MSDS Blatannex Gel (Imidakloprit)

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THE MINISTRY OF AGRICULTURE

OF
THE REPUBLIC OF INDONESIA

DIRECTORATE GENERAL
OF
AGRICULTURAL INFRASTRUCTURE AND FACILITIES
DIRECTORATE OF FERTILIZER AND PESTICIDE
Jl. Harsono RM No. 3, D Building 8-9th Floor, Ragunan Pasar Minggu - Jakarta Selatan
Phone (62.21) 7890043 - 7810044, Fax (62.21) 7890043

No. : 1142/Kompes/2016

In accordance with the Decree of the Minister of Agriculture number


693/Kpts/SR.330/10/2016

We hereby certify that :

Company name : PT. Bayer Indonesia


Company address : Jl. Jend. Sudirman Kav. 10/11 GD. MID PLAZA 1,
Lt. 11-15 KARET TENGSIN -TANAH ABANG
JAKARTA PUSAT

Is recognized as the registration holder of the following product :

Trade name : BLATTANEX 2.15 GEL


Common name and content of a.i. : imidacloprid:2.15%
Registration number : RI. 06090120072646

The product mentioned above is offically registered.

Expiry: 18 October 2021 Jakarta, 8 November 2016


Director,

Dr. Ir. Muhrizal Sarwani, MSc

This document is official document of Ministry of Agriculture which do not require signature
since being issued electronically from Sistem Informasi Manajemen Pelayanan Perizinan Pertanian (SIM-PPP).
Ministry of Agriculture is responsible for any information in this document.
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 1/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING

1.1 Product identifier


Trade name BLATTANEX 2.15 GEL
Product code (UVP) 05178819
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier PT. Bayer Indonesia
Jalan Rungkut Industri I no 12
Surabaya 60292
Indonesia
Telefax +62-31-8439541
Responsible Department Health and Safety Environmental (HSE Department)
+62-31-8438627 (During office hours only)
1.4 Emergency telephone no.
Indonesia Emergency 08071-801-801 (24 hours/day)
Number
Global Incident Response +1 (760) 476-3964 (Company 3E for Bayer CropScience)
Hotline (24h)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture


Classification in accordance with Regulation (ID) MPRI GHS of Classification & labels on
chemicals No. 23/M-ID/PER/4/2013 as amended.
Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling in accordance with Regulation (ID) MPRI GHS of Classification & labels on chemicals
No. 23/M-ID/PER/4/2013 as amended.
Hazard label for supply/use required.
Hazardous components which must be listed on the label:
 Imidacloprid
Signal word: Warning
Hazard statements
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P501 Dispose of contents/container in accordance with local regulation.
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 2/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

2.3 Other hazards


No other hazards known.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Bait (ready for use) (RB)
Imidacloprid 2,15 %
Hazardous components
Name CAS-No. / Conc. [%]
EC-No.
Imidacloprid 138261-41-3 2,15
1,2-Benzisothiazol-3(2H)-one 2634-33-5 > 0,005 – < 0,05
Glycerine 56-81-5 > 1,0
Further information
Imidacloprid 138261-41-3 M-Factor: 10 (acute), 100 (chronic)

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures


General advice Move out of dangerous area. Place and transport victim in stable
position (lying sideways). Remove contaminated clothing immediately
and dispose of safely.
Skin contact Wash off thoroughly with plenty of soap and water, if available with
polyethyleneglycol 400, subsequently rinse with water. If symptoms
persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Get medical attention if irritation
develops and persists.
Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison
control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms If large amounts are ingested, the following symptoms may occur:
Dizziness, Abdominal pain, Nausea
4.3 Indication of any immediate medical attention and special treatment needed
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 3/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

Treatment Treat symptomatically. Monitor: respiratory and cardiac functions. In


case of ingestion gastric lavage should be considered in cases of
significant ingestions only within the first 2 hours. However, the
application of activated charcoal and sodium sulphate is always
advisable. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media


Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.

5.2 Special hazards arising Dangerous gases are evolved in the event of a fire.
from the substance or
mixture
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. In the event
equipment for firefighters of fire, wear self-contained breathing apparatus.
Further information Contain the spread of the fire-fighting media. Do not allow run-off from
fire fighting to enter drains or water courses.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures


Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up The nature of this product, when contained in commercial packs,
makes spillage unlikely. However, if significant amounts are spilled
nevertheless, the following advice is applicable. Soak up with inert
absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Clean contaminated floors and objects thoroughly,
observing environmental regulations. Keep in suitable, closed
containers for disposal.

6.4 Reference to other Information regarding safe handling, see section 7.


sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling


SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 4/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

Advice on safe handling No specific precautions required when handling unopened


packs/containers; follow relevant manual handling advice.
Advice on protection No special precautions required.
against fire and explosion
Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Wash hands before breaks and immediately after handling
the product. Remove soiled clothing immediately and clean thoroughly
before using again. Garments that cannot be cleaned must be
destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in original container. Keep containers tightly closed in a dry, cool
areas and containers and well-ventilated place. Store in a place accessible by authorized
persons only. Keep away from direct sunlight.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
Suitable materials Sheet metal packages with LDPE (Low Density Polyethylene) interior
package.
7.3 Specific end use(s) Refer to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters


Components CAS-No. Control parameters Update Basis
Imidacloprid 138261-41-3 0,7 mg/m3 OES BCS*
(TWA)
Glycerine 56-81-5 10 mg/m3 11 2011 ID OEL
(Mist.) (NAB)
*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard"
8.2 Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection Respiratory protection is not required under anticipated
circumstances of exposure.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Please observe the instructions regarding permeability and


breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination on the outside cannot
be removed. Wash hands frequently and always before eating,
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 5/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

drinking, smoking or using the toilet.


