SAFETY DATA SHEET

Creation Date 10-Dec-2009 Revision Date 24-Dec-2021 Revision Number 4

1. Identification
Product Name Ammonium Peroxydisulfate

Cat No. : A682-3; A682-10; A682-500

CAS No 7727-54-0
Synonyms Ammonium peroxydisulfate; Peroxydisulfuric acid diammonium salt

Recommended Use Laboratory chemicals.

Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Company
Fisher Scientific Company
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100

Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300

CHEMTRECÒ, Outside the USA: 001-703-527-3887

2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Oxidizing solids Category 3

Acute oral toxicity Category 4
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Respiratory Sensitization Category 1
Skin Sensitization Category 1
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.

Label Elements

Signal Word
Danger

Hazard Statements
May intensify fire; oxidizer

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Harmful if swallowed
Causes skin irritation
Causes serious eye irritation
May cause an allergic skin reaction
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause respiratory irritation

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
In case of inadequate ventilation wear respiratory protection
Contaminated work clothing should not be allowed out of the workplace
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Inhalation
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash before reuse
If skin irritation or rash occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified

3. Composition/Information on Ingredients
Component CAS No Weight %
Ammonium persulfate 7727-54-0 >95

4. First-aid measures

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General Advice If symptoms persist, call a physician. Show this safety data sheet to the doctor in
attendance.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. SPEEDY ACTION IS
CRITICAL, GET MEDICAL AID IMMEDIATELY. Remove and wash contaminated clothing
and gloves, including the inside, before re-use.

Inhalation Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Consult a physician if necessary.

Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Clean
mouth with water and drink afterwards plenty of water. Never give anything by mouth to an
unconscious person.

Most important symptoms and May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause
effects allergic skin reaction. . Symptoms of allergic reaction may include rash, itching, swelling,
trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain,
muscle pain or flushing
Notes to Physician Treat symptomatically

5. Fire-fighting measures

Suitable Extinguishing Media Water spray.

Unsuitable Extinguishing Media No information available

Flash Point No information available

Method - No information available

Autoignition Temperature No information available

Explosion Limits
Upper No data available
Lower No data available
Oxidizing Properties Oxidizer

Sensitivity to Mechanical Impact No information available

Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical

Oxidizer: Contact with combustible/organic material may cause fire. Keep product and empty container away from heat and
sources of ignition. Thermal decomposition can lead to release of irritating gases and vapors. May ignite combustibles (wood
paper, oil, clothing, etc.).

Hazardous Combustion Products

Nitrogen oxides (NOx). Sulfur oxides. Ammonia. Oxygen.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

NFPA
Health Flammability Instability Physical hazards
2 1 2 OX

6. Accidental release measures

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Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust
formation. Avoid contact with skin, eyes or clothing. Evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological
Information. Do not flush into surface water or sanitary sewer system. Prevent further
leakage or spillage if safe to do so. Prevent product from entering drains.

Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Keep
Up combustibles (wood, paper, oil, etc) away from spilled material. Soak up with inert
absorbent material. Keep in suitable, closed containers for disposal. Sweep up and shovel
into suitable containers for disposal.

7. Handling and storage

Handling Wear personal protective equipment/face protection. Avoid dust formation. Do not breathe
dust. Do not get in eyes, on skin, or on clothing. Keep away from clothing and other
combustible materials. Pay attention to flashback. No information available.

Storage. Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near
combustible materials. Keep containers tightly closed in a cool, well-ventilated place. Keep
in properly labeled containers. Incompatible Materials. Reducing Agent. Metals.
Peroxides. Strong oxidizing agents. Strong reducing agents. Combustible material. .

8. Exposure controls / personal protection

Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Ammonium persulfate TWA: 0.1 mg/m3 TWA: 0.1 mg/m3

Legend

ACGIH - American Conference of Governmental Industrial Hygienists

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Tight sealing safety goggles.

Skin and body protection Impervious gloves.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures When using do not eat, drink or smoke. Provide regular cleaning of equipment, work area
and clothing.

