BALAJI AMINES LIMITED (UNIT-III)

STANDARD SOP No. :MSD/MOR/001-03 Effective Date: 01/07/2021

OPERATING Supersedes :MSD/MOR/001-02 Issue Date : 25/06/2021
PROCEDURE Department : Production Next Review: June-2023 Page: 1 of 5

TITLE: MATERIEL SAFETY DATA SHEET OF DI ETHYLENE GLYCOL

1. Product Identification
Synonyms: 2,2'-Oxydiethanol; 2,2'-Oxybisethanol; 2,2' Dihydroxydiethyl ether; CELLOSOLVE
CAS No.: 111-46-6
Molecular Weight: 106.14
Chemical Formula: C4H10O3
2. Composition/Information on Ingredients

Ingredient CAS No Percent Hazardous

--------------------------------------- ------------ ------------ --------

Diethylene Glycol 111-46-6 99 - 100% Yes

3. Hazards Identification
Emergency Overview
--------------------------
WARNING! HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION TO SKIN AND EYES.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)

-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate (Life)
Flammability Rating: 1 - Slight
Reactivity Rating: 1 - Slight
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)
-----------------------------------------------------------------------------------------------------------
Potential Health Effects
------------------------
Inhalation:
Low inhalation hazard unless heated because of low vapor pressure.

Ingestion:
Low acute toxicity. Probable lethal dose to humans is 0.5-5 g/kg. Causes nerve depression, liver and kidney lesions
and anuria (urination retardation). Causes irritation to the gastrointestinal tract. Symptoms may include nausea,
vomiting and diarrhea.
Skin Contact:
May be an irritant to skin on prolonged exposure.
Eye Contact:
May be an irritant to eyes and surrounding tissue.
Chronic Exposure:
Liver and kidney lesions and damage.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible
to the effects of the substance.
Prepared by Checked by Approved by
___________________ __________________ __________________ ________________
K.S. Kedar N.A. Mane L.V. Limkar B.R. Reddy
Safety Officer Assistant Manager-EHS AGM-Production DGM- QA & QC.
Date: __________ Date: __________ Date: __________ Date: __________
 BALAJI AMINES LIMITED (UNIT-III)
STANDARD SOP No. : MSD/MOR/001-03 Effective Date: 01/072021
OPERATING Supersedes: MSD/MOR/001-02 Issue Date : 25/06/2021
PROCEDURE Department: Production Next Review : June -2023 Page 2 of 5

TITLE: MATERIEL SAFETY DATA SHEET OF DI ETHYLENE GLYCOL

4. First Aid Measures

Inhalation:
Remove to fresh air. Not expected to require first aid measures.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious
person. Call a physician.
Skin Contact:
Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if
irritation develops or persists.
Eye Contact:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids
occasionally. Call a physician if irritation persists.
5. Fire Fighting Measures
Fire:
Flash point: 124C (255F) CC
Autoignition temperature: 229C (444F)
Flammable limits in air % by volume:
lel: 1.6; uel: 10.8
Fire is possible at elevated temperatures or by contact with an ignition source.
Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above.
Fire Extinguishing Media:
Powder, alcohol foam, water spray or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard
area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Collect
liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a
chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer!

7. Handling and Storage

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from
sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since they
retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
AIHA Workplace Environmental Exposure Level (WEEL): TWA = 10mg/m3.

Prepared by Checked by Approved by

___________________ __________________ __________________ _______________

Date:_________ Date:_________ Date:_________ Date:_________
 BALAJI AMINES LIMITED (UNIT-III)
STANDARD SOP No. : MSD/MOR/001-03 Effective Date: 01/072021
OPERATING Supersedes: MSD/MOR/001-02 Issue Date : 25/06/2021
PROCEDURE Department: Production Next Review : June -2023 Page 3 of 5

TITLE: MATERIEL SAFETY DATA SHEET OF DI ETHYLENE GLYCOL

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure
Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial
Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face respirator with an organic vapor cartridge and particulate filter (NIOSH
type P95 or R95 filter) may be worn for up to ten times the exposure limit or the maximum use concentration specified
by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an
organic vapor cartridge and particulate filter (NIOSH P100 or R100 filter) may be worn up to 50 times the exposure
limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. Please note that N series filters are not recommended for this material. For emergencies or
instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Clear, colorless liquid.
Odor: Odorless.
Solubility: Infinitely soluble.
Specific Gravity: 1.118 @ 20C/20C
pH:No information found.
% Volatiles by volume @ 21C (70F): 100
Boiling Point: 244 - 245C (471 - 473F)
Melting Point: -6.5C (21F)
Vapor Density (Air=1): 3.66
Vapor Pressure (mm Hg): 1 @ 91.8C (198F)
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Toxic gases and vapors may be released if involved in a fire. Carbon dioxide and carbon monoxide may form when
heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers, strong acids and strong bases.

Prepared by Checked by Approved by

___________________ __________________ __________________ _______________

Date:_________ Date:_________ Date:_________ Date:_________
 BALAJI AMINES LIMITED (UNIT-III)
STANDARD SOP No. : MSD/MOR/001-03 Effective Date: 01/072021
OPERATING Supersedes: MSD/MOR/001-02 Issue Date : 25/06/2021
PROCEDURE Department: Production Next Review : June -2023 Page 4 of 5

TITLE: MATERIEL SAFETY DATA SHEET OF DI ETHYLENE GLYCOL

Conditions to Avoid:
Incompatibles.

11. Toxicological Information

Oral rat LD50: 12565 mg/kg. Skin rabbit LD50: 11.89 g/kg Irritation: eye rabbit, standard Draize: 50 mg mild.
Investigated as a tumorigen and reproductive effector.
--------\Cancer Lists\---------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Diethylene Glycol (111-46-6) No No None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal
facility. Processing, use or contamination of this product may change the waste management options. State and local
disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

--------\Chemical Inventory Status - Part 1\-----------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ----------
Diethylene Glycol (111-46-6) Yes Yes Yes Yes

--------\Chemical Inventory Status - Part 2\-----------------------------Canada--

Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ------- -----
Diethylene Glycol (111-46-6) Yes Yes No Yes

Prepared by Checked by Approved by

___________________ __________________ __________________ _______________

Date:_________ Date:_________ Date:_________ Date:_________
 BALAJI AMINES LIMITED (UNIT-III)
STANDARD SOP No. : MSD/MOR/001-03 Effective Date: 01/072021
OPERATING Supersedes: MSD/MOR/001-02 Issue Date : 25/06/2021
PROCEDURE Department: Production Next Review : June -2023 Page 5 of 5

TITLE: MATERIEL SAFETY DATA SHEET OF DI ETHYLENE GLYCOL

--------\Federal, State & International Regulations - Part 1 -SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
Diethylene Glycol (111-46-6) No No No No
--------\Federal, State & International Regulations - Part 2 -RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
---------------------------------------- ------ ------ ------
Diethylene Glycol (111-46-6) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Pure / Liquid)

Australian Hazchem Code: None allocated.

Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 1 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION TO SKIN AND EYES.
Label Precautions:
Wash thoroughly after handling.
Avoid contact with eyes, skin and clothing.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
unconscious person. Call a physician. In case of contact, immediately flush skin or eyes with plenty of water for at
least 15 minutes. Call a physician if irritation develops or persists.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 1, 2, 15.
.
END OF THE DOCUMENT

Prepared by Checked by Approved by

___________________ __________________ __________________ _______________

Date:_________ Date:_________ Date:_________ Date:_________