Daily Practice Paper-1 (Fundamental Particles)

1. Where are protons located in an atom?

(A) Around the nucleus (B) Inside the nucleus (C) Both (A) & (B) (D) None of these
2. Which of the following statements is true?
(A) A ‘p’ is 1837 times heavier than an ‘e’. (B) A ‘p’ is 1/1837 times heavier than an ‘e’.
(C) A ‘p’ is 1837 times lighter than an ‘e’ (D) ‘p’ has the same mass as an ‘e’.
3. Nucleus consist of
(A) Proton and electron (B) Proton and neutron (C) Neutron and electron (D) Only neutron
4. Mass number of elements is -
(A) Number of protons in its nucleus (B) Number of electrons and protons in the atom
(C) Number of neutrons and protons in the nucleus (D) Number of neutrons in the nucleus
5. Neutron is a fundamental particle which have
(A) +1-unit charge and 1 unit mass (B) No charge and 1 unit mass
(C) Have no charge and no mass (D) Have-1 unit charge and I unit mass
6. Atomic number of any element
(A) Atomic weight divided by two (B) Number of neutrons in nucleus
(C) Nucleus weight (D) Nuclear charge
7. Lightest particle is
(A) n (B) e (C) p (D) None of these
8. Fundamental particle of atomic nucleus is
(A) p. e- (B) p. n. e (C) p. n (D) n, e
9. The total number of neutrons in zinc (z= 30) with mass number 70 is
(A) 40 (B) 20 (C) 36 (D) 38
10. The charge carried by an electron is in coulombs
(A) 1.602 x 1019 (B) 1.602 x 10-19 (C) 1.609 (D) 6.02 x 1019
11. The mass of a proton is:
(A) 1.609 g (B) 1.6 x 1024 g (C) 1.6 × 10-23 g (D) 1.6 × 10-24 g
12. Which of the following is false?
(A) Neutron has highest mass among fundamental particles (B) e/m is highest for a proton
(C) The mass of an electron is negligible (D) Charge of neutron is zero
13. Which of the following statement are wrong?
(A) An atom is electrically neutral
(B) An atom & its ion have an unequal number of protons
(C) The size of a cation is smaller than that of corresponding atom
(D) An atom & its corresponding anion have equal number of electrons
14. A proton is identical to
(A) the nucleus of helium (B) the nucleus of a hydrogen atom
(C) a molecule of a hydrogen (D) an atom of hydrogen
15. The e/m ratio of an electron for all type of substances is
(A) constant (B) less than one (C) greater than one (D) zero
16. Mass of electron is
(A) 9.1083 × 10-31 kg (B) 9.1083 x 10-24 kg (C) 9.1083 × 10-28 kg (D) 1.67 × 10-24 kg
 Daily Practice Paper-2 (Representation of an atom)
1. Total number of neutrons in dipositive Zinc ion (Zn²+) with mass number 70 is (Z=30)
(A) 30 (B) 40 (C) 50 (D) 20
2. An atom which has a mass number of 14 and has 8 neutrons is an
(A) isotope of oxygen (B) isobar of oxygen (C) isotope of carbon (D) isobar of carbon
3. Difference between Cl atom and CI- ion of
(A) ‘e’ (B) ‘p’ (C) ‘n’ (D) A & B
+2 -
4. Mg and F ions differ in which of the following fundamental particle?
(A) Electrons, protons and neutrons (B) Protons and neutrons
(C) Only protons (D) Neutrons and electrons
5. An atom of an element has 26 electrons and has a mass number 56. The nucleus of this atom
contains ......... neutrons.
(A) 26 (B) 36 (C) 30 (D) 56
35 37
6. 17Cl and 17Cl differ from other in number of
(A) ‘e’ (B) ‘p’ (C) ‘n’ (D) A & C
40 40
7. 18Ar and 20Ca have the same number of
(A) ‘e’ (B) ‘p’ (C) ‘n’ (D p+n
8. A monovalent anions has 10 electrons and 10 neutrons The atomic number and mass number
of the element are respectively
(A) 10, 20 (B) 9, 18 (C) 10,20 (D) 9, 19
9. A trivalent cation of an element contains 10 electrons. The atomic number of the element is
(A) 10 (B) 7 (C) 13 (D) None of these
10. 5B + ₂He → X+ 0n¹ 'X' in the above reaction is
10 4

(A) 7N¹2 (B) 7N13 (C) 6B13 (D) None of these

11. An atom has 12 protons and 12 neutrons; its mass and atomic numbers are:
(A) Mass number 12, atomic number 12 (B) Mass number 24, atomic number 12
(C) Mass number 12, atomic number 0 (D) None of these
12. The number of electrons and neutrons in tritium (₁T³) respectively is:
(A) 3, 1 (B) 1, 3 (C) 1, 2 (D) None of the above
13. An atom with atomic number 18 and mass number 40, has the following arrangement.
(A) 18p, 18e, 22n (B) 18p, 18e, 40n (C) 22p, 18e, 18n (D) 22p,22e, 18n
14. An anion has
(A) more electrons than protons (B) more protons than electrons
(C) more neutrons than protons (D) more protons than neutrons
15. Species 'X' contains 9 protons, 10 electrons and 11 neutrons. It is :
(A) A neutral atom (B) An isotope (C) A cation (D) An anion
235
16. If three neutrons are added to the nuclei of 92U , atomic number of new nucleus is :
(A) 89 (B) 95 (C) 90 (D) 92
 Daily Practice Paper-3 (isotope, isotone, isobar)
1. Neutron is present in all atom except
(A) Protium (B) Deuterium (C) Tritium (D) Helium
2. Select correct statement
(A) Isobars have the same mass number
(B) Isotopes have same mass but different atomic number having in elements
(C) mass number is negative charged particle
(D) isotone have same p-n
3. Which of the following statement is true?
(A) F- has more electrons than Na+ (B) F- has less electrons than Na+
(C) Na+ and F- has equal electrons (D) None of the above
4. Isotopes differ in:
(A) Physical properties (B) Chemical properties (C) Number of protons (D) None of these
5. Which of the following triad represents isotones?
(A) 6C¹2, 6C13, 6C14 (B) 18Ar40, 20Ca42, 21Sc43 (C) 18Ar40, 20Ca40, 21Sc41 (D) 7N14, 8O16, 9F19
6. Which of the following statements is correct?
(A) 7N¹4 and 6C¹3 are isotones (B) 7N¹4 and 6C¹4 are isotopes
(C) 7N¹4 and 6C¹2 are isobars (D) 7N¹4 and 6C¹5 are isotones
7. Isotopes of an elements have –
(A) different chemical properties (B) different atomic
(C) The same physical properties (D) Different number of neutrons
8. Isotopes of an element are the atom which have -
(A) The same number of neutrons in their nuclei (B) The same mass number
(C) Different number of electrons in their orbit (D) The same number of protons in their nuclei
9. The sum of number of neutron and protons in one of the isotopes of hydrogen is
(A) 3 (B) 4 (C) 5 (D) 6
40 40 40
10. 8Ar , 19K , 20Ca
(A) Isotopes (B) Isobars (C) A & B both (D) None
11. Which of the following statements is not correct?
(A) 11Na23 and 12Mg24 are isotones (B) 18Ar40 and 20Ca40 are isobars
(C) N–3 and P–3 are isoelectronic species (D) 92U235 and 92U238 are isotopes
 Daily Practice Paper-4 (Quantum numbers introduction)
1. The number of quantum numbers required to describe an electron in an atom completely is
(A) 1 (B) 2 (C) 3 (D) 4
2. The number of electrons which can be accommodated in an orbital is
(A) One (B) Two (C) Three (D) Four
3. The quantum number which specifies the location of an electron as well as energy is
(A) Principal quantum number (B) Azimuthal quantum number
(C) Spin quantum number (D) Magnetic quantum number
4.The electrons of the same orbitals can be distinguished by
(A) principal quantum number (B) azimuthal quantum number
(C) spin quantum number (D) magnetic quantum number.
5. Principal, azimuthal and magnetic quantum numbers are respectively related to
(A) Size, shape, and orientation (B) Shape, size and orientation
(C) Size, orientation, and shape (D) None of the above
6.Principal quantum number of an atom represents.
(A) Size of the orbital (B) Spin angular momentum
(C) Orbital angular momentum (D) Space orientation of the orbital
7. Two electrons occupying the same orbital are distinguished by :
(A) Spin quantum number (B) Principal quantum number
(C) Magnetic quantum number (D) Azimuthal quantum number
8. Which quantum number will determine the shape of the subshell
(A) Principal quantum number (B) Azimuthal quantum number
(C) Magnetic quantum number (D) Spin quantum number
9. The orientation of an atomic orbital is governed by :
(A) azimuthal quantum number (B) spin quantum number
(C) magnetic quantum number (D) principal quantum number
10.Which of the following statements concerning the four quantum numbers is false -
(A) n gives idea of the size of an orbital
(B) l gives the shape of an orbital
(C) ms gives the energy of the electron in the orbital in absence of magnetic field
(D) ms gives the direction of spin angular momentum of the electron in an orbital
11. Principal quantum number of an atom represents
(A) Size of the orbital (B) Spin angular momentum
(C) Orbital angular momentum (D) Space orientation of the orbital
 Daily Practice Paper-5 (Principal Quantum Number)
1. The principal quantum number ‘n’ can have integral values ranging from :
(A) 0 to 10 (B) 1 to  (C) 1 to (n – 1) (D) 1 to 50
2. The number of orbitals in a shell with principal quantum number ‘n’ is :
(A) 2n (B) 2n 2 (C) n 2 (D) n + 1
3. The total number of atomic orbitals in fourth energy level of an atom are :
(A) 8 (B) 16 (C) 32 (D) 4
rd
4. How many electrons can fit into the orbitals that comprise the 3 quantum shell n = 3
(A) 2 (B) 8 (C) 18 (D) 32
5. The maximum number of electrons that can be accommodated in fifth energy level is
(A) 10 (B) 25 (C) 50 (D) 32
6. The number of sub-shells in the fifth energy level is
(A) 4 (B) 11 (C) 9 (D) 5
7.The maximum number of electrons that can be accommodated in the Mth shell is
(A) 2 (B) 8 (C) 18 (D) 32
8. For the n=2 energy level, how many orbitals of all kinds are possible
(A) 2 (B) 3 (C) 4 (D) 5
9. What is the maximum number of electrons which can be accommodated in an atom in which
the highest principal quantum number value is 2
(A)10 (B)18 (C) 32 (D) 54
10. Maximum number of electrons present in 'N' shell is
(A)18 (B) 32 (C) 2 (D) 8
11. An electron has principal quantum number 3.
The number of its (i) sub-shells and (ii) orbitals would be respectively
(A) 3 and 5 (B) 3 and 7 (C) 3 and 9 (D) 2 and 5
12. Principal quantum number can be used to explain
(A) energy (B) size (C) both of them (D) none of these
13.The maximum energy is present in any electron at
(A) Nucleus (B) Ground state
(C) First excited state (D) Infinite distance from the nucleus
14. The principal quantum number represents
(A) Shape of an orbital (B) Distance of electron from nucleus
(C) Number of electrons in an orbit (D) Number of orbitals in an orbit
15. For an atom the energy of electron increases with increase in 'n' and the energy difference
between successive energy levels
(A) Increases (B) Decreases (C) Remains constant (D) Cannot be found
 Daily Practice Paper-6 (Azimuthal Quantum Numbers)
1. The maximum number of electrons which each sub-shell can occupy is
(A) 2n2 (B) 2n (C) 2(2l + 1) (D) (2l + 1)
2. If n and l are respectively the principal and azimuthal quantum numbers, then the expression
for calculating the total number of electrons in any orbit is –
= n = n −1 = n + 1 = n −1

