SAFETY DATA SHEET.

Issuing date 09-Oct-2017 Revision Date 31-Jan-2019 Version 1

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier
Product name MCN-18 NON CHLOR HD MOLD CLNR

Recommended use of the chemical

and restrictions on use

Product code F03996

Product Type Non-flammable aerosol

Synonyms None

Supplier's details

Recommended Use Mold Cleaner.

Uses advised against No information available

Manufacturer:
Plastic Process Equipment,Inc.
8303 Corporate Park Dr.
Macedonia, Ohio 44056
Phone: 800-321-0562

Emergency telephone number

Chemical Emergency Phone 1-800-535-5053
Number

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2. HAZARDS IDENTIFICATION
Classification

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 2A
Reproductive Toxicity Category 1B
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Gases under pressure Compressed Gas

GHS Label elements, including

precautionary statements

Emergency Overview
DANGER

Hazard Statements
Causes skin irritation.
Causes serious eye irritation.
May damage fertility or the unborn child
May cause respiratory irritation. May cause drowsiness or dizziness.
May cause damage to organs (Eyes, Skin, Respiratory System, Central Nervous System, and Peripheral Nervous System )
through prolonged and repeated exposure.
Contains gas under pressure; may explode if heated

Appearance Clear Physical state Aerosol Odor Solvent

Precautionary Statements - Prevention

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear protective gloves, protective clothing,eye protection,face protection.
Wash face, hands and any exposed skin thoroughly after handling.
Do not breathe dust, fume, gas, mist, vapors, spray.
Use only outdoors or in a well-ventilated area.

Precautionary Statements - Response

If exposed or concerned: Get medical advice, attention.
Specific treatment (see first aid on this label).
IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice, attention
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice, attention.
Take off contaminated clothing and wash it before reuse.
IF INHALED : Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor, physician if you feel unwell.

Precautionary Statements - Storage

Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Protect from sunlight

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Precautionary Statements - Disposal
Dispose of contents, container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC)

None

Other information

0% of the mixture consists of ingredient(s) of unknown toxicity.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight %*

N-PROPYL BROMIDE, STABILIZED 106-94-5 85-95
CARBON DIOXIDE 124-38-9 1-10

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

First aid measures for different exposure routes

General advice Avoid contact with eyes, skin, and clothing. Avoid breathing vapors, mist, or gas.

Eye contact Immediately flush with plenty of water for at least 15 minutes. After initial flushing, remove
any contact lenses and continue flushing. If eye irritation persists, consult a doctor.

Skin contact Wash off with soap and plenty of water. Remove and wash contaminated clothing before
re-use. If skin irritation persists, call a physician.

Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped,
contact emergency medical services immediately.

Ingestion Call a physician or Poison Control Center immediately. Do NOT induce vomiting. Never
give anything by mouth to an unconscious person. Risk of product entering the lungs on
vomiting after ingestion.

Protection of First-aiders Remove all sources of ignition.

Most important symptoms/effects, acute and delayed

Main Symptoms Causes skin and serious eye irritation. May damage fertility or the unborn child. May cause
respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs
through prolonged or repeated exposure.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Water fog.Dry chemical. Foam.Carbon dioxide (CO2). Cool containers/tanks with water spray.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. Keep away from sources
of ignition - No smoking.

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Specific hazards arising from the chemical
Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray.

Explosion Data
Sensitivity to Mechanical Impact none.
Sensitivity to Static Discharge Yes.

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Use shielding to protect fire-fighters from bursting containers. In the event of fire and/or explosion do not breathe
fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Use with adequate ventiliation to keep the exposure levels below the OELS. Follow safe
handling advice and personal protective equipment recommendations.

Environmental precautions

Environmental precautions Vapors can accumulate in low areas. Report spills as required by local and federal
regulations. Do not flush into surface water or sanitary sewer system. Do not allow material
to contaminate ground water system. Prevent product from entering drains. Should not be
released into the environment.

Methods and materials for containment and cleaning up

Methods for Containment Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal. Prevent further leakage or spillage if safe to do so. Do not allow material to
contaminate ground water system. Prevent product from entering drains.

