Course Description 1. Chemistry of d-block elements and coordination complexes:
Back ground of coordination chemistry and structure of coordination complexes with coordination number 2-6, chelates and chelate effect, theories of coordination complexes, crystal field theory (CFT) and molecular orbital theory (MOT), Jahn-Teller theorem, magnetic properties, spectral properties, isomerism, stereochemistry and stability constants of coordination complexes. Chemistry of f-block elements: i. Lanthanides: General characteristics, occurrence, extraction and general principles of separation, electronic structure and position in the periodic table, lanthanides contraction, oxidation states, spectral and magnetic properties and uses. ii. Actinides: General characteristics, electronic structure, oxidation state and position in the periodic table, half-life and decay law. Course Type: Elective Course (Compulsory/Core/ Elective) Pre-requisites Students must have knowledge of coordination chemistry and its use in various fields. Goals After completing this program students will be able to learn the following: 1. The historical development of transition element chemistry 2. The importance and applications of the transition elements 3. To learn about coordination chemistry and various theories developed to explain the structure and properties of these complexes 4. Chemistry of f block elements Text Books 1. Cotton, F. A., Wilkinson, G., Murillo, C. A. and Bochmann, M., Advanced Inorganic Chemistry, 6th ed., Wiley-Interscience, (1999). 2. Housecraft, C. and Sharpe, A. G., Inorganic Chemistry, 4th ed., Prentice Hall, (2012). 3. Miessler, G. L. and Tarr, D.A., Inorganic Chemistry, 4th ed., Pearson Prentice Hall International, (2010). 4. Douglas, B., McDanial, D., Alexander, J., Concepts and Models of Inorganic Chemistry, 3rd ed., John-Wiley & Sons, New York, (1994). 5. Shriver, D. and Atkins, P., Inorganic Chemistry, 5th ed., W. H. Freeman & Company, (2010). 6. Lee, J. D., Concise Inorganic Chemistry, 5th ed., Blackwell Science Ltd., (1996). 7. Atkins, P. and Jones, L., Chemicals Principles, 5th ed., W. H. Freeman & Company, (2010). 8. Cullen Dolphin and James, Biological aspects of Inorganic Chemistry, (2005). 9. Williams, An Introduction to Bioinorganic Chemistry, (2003). Additional Readings 1. Huheey, J. E., Keiter, E. A. and Keiter, R. L., “Inorganic Chemistry: th Principles of Structure and Reactivity”, 4 Ed., Harper and Row, New York, 2001. 2. Basalo, F., Johnson, R.C., Coordination Chemistry “The Chemistry of Metal Complexes”, W. A. Benjamin, Inc., 1964. Lectures 32 Sessions of 90 Minutes each Attendance Policy A minimum of 70% attendance is required for a student to be eligible to take the final examination. The students with less than 70% of the attendance in a course shall be given the grade SA (Short Attendance) in such a course and shall not be allowed to take its End Term Exams and will have to reappear in the course to get the required attendance to be eligible to sit in the exam when the course is offered the next time. Grading The course will be evaluated on the basis of the following percentage: Marks of Mid Examination = 25 Marks of Final Examination = 50 Assignment Mark = 10 Presentation Marks = 05 Quiz Marks = 10 Total Marks=100 Quizzes, Midterm 9th week of semester Assignments and 1st Quiz and Assignment 4th week of semester Presentation 2nd Quiz and Assignment 11th week of semester Schedule (tentative) Presentations starts from 11th week of semester UNIVERSITY OF GUJRAT Department of Chemistry Session Schedule
Week # Topic Readings
01 Introduction of course contents, history Recommended and
Back ground of coordination chemistry Supplementary Material
02 structure of coordination complexes with coordination #
number 2-6 03 chelates and chelate effect, theories of coordination # complexes, 04 Assignment 1 crystal field theory (CFT) #
05 molecular orbital theory (MOT) #
06 Quiz 1 Jahn-Teller theorem #
07 magnetic properties #
08 spectral properties, Isomerism
09 Mid Term #
10 stereochemistry #
11 stability constants of coordination complexes. #
12 Lanthanides: General characteristics, occurrence, extraction #
and general principles of separation 13 electronic structure and position in the periodic table, # lanthanides contraction, oxidation states, 14 Presentations, Quiz 2, Assignment 2 spectral and magnetic # properties and uses. 15 Presentations, Actinides: General characteristics, electronic # structure, oxidation state 16 position in the periodic table, half-life and decay law. #