= 1
2 (2 + 1) =1
2 (2 + 1) = 0
2(2 + 1) = 0
2(2 + 1)
(A) (B) (C) (D)
3. The total number of electrons that can be accommodated in all the orbitals having
principal quantum number 2 and azimuthal quantum number 1 is:
(A) 2 (B) 4 (C) 6 (D) 8
4. For (n = 3), the possible values of azimuthal quantum number (l) is
(A) 0, 1, 2, 3 (B) 0, 1, 2 (C) –2, – 1, 0, 1, 2 (D) 1, 2, 3
5. For a shell of principal quantum number n = 4, which is incorrect:
(A) 16 orbitals (B) maximum 32 electrons
(C) 4 subshells (D) l = 0, 1, 2, 3, 4
6. For an orbital with azimuthal quantum n umber l = 3, the maximum number of
electrons will be:
(A) 2 (B) 6 (C) zero (D) 1
7. For azimuthal quantum number l = 3, the maximum number of electrons will be
(A) 2 (B) 6 (C) 0 (D) 14
8. A sub-shell with n = 6, l = 2 can accommodate a maximum of
(A) 12 electrons (B) 36 electrons (C) 10 electrons (D) 72 electrons
9. The total number of electrons that can be accommodated in all the orbitals having principal
quantum number 2 and azimuthal quantum number 1 is
(A) 2 (B) 4 (C) 6 (D) 8
10. The maximum number of electrons in a subshell is given by the expression.
(A) 4l – 2 (B) 4l + 2 (C) 2l + 2 (D) 2n2
11. Maximum numbers of electrons in a subshell is given by -
(A) (2l+1) (B) 2(2l+1) (C) (2l+1)2 (D) 2(2l+1)2
12. If n = 3, then the value of 'l' which is incorrect
(A) 0 (B)1 (C) 2 (D) 3
13. The maximum number of electrons in a subshell for which l = 3 is:
(A) 14 (B) 10 (C) 8 (D) 4
14. How many electrons can fit in the orbital for which n = 3 and l = 1?
(A) 14 (B) 2 (C) 6 (D) 10
15. Maximum number of electrons in a subshell having n = 4 and l = 3 are:
(A) 14 (B) 16 (C) 10 (D) 12
16. How many electrons can be accommodated in a sub-shell for which n = 3, l = 1
(A) 8 (B) 6 (C) 18 (D) 32
17. The maximum number of electrons present in an suborbit l = 3, is
(A) 6 (B) 8 (C) 10 (D) 14
 Daily Practice Paper-7 (shape of orbitals)
1.The quantum number which may be 13. The shape of s-orbital is
designated by s,p,d and f instead of number is (A) Pyramidal (B) Spherical
(A) n (B) l (C) 𝑚𝑙 (D) 𝑚𝑠 (C) Tetrahedral (D) Dumbbell shaped
2.. The shape of an orbital is given by the 14. The azimuthal quantum number is related to
quantum number (A) Size (B) Shape
(A) n (B) l (C) m (D) s (C) Orientation (D) Spin
3. When the azimuthal quantum number has a 15. When the azimuthal quantum number has a
value of l = 0, the shape of the orbital is value of l = 1, the shape of the orbital is
(A) Rectangular (B) Spherical (A) Unsymmetrical
(C) Dumbbell. (D) Unsymmetrical (B) Spherically symmetrical
4. The shape of p-orbital is (C) Dumb-bell
(A) Elliptical (D) Complicated
(B) Spherical 16.An orbital with l = 0 is symmetrical about
(C) Dumb-bell the
(D) Complex geometrical (A) x-axis only (B) y-axis only
5.Which is not permissible subshell? (C) z-axis only (D) All
(A) 2d (B) 4f (C) 6p (D) 3s 17.Which orbital is dumb-bell shaped ?
6.Which orbital is non-directional (A) 1s (B) 2p (C) 3s (D) 3d
(A) s (B) p (C) d (D) All 18. The number of orbitals in d sub-shell is.
7.For the dumb-bell shaped orbital, the value of (A) 1 (B) 3 (C) 5 (D) 7
l is 19.A sub-shell l = 2 can take how many
(A) 3 (B) 1 (C) 0 (D) 2 electrons
8. The value of Azimuthal quantum number for (A) 3 (B) 10 (C) 5 (D) 6
all electrons presents in 5p orbitals is 20.For d electrons, the azimuthal quantum
(A) 4 (B) 5 (C) 2 (D) 1 number is
9. If n + l = 6, then total possible number of (A) 0 (B) 1 (C) 2 (D) 3
subshells would be
21. The maximum number of electrons
(A) 3 (B) 4 (C) 2 (D) 5
accommodated in 5ƒ orbitals are
10. The number of orbitals in 3p sub-shell is.
(A) 5 (B) 10 (C) 14 (D) 18
(A) 6 (B) 2 (C) 3 (D) 4
22. The maximum number of electrons in an
11. Which of the following orbital is not
atom with l = 2 and n = 3 is
possible
(A) 3 f (B) 4 f (C) 5 f (D) 6 f (A) 2 (B) 6 (C) 12 (D) 10
12. 2p orbitals have 23. Which of the sub-shell is circular?
(A) 𝑛 = 1, 𝑙 = 2 (B) 𝑛 = 1, 𝑙 = 0 (A) 4s (B) 4f (C) 4p (D) 4d
(C) 𝑛 = 2, 𝑙 = 1 (D) 𝑛 = 2, 𝑙 = 0
 Daily Practice Paper-8 (angular momentum)
1.The quantum numbers n = 2, l = 1 represent
(A) 1s orbital (B) 2sorbital (C) 2p orbital (D) 3d orbital
2. Azimuthal quantum number defines
(A) e/m ratio of electron (B) Spin of electron
(C) Angular momentum of electron (D) Magnetic momentum of electron
3. Number of orbitals in h sub-shell is
(A) 11 (B) 15 (C) 17 (D) 19
4. For principal quantum number n = 4 the total number of orbitals having l = 3
(A) 3 (B) 7 (C) 5 (D) 9
5. The maximum number of electrons that can be accommodated in 'ƒ' subshell is
(A) 2 (B) 8 (C) 32 (D) 14
6. Energy of atomic orbitals in a particular shell is in the order
(A) 𝑠<𝑝<𝑑<𝑓 (B) 𝑠>𝑝>𝑑>𝑓 (C) 𝑝<𝑑<𝑓<𝑠 (D)𝑓>𝑑>𝑠>𝑝
7. There is no difference between a 2p and a 3p orbital regarding
(A) Shape (B) Size (C) Energy (D) Value of 𝑛
8.For a d-electron, the orbital angular momentum is
(A) √6ℏ (B) √2ℏ (C) ℏ (D) 2ℏ
9.The orbital angular momentum of an electron in 2s-orbital is -
ℎ ℎ ℎ
(A) 4𝜋 (B) zero (C) 2𝜋 (D) 2 2𝜋
10.The orbital angular momentum of a p-electron is given as :
ℎ ℎ 3ℎ ℎ
(A) (B) √3 (C) √ (D) √6.
√2𝜋 2𝜋 2𝜋 2𝜋
11.The orbital angular momentum of an electron in 3s-orbital is :
1 ℎ ℎ ℎ
(A) +2 2𝜋 (B) zero (C) 2𝜋 (D) √2 2𝜋
12.The orbital with zero angular momentum is -
(A) s (B) p (C) d (D) f
13.The orbital angular momentum of an electron in the orbitals 1s, 3s, 3d and 2p is respectively
ℎ ℎ ℎ ℎ
(A) 0, 0, 2𝜋 √6, 2𝜋 √2 (B) 1, 1, 2𝜋 √4, 2𝜋 √2
ℎ ℎ ℎ ℎ
(C) 0, 1, 2𝜋 √6,2𝜋 √3 (D) 0, 0, 2𝜋 √20, 2𝜋 √6
14.In which of the following sets of orbitals, electrons have equal orbital angular momentum?
(A) 1s and 2s (B) 2s and 2p (C) 2p and 3p (D) 3p and 3d
 Daily Practice Paper-9 (magnetic quantum number)
1. For a given value of quantum number 𝑙, the 10. The energy of an electron of 2py orbital is
number of allowed values of 𝑚 is given by (A) Greater than that of 2px orbital
(A) l + 2 (B) 2l + 2 (C) 2l + 1 (D) l + 1 (B) Less than that of 2px orbital
2. Which statement is not correct for (C) Equal to that of 2s orbital
n = 5, m = 3 (D) Same as that of 2px and 2pz orbital
1 11. What is the maximum number of orbitals
(A) l = 4 (B) 𝑙 = 0,1,3; 𝑠 = + 2
that can be identified with the following
(C) l = 3 (D) All are correct
– quantum number n = 3, l = 1, m = 0
3. An e has magnetic quantum number as –3,
(A) 1 (B) 2 (C) 3 (D) 4
what is its principal quantum number
12. The maximum value of m for an electron in
(A) 1 (B) 2 (C) 3 (D) 4
fourth energy level is:
4. When the value of azimuthal quantum
(A) +4 (B) +3 (C) +5 (D) +9
number is 3, magnetic quantum number can
13. The orbital angular momentum
have value
corresponding to n = 4 and m = –3 is :
(A) + 1, 0, – 1 h 6h 3h
(B) + 2, + 1, 0, – 1, – 2 (A) 0 (B) (C) (D)
2 2 
(C) – 3, – 2, – 1, – 0, + 1, + 2, + 3 14. Which is not correct for an electron having
(D) + 1, – 1 n = 5, m = 2 :
5. The total magnetic quantum numbers for d- (A) l = 4 (B) l = 0, 1, 2, 3
orbital is given by (C) l = 3 (D) l = 2, 3, 4
(A) 2 (B) 0,  1,  2 15. Which of the following orbital quantum
(C) 0, 1, 2 (D) 5 number value is not possible for an electron
6. The quantum number ‘m’ of a free gaseous present in 4d subshell:
atom is associated with (A) n = 4 (B) l = 1 (C) m = 1 (D) m = 2
(A) The effective volume of the orbital 16. Maximum number of orbitals in an atom
(B) The shape of the orbital having quantum numbers
(C) The spatial orientation of the orbital n = 3, l = 2, m = + 2 are
(A) 1 (B) 2 (C) 3 (D) 4
(D) The energy of the orbital in the absence of a
17. Which of the following statements is/are
magnetic field
correct for an electron of quantum numbers
7.The maximum number of electrons in p-
n = 4 and m = 2 ?
orbital with n = 5, m = 1 is
(A) The value of l may be 2.
(A) 6 (B) 2 (C) 14 (D) 10
(B) The value of l may be 4.
8. The number of electrons that can be (C) The value of l may be +1/2.
accommodated in dz2 orbital is (D) The value of l may be 0, 1, 2, 3.
(A) 10 (B) 1 (C) 4 (D) 2 18. A given orbital is labelled by the magnetic
9. Maximum electrons in a d-orbital are quantum number m = –1. This can not be -