Methods for cleaning up Soak up with inert absorbent material. Contain liquid and collect with an inter,
non-combustible material. Pick up and transfer to properly labeled containers. Clean
contaminated surface thoroughly . After cleaning, flush away traces with water. Prevent
product from entering drains. Take precautionary measures against static discharges.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing. Keep away
from open flames, hot surfaces and sources of ignition. Contents under pressure. Do not
puncture or incinerate cans. Handle in accordance with good industrial hygiene and safety
practice. Take precautionary measures against static discharges.

Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep container tightly closed in a dry and well-ventilated place. Keep away from open
conditions flames, hot surfaces, and sources of ignition. Keep in properly labeled containers. Keep out
of the reach of children. Store locked up.

Incompatible products Strong acids, alkalis, oxidizing agents.

Aerosol Level 1

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

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N-PROPYL BROMIDE, STABILIZED TWA: 0.1 ppm - -
106-94-5
CARBON DIOXIDE STEL: 30000 ppm TWA: 5000 ppm IDLH: 40000 ppm
124-38-9 TWA: 5000 ppm TWA: 9000 mg/m3 TWA: 5000 ppm
(vacated) TWA: 10000 ppm TWA: 9000 mg/m3
(vacated) TWA: 18000 mg/m3 STEL: 30000 ppm
(vacated) STEL: 30000 ppm STEL: 54000 mg/m3
(vacated) STEL: 54000 mg/m3
ACGIH: (American Conference of Governmental Industrial Hygienists)
OSHA: (Occupational Safety & Health Administration)
NIOSH IDLH: Immediately Dangerous to Life or Health

Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Exposure controls

Engineering Measures Ventilation systems. Use adequate ventilation to keep the exposure levels below the
occupational exposure limits.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing.(PPE). Impervious Gloves.

Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.

Hygiene measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and chemical properties

Physical state Aerosol

Appearance Clear Odor Solvent
Color Odor Threshold

Property Values Remar

ks •Met
hods
pH No information available
Melting/freezing point No information available
Boiling point/boiling range
Flash Point No flashpoint Additionally, propellant has no
flashpoint.
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limits in Air
upper flammability limit
lower flammability limit
Vapor pressure
Vapor density
Specific Gravity 1.308
Water solubility Insoluble in water
Partition coefficient: n-octanol/water
Autoignition temperature No information available
Decomposition temperature
Viscosity No information available
Explosive properties

Other information

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VOC Content(%) 90.53

10. STABILITY AND REACTIVITY

Reactivity
No data available. Stable under
recommended storage conditions

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions

None under normal processing.

Conditions to Avoid
Extremes of temperature and direct sunlight.

Incompatible Materials
Strong acids, alkalis, oxidizing agents.

Hazardous Decomposition Products

Carbon oxides , Hydrocarbons, Fumes.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation May cause respiratory irritation, May cause drowsiness or dizziness.

Eye contact Causes serious eye irritation.

Skin contact Causes skin irritation.

Ingestion May be fatal if swallowed and enters airways.

Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
N-PROPYL BROMIDE, > 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) = 14374 ppm ( Rat ) 4 h
STABILIZED
106-94-5

Information on toxicological effects

Symptoms Causes skin and serious eye irritation. May damage fertility or the unborn child. May cause
drowsiness or dizziness. May cause respiratory irritation. May cause damage to organs
(listed below) through prolonged or repeated exposure.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Irritating to skin.

