Environmental Pollution Supplemental Notes
Environmental Pollution Supplemental Notes
Environmental Pollution Supplemental Notes
Environmental Science :
5 Pollution and its Factors
INTRODUCTION
Pollution may be defined as an undesirable change in the physical, chemical or biological
characteristics of air, water and land that may be harmful to human life and other animals,
living conditions, industrial processes and cultural assets. Pollution can be natural or man-
made. The agents that pollute are called pollutants.
Pollutants
Pollutants are by-products of man’s action. The important pollutants are summarised
below:
• Deposited matter—Soot, smoke, tar or dust and domestic wastes.
• Gases—CO, nitrogen oxides, sulphur oxides, halogens (chlorine, bromine and iodine).
• Metals—Lead, zinc, iron and chromium.
• Industrial pollutants—Benzene, ether, acetic acid etc., and cyanide compounds.
• Agriculture pollutants—Pesticides, herbicides, fungicides and fertilizers.
• Photochemical pollutants—Ozone, oxides of nitrogen, aldehydes, ethylene,
photochemical smog and proxy acetyl nitrate.
• Radiation pollutants—Radioactive substances and radioactive fall-outs of the
nuclear test.
Classification of Pollutants
On the basis of natural disposal, pollutants are of two types:
(i) Non-degradable pollutants
These are the pollutants, which degrade at a very slow pace by the natural biological
processes. These are inorganic compounds such as salts (chlorides), metallic oxides waste
producing materials and materials like, aluminium cans, mercuric salts and even DDT.
These continue to accumulate in the environment.
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162 ENVIRONMENTAL SCIENCE
AIR POLLUTION
The WHO defines air pollution as the presence of materials in the air in such
concentration which are harmful to man and his environment. A number of ingredients find
their way in the air and these are mostly gases, which rapidly spread over wide areas.
pollutants released from automobiles, locomotives, aircraft etc., include CO, unburnt
hydrocarbons and nitrogen oxide.
(iii) Industries
Paper and pulpfactories, petroleum refineries, fertilizer plants, and steel industries,
thermal power plants are the main sources of air pollution. They add various harmful gases
like CO, SO3, NO, Hydrocarbons etc., to the atmosphere. Textile factories release cotton dust
into the air. Cities experiencing this type of pollution are Kanpur, Surat and Ahmedabad.
The pesticide and insecticide industries are posing serious threat to the environment. Food
processing industries and tanneries emit offensive odors. Release of poisonous gases from
accidents also poses serious threats. e.g. Bhopal Gas Tragedy in which methyl isocynate
(MIC) gas leakage killed several people. In Tokyo, about 34 tones of carbon particles mixed
with other suspended particles settle per square kilometer every day.
(v) Wars
Various forms of explosives used in war pollute the air by releasing poisonous gases.
This greatly disturbs the ecology of the area. Nuclear explosions pollute air by radioactive
rays. The effects of nuclear explosions on Hiroshima and Nagasaki are well-known examples.
(vi) Natural Causes
Gas emissions from active volcanoes, marsh gas, spores of fungi and pollens are the
natural causes of air pollution.
(vi) Hydrocarbons
These are unburnt discharges from incomplete combustion of fuel in automobiles. These
form PAN with nitrogen oxides, which is highly toxic.
(viii) Aerosols
Aerosols are chemicals released in the air in vapour form. These include fluorocarbon
(carbon compound having fluorine) present in emissions from the Jet aeroplanes. Aerosols
deplete the ozone layer. Thinning of ozone layer results in more harmful ultraviolet rays
reaching the earth, which are harmful to skin, and can lead to skin cancer also.
(x) Fluorides
Rocks, soils and. minerals containing fluorides release an extremely toxic gas called
hydrogen fluoride on heating. This gas is highly injurious to livestock and cattle.
POLLUTION IN INDIA
India supports a large network of factories and industries. These factories are generally
localized in eight or ten large industrial centres. These are also a great source of air as well
ENVIRONMENTAL SCIENCE : POLLUTION AND ITS FACTORS 165
water pollution. To be on a safer side delocalisation of industries is the need of the time.
This would lead to an even distribution of pollutants and faster degeneration of pollutants.
The major pollutants coming out from these industries are -
(i) Industrial Pollutants. The common air pollutants from industries are SO2, CO,
CO2, H2S and hydrocarbons together with dust, smoke and grit. These are produced
by the burning of coal and petroleum and by the combustion of lignite at thermal
power stations. The chemical industries release HCl, chlorine, nitrogen oxide and
oxides of copper, zinc, lead and arsenic.