(A) 2 (B) 10 (C) 6 (D) 14 (A) s-orbital (B) d-orbital
(C) p-orbital (D) f-orbital
19. Which quantum number will determine the shape of the subshell
(A) Principal quantum number (B) Azimuthal quantum number
(C) Magnetic quantum number (D) Spin quantum number
20. For an electron, magnetic quantum number m = +2. The electron may be present in
(A) 5s-sub-shell (B) 5d-sub-shell (C) 5p-sub-shell (D) 5f-sub-shell
21. The magnetic quantum number specifies
(A) Size of orbitals (B) Shape of orbitals
(C) Orientation of orbitals (D) Nuclear stability
22. If value of azimuthal quantum number 𝑙 is 2, then total possible values of magnetic quantum
number will be
(A) 7 (B) 5 (C) 3 (D) 2
23. For p-orbital, the magnetic quantum number has value
(A) 2 (B) 4, – 4 (C) – 1, 0, +1 (D) 0
24. If the value of azimuthal quantum number is 3, the possible values of magnetic quantum
number would be
(A) 0, 1, 2, 3 (B) 0, – 1, – 2, – 3 (C) 0, ±1, ±2, ± 3 (D) ±1, ±2, ±3
25. If magnetic quantum number of a given atom represented by –3, then what will be its
principal quantum number
(A) 1 (B) 2 (C) 3 (D) 4
26. The magnetic quantum number for an electron when the value of principal quantum number
is 2 can have
(A) 3 values (B) 2 values (C) 9 values (D) 6 values
27. Match List-I with List-II and select the correct answer using the codes given below the lists
List-I List-II
(P) Number of value of l for an energy level (1) 0, 1, 2, ............. (n - 1)
(Q) Value of l for a particular type of orbital (2) +l to –l through zero
(R) Number of values of m for l = 2 (3) 5
(S) Value of 'm' for a particular type of orbital (4) n
Code : P Q R S P Q R S
(A) 4 1 2 3 (B) 4 1 3 2
(C) 1 4 2 3 (D) 1 4 3 2
28. Which of the following statements is not correct for an electron that has the quantum
numbers 𝑛 = 4 and 𝑚 = 2
1
(A)The electron may have the quantum number 𝑠 = + 2
(B)The electron may have the quantum number l = 2
(C) The electron may have the quantum number l = 3
(D) The electron may have the quantum number l = 0,1,2,3
 Daily Practice Paper-10 (shape of orbitals)
1. The maximum probability of finding electron in the dxy orbital is –
(A) Along the x-axis (B) Along the y-axis
(C) At an angle of 45º from the x and y-axis
(D) At an angle of 90º from the x and y-axis
2. Which d - orbital has different shape from rest of all d - orbitals ?
(A) 𝑑𝑧 2 (B) dxy (C) d xz (D) d yz
3. 3py orbital has..........nodal plane :
(A) XY (B) YZ (C) ZX (D) All of these
4. In case of 𝑑𝑥2 −𝑦2 orbital
(A) Probability of finding the electron along x-axis is zero.
(B) Probability of finding the electron along y-axis is zero.
(C) Probability of finding the electron is maximum along x and y-axis.
(D) Probability of finding the electron is zero in x-y plane
5. Which d-orbital does not have four lobes
(A) 𝑑𝑥2 −𝑦 2 (B) dxy (C) 𝑑𝑧 2 (D) dxz
6. Which of the following d-orbitals has dough-nut shape ?
(A) dxy (B) dyz (C) 𝑑𝑥2 −𝑦2 (D) 𝑑𝑧 2
7. Magnetic quantum number specifies -
(A) Size of orbitals (B) Shape of orbitals
(C) Orientation of orbitals (D) Nuclear stability
8. A p-orbital can accommodate
(A) 4 electrons (B) 6 electrons
(C) 2 electrons with parallel spins (D) 2 electrons with opposite spin
9. A given orbital is labeled by the magnetic quantum number m = –1. This could not be
(A) s - orbital (B) p-orbital (C) d-orbital (D) f-orbital
10. Non-directional orbital is :
(A) 3s (B) 4f (C) 4d (D) 4p
11. Which of the following pairs of d-orbitals will have electron density along the axis
(A) 𝑑𝑥𝑦 ,𝑑𝑥2 –𝑦2 (B) 𝑑𝑧 2 , 𝑑𝑥𝑧 (C) 𝑑𝑥𝑧 , 𝑑𝑦𝑧 (D) 𝑑𝑧 2 , 𝑑𝑥2 –𝑦2
12. The probability of finding an electron residing in a p x orbital is not zero
(A) In yz plane (B) In xy plane (C) In y direction (D) In z direction
13. The shape of dxy orbital will be
(A) Circular (B) Dumb-bell (C) Double dumb-bell (D) Trigonal
 Daily Practice Paper-11 (nodes )
1. For an electron, with n = 3 has only one radial node. The orbital angular momentum of the
electron will be
ℎ ℎ ℎ
(A) 0 (B) 6 2𝜋 (C) 2 2𝜋 (D) 3 (2𝜋)
2. Number of nodal centers for 2s orbital
(A) 1 (B) 0 (C) 4 (D) 3
3. The number of nodal planes in a p x orbital is :
(A) 1 (B) 2 (C) 3 (D) zero
4. The number of radial nodes in 3s and 2p respectively are:
(A) 2 and 0 (B) 1 and 2 (C) 0 and 2 (D) 2 and 1
5. Which of the following orbitals has (have) one spherical node?
(A) 1s (B) 2s (C) 2p (D) 3p
6. The number of nodal planes in a px orbital is
(A) one (B) two (C) three (D) Zero
7. The sum of angular nodes and radial nodes of 4dxy atomic orbital are
(A) 1 (B) 2 (C) 3 (D) 4
8. Which of the following pair of orbitals posses two nodal planes
(A) 𝑝𝑥 , 𝑑𝑥2 −𝑦2 (B) 𝑑𝑥𝑦 , 𝑑𝑧𝑥 (C) 𝑝𝑥𝑦 , 𝑑𝑧𝑥 (D) 𝑑𝑧 2 , 𝑑𝑥2 −𝑦2
9. The number of radial nodes of 3s and 2p orbitals are respectively.
(A) 2, 0 (B) 0, 2 (C) 1, 2 (D) 2, 1
10. The electron density between 1s and 2s orbital is
(A) High (B) Low (C) Zero (D) None of these
11. A 3p orbital has
(A) Two spherical nodes
(B) Two non-spherical nodes
(C) One spherical and one non-spherical nodes
(D) One spherical and two non-spherical nodes
 Daily Practice Paper-12 (spin quantum numbers)
1.An electron has spin quantum number, ms = + 1/2 and magnetic quantum number, ml = +1. It
cannot be present in
(A) s-orbital (B) p-orbital (C) d-orbital (D) f-orbital
2.The maximum number of electrons with clockwise spin that can be accommodated in a f-sub-
shell is
(A) 14 (B) 7 (C) 5 (D) 10
3.The quantum numbers + 1/2 and – 1/2 for the electron spin represent:
(A) Rotation of the electron in clockwise and anticlockwise direction, respectively.
(B) Rotation of the electron in anticlockwise and clockwise direction, respectively.
(C) Magnetic moment of the electron pointing up and down respectively,
(D) Two quantum mechanical spin states which have no classical analogue.
4.The maximum number of 3d-electrons that can have s = –1/2, are
(A) 10 (B) 3 (C) 5 (D) 7
5.Spin angular momentum for an electron is given as :
ℎ ℎ ℎ
(A) √𝑠(𝑠 + 1) ∗ 2𝜋 (B) √2𝑠(𝑠 + 1) ∗ 2𝜋 (C) √𝑠(𝑠 + 2) ∗ 2𝜋 (D) None
6.For a given subshell let maximum number of electrons with same spin be x and number of
possible ml values be y.
𝑥 𝑦
(A) x = 2y (B) x = y (C) 2 = y (D) x = 2
7.Assertion: Spin quantum number can have two values, +1/2 and –1/2
Reason: + and – signs signify the positive and negative wave functions.
(A) If both assertion and reason are true and reason is the correct explanation of assertion.
(B) If both assertion and reason are true but reason is not the correct explanation of assertion.
(C) If Assertion is true but reason is false.
(D) If both assertion and reason are false.
8.The electrons occupying the same orbital have always ________ spin.
(A) parallel (B) antiparallel (C) both (A) and (B) (D) none of these
9. Which of the following rules limits the maximum number of electrons in an orbital to two
(A) Aufbau principle (B) Pauli's exclusion principle
(C) Hund's rule of maximum multiplicity (D) Heisenberg's uncertainty principle
10. In a given atom no two electrons can have the same values for all the four quantum numbers.
This is called
(A) Hund's rule (B) Aufbau's principle
(C) Uncertainty principle (D) Pauli's exclusion principle
11. The number of 2p electrons having spin quantum number s = –1/2 are
(A) 6 (B) 0 (C) 2 (D) 3
 Daily Practice Paper-13 (set of quantum numbers)
1. For principal quantum number n = 4, the 11. All electrons on the 4p sub-shell must be
total number of orbitals having l = 3 is characterized by the quantum number
(A) 3 (B) 7 (C) 5 (D) 9 (A) 𝑛 = 4, 𝑚 = 0, 𝑠 = ±1/2 (B) l = 1
2. An orbital containing electron having (C) 𝑙 = 0, 𝑠 = ±1/2 (D) 𝑠 = −1/2
quantum number 12. If an electron has spin quantum number
n = 4, l = 3, m = 0 and s = +1/2 is called 1
of + 2 and a magnetic quantum number of –
(A) 3s (B) 3p (C) 4d (D) 4f orbital
3. Which of the following represents the 1, it cannot be presented in which orbital
correct sets of the four quantum numbers of (A) d (B) f (C) p (D) s
a 4d electron. 13. Which one of the following represents
(A) 4,3,2,1/2 (B) 4, 2, 1, 0 an impossible arrangement?
