Technical Data Sheet

LOCTITE® 4307™
August-2022

PRODUCT DESCRIPTION 14
LOCTITE® 4307™ provides the following product 12

Depth of Cure, mm
characteristics:
Technology Cyanoacrylate/UV 10
Chemical Type Ethyl cyanoacrylate with 8
photoinitiator
Appearance Transparent, light yellow-green to 6
dark blue-green liquidLMS
4
Fluorescence Positive under UV lightLMS
Components One part - requires no mixing 2
Cure Ultraviolet (UV) / Visible light 0
Secondary Cure Humidity 0 10 20 30 40 50 60
Application Bonding Cure Time, seconds
Key Substrates Plastics, Rubbers and Metals

LOCTITE® 4307™ is designed for bonding applications that Tack Free Time / Surface Cure
require very rapid fixturing, fillet cure or surface cure. The UV Tack Free Time is the time in seconds required to achieve a
light cure properties facilitate rapid curing of exposed surface tack free surface
UV/Visible Light Sources:
areas thereby minimizing blooming and providing an alternative
Electrodeless, H bulb:
to solvent borne accelerators. Suitable for use in the assembly 30 mW/cm², measured @ 365 nm ≤10LMS
of disposable medical devices. Zeta® 7400:
30 mW/cm², measured @ 365 nm ≤5
ISO-10993 Electrodeless, D bulb:
LOCTITE® 4307™ has been tested to Henkel's test protocols 100 mW/cm², measured @ 365 nm ≤5
based on ISO 10993 biocompatibility standards, as a means to
assist in the selection of products for use in the medical device
industry.
Cure Speed vs. Substrate
TYPICAL PROPERTIES OF UNCURED MATERIAL The rate of cure will depend on the substrate used. The table
Specific Gravity @ 25 °C 1.06 below shows the fixture time achieved on different materials at
22 °C / 50 % relative humidity. This is defined as the time to
Flash Point - See SDS develop a shear strength of 0.1 N/mm². Fixture time
measurements relate to non-UV cure.
Viscosity, Cone & Plate, mPa·s (cP): Fixture Time, seconds:
Temperature: 25 °C, Shear Rate: 100 s-1 600 to 1,200LMS ABS 5 to 10
Aluminum (grit blasted) 5 to 10
Neoprene 5 to 10
Phenolic 30 to 45
TYPICAL CURING PERFORMANCE Polycarbonate 45 to 65
Polyethylene >300
Polyethylene (Primer 770) 20 to 30
Primary Cure Mechanism, UV
Polypropylene >300
Depth of Cure:
Polypropylene (Primer 770) 5 to 10
Electrodeless, D bulb, 100 mW/cm², measured @
PVC 45 to 60
365 nm
Steel (grit blasted) 10 to 20
 TDS LOCTITE® 4307™, August-2022

TYPICAL PROPERTIES OF CURED MATERIAL TYPICAL ENVIRONMENTAL RESISTANCE

Cured @ 100 mW/cm², measured @ 365 nm, for 30 seconds per Cured @ 30 mW/cm², measured @ 365 nm, for 10 seconds.
side using an Electrodless system, D bulb. Block Shear Strength, ISO 13445:
Physical Properties: Polycarbonate
Coefficient of Thermal Expansion,
ISO 11359-2, K-1:
Pre Tg 87×10-6 Heat Aging
Aged at temperature indicated and tested @ 22 °C
Glass Transition Temperature, ASTM E 228, °C 114 125
Shore Hardness, ISO 868, Durometer D 82 80 °C
Volume Shrinkage, ASTM D 792, % 15

% Strength @ 22 °C
100
Water Absorption, ISO 62, %:
2 hours in boiling water 2.6 100 °C
7days in water @ 22 °C 1.2 75
Elongation, at break, ISO 527-3, % 2.2
Tensile Strength, ISO 527-3 N/mm² 33.4 50
(psi) (4,840)
Tensile Modulus, ISO 527-3 N/mm² 1,813 25
(psi) (263,000)

0
TYPICAL PERFORMANCE OF CURED MATERIAL 0 200 400 600 800 1000
Adhesive Properties
Cure Time, hours

Cured @ 30 mW/cm², measured @ 365 nm, for 10 seconds Chemical/Solvent Resistance

Block Shear Strength, ISO 13445: Aged under conditions indicated and tested @ 22 °C.
Polycarbonate N/mm² ≥9.0LMS % of initial strength
(psi) (≥1,305)
Environment °C 24 h 100 h 500 h 1000 h
Water 22 ------ 140 115 110