The fertilizer factories at Gorakhpur and Ahmedabad; the steel industries at Bhilai,
Rourkela, Jamshedpur and Durgapur pollute the air with above-said gases.
(ii) Automobile Exhausts. Automobiles run by petrol and diesel produce CO, nitrogen
oxides and hydrocarbons. Hundreds and thousands tons of hydrocarbons and CO
are emitted into air daily. Metropolitan cities harbour lakhs and crores of
automobiles. Every gallon of petrol consumed by automobiles produces 3 pounds of
carbon monoxide and 15 pounds. of nitrogen oxide.
(iii) Ionizing Radiations from Radioactive Substances. Ionizing radiations include alpha,
beta particles and the gamma rays etc. These are produced by atomic explosions
and testing of atomic weapons.
Change in Climate
CO2 content of air is increasing due to deforestation and combustion of fuel. This
increase is affecting the composition and balance of gases in the atmosphere. Increase in
CO2 concentration may increase the atmospheric temperature, producing green house effect
A rise of global temperature by more than 2-3 degrees may melt glaciers and polar ice. This
would lead to a rise in ocean level and consequent flooding and submergence of coastal
areas. Rainfall pattern may also change, affecting agricultural output in various regions of’
the world. Aerosols deplete the ozone layer in the stratosphere. Thinning of ozone layer
would permit more of the harmful ultraviolet rays to reach the earth. This may cause,
sunburn, blindness and inactivation of proteins, RNA, DNA and plant pigments.
Aesthetic Loss
Dust and smoke spoils the beauty of nature. Especially the mountain environments,
which serve as a great attraction for tourists. Foul odours emitted by industries, automobiles,
dirty drains and garbage heaps in cities are a great nuisance.
Water Pollution
Water is extremely essential for life, this common fact is known to all. It is required to
meet our basic needs in day to day life viz., cooking, drinking, bathing, disposal of sewage,
irrigation, generating electricity in power plants, cooling and manufacturing different products
in industries and the disposal of industrial wastes. During all these processes the undesirable
substances are added to the water resources to a great extent. This alters the basic chemistry
of water in rivers and streams.
2. Mercury when dissolved in water is absorbed by aquatic plants and enters the food
chain. Lead impairs metabolism and brings about congenital deformities, anaemia
etc.
3. Cadmium damages kidneys and liver.
4. Inorganic nitrates and phosphates promote growth of oxygen-consuming algae,
which result in the death of fishes and other aquatic animals.
5. Presence of dyes and compounds in the discharged water changes the colour of
water.
6. Soap, detergents and, alkalis result in foam formation.
7. Industrial effluents containing iron, free chlorine, phenol, manganese, oils,
hydrocarbons, ammonia, algae and microorganisms impair the taste and odours of
water.
8. The nitrates and phosphates dissolved in water accelerate the growth of
microorganisms, which consume much of the dissolved oxygen depriving fish and
other aquatic life (Eutrophication).
9. Biomagnifications is the increase of toxic materials at each tropic level of a food
chain.
For example, DDT after reaching a water system is absorbed by the microorganisms on
which smaller fishes feed. From them, DDT reaches the carnivorous animals. Since bigger
fishes consume more food, large amounts of DDT accumulates in their body.
Secondary treatment. Sewage obtained after primary treatment is sent to aeration tank
where it is mixed with air and sludge laden with bacteria and algae. The algae provide
oxygen to the bacteria and decompose organic matter into simple compounds. Chlorination
is finally done to remove bacteria.
Tertiary treatment. In the third and last step water is passed through ion exchangers
to remove dissolved salts.
(ii) Treatment of industrial effluents
Treatment of industrial effluents involves neutralization of acids and bases, removal of
toxic compounds, coagulation of colloidal impurities, precipitation of metallic compounds
and reducing the temperature of effluents to decrease thermal pollution.
SOIL POLLUTION
Soil Pollution
Like water and air, soil is also equally important for living organisms. It supports
plants on which. all other living organisms depend. The process of soil formation is so slow
that the soil may be regarded as a non-renewable source. Therefore, the study and control
of soil pollution is important. Any substance that reduces soil productivity is called soil
pollutant.
Sources of Soil Pollution
There are several materials, which adversely affect physical, chemical and biological
properties of the soil and thus reduce its productivity. These are
1. Chemicals present in industrial waste.
2. Pesticides and insecticides that are sprayed on crops. .
3. Fertilizers and manures that are added to the soil to increase the crop yield.
Salination of Soil
Increase in the concentration of soluble salts is called salination. This adversely affects
the quality and productivity of soil. It takes place in two ways: accumulation of salts dissolved
in irrigation water on the soil surface due to intensive farming and poor drainage, and
deposition of salts as white crust during summer months drawn by capillary action from the
lower surface to the top surface.