(C) 4,3, −2, +1/2 (D) 4,2,1, −1/2 n l m s
4. The following quantum number are (A) 3 2 –2 -½
possible for how many orbitals? (B) 4 0 0 +½
n = 3, l = 2, m = +2 (C) 3 2 –3 +½
(A) 3 (B) 2 (C) 1 (D) 4 (D) 5 3 0 -½
5. Maximum number of electrons that can 14. The set of quantum numbers not
have n = 3, l = 2, m = +2, s = +1/2 in an applicable for an electron in an atom is
atom are : (A) 𝑛 = 1, 𝑙 = 1, 𝑚𝑙 = 1, 𝑚𝑠 = +1/2
(A) 18 (B) 6 (C) 24 (D) 1 (B) 𝑛 = 1, 𝑙 = 0, 𝑚𝑙 = 0, 𝑚𝑠 = +1/2
6. Which of the following represents the (C) 𝑛 = 1, 𝑙 = 0, 𝑚𝑙 = 0, 𝑚𝑠 = −1/2
correct set of quantum numbers of a 4d (D) 𝑛 = 2, 𝑙 = 0, 𝑚𝑙 = 0, 𝑚𝑠 = +1/2
electron? 15. Which of the following sets of quantum
(A) 4, 3, 2, +1/2 (B) 4, 2, 1, 0 number are correct ?
(C) 4, 3, – 2, +1/2 (D) 4, 2, 1, – 1/2 (A) n = 3, l = 2, m = + 1, s = +1/2
7. An electron having the quantum numbers (B) n = 3, l = 3, m = + 3, s = +1/2
𝑛 = 4, 𝑙 = 3, 𝑚 = 0, 𝑠 = −1/2 would be in (C) n = 4, l = -1, m = 0, s = +1/2
the orbital (D) n = 5, l = 2, m = + 4, s = +1/2
(A) 3s (B)3p (C) 4d (D) 4f 16. Which set of quantum numbers for an
8. Number of two electron can have the electron of an atom is not possible
same values of …… quantum numbers (A) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0, 𝑠 = +1/2
(A) One (B) Two (C) Three (D) Four (B) 𝑛 = 1, 𝑙 = 1, 𝑚 = 1, 𝑠 = +1/2
9. An electron having the quantum numbers (C) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0, 𝑠 = −1/2
𝑛 = 4, 𝑙 = 3, 𝑚 = 0, 𝑠 = −1/2 would be in (D) 𝑛 = 2, 𝑙 = 1, 𝑚 = −1, 𝑠 = +1/2
the orbital 17. Which of the following sets of quantum
(A) 3s (B)3p (C) 4d (D) 4f number is not possible?
(A) n = 3; l = 0 + 2, ml = 0, ms = + 1/2
10. The number of possible spatial
orientations of an electron in an atom is (B) n = 3; l = 0, ml = 0, ms = – 1/2
given by its (C) n = 3; l = 0, ml = –1, ms = +1/2
(A) Spin quantum number (D) n = 3; l = 1, ml = 0, ms = –1/2
(B) Spin angular momentum
(C) Magnetic quantum number
(D) Orbital angular momentum
18. Which of the following sets of the 25. Which of the following sets of quantum
quantum numbers is permitted? number is(are) correct:
(A) n = 4, l = 2, ml = +3, ms = + 1/2 (A) n = 5, l = 4, m = 0, s = + 1/2
(B) n = 3, l = 3, ml = +3, ms = + 1/2 (B) n = 3, l = 3, m = +3, s = +1/2
(C) n = 6, l = 0, m = +1, s = – 1/2
(C) n = 4, l = 0, ml = 0, ms = + 1/2
(D) n = 4, l = 2, m = +2, s = 0
(D) n = 4, l = 3, ml = +1, ms = 0 26. Which of the following sets of quantum
19. Which of the following set of quantum numbers is correct for an electron in 4ƒ
numbers is not valid. orbital
(A) n = 3, l = 2, m = 2, s = +1/2 (A) 𝑛 = 4, 𝑙 = 3, 𝑚 = +1, 𝑠 = +1/2
(B) n = 2, l = 0, m = 0, s = +1/2 (B) 𝑛 = 4, 𝑙 = 4, 𝑚 = −4, 𝑠 = +1/2
(C) n = 4, l = 2, m = –1, s = +1/2 (C) 𝑛 = 4, 𝑙 = 3, 𝑚 = +4, 𝑠 = +1/2
(D) n = 4, l = 3, m = 4, s = +1/2
(D) 𝑛 = 3, 𝑙 = 2, 𝑚 = −2, 𝑠 = +1/2
20. Which of the following combinations of
quantum numbers is allowed? 27.Which of the following sets is possible
n l m ms for quantum numbers
(A) 𝑛 = 4, 𝑙 = 3, 𝑚 = −2, 𝑠 = 0
(A) 3 2 1 0
(B) 2 0 0 +1/2 (B) 𝑛 = 4, 𝑙 = 4, 𝑚 = +2, 𝑠 = +1/2
(C) 3 -3 -2 +1/2 (C) 𝑛 = 4, 𝑙 = 4, 𝑚 = −2, 𝑠 = +1/2
(D) 1 0 1 +1/2 (D) 𝑛 = 4, 𝑙 = 3, 𝑚 = −2, 𝑠 = +1/2
21. Which set of quantum numbers for an 28. Which one of the following set of
electron of an atom is not possible quantum numbers is not possible for 4p
(A) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0, 𝑠 = +1/2 electron
(B) 𝑛 = 1, 𝑙 = 1, 𝑚 = 1, 𝑠 = +1/2 (A) 𝑛 = 4, 𝑙 = 1, 𝑚 = −1, 𝑠 = +1/2
(C) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0, 𝑠 = −1/ (B) 𝑛 = 4, 𝑙 = 1, 𝑚 = 0, 𝑠 = +1/2
(D) 𝑛 = 2, 𝑙 = 1, 𝑚 = −1, 𝑠 = +1/2 (C) 𝑛 = 4, 𝑙 = 1, 𝑚 = 2, 𝑠 = +1/2
22. Consider the following sets of quantum (D) 𝑛 = 4, 𝑙 = 1, 𝑚 = −1, 𝑠 = +1/2
numbers : n l m s 29. Which of the following sets of quantum
(i) 3 0 0 +1/2 numbers is not allowed
(ii) 2 2 1 +1/2
(iii) 4 3 –2 –1/2 (A) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0, 𝑠 = +1/2
(iv) 1 0 –1 –1/2 (B) 𝑛 = 1, 𝑙 = 1, 𝑚 = 0, 𝑠 = −1/2
(v) 3 2 3 +1/2 (C) 𝑛 = 2, 𝑙 = 1, 𝑚 = 1, 𝑠 = +1/2
Which of the following sets of quantum (D) 𝑛 = 2, 𝑙 = 1, 𝑚 = 0, 𝑠 = −1/2
numbers is not possible ? 30. Which of the following set of quantum
(A) (i) and (iii) (B) (ii), (iii) and (iv) numbers is permitted
(C) (i), (ii), (iii) and (iv) (D) (ii), (iv) and (v) (A) n = 3, l = 2, m = – 2, s = +1/2
24. Which of the following sets of the (B) n = 3, l = 2, m = – 1, s = 0
quantum numbers is not possible? (C) n = 2, l = 2, m = +1, s = – 1/2
(A) n = 2, l = 1, m = –1, s = +1/2 (D) n = 2, l = 2, m = +1, s = – ½
(B) n = 2, l = 0, m = 0, s = + 1/2 31. What is the correct orbital
(C) n = 3, l = 2, m = –2, s = +1/2 designation for the electron with the
(D) n = 3, l = 2, ml = –3, s = +1/2 quantum numbers,
n = 4, l = 3, m = – 2, s = +1/2
(A) 3 s (B) 4 f (C) 5 p. (D) 6 s
 Daily Practice Paper-14 (energy of orbitals)
01. In hydrogen atom, which is incorrect order of their energies.
(A) 1s < 2p (B) 2p = 2s (C) 2p > 2s (D) 2p < 3s
02. Which of the following sets of orbitals may degenerate
(A) 2𝑠, 2𝑝𝑥 , 2𝑝𝑦 (B) 3𝑠, 3𝑝𝑥 , 3𝑑𝑥𝑦 (C) 1𝑠, 2𝑠, 3𝑠 (D) 2𝑝𝑥 , 2𝑝𝑦 , 2𝑝𝑧
03. If n = 6, the correct sequence for filling of electrons will be :
(A) ns → (n – 2)f → (n – 1)d → np (B) ns → (n – 1)d → (n – 2)f → np
(C) ns → (n – 2)f → np → (n – 1)d (D) ns → np(n – 1)d → (n – 2)f
04. 4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is
(A) 5f > 6p > 4d > 5p (B) 5f > 6p > 5p > 4d
(C) 6p > 5f > 5p > 4d (D) 6p > 5f > 4d > 5p
05. Which of the following has the least energy
(A) 2p (B) 3p (C) 2s (D) 4d
06. The correct order of increasing energy of atomic orbitals is
(A) 5𝑝 < 4𝑓 < 6𝑠 < 5𝑑 (B) 5𝑝 < 6𝑠 < 4𝑓 < 5𝑑
(C) 4𝑓 < 5𝑝 < 5𝑑 < 6𝑠 (D) 5𝑝 < 5𝑑 < 4𝑓 < 6𝑠
07. The orbital with maximum energy is
(A) 3d (B) 5p (C) 4s (D) 6d
08. Which of the following sequence is correct as per Aufbau principle
(A) 3𝑠 < 3𝑑 < 4𝑠 < 4𝑝 (B) 1𝑠 < 2𝑝 < 4𝑠 < 3𝑑
(C) 2𝑠 < 5𝑠 < 4𝑝 < 5𝑑 (D) 2𝑠 < 2𝑝 < 3𝑑 < 3𝑝
09. Which of the following set of quantum numbers represents the highest energy of an atom ?
1 1
(A) n = 3, l = 0, m = 0, s = +2 (B) n = 3, l = 1, m =1, s = +2
1 1
(C) n = 3, l = 2, m = 1, s = + (D) n = 4, l = 0, m = 0, s = +
2 2
10. The electrons identified by quantum numbers n and l :
(1) n = 4, l = 1 (2) n = 4, l = 0 (3) n = 3, l = 2 (4) n = 3, l = 1
can be placed in the order of increasing energy as :
(A) 3 < 4 < 2 < 1 (B) 4 < 2 < 3 < 1 (C) 2 < 4 < 1 3 (D) 1 < 3 2 < 4
11. In any atom which sub-shell will have the highest energy in the following
(A) 3p (B) 3d (C) 4s (D) 3s
12. Which of the following set of quantum numbers belong to highest energy
1 1
(A) 𝑛 = 4, 𝑙 = 0, 𝑚 = 0, 𝑠 = + 2 (B) 𝑛 = 3, 𝑙 = 0, 𝑚 = 0, 𝑠 = + 2
1 1
(C) 𝑛 = 3, 𝑙 = 1, 𝑚 = 1, 𝑠 = + 2 (D) 𝑛 = 3, 𝑙 = 2, 𝑚 = 1, 𝑠 = + 2
13. n and l for some electrons are given. Which of the following is expected to have least
energy?
(A) n = 3, l = 2 (B) n = 3, l = 0 (C) n = 2, l = 1 (D) n = 4, l = 0
14. The electrons, identified by quantum numbers n and l
(i) n = 4, l = 1 (ii) n= 4, l = 0 (iii) n = 3, l = 2 (iv) n = 3, l = 1
can be placed in order of increasing energy, from the lowest to highest, as
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (v) < (iii)
(C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
15. The atomic orbitals are progressively filled in order of increasing energy. This principle is
called as
(A) Hund’s rule (B) Aufbau principle (C) Exclusion principle (D) de-Broglie rule
16. The electron should be filled in the orbital in accordance with the increasing order of their
energy. This statement is related with –
(A) Aufbau principle (B) Pauli principle (C) Hund's principle (D) Plank's rules
17. According to Aufbau's principle, which of the three 4d, 5p and 5s will be filled with
electrons first
(A) 4d (B) 5p (C) 5s (D) 4d and 5s will be filled simultaneously
18. The order of filling of electrons in the orbitals of an atom will be
(A) 3𝑑, 4𝑠, 4𝑝, 4𝑑, 5𝑠 (B) 4𝑠, 3𝑑, 4𝑝, 5𝑠, 4𝑑
(C) 5𝑠, 4𝑝, 3𝑑, 4𝑑, 5𝑠 (D) 3𝑑, 4𝑝, 4𝑠, 4𝑑, 5𝑠
19. Which of the following transition neither shows absorption nor emission of energy in case of
