Safety Data Sheet according to GB/T 16483-2008

Page 1 of 8 .
LOCTITE LB 8008 C5-A ANTI SEIZE known as LOCTITE C5A
SDS No. : 242144
CO BSE A/S 2.5LB. V001.6
Revision: 28.08.2018
printing date: 19.02.2019

1. Identification of the substance/preparation and of the company/undertaking

Product name: LOCTITE LB 8008 C5-A ANTI SEIZE known as LOCTITE C5A CO BSE A/S 2.5LB.

Intended use: Lubricant

Company name:
Henkel (China) Investment Co. Ltd.
No.928 Zhangheng Rd.
201203 Pudong, Shanghai, P.R. China

China

Phone: +86-21-2891 8000

Fax-no.: +86-21-2891 5137

Revision date: 28.08.2018

2. Hazards identification
Classification of the substance or mixture according to GB 13690-2009 (General rule for classification and hazard
communication of chemicals):

Hazard Class Hazard Category

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Aspiration hazard Category 1
Acute hazards to the aquatic Category 2
environment

Label elements according to GB 15258-2009 (General rules for preparation of precautionary label for chemicals):
Hazard pictogram:

Signal word: Danger

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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
LOCTITE C5A CO BSE A/S 2.5LB.

Hazard statement: H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.
H318 Causes serious eye damage.
H401 Toxic to aquatic life.

Prevention: P264 Wash hands thoroughly after handling.

P273 Avoid release to the environment.
P280 Wear protective gloves, eye protection, and face protection.

Response: P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.

P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents/container to an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product characteristics at time of
disposal.

3. Composition / information on ingredients

General description: Mixture
Declaration of the ingredients according to GB 13690-2009:

Hazard component CAS-No. Content GHS Classification

Calcium dihydroxide 10- < 20 % Skin corrosion/irritation 2; Dermal
1305-62-0 H315
Serious eye damage/eye irritation 1
H318
Acute hazards to the aquatic environment 3
H402
Copper 10- < 20 % Acute hazards to the aquatic environment 1
7440-50-8 H400
Chronic hazards to the aquatic environment 3
H412

Only hazardous ingredients for which a classification according to GB 13690-2009 is already available are displayed in this table. For full
text of the Hazard statements see section 16 “Other information”.

4. First aid measures

Skin contact: Rinse with running water and soap.
Seek medical advice.

Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if
necessary.

Inhalation: Move to fresh air. If symptoms persist, seek medical advice.

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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
LOCTITE C5A CO BSE A/S 2.5LB.

Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting.
Seek medical advice.

5. Fire fighting measures

Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors.
Sulphur oxides

Extinguishing media: Carbon dioxide, foam, powder

Fire-fighting method: In case of fire, keep containers cool with water spray.

Notice and measures for firing Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
fighting:

6. Accidental release measures

Emergency measures: Avoid skin and eye contact.
Do not let product enter drains.
Ensure adequate ventilation.

Clean-up methods: For small spills wipe up with paper towel and place in container for disposal.
For large spills absorb onto inert absorbent material and place in sealed container for
disposal.

7. Handling and storage

Notice for handling: Use only in well-ventilated areas.
Vapours should be extracted to avoid inhalation.
Prolonged or repeated skin contact should be avoided
Notice for storage: Store in a cool, well-ventilated place.
Store in original containers at 8-21°C (46.4-69.8°F) and do not return residual materials to
containers as contamination may reduce the shelf life of the bulk product.

8. Exposure controls / personal protection

Hazardous components GBZ 2.1-2007 ACGIH NIOSH OSHA
Copper 1 mg/m3PC-TWA Dust. 0.2 mg/m3 TWA none
0.2 mg/m3PC-TWA Fume.
Fume. 1 mg/m3 TWA Dust
and mist.
Graphite 2 mg/m3PC-TWA 2 mg/m3 TWA none
Respirable dust. Respirable fraction.
4 mg/m3PC-TWA Total
dust.

Engineering controls: Use only with adequate ventilation.

Local exhaust ventilation is recommended when general ventilation is not sufficient to
control airborne contamination below occupational exposure limits.

Respiratory protection: Use only in well-ventilated areas.

Eye protection: Wear protective glasses.

Body protection: Wear suitable protective clothing.

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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
LOCTITE C5A CO BSE A/S 2.5LB.