Land Degradation
Besides pollution, land and soil face several other problems. Removal of topsoil is called
soil erosion. Soil erosion factors are water, wind, ocean, waves and glaciers, felling of trees,
overgrazing by cattle, over-cropping etc. Erosion occurs both in wet and dry regions. It leads
to floods.
by wind and .over-grazing. That desert in India is spreading at the rate of 12,000 hectares
of land every year.
(iii) Shifting cultivation
Tribal communities follow the practice of cutting down trees and setting them on fire
and then raising the crops on the resulting ash. This is called Jhuming in northeastern
India. It is harmful if the Jhuming cycles are longer than ten years but short cycles destroy
forests and cause soil erosion. e.g. Asia and Africa. .
(iv) Developmental activities
Large areas of fertile and productive croplands, woodlands and grasslands are lost to
various developmental activities such as rapid urbanization, building of airports, industries,
railways, roads, mining and construction of dams.
Noise Pollution
Noise can be defined as unwanted/unpleasant sound. So noise pollution is unwanted
sound dumped into the atmosphere without regard to the adverse effects it may have. In
our country urbanization and industrialization have become twin problems. Cities and towns
have sprouted up where industries are concentrated. Lack of town’ planning had led to
residential, commercial and industrial areas being mixed up. Houses, schools and hospitals
are situated near industries. All the boons of industrialization and civilization such as
motors, horns, heavy and light machinery, work and movement, blaring radios, supersonic
aeroplanes have become disturbing and irritant. Our ears can hear ordinary conversation
between 30-60 decibels. Modern conversation has a noise value of 60 decibels. A decibel
value greater than 80 decibels causes noise pollution. Noise becomes troublesome above 140
decibels.
4. Loud and sudden noise affect the brain. Intermittent noise leads higher incidence
of psychiatric illness and also a danger to health of pregnant mothers and small
infants.
5. Noise has harmful effects on nonliving materials too, e.g. cracks develop under the
stress of explosive sound.
Radiation
The radiations from the atomic blasts cause several health hazards. The radiations
carry high energy and remove electrons from atoms and attach them to other atoms producing
positive and negative ion pairs. Hence, they are known as ionizing radiations. The ionization
property of these radiations proves to be highly injurious to the protoplasm. The ionizing
radiations of ecological concern are classified as follows:
Corpuscular Radiations
These consist of streams of atomic or subatomic particles, which transfer their energy
to the matter they strike.
(i) Alpha particles
These particles are large and travel few centimeters in the air. These cause large
amount of local ionization.
(ii) Beta particles
These are small particles characterized by having high velocities. They can travel a few
meters in space. These are capable of entering into the tissues for few centimeters.
Since alpha and beta particles have low penetration power they can produce harmful
effects only when absorbed, ingested or deposited in or near living tissues.
(iii) Electromagnetic radiations
Electromagnetic radiations include waves of shorter wavelengths. These are capable of
traveling long distances and can readily penetrate the living tissue. These include gamma
rays. These can penetrate and produce effect even without being taken inside.
(i) Neutrons
These are large uncharged particles, which do not cause radiation by themselves, but
they produce radioactivity in non-radioactive materials through which they pass.
(ii) X-rays
These are electromagnetic waves very similar to gamma rays, but originate from the
outer electron shell of radioactive substances, which are not dispersed in nature.
(iii) Cosmic rays
These are radiations from the outer space, which contain alpha and beta particles
together with gamma rays.
Sources of Radiations
The radiations are produced from the radioactive elements, which are known as
radionuclides or radioactive isotopes, e.g. Uranium. Radium, Thorium, and Carbon-14. These
contribute to background radiation. But isotopes of certain metabolically important elements
like Carbon-14, Cobalt-60, Calcium 45, Iodine-131, Phosphorus-32, etc. are not ecologically
harmful but are used as tracers. The third category of radionuclides comprises of fission
products of uranium and certain other elements. These are cesium, strontium, and plutonium
etc.
irreversible genetic changes in different organisms. The fallout radiations do cause changes
in the genetic constitution of organisms, resulting in gene mutations and chromosomal
aberrations. Their considerable, doses may kill, cripple and alter the animals and plants in
the areas.