Hydrogen atom:
(A) 3px, 3s (B) 3dxy, 3dyz (C) 3s, 3dxy (D) All the above
20. When 3d orbital is complete, the new electron will enter the
(A) 4p-orbital (B) 4f-orbital (C) 4s-orbital (D) 4d-orbital
21. In a potassium atom, electronic energy levels are in the following order
(A) 4s > 3d (B) 4s > 4p (C) 4s < 3d (D) 4s < 3p
22. After np orbitals are filled, the next orbital filled will be :
(A) (n + 1) s (B) (n + 2) p (C) (n + 1) d (D) (n + 2) s
23. In a multi-electron atom, which of the following orbitals described by the three quantum
members will have the same energy in the absence of magnetic and electric fields
(a) 𝑛 = 1, 𝑙 = 0, 𝑚 = 0 (b) 𝑛 = 2, 𝑙 = 0, 𝑚 = 0(c) 𝑛 = 2, 𝑙 = 1, 𝑚 = 1
(d) 𝑛 = 3, 𝑙 = 2, 𝑚 = 0 (e) 𝑛 = 3, 𝑙 = 2, 𝑚 = 0
(A) (a) and (b) (B) (b) and (c) (C) (c) and (d) (D) (d) and (e)
 Daily Practice Paper-15 (electronic configuration)
01. Aufbau principle is obeyed in which of 09. Fe (atomic number = 26) atom has the
the following electronic configurations electronic arrangement
(A) 1𝑠 2 2𝑠 2 2𝑝6 (B) 1𝑠 2 3𝑝3 3𝑠 2 (A) 2, 8, 8, 8 (B) 2, 8, 16
(C) 1𝑠 2 3𝑠 2 3𝑝6 (D) 1𝑠 2 2𝑠 2 3𝑠 2 (C) 2, 8,14, 2 (D) 2, 8, 12, 4
02. The orbital diagram in which the 10. The electronic configuration of an
Aufbau’s principle is violated is element with atomic number 17 is
2s 2𝑝𝑥 2𝑝𝑦 2𝑝𝑧 (A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 1 3𝑝6
(A) ↑↓ ↑↓ ↑ (B) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝4 , 4𝑠 1
(B) ↑ ↑↓ ↑ ↑ (C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝5
(C) ↑↓ ↑ ↑ ↑ (D) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 1 3𝑝4 , 4𝑠 2
(D) ↑↓ ↑↓ ↑↓ ↑ 11. The total number of electrons present
03. Which electronic configuration is not in all the s-orbitals, all the p-orbitals and
observing the (n + 1) rule all the d-orbitals of cesium ion are
(A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑1 , 4𝑠 2 respectively
(B) 1𝑠 2 , 2𝑠 2 𝑠𝑝6 , 3𝑠 2 3𝑝6 3𝑑 7 , 4𝑠 2 (A) 8, 26, 10 (B) 10, 24, 20
(C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 5 , 4𝑠 1 (C) 8, 22, 24 (D) 12, 20, 22
(D) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 8 , 4𝑠 2 12. Which element is represented by the
04. The 19th electron of chromium has following electronic configuration
which of the following sets of quantum 2𝑝
numbers? 2𝑠 ↑↓ ↑↓ ↑
n l m ms 1𝑠 ↑↓
(A) 3 0 0 –1/2 ↑↓
(B) 3 2 –2 –1/2
(C) 4 0 0 –1/2 (A) Nitrogen (B) Oxygen
(D) 4 1 –1 – 1/2 (C) Fluorine (D) Neon
05. Electronic configuration of deuterium 13. Given is the electronic configuration of
atom is element X : K L M N
(A) 1s1 (B) 2s2 (C) 2s1 (D) 1s2 2 8 11 2
06. The configuration [Ar] 3d10 4s2 4p4 is The number of electrons present with l = 2
similar to that of in an atom of element X is :
(A) boron (B) nitrogen (A) 3 (B) 6 (C) 5 (D) 4
(C) Sulphur (D) aluminum 14. The four quantum numbers of the
07. The type of orbitals present in Fe is outermost orbital of K (atomic no. =19)
(A) s (B) s and p are
1
(C) s, p and d (D) s,p,d and f (A) 𝑛 = 2, 𝑙 = 0, 𝑚 = 0, 𝑠 = + 2
08. Which of the following electronic 1
(B) 𝑛 = 4, 𝑙 = 0, 𝑚 = 0, 𝑠 = + 2
configuration is not possible
1
(A) 1𝑠 2 2𝑠 2 (B) 1𝑠 2 , 2𝑠 2 2𝑝6 (C) 𝑛 = 3, 𝑙 = 1, 𝑚 = 1, 𝑠 = +
2
1
(C) [𝐴𝑟]3𝑑10 , 4𝑠 2 4𝑝2 (D) 𝑛 = 4, 𝑙 = 2, 𝑚 = −1, 𝑠 = + 2
(D) 1𝑠 2 , 2𝑠 2 2𝑝2 , 3𝑠 1
15. Azimuthal quantum number for last
electron of Na atom is
(A) 1 (B) 2 (C) 3 (D) 0 24. Be's 4th electron will have four
16. The number of electrons in the M-shell quantum numbers
of the element with atomic number 24 are : n l m s
(A) 24 (B) 12 (C) 8 (D) 13 (A) 1 0 0 +1/2
17. Krypton (36Kr) has the electronic (B) 1 1 +1 +1/2
configuration (18Ar) 4𝑠 2 , 3𝑑10 , 4𝑝6 . The (C) 2 0 0 –½
37th electron will go into which one of the (D) 2 1 0 +1/2
following sub-levels 25. Electronic configuration of Sc21 is
(A) 4f (B) 4d (C) 3p (D)5s (A) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝6 4𝑠 2 3𝑑1
18. Electronic configuration of C is (B) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 4𝑠 1 3𝑑 2
(A) 1𝑠 2 , 2𝑠 2 2𝑝2 (B) 1𝑠 2 , 2𝑠 2 2𝑝3 (C) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 4𝑠 0 3𝑑 3
(C) 1𝑠 2 , 2𝑠 2 (D) 1𝑠 2 , 2𝑠 2 2𝑝6 (D) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝2 4𝑠 2 3𝑑 2
19. The correct electronic configuration of 26. Values of the four quantum numbers
𝑇𝑖(𝑍 = 22) atom is for the last electron in the atom are
(A) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝6 4𝑠 2 3𝑑 2 𝑛 = 4, 𝑙 = 1, 𝑚 = +1 and 𝑠 = −1/2.
(B) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 3𝑑 4 Atomic number of the atom can’t be
(C) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 3𝑑 4 (A) 22 (B) 32
(D) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝6 4𝑠 1 3𝑑 3 (C) 33 (D)36
20. Which of the following configuration 27. The correct set of quantum numbers
is correct for iron for the unpaired electron of Xenon
(A) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝6 3𝑑 5 (single positive) ion is
(B) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 4𝑠 2 3𝑑 5 n l m
(C) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 4𝑠 2 3𝑑 7 (A) 6 1 0
(D) 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 23𝑝6 4𝑠 2 3𝑑 6 (B) 4 1 1
21. An atom has 2 electrons in K shell, 8 (C) 5 1 1
electrons in L shell and 6 electrons in M (D) 3 0 0
shell. The number of s-electrons present in 28. the species not having same number of
that element is d-electron in last possible filled d-subshell
(A) 6 (B)5 (C) 7 (D) 10 as in Zn.
22. The total number of electrons present (A) Ga (B) Pd (C) Cd (D) Pt
in all the p-orbitals of bromine are 29. Which of the following elements will
(A) 5 (B) 18 (C) 17 (D) 30 have the same total number of electrons in
's' as well as 'd' subshells in the ground
23. Which of the following electronic
state electronic configuration?
configurations is not possible.
(A) Zn (B) Ni (C) Cr (D) Cu
(A) 1𝑠 2 2𝑠 2 (B) 1𝑠 2 2𝑠 2 2𝑝6
(C) 3𝑑10 4𝑠 2 4𝑝2 (D) 1𝑠 2 2𝑠 2 2𝑝2 3𝑠 1
 Daily Practice Paper-16 (Hund's and Pauli)
1. For sodium atom the number of 14.
electrons with m = 0 will be 15. Calculate the minimum and maximum
(A) 2 (B) 7 (C) 9 (D) 8 number of electrons which may have
2. Number of unpaired electrons in magnetic quantum number, m = +1 and
1s 2 2s 2 2p3 is spin quantum number, s = –1/2 in
chromium (Cr) :
(A) 2 (B) 0 (C) 3 (D) 1
(A) 0, 1 (B) 1, 2 (C) 4, 6 (D) 2, 3
3. The number of unpaired electrons in
16. Which of the following has the
1s 2 , 2s 2 2p4 is
maximum number of unpaired electrons ?
(A) 4 (B) 2 (C) 0 (D)1
(A) Mn (B) Ti (C) V (D) Al
4. Number of unpaired electrons in the 17. The total spin resulting from a d7
ground state of beryllium atom is configuration is :
(A) 2 (B) 1 (C) 0 (D) All the above (A) 1 (B) 2 (C) 5/2 (D) 3/2
5. The maximum number of unpaired 18. The electronic configuration
electron can be present in d subshell are 1s 2 2s 2 2p1x 2p1y 2p1z
(A) 1 (B)3 (C) 5 (D) 7
(A) Oxygen (B) Nitrogen
6. The total number of unpaired electrons (C) Hydrogen (D) Fluorine
in d-orbitals of atoms of element of atomic
19. Which electronic configuration does
number 29 is
not follow the Pauli’s exclusion principle
(A) 10 (B) 1 (C) 0 (D) 5
(A) 1s2, 2s2 2p4 (B) 1s2, 2s2 2p4 3s2
7. The outer electronic structure 3s 2 3p5 is
possessed by (C) 1s2, 2p4 (D) 1s2, 2s2 2p6 3s3
(A) Cl (B) O (C) Ar (D) Br 20. The electronic configuration of an
element is 1s 2 2s 2 2p6 3s 2 3p6 3d6 4s 2 . This
8. How many unpaired electrons are
represents its
present in cobalt [Co] metal
(A) Excited state (B) Ground state
(A) 2 (B) 3 (C) 4 (D)7
(C) Cationic form. (D) Anionic form
9. The number of unpaired electrons in
21. Consider the ground state of (Z = 24).
nitrogen is
The numbers of electrons with the
(A) 1 (B)3 (C) 2. (D) None of these
azimuthal quantum numbers, l = 1 and 2
10. For sodium atom the number of
are, respectively
electrons with m = 0 will be :
(A)16 and 4 (B)12 and 5
(A) 2 (B) 7 (C) 9 (D) 8
(C)12 and 4 (D)16 and 5
11. The total spin resulting from a d7
22. Which of the following explains the
configuration is :
sequence of filling the electrons in
(A) 1 (B) 2 (C) 5/2 (D) 3/2
different shells
