12.5 Hypo Rho Rite Solution MSDS
12.5 Hypo Rho Rite Solution MSDS
12.5 Hypo Rho Rite Solution MSDS
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Hasa Inc. 23119 Drayton Street Saugus, California 91350 Telephone 661.259.5848 Fax 661.259.1538
CAS # (Chemical Abstracts Service): RTECS (Registry of Toxic Effects of Chemical Substances): EINECS (European Inventory of Existing Commercial Substances):
HASA 12.5% SODIUM HYPOCHLORITE SOLUTION 7681-52-9 NH3486300 231-668-3 231-668-3 Bleach, Hypo, Hypochlorite, Liquid Chlorine Solution Sodium Hypochlorite NaOCl Manufacturing use product. Hasa Inc. 23119 Drayton Street Saugus, California 91350 CHEMTREC 1-800-424-9300 (24 hour) 661-259-5848 (8 AM 5 PM PST / PDT)
EC Number: Synonym: Chemical Name: Chemical Formula: 1.2 Recommended Uses: 1.3 Company Identification:
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2.2 Routes of Entry: 2.3 Short Term Exposure: 2.3.1 Eyes: Causes serious eye irritation. Blurred vision. May cause impairment of vision and corneal damage. 2.3.2 Skin: May cause skin irritation and/or dermatitis. Prolonged skin exposure may cause destruction of the dermis with impairment of the skin to regenerate at site of contact. 2.3.3 Inhalation: Accidental mixing with other chemicals or decomposition of sodium hypochlorite vapor is irritating to the respiratory system. 2.3.4 Ingestion: Ingestion of high concentrations may cause injuries to gastrointestinal tract, liver, kidneys and central nervous system. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. 2.3.5 Aggravated Asthma, heart disease, respiratory disorders. Medical Conditions: 2.4 Long Term Based on the toxicity profile and exposure scenarios for sodium Exposure: hypochlorite, EPA concludes that the risks from chronic and subchronic exposure to low levels of this pesticide are minimal and without consequence to human health.
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4.2 IF ON SKIN OR
CLOTHING
4.3 IF INHALED
4.4 IF SWALLOWED
NOTE TO PHYSICIAN
Probable mucosal damage may contraindicate the use of gastric lavage.
Not applicable. Nonflammable and noncombustible. Not applicable. Not pertinent. May decompose, generating irritating chlorine gas. Not explosive. Use extinguishing measures appropriate to local circumstances and the surrounding environment. Use carbon dioxide, or water spray. Use flooding quantities of water as fog. Do not use Mono Ammonium Phosphate (MAP) fire extinguishers. Such use may cause explosion with release of toxic gases.
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Skin Protection:
8.2.3
Respiratory Protection:
8.2.4
8.3.2
0.5 ppm 1 ppm 0.5 ppm Not established 10 ppm 1 ppm as Cl2
8.3.7 8.3.8
Not established. 0.5 ppm * Chlorine is unlikely to be present as a decomposition product, but may be present in incidents of accidental mixing with other chemicals.
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10.3 Conditions of Instability: 10.4 Incompatibility with Various Substances: 10.5 Corrosivity: 10.6 Special Remarks on Reactivity: 10.7 Special Remarks on Corrosivity: 10.8 Hazardous Polymerization:
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Fish Toxicity:
12.1.2 Invertebrate
Toxicity:
Sodium hypochlorite is low in toxicity to avian wildlife, but it is highly toxic to freshwater fish and invertebrates. Atlantic Herring (clupea harengus) LC50 = 0.033 - 0.097 mg//l/96 hr, flow through bioassay (pH: 8) Shiner Perch (cymatogaster aggregata) LC50 = 0.045 - 0.098 mg/l/96 hr, flow through bioassay (pH: 8) Three Spine Stickleback (gasterosteus aculeatus) LC50 = 0.141 - 0.193 mg/l/96 hr, flow through bioassay (pH: 8) Pink Salmon (oncorhynchus gorbuscha) LC50 = 0.023 - 0.052 mg/l/96 hr, flow through bioassay (pH: 8) Coho Salmon (oncorhynchus kisutch) LC50 = 0.026 - 0.038 mg/l/96 hr, flow through bioassay (pH: 8) English Sole (parophrys vetulus) LC50 = 0.044 - 0.144 mg/l/96 hr, flow through bioassay (pH: 8) Fat Head Minnow (pimephales promelas) LC50 = 0.22 - 0.62 mg/l/96 hr, flow through bioassay (pH: 7) Water Flea (ceriodaphnia sp. 0) LC50 = 0.006 mg/l/24 hr Water Flea (daphnia magna) LC50 = 0.07 - 0.7 mg/l/24 hr Water Flea (daphnia magna) LC50 = 2.1 mg/l/96 hr Fresh Water Shrimp (gammarus fasciatus) LC50 = 0.4 mg/l/96 hr No common name (nitocra spinipes) LC50 = 0.40 mg/l/96 hr Grass Shrimp (palaemonetes pugio) LC50 = 0.52 mg/l/96 hr No data available. In fresh water, sodium hypochlorite breaks down rapidly into nontoxic compounds when exposed to sunlight. In seawater, chlorine levels decline rapidly; however, hypobromite (which is acutely toxic to aquatic organisms) is formed. EPA believes that the risk of acute exposure to aquatic organisms is sufficiently mitigated by precautionary labeling and National Pollutant Discharge Elimination System (NPDES) permit requirements. This material is not expected to bioconcentrate in organisms. This material is inorganic and not subject to biodegradation.