Case studies
Hiroshima and Nagasaki Episode
The tale of Hiroshima and Nagasaki is a painful experience. It is for the first time that
an atomic bomb has been exploded over human population. The incident took place on
August 6,1945 at 8:15 a.m. The bomb with an approximate temperature of around 100
million 0°C was exploded on a fine morning in Hiroshima (Japan). The temperature of the
city hiked like anything, almost like an oven. After three days, Nagasaki too suffered the
ravages of a nuclear attack. More than 1,00,000 people were reported to die just after the
event took place. Since radiations from nuclear elements remain active even after, the
generations to follow up also suffered from various diseases. Even the babies in the mother’s
womb were affected and a few perished. Blindness, deafness, skin diseases and cancers,
distortion of bones and other parts became the fortune of human civilization.
Chernobyl Accident
This incident took place in Ukraine on April 26, 1986. There was a Chernobyl nuclear
power plant in Ukraine after which the event has been named. Approximately four million
people had been reported to suffer from the accident. The accident contaminated neighboring
environment up to several kilometers. The sites were evacuated and resettlement was done
for the affected people. The radiations released affected ground water and surface waters,
affecting large areas of Europe. 131 Iodine and 137 Cesium are the most dangerous amongst
the 20-odd radioactive elements released during Chernobyl disaster. As per the Soviet Health
Ministry, 31-persons died shortly after the disaster. Of the 276,614 people who worked for
rehabilitation and cleaning operations, a total of 1065 died by the end of 1990.
Marine Pollution
All river drainages end up in the seas. On the way to sea, rivers carry large amounts
of sewage, garbage, and agricultural discharge, biocides, including heavy metals. Besides
this discharge of oils and petroleum products and dumping of radionuclides waste into sea
also cause marine pollution. Huge quantity of plastic is being added to sea and oceans. Over
50 million lb plastic packing material is being dumped in sea of commercial fleets. Many
marine birds ingest plastic that causes gastro-intestinal disorders. The chemical principle in
ENVIRONMENTAL SCIENCE : POLLUTION AND ITS FACTORS 175
PCBs causes more damage as thinning of eggshell and tissue damage of egg. Radionuclide
waste in sea includes Sr-90, Cs-137, Pu-239, and And Pu-240.
The pollutants in sea may become dispersed by turbulence and ocean currents and
finally becomes a part of food chain. Bioaccumulation in food chain may result into loss of
species diversity. The pollution in Baltic sea along the coast of Finland, took place largely
from sewage and effluents from wood industries. This pollution effect brought changes. in
species diversity in the bottom fauna. In less polluted water there was rich species diversity,
which tended to decrease with increasing pollution load. In heavily polluted areas, macroscopic
benthic animals were absent, but chirognomy larvae occurred at the bottom. In marine
water the most serious pollutant is oil. Spill of oil or petroleum products due to accidents/
deliberate discharge of oil polluted waste brings about pollution. About 285 million gallons
of oil are spilled each year into ocean, mostly from transport tankers. Oil pollution causes
damage to marine fauna and flora including algae, fish, birds, and invertebrates. About
50,000 to 2,50,000 birds are killed every year by oil. The oil is soaked in feathers, displacing
the air and thus interferes with buoyancy and maintenance of body temperature.
Hydrocarbons and benzpyrene accumulate in food chain and consumption of fish by man
may cause cancer. Detergents used to clean up the spill are also harmful to marine life.
Thermal Pollution
The increase in water temperature by industrial units such as steel and iron factories,
electric powerhouses and atomic power plants may be called as thermal pollution. Some of
the industries generate their own power supply where water is used to cool the generators.
This hot water is released into the main stream, causing a warming trend of surface waters.
If the drainage is poorly flushed, a permanent increase in the temperature may result.
Many organisms are killed instantly by the hot water resulting into a high mortality.
It may bring other disturbance in the ecosystem. The eggs of fish may hatch early or fail
to hatch at all. It may change the diurnal and seasonal behaviour and metabolic responses
of organisms” It may lead to unplanned migration of aquatic animals. Macrophysics population
may also be changed. As temperature is an important limiting factor, serious changes may
be brought about even by a slight increase in temperature in a population. Heat stress
(5-1 one above the normal growing temperature of organism) induces expression of specific
gene families called heat shock genes, which lead to the synthesis of a new set of proteins
called heat shock proteins. Heat shock proteins have been found in every organism from
unicellular prokaryotes to multicultural organisms including Homo sapiens. Heat Shock
Proteins synthesis lead to acquired thermo tolerance, i.e. the ability of an organism to
withstand a normally lethal temperature. Thermo tolerant genotypes show adaptations at
various levels of organization besides showing qualitative and quantitative differences in
heat shock proteins as compared to the thermo sensitive genotypes.