Haloalkane and Haloarenes DPP 2

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1

GYANA VIKASH ACADEMY


Haloalkanes and Haloarenes DPP-02

1. 2-Methyl butane on reacting with bromine in the 5. Which of the following leads to the formation of an
presence of sunlight gives mainly alkyl halide -
2 Red P +Br
(1) 1-Bromo-3-methylbutane (1) C H OH 
(2) 2-Bromo-3-methylbutane 2
(2) C H OH 
SOCl
(3) 2-Bromo-2-methylbutane KBr + Conc. H SO
2 4
(3) C H OH  
(4) 1-Bromo-2-methylbutane
(4) All

2 Cl water 6. Which reagent cannot be used to prepare an alkyl


2. 

CH3  CH  CH  CH3 halide from an alcohol?
(1) | | (1) HCl  ZnCl2 (2) NaCl
Cl Cl
(3) PCl5 (4) SOCl 2
CH3  CH  CH  CH3
(2) | |
Cl OH
7. What is the major product of the following
(3) Both (1) & (2) Reaction?
(4) None of these CH3 HBr
   [P]
3. Give the product obtained from the Reaction?
NBS Br CH2Br

hv
P
(1) (2)
Br CH3 CH3
Br (3) (4) Br
(1) (2)
Br
Br

Br

(3) (4) All of these

4. Which reagent will you use for the following


reaction?
CH3CH2CH2CH3  CH3CH2CH2CH2Cl +
CH3CH2CHClCH3
(1) Cl /UV light
(2) NaCl + H SO
(3) Cl gas in dark
(4) Cl gas in the presence of iron in dark

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