Hand protection: The use of chemical resistant gloves such as Neoprene or Natural Rubber is recommended
Please note that in practice the working life of chemical resistant gloves may be
considerably reduced as a result of many influencing factors (e.g. temperature). Suitable
risk assessment should be carried out by the end user. If signs of wear and tear are noticed
then the gloves should be replaced.

Other protection: The selection of PPE shall at least compliant with "Law of the People's Republic of China
on Prevention and Control of Occupational Diseases" and "Code of practice for selection
of personal protective equipments" (GB/T 11651-2008).

Pictograms for recommended PPE:

9. Physical and chemical properties

Physical state: paste Appearance: copper
paste
pH: Not applicable Melting point: Not applicable
Boiling point: > 260 °C (> 500 °F) Density: 1.3 g/cm3
Flash point: > 93 °C (> 199.4 °F) Ignition temperature: Not available.
Solubility in water Insoluble Viscosity: Not available.

10. Stability and reactivity

Stability: Stable under recommended storage conditions.
Conditions to avoid: Stable under normal conditions of storage and use.
Incompatible products: Oxidizing agents.
Strong acids and strong bases.
Decomposition products: Hydrocarbons.
Oxides of carbon.
Hazardous polymerization: Will not occur.

11. Toxicological information

General toxicological information:

No experimental toxicological data on the preparation as such is available.
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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
LOCTITE C5A CO BSE A/S 2.5LB.

Other remarks:
Not available.

Acute toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Calcium dihydroxide LD50 > 7,340 mg/kg oral rat OECD Guideline 401 (Acute
1305-62-0 LD50 > 2,500 mg/kg rat Oral Toxicity)
dermal OECD Guideline 402 (Acute
Dermal Toxicity)
Copper LC50 > 5.11 mg/l 4h rat OECD Guideline 436 (Acute
7440-50-8 inhalation Inhalation Toxicity: Acute
Toxic Class (ATC) Method)

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Calcium dihydroxide irritating 4h rabbit OECD Guideline 404 (Acute
1305-62-0 Dermal Irritation / Corrosion)

Serious eye damage/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Calcium dihydroxide Category 1 (irreversible effects on the eye) rabbit OECD Guideline 405 (Acute
1305-62-0 Eye Irritation / Corrosion)

Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
Calcium dihydroxide negative bacterial reverse with and without OECD Guideline 471
1305-62-0 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Copper negative bacterial reverse with and without OECD Guideline 471
7440-50-8 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Copper negative oral: gavage mouse EU Method B.12
7440-50-8 negative rat (Mutagenicity
OECD Guideline 486
(Unscheduled DNA Synthesis
(UDS) Test with Mammalian
Liver Cells in vivo)

12. Ecological information

General ecological information:
Do not empty into drains / surface water / ground water.

Ecotoxicity:
No data available for the product.
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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
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Other adverse effects:

Not available.

Toxicity:

Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
Calcium dihydroxide LC50 50.6 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline
1305-62-0 203 (Fish, Acute
Toxicity Test)
Calcium dihydroxide EC50 49.1 mg/l Daphnia 48 h Daphnia magna OECD Guideline
1305-62-0 202 (Daphnia sp.
Acute
Immobilisation
Test)
Calcium dihydroxide EC50 184.57 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline
1305-62-0 201 (Alga, Growth
Inhibition Test)
Calcium dihydroxide NOEC 48 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline
1305-62-0 201 (Alga, Growth
Inhibition Test)
Calcium dihydroxide EC20 229.2 mg/l Bacteria 3h activated sludge of a OECD Guideline
1305-62-0 predominantly domestic sewage 209 (Activated
Sludge, Respiration
Inhibition Test)
Copper LC 50 > 0.1 - 1 mg/l Fish 96 h not specified OECD Guideline
7440-50-8 203 (Fish, Acute
Toxicity Test)
Copper NOEC > 0.1 - 1 mg/l Fish 28 d not specified OECD Guideline
7440-50-8 210 (fish early lite
stage toxicity test)
Copper EC50 > 0.1 - 1 mg/l Daphnia 48 h Daphnia magna OECD Guideline
7440-50-8 202 (Daphnia sp.
Acute
Immobilisation
Test)
Copper EC50 > 0.1 - 1 mg/l Algae 72 h not specified OECD Guideline
7440-50-8 201 (Alga, Growth
Inhibition Test)
Copper NOEC > 0.1 - 1 mg/l Algae 72 h not specified OECD Guideline
7440-50-8 201 (Alga, Growth
Inhibition Test)
Copper EC50 > 0.1 - 1 mg/l Bacteria 3h activated sludge OECD Guideline
7440-50-8 209 (Activated
Sludge, Respiration
Inhibition Test)