Material Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0,4 mm
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 6 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


Form gel
Colour white to beige
Odour weak, characteristic
Flammability (solid, gas) The product is not highly flammable.
Auto-ignition temperature > 381 °C
Vapour pressure 21,3 hPa at 20 °C
25,2 hPa at 25 °C
53,6 hPa at 50 °C
Density ca. 1,21 g/cm³ at 20 °C
Water solubility miscible
Partition coefficient: n- Imidacloprid: log Pow: 0,57
octanol/water
Surface tension 60,1 mN/m at 20,2 °C
Impact sensitivity Not impact sensitive.
Oxidizing properties No oxidizing properties
Explosivity Not explosive
92/69/EEC, A.14 / OECD 113
9.2 Other information Further safety related physical-chemical data are not known.
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 6/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Thermal decomposition to 168 °C
Endothermic.
from 168 °C
Exothermic decomposition.
10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of No hazardous reactions when stored and handled according to


hazardous reactions prescribed instructions.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.


decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects


Acute oral toxicity LD50 (Rat) > 5.000 mg/kg
Acute inhalation toxicity
During intended and foreseen applications, no respirable aerosol is
formed.
Acute dermal toxicity LD50 (Rat) > 5.000 mg/kg
Skin irritation No skin irritation (Rabbit)
Eye irritation Slight irritant effect - does not require labelling. (Rabbit)
Sensitisation Non-sensitizing. (Guinea pig)
OECD Test Guideline 406, Buehler test
Non-sensitizing. (Guinea pig)
OECD Test Guideline 406, Magnusson & Kligman test
Assessment STOT Specific target organ toxicity – repeated exposure
Imidacloprid did not cause specific target organ toxicity in experimental animal studies.
Assessment mutagenicity
Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in
vitro and in vivo tests.
Assessment carcinogenicity
Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice.
Assessment toxicity to reproduction
Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic
to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity.
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 7/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

Assessment developmental toxicity


Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental
effects seen with Imidacloprid are related to maternal toxicity.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 211 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient imidacloprid.
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 85 mg/l
invertebrates Exposure time: 48 h
The value mentioned relates to the active ingredient imidacloprid.

EC50 (Chironomus riparius (non-biting midge)) 0,0552 mg/l

Exposure time: 24 h
The value mentioned relates to the active ingredient imidacloprid.

Chronic toxicity to aquatic EC10 (Chironomus riparius (non-biting midge)): 0.87 µg/l
invertebrates Exposure time: 28 d
The value mentioned relates to the active ingredient imidacloprid.

Toxicity to aquatic plants IC50 (Desmodesmus subspicatus (green algae)) > 10 mg/l
Growth rate; Exposure time: 72 h
The value mentioned relates to the active ingredient imidacloprid.
12.2 Persistence and degradability
Biodegradability Imidacloprid:
Not rapidly biodegradable
Koc Imidacloprid: Koc: 225
12.3 Bioaccumulative potential
Bioaccumulation Imidacloprid:
Does not bioaccumulate.
12.4 Mobility in soil
Mobility in soil Imidacloprid: Moderately mobile in soils
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Imidacloprid: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Additional ecological No other effects to be mentioned.
information
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 8/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods


Product In accordance with current regulations and, if necessary, after
consultation with the site operator and/or with the responsible authority,
the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging Not completely emptied packagings should be disposed of as
hazardous waste.

SECTION 14: TRANSPORT INFORMATION

ADR/RID/ADN
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(IMIDACLOPRID MIXTURE)
14.3 Transport hazard class(es) 9
14.4 Packing group III
14.5 Environm. Hazardous Mark YES
Hazard no. 90
Tunnel Code E

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.

IMDG
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(IMIDACLOPRID MIXTURE)
14.3 Transport hazard class(es) 9
14.4 Packing group III
14.5 Marine pollutant YES

IATA
14.1 UN number 3077
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S.
(IMIDACLOPRID MIXTURE )
14.3 Transport hazard class(es) 9
14.4 Packing group III
14.5 Environm. Hazardous Mark YES

14.6 Special precautions for user


See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
No transport in bulk according to the IBC Code.
SAFETY DATA SHEET according to Regulation (ID) MPRI GHS of
Classification & labels on chemicals No. 23/M-ID/PER/4/2013 as amended

BLATTANEX 2.15 GEL 9/9


Version 1 / ID Revision Date: 30.09.2016
102000007347 Print Date: 01.12.2016

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Further information
WHO-classification: U (Unlikely to present acute hazard in normal use)

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms


ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
TWA Time weighted average
UN United Nations
WHO World health organisation

The information given in the safety data sheet is correct as of the date made.
But along with the development of science and technology, the information may be wrong in the future.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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