12. Number of electrons having l = 1 and
(A) Hund's rule (B) Octet rule
m=0 in P-atom in its ground state :
(C) Aufbau principle. (D) All of these
(A) 3 (B) 1 (C) 2 (D) 0
23. Nitrogen has the configuration
13. Which element contains six unpaired
1s 2 2s 2 2p1x 2p1y 2p1z not 1s 2 2s 2 2p2x 2p1y 2p0z
electron
which is determined by
(A) Fe (B) Co (C) Ni (D) Cr
(A) Aufbau's principle
(B) Pauli's exclusion principle (A) Total number of s electrons - 8
(C) Hund's rule (B) Total number of p electrons - 12
(D) Uncertainty principle (C) Total number of d electrons -1
24. Which one of the following (D) Number of unpaired electrons in
configurations represents a noble gas element - 3
(A) 1s 2 , 2s 2 2p6 , 3s 2 31. The correct set of n, l, m for the
(B) 1s 2 , 2s 2 2p6 , 3s1 unpaired electron of chlorine atom is
(C) 1s 2 , 2s 2 2p6 respectively
(D) 1s 2 , 2s 2 sp6 , 3s 2 3p6 , 4s 2 (A)2,1,0 (B) 2,1,1 (C) 3,1,1 (D) 3,0,0
25. The two electrons in K sub-shell will 32.The electronic configuration of an
differ in element with atomic number 7 is
(A) Principal quantum number (A) 1s 2 , 2s1 , 2p3x (B) 1s 2 , 2s 2 2p1x 2p1y 2p1z
(B) Azimuthal quantum number (C) 1s 2 , 2s 2 2p2x 2p1y (D) 1s 2 , 2s 2 2p1x 2p2y
(C) Magnetic quantum number 33. Pauli's exclusion principle states that
(D) Spin quantum number (A) Nucleus of an atom contains no
26. The explanation for the presence of negative charge
three unpaired electrons in the nitrogen (B) Electrons move in circular orbits
atom can be given by around the nucleus
(A) Pauli's exclusion principle (C) Electrons occupy orbitals of lowest
(B) Hund's rule energy
(C) Aufbau's principle (D) All the four quantum numbers of two
(D) Uncertainty principle electrons in an atom cannot be equal
27. Which of the following electronic 34. Which electronic configuration for
configuration is not possible according to oxygen is correct according to Hund's rule
Hund’s rule of multiplicity
(A) 1s 2 2s 2(B) 1s 2 2s1 (A) 1s 2 , 2s 2 2p2x 2p1y 2p1z
(C)1s 2 2s 2 2p1x 2p1y 2p1x (D) 1s 2 2s 2 2p2x (B) 1s 2 , 2s 2 2p2x 2p2y 2p0z
28. The atom having atomic number 14 (C) 1s 2 , 2s 2 2p3x 2p1y 2p0z
should have --------- unpaired electrons (D) None of these
(A) 1 (B) 2 (C) 3 (D) 4 35. The electrons would go to lower
29. Electron enters the sub-shell for which energy levels first and then to higher
(n + l) value is minimum. This is energy levels according to which of the
enunciated as following
(A) Hund’s rule (A) Aufbau principle
(B) Aufbau principle (B) Pauli's exclusion principle
(C) Heisenberg uncertainty principle (C) Hund's rule of maximum multiplicity
(D) Pauli’s exclusion principle (D) Heisenberg's uncertainty principle
30. A neutral atom of an element has 2K,
8L, 9M and 2N electrons. Which of the
following is/are incorrectly matched :
 Daily Practice Paper-17 (exceptions of electronic configuration)
1. The electronic configuration of silver atom in ground state is
(A) [Kr]3d10 4s1 (B) [Xe]4f 14 5d10 6s1
(C) [Kr]4d10 5s1 (D) [Kr]4d9 5s 2
2. The correct ground state electronic configuration of chromium atom is
(A) [Ar]3d5 4s1 (B) [Ar]3d4 4s 2 (C) [Ar]3d6 4s 0 (D) [Ar]4d5 4s1
3. Chromium has the electronic configuration 4s1 3d5 rather than 4s 2 3d4 because
(A) 4s and 3d have the same energy (B) 4s has a higher energy than 3d
1
(C) 4s is more stable than 4s 2
(D) 4s1 3d5 half-filled is more stable than
4s 2 3d4
4. The electronic configuration of copper (29 Cu) is
(A) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d9 , 4s 2 (B) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d10 , 4s1
(C) 1s 2 . 2s 2 2p6 , 3s 2 3p6 , 4s 2 4p6 (D) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d10
5. The electronic configuration of chromium is
(A) [Ne]3s 2 3p6 3d4 , 4s 2 (B) [Ne]3s 2 3p6 3d5 , 4s1
(C) [Ne]3s 2 3p6 , 4s 2 4p4 (D) [Ne]3s 2 3p6 3d1 , 4s 2 4p3
6. The electronic configuration of gadolinium (atomic no. 64) is
(A) [Xe]4s 8 5d9 6s 2 (B) [Xe]4f 7 5d1 6s 2
(C) [Xe]4s 3 5d5 6s 2 (D) [Xe]4f 6 5d2 6s 2
7. The electronic configuration of element with atomic number 24 is
(A) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d4 , 4s 2 (B) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d10
(C) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d6 (D) 1s 2 , 2s 2 2p6 , 3s 2 3p6 3d5 4s1
8. Total number of unpaired electrons in an atom of atomic number 29 is
(A) 1 (B) 3 (C) 4 (D) 2
9. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the
azimuthal quantum numbers l = 1 and 2 are, respectively :
(A) 16 and 5 (B) 12 and 5 (C) 16 and 4 (D) 12 and 4
10. Aufbau principle is not satisfied by
(A) Cr and Cl (B) Cu and Ag (C) Cr and Mg (D) Cu and Na
11. Correct statement is
(A) K = 4s1 , Cr = 3d4 4s 2 , Cu = 3d10 4s 2 (B) K = 4s 2 , Cr = 3d4 4s 2 , Cu = 3d10 4s 2
(C) K = 4s 2 , Cr = 3d5 4s1 , Cu = 3d10 4s 2 (D) K = 4s1 , Cr = 3d5 4s1 , Cu = 3d10 4s1
 Daily Practice Paper-18 (effective nuclear charge)
01. Effective nuclear charge of an atom depends on:
(A) The atomic number of the atom (B) The charge on the ion
(C) The shielding effect (D) Both the actual nuclear charge and the shielding effect
02.The screening effect of d-electrons is
(A) equal to the p-electrons (B) more than p-electrons
(C) same as f-electrons (D) less than p-electrons
03.In a given energy level, the order penetration effect of different orbitals is
(A) f < d < p < s (B) s = p = d = f (C) s < p < d < f (D) p > s > d > f
04. Which statement is false:-
(A) screening constant increases in a period (B) Zeff decreases in a period
(C) Zeff. increases in a period (D) None
05. The formula for effective nuclear charge is (if  is screening constant)
(A) Z -  (B) Z +  (C) Z  − (D) Z 
06. Effective nuclear charge in group generally
(A) Increases down the group (B) Decreases down the group
(C) Remains constant (D) First increases than decreases
07. In sodium atom the screening is due to :-
(A) 3s2, 3p6 (B) 2s1 (C) 1s2, 2s2, 2p6 (D) 1s2, 2s2
08.The screening effect of d- electrons is :-
(A) Equal to the p - electrons (B) Much more than p - electrons
(C) Same as f - electrons (D) Less than p – electrons
09.Which of the following is not different for an atom and its corresponding ion:-
(A) Number of electrons (B) Nuclear charge
(C) Ionization energy (D) Size
10.The screening effect of s orbital electron is :-
(A) Greater than p but lesser than d and f electrons (B) Less than p, d and f electrons
(C) Greater than p, d and f electrons (D) Is equal to p , d and f electrons
11.Which statement is false :
(A) Screening effect increases down the group (B) Zeff increases down the group
(C) Zeff. increases in a period (D) none
12. Which of the following is generally true regarding effective nuclear charge (Z eff) :
(A) It increases on moving left to right in a period.
(B) It remains almost constant on moving top to bottom in a group.
(C) For isoelectronic species, as Z increases, Z eff decreases.
(D) Both (A) and (B).
13. Among following species which of them have maximum Z eff.
(A) Sn (B) Sn4+ (C) In (D) In+
 Daily Practice Paper-19 (configuration of ions)
01.Electronic configuration of H– is 10.Correct configuration of Fe+3 [26] is
(A) 1s0 (B)1s1 (C) 1s2 (D) 1s12s1 (A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 5
02.The electronic configuration of calcium (B) 1𝑠 2 , 2𝑠 2 𝑠𝑝6 , 3𝑠 2 3𝑝6 3𝑑 3 , 4𝑠 2
ion (𝐶𝑎2+ ) is (C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 6 , 4𝑠 2
(A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 2 (D) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 5 , 4𝑠 1
(B) 1𝑠 2 , 2𝑠 2 𝑠𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 1 11.Which one pair of atoms or ions will
(C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 2 have same configuration
(D) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 , 4𝑠 0 (A) F+ and Ne (B) Li+ and He–
03.Which of the following ions is not (C) Cl– and Ar (D) Na and K
having the configuration of neon 12.The number of d electrons in Fe+2
(A) F– (B)Mg+2 (C) Na+ (D) Cl– (atomic number of Fe = 26) is not equal to