9. Physical and chemical properties

Physical State Powder Solid
Appearance White
Odor Odorless
Odor Threshold No information available
pH 3.2 100 g/L
Melting Point/Range 120 °C / 248 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable

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Flammability (solid,gas) No information available

Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure negligible
Vapor Density Not applicable
Specific Gravity 1.980
Bulk Density 900-1100 kg/m3
Solubility Soluble in water
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature > 120°C
Viscosity Not applicable
Molecular Formula H8 N2 O8 S2
Molecular Weight 228.19

10. Stability and reactivity

Reactive Hazard Yes

Stability Oxidizer: Contact with combustible/organic material may cause fire. Moisture sensitive.

Conditions to Avoid Avoid dust formation. Combustible material. Excess heat. Exposure to moisture.
Incompatible products.

Incompatible Materials Reducing Agent, Metals, Peroxides, Strong oxidizing agents, Strong reducing agents,
Combustible material,

Hazardous Decomposition Products Nitrogen oxides (NOx), Sulfur oxides, Ammonia, Oxygen

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information

Acute Toxicity

Product Information
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Ammonium persulfate LD50 = 495 mg/kg ( Rat ) > 2000 mg/kg LC50 > 2.95 mg/L ( Rat ) 4 h

Toxicologically Synergistic No information available

Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes, respiratory system and skin

Sensitization May cause sensitization by skin contact

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS No IARC NTP ACGIH OSHA Mexico

Ammonium persulfate 7727-54-0 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

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Teratogenicity No information available.

STOT - single exposure Respiratory system

STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms / effects,both acute and Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
delayed of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information

Ecotoxicity
Do not empty into drains. Contains a substance which is:. Harmful to aquatic organisms. The product contains following
substances which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea

Ammonium persulfate Not listed LC50: = 76.3 mg/L, 96h Not listed EC50: = 120 mg/L, 48h
static (Oncorhynchus (Daphnia magna)
mykiss)
LC50: = 323 mg/L, 96h
(Poecilia reticulata)
LC50: = 103 mg/L, 96h static
(Lepomis macrochirus)

Persistence and Degradability Soluble in water Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility Will likely be mobile in the environment due to its water solubility.

13. Disposal considerations

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.

14. Transport information

DOT
UN-No UN1444
Proper Shipping Name AMMONIUM PERSULFATE
Hazard Class 5.1
Packing Group III
TDG
UN-No UN1444
Proper Shipping Name AMMONIUM PERSULFATE
Hazard Class 5.1
Packing Group III
IATA
UN-No UN1444
Proper Shipping Name AMMONIUM PERSULPHATE
Hazard Class 5.1
Packing Group III
IMDG/IMO
UN-No UN1444
Proper Shipping Name AMMONIUM PERSULPHATE
Hazard Class 5.1

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Packing Group III

15. Regulatory information
United States of America Inventory

Component CAS No TSCA TSCA Inventory notification - TSCA - EPA Regulatory

Active-Inactive Flags
Ammonium persulfate 7727-54-0 X ACTIVE -

Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea
(KECL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Ammonium persulfate 7727-54-0 X - 231-786-5 X X X X X KE-09815

KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313
Component CAS No Weight % SARA 313 - Threshold
Values %
Ammonium persulfate 7727-54-0 >95 1.0

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

OSHA - Occupational Safety and Not applicable

Health Administration

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know

Regulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Ammonium persulfate - X - - -

U.S. Department of Transportation

Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N

U.S. Department of Homeland This product does not contain any DHS chemicals.
Security

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Other International Regulations

Mexico - Grade No information available

Authorisation/Restrictions according to EU REACH

Component REACH (1907/2006) - Annex XIV - REACH (1907/2006) - Annex XVII - REACH Regulation (EC
Substances Subject to Restrictions on Certain Dangerous 1907/2006) article 59 - Candidate
Authorization Substances List of Substances of Very High
Concern (SVHC)
Ammonium persulfate - Use restricted. See item 75. -
(see link for restriction details)

https://echa.europa.eu/substances-restricted-under-reach

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component CAS No OECD HPV Persistent Organic Ozone Depletion Restriction of

Pollutant Potential Hazardous
Substances (RoHS)
Ammonium persulfate 7727-54-0 Listed Not applicable Not applicable Not applicable

Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
Ammonium persulfate 7727-54-0 Not applicable Not applicable Not applicable Not applicable

16. Other information

Prepared By Regulatory Affairs
Thermo Fisher Scientific
Email: [email protected]

Creation Date 10-Dec-2009

Revision Date 24-Dec-2021
Print Date 24-Dec-2021
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of SDS

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