Eye damage/irritation Irritating to eyes.
Sensitization Not a known sensitizer.
Germ cell mutagenicity Not a germ cell mutagen.
Carcinogenicity The table below indicates whether each agency has evaluated a listed ingredient as a
carcinogen.
Chemical Name ACGIH IARC NTP OSHA
N-PROPYL BROMIDE, A3 Group 2B Reasonably Anticipated X
STABILIZED
106-94-5

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ACGIH: (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC: (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
NTP: (National Toxicity Program)
Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen
OSHA: (Occupational Safety & Health Administration)
X - Present
Reproductive toxicity This product contains a chemical(s) which is a known or suspected reproductive hazard .
Specific target organ systemic May cause respiratory irritation. May cause drowsiness or dizziness.
toxicity (single exposure)
Specific target organ systemic May cause damage to target organs listed below through prolonged and repeated
toxicity (repeated exposure) exposure.
Chronic toxicity Intentional misuse by deliberately concentrating and inhaling contents may be harmful or
fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and
potential cardiac arrest.
Target Organ Effects Eyes, Skin, Respiratory System, Central Nervous System, and Peripheral Nervous System.
Neurological effects Intentional misuse by deliberately concentrating and inhaling contents may be harmful or
fatal.
Aspiration hazard May be fatal if swallowed and enters airways.

Numerical measures of toxicity - Product Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 2211 mg/kg
ATEmix (dermal) 2211 mg/kg
ATEmix (inhalation-vapor) 27.6 mg/l

12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Toxicity to algae Toxicity to fish Toxicity to Toxicity to daphnia and
microorganisms other aquatic invertebrates
N-PROPYL BROMIDE, - 67.3 mg/L LC50 Pimephales - -
STABILIZED promelas 96h flow-through
106-94-5
CARBON DIOXIDE - 0.46 mg/L LC50 - -
124-38-9 Oncorhynchus mykiss

Persistence and degradability

.

Bioaccumulation

Chemical Name log Pow

N-PROPYL BROMIDE, STABILIZED 2.1
106-94-5

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment

Waste Disposal Methods Dispose of in accordance with local regulations. Dispose of in accordance with federal,
state, and local regulations. This material, as supplied, is a hazardous waste according to
federal regulations (40 CFR 261). Dispose of in accordance with federal, state, and local
regulations.

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Contaminated packaging Do not re-use empty containers.

14. TRANSPORT INFORMATION

DOT Ground CONSUMER COMMODITY ORM-D

or
LIMITED QUANTITY

IATA UN1950, AEROSOLS, NON-FLAMMABLE, 2.2, LTD. QTY

IMDG UN1950, AEROSOLS, 2.2,LTD. QTY.

15. REGULATORY INFORMATION

International Inventories

Chemical Name TSCA DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS
NCS
N-PROPYL X X X X X X X X
BROMIDE,
STABILIZED
CARBON DIOXIDE X X X X X X X X

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
CHINA - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

U.S. Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain a
chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,
Part 372:

Chemical Name CAS-No Weight %* SARA 313 - Threshold

Values %
N-PROPYL BROMIDE, STABILIZED - 106-94-5 106-94-5 85-95 0.1

SARA 311/312 Hazard Categories

Acute Health Hazard Yes
Chronic Health Star Hazard Yes
Fire Hazard No
Sudden Release of Pressure Hazard Yes
Reactive Hazard No

Clean Water Act

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

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CFR 122.42).

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.

U.S. State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals:

This product can expose you to chemicals including those listed below, which is [are] known to the State of California to cause cancer, birth defects
or other reproductive harm. For more information go to www.P65Warnings.ca.gov

Chemical Name California Prop. 65

N-PROPYL BROMIDE, STABILIZED - 106-94-5 Developmental
Female Reproductive
Male Reproductive 85-95%

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

N-PROPYL BROMIDE, X X X
STABILIZED
106-94-5
CARBON DIOXIDE X X X
124-38-9
EPA Pesticide Registration Number Not applicable

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the SDS contains all the information required by the CPR.

16. OTHER INFORMATION

NFPA Health Hazard 1 Flammability 1 Instability 0 Physical and chemical
hazards Other
HMIS Health Hazard 1* Flammability 1 Physical Hazard 1 Personal protection B
Chronic Hazard Star Legend Chronic Health Star Hazard Repeated or prolonged exposure may cause central nervous system
damage

Issuing date 09-Oct-2017

Revision Date 31-Jan-2019
Revision Note
(M)SDS sections updated 3

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Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.

End of Safety Data Sheet

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