Tipa 85 MSDS

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FECT

FAR-EAST CHEMICAL TRADING CO., LTD.


PROPALACE-AZUCHIMACHI-BUILDING, TEL : ++81-6-6262-2764
4TH FL.-C,1-6-19,AZUCHIMACHI, CHUO-KU, FAX : ++81-6-6262-2765
OSAKA, 541-0052, JAPAN E-MAIL : [email protected]

Product Name: Triisopropanolamine 85%


Date of revision: 2018/2/1
Version: 4.0

SAFETY DATA SHEET


SECTION 1 IDENTIFICATION

1.1 Product identifier


Trade name: Triisopropanolamine / TIPA
Chemical name: 1, 1’, 1’’-Nitrilotri-2-PROPANOL

1.2 Recommended used of the chemical and restrictions on use


Identified uses: Chemical additive. Chemical intermediate.
Restrictions on use: No data available.

1.3 Supplier
Name :Far-East Chemical Trading Co., Ltd.
Address: Azuchimachi, Chuo-ku, Osaka, 541-0052,JAPAN
Telephone: 0081-6-6262-2764
E-mail: [email protected]

SECTION 2 HAZARDS IDENTIFICATION


2.1 Hazard classification
Serious eye damage/eye Irritation- Category 2
2.2 Label elements

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Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

Hazard pictograms

Signal word: Warning!

Hazards
Causes eye irritation.

Precautionary statements
Prevention:
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.

2.3 Other hazards


No information available

SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS


This product is a mixture.

Chemical Entity CAS No. Proportions (%)


Triisopropanolamine [122-20-3] 85.0 min.

Water [7732-18-5] 10.0-15.0

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Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

SECTION 4 FIRST-AID MEASURES

4.1 Description of first aid measures


General advice:
In all cases of doubt, or when symptoms persist, seek medical attention.

Eye contact:
Immediately flush eyes in clear running water for at least 15 minutes,
lifting upper and lower lids periodically. Get medical consultant
immediately and preferable an eye specialist.

Skin contact:
Wash off in flowing water.

Ingestion:
Seek medical consultant. Do not vomit unless directed to do so by a
medical personnel.

Inhalation:
Remove the patient to fresh air.

4.2 Most important symptoms and effects, both acute and delayed
Causes serious eye irritation.
4.3 Indication of the immediate medical attention and special treatment
needed
No information available.
SECTION 5 FIRE-FIGHTING MEASURES
5.1 Extinguishing Media:
Suitable extinguishing media: Water fog or fine spray, carbon dioxide, dry
chemical, foam. Alcohol resistant foams are preferred if available. Page 3 of 9
Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0
Unsuitable extinguishing media: Do not use direct water stream. Will spread fire.

5.2 Special hazards arising from the substance or mixture


Thermal decomposition can lead to release of irritating or toxic gases/vapors.

5.3 Advice for fire-fighters


Fire-fighters should wear appropriate breathing apparatus and protective
equipment. Fire-fighting in the wind. Ensure adequate ventilation. Move
container from fire area if it can be done without risk. Cool containers with
water spray. Prevent fire-fighting water from entering surface water or groundwater.

SECTION 6 ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
Wear adequate protective equipment(Refer to Section 8). Ensure adequate
ventilation. Avoid contact with the skin, eyes and clothing.

6.2 Environmental precautions


Do not discharge into drains/surface waters/groundwater. Discharge into the
environment must be avoided.
6.3 Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.

SECTION 7 HANDLING AND STORAGE


7.1 Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. Use
this material with adequate ventilation. Do not get in eyes, on skin, or on
clothing. Use personal protective equipment as required. Keep away from heat,
sparks, open flame, and hot surfaces - No smoking. Do not eat, drink, or
smoke when using this product. Wash thoroughly after handling. Page 4 of 9
Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

7.2 Conditions for safe storage


Store sealed in a cool, dry, well ventilated area away from acids, alkali,
oxidizers, toxic or corrosive materials, combustible or explosive materials, long
exposure to the sunlight. Avoid contacting with copper or copper containing metals.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters


Not data available.

8.2 Exposure controls


Appropriate engineering controls
Provide local exhaust or process enclosure ventilation system. Prepare safety
shower and eye wash equipment.

Personal protective equipment:

Eye and protection: Wear appropriate protective eyeglasses or chemicalsafety goggles.