04.Ions which have the same electronic that of the
configuration are those of (A) p-electrons in Ne
(A) Li and Na (B) Na and K (B) s-electrons in Mg
(C) K and Ca (D) O and Cl (C) d-electrons in Fe
05.Cu2+ will have the following electronic (D) p-electrons in Cl–
configuration 13.The atomic number of metal X has a
(A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑10 configuration [Ar]3d4 in its +3 oxidation
(B) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 9 , 4𝑠 1 state.
(C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 9 (A) 25 (B) 26. (C) 22 (D) 19
(D) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑10, 4𝑠 1 14.Which set has the same number of s-
electrons
06.Which one is the electronic
(A) C, Cu2+ , Zn (B) Cu2+ , Fe2+, Ni2+
configuration of Fe+2
(C) S2-, Ni2+ ,Zn (D) None of these
(A) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 6
15. Which of the following ion has inert
(B) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 4 , 4𝑠 2
gas configuration and having complete
(C) 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝6 3𝑑 5 , 4𝑠 1 octet.
(D) None of these (A) B+3 (B) Al+3
07.The electronic configuration (C) Ga+3 (D) All of these
(outermost) of Mn+2 ion (atomic number of 16. Which one of the following ion have 2
Mn = 25) in its ground state is electrons in outermost shell and 18
(A) 3d5, 4s0 (B) 3𝑑 4 , 4𝑠 1 electron in penultimate shell ?
(C) 3𝑑 3 , 4𝑠 2 (D) 3𝑑 2 , 4𝑠 2 4𝑝2 (A) Fe2+ (B) Sn2+ (C) Zn2+. (D) Mg2+
08.An ion has 18 electrons in the 17. Which of the following is electronic
outermost shell, it is configuration of Cu2+ (Z = 29) ?
(A) Cu+ (B) Th4+ (C) Cs+ (D) K+ (A) [Ar]4s1 3d8 (B) [Ar]4s2 3d10 4p1
09. 3𝑑10 4𝑠 0 exhibits by (C) [Ar]4s1 3d10 (D) [Ar] 3d9
(A) Zn++ (B) Cu++ (C) Cd++ (D) Hg++
 Daily Practice Paper-20 (isoelectronic species)
01. Z/e ratio for N3–, O2– and F– respectively will be -
(A) 0.7, 0.8 and 0.9 (B) 0.9, 0.8 and 0.7 (C) 7, 8 and 9 (D) 9, 8 and 7
02.Among the following transition metal ions, the one set where all the metal ions have 3d 2
electronic configuration is
(A) Ti3+, V2+, Cr3+, Mn4+ (B) Ti4+, V4+, Cr6+ Mn7+
(C) Ti4+, V3+, Cr2+, Mn3+ (D) Ti2+, V3+, Cr4+, Mn5+
03. Which of the following set of species is not isoelectronic?
(A) Cu+, Zn2+, Ga3+ (B) N3–, Ne, Mg2+ (C) N3–, S2–, Cl– (D) He, Li+, H–
04.Which one of the following group of atoms or ions is not isoelectronic?
(A) He, H–, Li+ (B) Na+, Mg2+, Al3+. (C) F–, O2–, N3– (D) K+, Ca2+,Ne
05. The size of isoelectronic species F–, Ne and Na+ is affected by :
(A) nuclear charge (Z)
(B) valence principal quantum number (n)
(C) electron-electron interaction in the outer orbitals
(D) none of the factors because their size is the same.
06. Screening effect is not observed in :
(A) He+ (B) Li+2 (C) Be+3 (D) In all cases
07. Which one of the following sets of ions are isoelectronic species?
(A) N-3 , O-2 , F- , S-2 (B) Li+ , Na+ , Mg+2, Ca+2
(C) K+, Cl-, Ca2+, Sc3+ (D) Ba+2 , Sr+2 , K+2 , Ca+2
08. K+, Ar, Ca+2 and S-2 contains _
(A) Same electronic configuration and atomic volume
(B) Different electronic configuration but same IP.
(C) Same electronic configuration but different atomic volume
(D) None
09.Which of the following is not isoelectronic series: -
(A) Cl- , P-3, Ar (B) N-3, Ne, Mg+2 (C) B+3, He, Li+ (D) N-3, S-2, Cl-
10. Which one of the following groups represent a collection of isoelectronic species?
(A) N-3, F-, Na+ (B) Be, Al+3, Cl- (C) Ca+2, Cs+, Br (D) Na+, Ca+2, Mg+2
11. The group having isoelectronic species is:
(A) O2–, F– , Na+ Mg2+ (B) O–, F–, Na+, Mg2+
(C) O2–, F , Na+, Mg2+ (D) O–, F–, Na+ Mg+2
 Daily Practice Paper-21 (unpaired electrons)
01. How many unpaired electrons are 13. Magnetic moment 2.84 B.M. is given
present in Ni2+ cation by
(A) 0 (B) 2 (C) 4 (D) 6 (A) Ti3+ (B) Cr2+ (C) Co2+ (D) Ni2+
02. The no. of unpaired electrons in a Cr3+ 14. A compound of metal ion MX+ ( Z=
(A) 6 (B) 4 (C) 3 (D) 1 24) has a spin only magnetic moment of
03. Which of the following metal ions will √15 Bohr Magnetons. The number of
have maximum no. of unpaired electrons unpaired electrons in the compound are
(A) Fe+2 (B) Co+2 (C) Ni+2 (D) Mn+2 (A) 2 (B) 4 (C) 5 (D) 3
04. Which of the metal ion will have 15. A gas metal in bivalent state have
highest number of unpaired electrons approximately 23e– what is spin magnetic
(A) Cu+ (B) Fe2+ (C) Fe3+ (D) Co2+ moment in elemental state
(A) 2.87 (B) 5.5 (C) 5.9. (D) 4.9
05. Which of the following has the
16. What is the total spin value in case of
maximum number of unpaired electrons 3+
26Fe ion.
(A) Mg2+ (B) Ti3+ (C) V3+ (D) Fe2+
(A) +1 or –1 (B) +2 or –2
06. Which of the following has more
(C) + 2.5 or – 2.5 (D) +3 or –3
unpaired d-electrons
17. A compound of vanadium has a
(A) Zn+ (B) Fe2+ (C) N3+ (D) Cu+ magnetic moment of 1.73 BM. What will
07. The no. of unpaired electrons in Fe3+ be the electronic configurations:
(A) 5 (B) 6 (C) 3 (D) 4 (A) 1s2 2s2 2p6 3s2 3p6 3d1
08. No. of unpaired electrons in Mn4+ is (B) 1s2 2s2 2p6 3s2 3p6 3d2
(A) 3 (B) 5 (C) 6 (D) 4 (C) 1s2 2s2 2p6 3s2 3p6 3d3
09. Which of the following ions has the (D) 1s2 2s2 2p6 3s2 3p6 3d4
maximum number of unpaired d-electrons? 18. Which of the following ions has the
2+ 2+ 3+ +
(A) Zn (B) Fe (C) Ni (D) Cu maximum number of unpaired d-electrons?
10. Ratio of number of unpaired electrons (A) Zn2+ (B) Fe2+ (C) Ni3+ (D) Cu+
in Fe2+ to that of Ti is 19. The possible value of l and m for the
(A) 1.2 (B) 3 (C) 2 (D) 4 last electron in the Cl– ion are :
11. Magnetic moment of Xn+ (Z = 26) is (A) 1 and 2 (B) 2 and +1
(C) 3 and –1 (D) 1 and –1
√24 B.M. Hence number of unpaired
20. Which of the following has maximum
electrons and value of n respectively are :
number of paired electrons.
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2
(A) Cu+. (B) Fe2+ (C) Zn+2 (D) Sc+
12. A compound of Vanadium has a spin
21. A correct set of four quantum numbers
magnetic moment 1.73 BM. Work out the
for unpaired electron in Cl-atom :
electronic configuration of the Vanadium
n l m s
ion in the compound :
(A) 3 2 0 +½
(A)1s22s22p63s23p64s1 (B) 3 1 0 +½
(B) 1s22s22p63s23p63d2 (C) 3 1 +1 0
(C) 1s22s22p63s23p63d1 (D) 3 0 –1 +½
(D) nothing can be said with certainty
22. The value of the spin magnetic moment of a particular ion is 2.83 Bohr magneton. The
ion is :
(A) Fe2+ (B) Ni2+ (C) Mn2+ (D) Co3+
23. If element 25X+Y has spin magnetic moment 1.732 B.M then
(A) number of unpaired electron = 1
(B) number of unpaired electron = 2
(C) Y = 4
(D) Y = 6
24. Which of the following statement(s) is incorrect?
(A) The electronic configuration of Cr is [Ar] (3d)5(4s)1. (Atomic number of Cr = 24)
(B) The magnetic quantum number may have negative values.
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type
(D) None of these
25. Number of unpaired electrons in Mn4+ is
(A) 3 (B)5 (C) 6 (D) 4
26. No. of unpaired electron in 1s2,2s2,2p4
(A) 4 (B) 2 (C) 0 (D) 1
27. Which of the following has maximum number of unpaired electrons :
(A) Fe2+ (B) Fe3+. (C) Sc3+ (D) Cu2+
 Daily Practice Paper-22 (valence electron)
01. An element has the electronic configuration 1𝑠 2 , 2𝑠 2 2𝑝6 , 3𝑠 2 3𝑝2. Its valency electrons
are
(A) 6 (B) 2 (C) 3 (D) 4
02. The following has zero valency
(A) Sodium (B) Beryllium (C) Aluminum (D)
Krypton
03. The number of electrons in the valence shell of calcium is
(A) 6 (B) 8 (C) 2 (D) 4
04. The valence electron in the carbon atom are
(A) 0 (B) 2 (C) 4 (D) 6
05. The structure of external most shell of inert gases is
(A) 𝑠 2 𝑝3 (B)𝑠 2 𝑝6 (C) 𝑠 1 𝑝2 (D) 𝑑10 𝑠 2
06. The four-quantum number for the valence shell electron or last electron of sodium (Z =
11) is
1 1
(A) 𝑛 = 2, 𝑙 = 1, 𝑚 = −1, 𝑠 = − 2 (B) 𝑛 = 3, 𝑙 = 0, 𝑚 = 0, 𝑠 = + 2
1 1
(C) 𝑛 = 3, 𝑙 = 2, 𝑚 = −2, 𝑠 = − 2 (D) 𝑛 = 3, 𝑙 = 2, 𝑚 = 2, 𝑠 = + 2
07. The magnetic quantum number for valency electrons of sodium is
(A) 3 (B) 2 (C) 1 (D) 0
08. The four quantum numbers of the valence electron of potassium are
1 1 1 1
(A) 4, 1, 0 and 2 (B) 4, 0, 1 and 2 (C) 4, 0, 0 and +2 (D) 4, 1, 1 and 2
 Answer Key (DPP - 1)