Persistence and degradability:

Hazardous components Result Route of Degradability Method

CAS-No. application
Copper Rapidly degradable not specified > 60 % OECD 301 A - F
7440-50-8

13. Disposal considerations

Product disposal: Dispose of in accordance with local and national regulations.
Not list in National Hazardous Waste Catalogue, dispose of as normal chemical waste.
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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
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Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as
chemically contaminated waste in an authorised legal land fill site or incinerated.

14. Transport information

Road transport ADR:

Not dangerous goods

Railroad transport RID:

Not dangerous goods

Marine transport IMDG:

Class: 9
Packing group: III
UN no.: 3082
Label: 9
EmS: F-A ,S-F
Seawater pollutant: Marine pollutant
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Copper)

Air transport IATA:

Not dangerous goods

Notice For Transportation: Transport according to local and national regulations. Ensure
containers will not leak, collapse, or being damaged when transported.
DO NOT transport with incompatible materials. Transportation vehicle
should be equipped with right fire-fighting equipment in case of
emergency. Avoid solarization, drenched and high temperature when
transported.

15. Regulatory information

The following laws and regulations lay down provisions in terms of chemicals safety use, storage, transportation, loading/
unloading, classification as well as symbol.
“Law of the People's Republic of China on Work Safety” (Adopted by the 28th meeting of 9th NPC standing committee on 29th
June 2002, revised by 10th meeting of 12nd NPC standing committee on 31st Aug 2014).
“Law of the People's Republic of China on the Prevention and Treatment of Occupational Diseases” (Adopted by the 24th
meeting of 9th NPC standing committee on 27th October 2001, revised by 21st meeting of 12nd NPC standing committee on 2nd
Jul 2016).
“Law of the People's Republic of China on environmental protection” (Adopted by 11st meeting of 7th NPC standing committee
on 26th December 1989, revised by 8th meeting of 12nd NPC standing committee on 24th Apr 2014).
“Regulation on the Safety Management of Hazardous Chemicals” (Adopted by 32nd State Council executive meeting on 4th
December 2013).
“Regulations on License to Work Safety” (Adopted by 54th State Council executive meeting on 29th July 2014).

China Inventory of Existing All components are listed or are exempt from Inventory of Existing Chemical Substances
Chemicals: in China.

16. Other information

Issue date: 19.02.2019
Issue department: Regulatory Affairs
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V001.6 LOCTITE LB 8008 C5-A ANTI SEIZE known as
LOCTITE C5A CO BSE A/S 2.5LB.

Disclaimer: This Safety Data Sheet has been generated in accordance with Chinese law only. It
provides information on the chemical product in the aspects of safety, health, environment,
etc, recommending preventive and protective measures and countermeasures in case of
emergency. The information contained herein does not constitute a guarantee concerning
the properties of the material. No warranty or representation of any kind is given with
respect to the substantive or export laws of any other jurisdiction or country. Please
confirm that the information provided herein conforms to the substantive export or other
law of any other jurisdiction prior to export. Please contact Henkel Product Safety and
Regulatory Affairs for additional assistance.This information is based on our current level
of knowledge and relates to the product in the state in which it is delivered. It is intended
to describe our products from the point of view of safety requirements and is not intended
to guarantee any particular properties.The data contained herein are furnished for
information only and are believed to be reliable. However, Henkel Corporation and its
affiliates (“Henkel”) does not assume responsibility for any results obtained by persons
over whose methods Henkel has no control. It is the user’s responsibility to determine the
suitability of Henkel’s products or any production methods mentioned herein for a
particular purpose, and to adopt such precautions as may be advisable for the protection of
property and persons against any hazards that may be involved in the handling and use of
any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all
warranties, express or implied, including warranties of merchantability and fitness for a
particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims
any liability for consequential or incidental damages of any kind, including lost profits.

Others: The full text of all abbreviations indicated by codes in this safety data sheet section 3
are as follows:

H315 Causes skin irritation.

H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H402 Harmful to aquatic life.
H412 Harmful to aquatic life with long lasting effects.