Hand protection: Wear appropriate protective gloves to prevent hand exposure.
Skin protection: Wear suitable protective clothing.
Respiratory protection: In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls:


Avoid entering into surface water or sanitary sewer system.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES


For TIPA 85%
Appearance: Colorless to light yellow liquid
Odor: Light ammonia odor
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Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

Odor threshold: N/A


PH: N/A
Melting Point/Freezing point: 3-8℃
Boiling point: 104-107℃
Flash Point: 154℃ on dry base
Evaporation rate: N/A
Flammability: Not applicable to liquid
Upper explosion limits: N/A
Lower explosion limits: N/A
Vapor Pressure: N/A
Vapor Density: N/A
Relative Density (25/4℃): 1.01
Solubility(ies): Soluble in water and any ethyl alcohol
Partition coefficient: n-octanol/water: N/A
Auto-ignition temperature: N/A
Decomposition temperature: N/A
Formula: C9H21NO3
Color: Colorless to light yellow

SECTION 10 STABILITY AND REACTIVITY


10.1 Reactivity No data available

10.2 Chemical stability Stable under recommended storage conditions in Section 7.

10.3 Possibility of hazardous reactions Hazardous polymerization: Will not occur.

10.4 Conditions to avoid Product can decompose at elevated temperature.

10.5 Incompatible materials Strong oxidizing materials, strong acid.

10.6 Hazardous decomposition products Hazardous decomposition


products depend on temperature, air and the presence of other materials. Hazardous
decomposition products may include and are not limited to Nitrogen oxide. Page 6 of 9
Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

SECTION 11 TOXICITY INFORMATION

11.1 Information on toxicological effects

Acute toxicity:
Oral: LD50= 4000 mg/kg (Rat)
Inhalation: Not available.
Dermal: LD50: > 5000 mg/kg (rabbit, female)

Skin corrosion/irritation: Rabbit test: slightly irritating.

Serious eye damage/irritation:Rabbit test: Irritating.

Respiratory or skin sensitization: Guinea pig: Not sensitizing.


Germ cell mutagenicity: Evaluation of results: negative.

Carcinogenicity: Not listed by the International Agency for Research on Cancer (IARC)

Reproductive toxicity: Insufficient data to classify.

STOT-single exposure: Insufficient data to classify.

STOT-repeated exposure: Insufficient data to classify.

Aspiration hazard: Insufficient data to classify.

SECTION 12 ECOLOGICAL INFORMATION


12.1 Toxicity
Acute fish toxicity: LC50= 3158.48 mg/L/96h (Leuciscus idus)
Acute daphnia toxicity: EC50> 500 mg/L/48h (Daphnia magna) Page 7 of 9
Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

Acute algae toxicity: EC50 = 50 mg/L/72h (Scenedesmus subspicatus)

12.2 Persistence and degradability


No information available.

12.3 Bioaccumulative potential


No information available.

12.4 Mobility in soil


No information available.

12.5 Results of PBT and vPvB assessment


Not a PBT and vPvB substance.

12.6 Other adverse effects


No information available.

SECTION 13 DISPOSAL CONSIDERATIONS


13.1 Disposal methods
Dispose in accordance with all applicable federal, state/regional and local laws
and regulations. Recommended wash container recycling.
This product when disposed of in its unused and uncontaminated state should
be treated as a hazardous waste.

SECTION 14 TRANSPORTATION INFORMATION


14.1 Classification for ROAD and Rail transport
Not regulated for transport
14.2 Classification for SEA transport (IMO-IMDG)
Not regulated for transport
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Product Name: Triisopropanolamine 85%
Date of revision: 2018/2/1
Version: 4.0

14.3 Classification for AIR transport (IATA-IACO)


Not regulated for transport

SECTION 15 REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for


the substance or mixture
EU regulation:
Authorisations: No information available.
Restrictions on use: No information available.
EINECS: listed in.
DSD (67/548/EEC): listed in.

15.2 Chemical Safety Assessment


Chemical Safety Assessment has not been carried out for this product.

SECTION16 OTHER INFORMATION


16.1 Revision
Date of the previous revision: 2015/11/16
Date of this revision: 2016/08/29
Version: 4.0

16.2 Information source and reference


The information for this SDS is provided by internal reference within our company.
The information contained herein is believed to be accurate. However, it is
provided solely for the customer’s consideration, investigation and verification.

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