1 2 3 4 5 6 7 8 9 10
B A B C B D B C A B
11 12 13 14 15 16
D B B,D B A A

Answer Key (DPP - 2)

1 2 3 4 5 6 7 8 9 10
B C A B C C D D C B
11 12 13 14 15 16
B C A A D D

Answer Key (DPP - 3)

1 2 3 4 5 6 7 8 9 10
A A C A B A D D A B
11
C
Answer Key (DPP - 4)

1 2 3 4 5 6 7 8 9 10
D B A C A A A B C C
11
A
Answer Key (DPP - 5)

1 2 3 4 5 6 7 8 9 10
B C B C C D C C A B
11 12 13 14 15
C C D B,C,D B

Answer Key (DPP - 6)

1 2 3 4 5 6 7 8 9 10
C D C B D A D C C B
11 12 13 14 15 16 17
B D A C A B D

Answer Key (DPP - 7)

1 2 3 4 5 6 7 8 9 10
B B B C A A B D A C
11 12 13 14 15 16 17 18 19 20
A C B B C D B C B C
21 22 23
C D A
 Answer Key (DPP - 8)

1 2 3 4 5 6 7 8 9 10
C C A B D A A A B A
11 12 13 14
B A A A,C

Answer Key (DPP - 9)

1 2 3 4 5 6 7 8 9 10
C B D C B C B D A D
11 12 13 14 15 16 17 18 19 20
A B D B B A A A B B,D
21 22 23 24 25 26 27 28
C B C C D A B D
Answer Key (DPP - 10)

1 2 3 4 5 6 7 8 9 10
C A C C C D C D A A
11 12 13
C B C
Answer Key (DPP - 11)

1 2 3 4 5 6 7 8 9 10
C A A A B A C B A C
11
C
Answer Key (DPP - 12)

1 2 3 4 5 6 7 8 9 10
A B A C A B C B B D
11
D

Answer Key (DPP - 13)

1 2 3 4 5 6 7 8 9 10
B D D C D D D C D C
11 12 13 14 15 16 17 18 19 20
B D C A A B C C D B
21 22 24 25 26 27 28 29 30 31
B D D A A D C B A B

Answer Key (DPP - 14)

1 2 3 4 5 6 7 8 9 10
C D A B C B D B C B
11 12 13 14 15 16 17 18 19 20
B D C A B A C B D A
21 22 23
C A D
 Answer Key (DPP - 15)

1 2 3 4 5 6 7 8 9 10
A B C C A C C D C C
11 12 13 14 15 16 17 18 19 20
B C A B D D D A A D
21 22 23 24 25 26 27 28 29
A C D C A A C D B

Answer Key (DPP - 16)

1 2 3 4 5 6 7 8 9 10
B C B C C C A B B B
11 12 13 14 15 16 17 18 19 20
D A D D A D B D B
21 22 23 24 25 26 27 28 29 30
B C C C D B D B B D
31 32 33 34 35
C B D A A
Answer Key (DPP - 17)

1 2 3 4 5 6 7 8 9 10
C A D B B B D A B B
11
D
Answer Key (DPP - 18)

1 2 3 4 5 6 7 8 9 10
D D A B A A C D B C
11 12 13
B D B

Answer Key (DPP - 19)

1 2 3 4 5 6 7 8 9 10
C D D C C A A A A A
11 12 13 14 15 16 17
C D A B B B D

Answer Key (DPP - 20)

1 2 3 4 5 6 7 8 9 10
A D C D A D C C D A
11
A
 Answer Key (DPP - 21)

1 2 3 4 5 6 7 8 9 10
B C D C D B A A B C
11 12 13 14 15 16 17 18 19 20
A C D D C C A B D C
21 22 23 24 25 26 27
B B A D A B B

Answer Key (DPP - 22)

1 2 3 4 5 6 7 8
D D C C B B D C