14.2
14.3 14.4
Not listed in Appendix B of the Hazardous Material Table. 14.1.5 Deposit Container RESIDUE: LAST CONTAINED CONSUMER Returns: COMMODITY ORM-D, PGIII. Inside containers or single containers exceeding 1.3 gallons. 14.2.1 DOT Classification: Hypochlorite Solutions. 14.2.2 DOT Hazard Class: 8, UN1791, P.G. III. 14.2.3 Label: Corrosive 8. 14.2.4 Deposit Container RESIDUE: LAST CONTAINED, UN 1791, Returns: HYPOCHLORITE SOLUTIONS, 8, PGIII, Reportable Quantity (RQ): 100 lb (45.4 kg) or 80 gallons (based on 12.5% active ingredient)
Materials of Trade (MOT) Exceptions. Under certain conditions, spa and pool maintenance chemicals may be loaded into pool service and builders trucks and shipped as a MOT, not subject to DOT regulations. A MOT means a hazardous material, other than a hazardous waste, that is carried on a motor vehicle by a private motor carrier in direct support of his/her principal business that is other than transportation by motor vehicle. To qualify as a MOT, the hazardous material must fit into any one of the following classes or divisions (but not limited to) Corrosive Materials (Class 8) or Consumer Commodities (ORM-D). Quantity Limit for MOT: For Corrosive Materials (Class 8) that belongs to Packing Group II or III, or is a consumer commodity (ORM-D) the maximum amount of material in each package is 30 kg (66 lbs) for solids, or 30 L (8 gal) for liquids. The aggregate gross weight of all MOTs on a motor vehicle may not exceed 200 kg (440 pounds). Packaging requirement: Packagings must be leak tight for liquids and gases, sift proof for solids, and be securely closed, secured against shifting, and protected against damage. Each material must be packaged in the manufacturer's original packaging, or a packaging of equal or greater strength and integrity. Outer packagings are not required for receptacles (e.g., cans and bottles) that are secured against shifting in cages, carts, bins, boxes or compartments. Hazard communication: A non-bulk packaging other than a cylinder (including a receptacle transported without an outer packaging) must be marked with a common name or proper shipping name to identify the material it contains, including the letters RQ if it contains a reportable quantity of a hazardous substance. The operator of a motor vehicle that contains a material of trade must be informed of the presence of the hazardous material (including whether the package contains a reportable quantity) and must be informed of the requirements of 49 CFR 173.6. Other exceptions: A MOT may be transported on a motor vehicle under the provisions of 49 CFR 173.6 (e) with other hazardous materials without affecting its eligibility for these exceptions. The MOTs regulations do not require: shipping papers; emergency response information; placarding; or formal training or retention of training records. This information is not intended to convey all specific regulatory or operational requirements / information relating to this product. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.
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15.2 State of California Regulations: 15.2.1 Safe Drinking Water and Toxic Enforcement Act of 1986 [Proposition 65, California only]: Small quantities less than 100 ppm (parts per million) of impurities,
including bromates, may be found in all chlorinating products, including this product. Bromates are derived from bromides, which are present in sodium chloride (table salt) from which chlorine is manufactured. Additional small quantities of bromates may be generated during the disinfection process. Bromates are known by the State of California to cause cancer when administered by the oral (drinking or ingesting) route. Read and follow label directions and use care when handling or using this product. The US Environmental Protection Agency has established a maximum contaminant level (MCL) for bromates in drinking water at 10 ppb (parts per billion). Application of this product in accordance with label directions at use dilution will not exceed this level. This warning is provided pursuant to Proposition 65, Chapter 6.6 of the California Health and Safety Code, which requires the Governor of California to publish a list of chemicals known to the state to cause cancer or reproductive toxicity. This list is compiled in accordance with the procedures established under the proposition, and can be obtained on the internet from Californias Office of Environmental Health Hazard Assessment at http://www.oehha.ca.gov. Registration No: 10897-22-AA 15.2.2 CDPR (California Department of Pesticide Regulation) 15.2.3 CalARP (California Accidental Release Prevention Not regulated. Program)
Classification: E (Corrosive Materials) Health Effects Criteria Met by this Chemical: E - Corrosive to skin E - TDG class 8 - corrosive substance Ingredient Disclosure List: Included for disclosure at 1% or greater. All components of this product are on the DSL. On inventory or in compliance with inventory. On inventory or in compliance with inventory. On inventory or in compliance with inventory. On inventory or in compliance with inventory. On inventory or in compliance with inventory.
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16.2
16.3 16.4
Complies with ANSI Z400.1 2004. Complies with ANSI Z129.1 2006.
16.5
Skin Corrosion / Irritation (Category 1). Serious Eye damage / Eye Irritation (Category 1)
16.5.2 Symbol:
Note: The information contained herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR GUARANTEE, express or implied, is made regarding the product performance, product stability, or as to any other condition of use, handling, transportation, and storage. Customer use, handling, transportation, and storage may involve additional safety and/or performance considerations. Our technical personnel will be happy to respond to questions regarding safe handling, storage, transportation, and use procedures. The safe handling, storage, transportation, and use procedures remain the sole responsibility of the customer. No suggestions for handling, storage, transportation, or use are intended as or to be construed as recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law and/or regulation, ordinance, standard, etc. This Material Data Safety Sheet has been prepared by HASA, Inc. staff from test reports and other information available in the public domain.
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