm Hg. SECTION ~ C (Detailed - Answer Questions) (32 Marks) Answer any Two questions. All questions carry equal marks. (@) Write the postulates of VSEPR theory. Explain the shape of polyatomic molecules according to VSEPR theory containing: * Two bond pairs and two lone pairs * Three bond pairs and one lone pair (&) State Le-Chatelier principle and give its application in the synthesis of ammonia by Haber’s process. Differentiate between the following: (Any Four) * Sigma and pi bond * Oxidation and reduction * Exothermic and endothermic reaction * Crystalline solids and amorphous solids * Alpha particles and beta particles * Solution and suspension * Isomorphism and polymorphism * Ideal gas and non-ideal gas (a) __ State the main postulates of Bohr’s atomic theory and derive an expression for the frequency of radiation of hydrogen atom and wave number of photon from the following given values. KE = Ze PE -Ze r= eh? Breet rer MZ (b) Derive Van der Waal’s equation for real gases. One mole of ammonia gas is kept in acylinder of: at 27°C. Assuming ammonia gas as a real gas, then determine its pressure, (Van der Waal constant for ammonia: a= 4.17 atm.dm®.mol, b= 0.0371 dm'.mot") State the First law of thermodynamics and show that AH = AE + PAV. ‘What is meant by electrode potential and standard hydrogen electrode? Describe how the electrode potential of copper is determined. Balance the following equation according to ion-electron method. (Any TWO) @ * Ch+OH ~=——> Clo,+Cl+m0 + (CnO)*+h ———> CH+I0; (acidic) MnO, +(C0)?——> Mn+ C0; +20 State and explain Hess’s law of constant heat summation? Calculate the enthalpy of combustion of propane (C3Hs) at 25°C by the given information. CaHay) +502 = ———® 3COrg) + 4H:0 (aH? =2) ~ 104 Ki/mol) = (- 393.5 Ki/mol) — 2858 KI/mol) (b) AHrof CsHs ‘AH; of COx ‘AHrof H20u