Cured @ 100 mW/cm², measured @ 365 nm, for 30 seconds. 95% RH 40 ------ 115 100 100
Block Shear Strength, ISO 13445: Heptane 22 105 ------ ------- -------
Acrylic to Glass N/mm² 2.3 Isopropanol 22 110 ------ ------- -------
(psi) (320)
Acrylic to Acrylic N/mm² 7.5
Thermal Stability of Needle Assemblies
(psi) (1,090)
Aged @ 60°C and tested @ 22 °C
G-10 Epoxy to Glass N/mm² 3.2
Needle Pullout Strength, % of initial strength 4 weeks 8 weeks:
(psi) (470)
Polycarbonate:
Nylon to Glass N/mm² 1.6
(psi) (240) 22 Gauge Cannula 40 35
Polybutylene Terephthalate to Glass N/mm² 4.8 27 Gauge Cannula 100 100
(psi) (690) Polypropylene (plasma treated):
Polycarbonate to Polycarbonate N/mm² 14.2 22 Gauge Cannula 200 125
(psi) (2,060)
27 Gauge Cannula 200 165
PVC to Glass N/mm² 2.8
(psi) (410) Polystyrene:
Aluminum (grit blasted) to Glass N/mm² 6.0 22 Gauge Cannula 125 70
(psi) (870) 27 Gauge Cannula 50 100
Steel (grit blasted) Glass N/mm² 10.2
(psi) (1,480)

Cured @ 1,000 mW/cm², for 10 seconds using an Electrodeless

system, D bulb Sterilization Resistance of Needle Assemblies
Needle Pullout Strength: Sterilized as indicated and tested @ 22 °C
Material 22 Gauge Cannula 27 Gauge Cannula Needle Pullout Strength, % of initial strength:
ABS N 178 N 9 Gamma ETO Autoclave
(lb) (40) (lb) (2) 30kGy 1 Cycle 1 Cycle 5 Cycles
Acrylic N 151 N 9 Polycarbonate:
(lb) (34) (lb) (2) 22 Gauge Cannula 120 90 25 20
Polycarbonate N 116 N 9 27 Gauge Cannula 50 200 100 100
(lb) (26) (lb) (2) Polypropylene (plasma treated):
Polyethylene N 4 N 4 22 Gauge Cannula 75 75 75 75
(lb) (1) (lb) (1) 27 Gauge Cannula 50 100 65 65
Polyethylene N 98 N 22 Polystyrene:
(plasma treated) (lb) (22) (lb) (5) 22 Gauge Cannula 75 135 N/A N/A
Polypropylene N 4 N 4 27 Gauge Cannula 50 100 N/A N/A
(lb) (1) (lb) (1)
Polypropylene N 18 N 13 N/A = Not available. The polystyrene was not compatabile with the
(plasma treated) (lb) (4) (lb) (3) autoclave sterilization process.
Polystyrene N 89 N 9
(lb) (20) (lb) (2)
Polyurethane N 147 N 27
(lb) (33) (lb) (6)

For the most direct access to local sales and technical support visit: https://www.henkel-adhesives.com
 TDS LOCTITE® 4307™, August-2022

GENERAL INFORMATION Disclaimer

This product is not recommended for use in pure oxygen and/or The information provided in this Technical Data Sheet (TDS) including the
oxygen rich systems and should not be selected as a sealant for recommendations for use and application of the product are based on our
chlorine or other strong oxidizing materials. knowledge and experience of the product as at the date of this TDS. The product
can have a variety of different applications as well as differing application and
working conditions in your environment that are beyond our control. Henkel is,
For safe handling information on this product, consult the Safety
therefore, not liable for the suitability of our product for the production processes
Data Sheet (SDS). and conditions in respect of which you use them, as well as the intended
applications and results. We strongly recommend that you carry out your own
prior trials to confirm such suitability of our product. Any liability in respect of the
Directions for use information in the Technical Data Sheet or any other written or oral
1. This product is light sensitive; exposure to daylight, UV recommendation(s) regarding the concerned product is excluded, except if
light and artificial lighting should be kept to a minimum otherwise explicitly agreed and except in relation to death or personal injury
caused by our negligence and any liability under any applicable mandatory
during storage and handling. product liability law.
2. For best performance bond surfaces should be clean and In case products are delivered by Henkel Belgium NV, Henkel Electronic
free from grease. Materials NV, Henkel Nederland BV, Henkel Technologies France SAS and
Henkel France SA please additionally note the following:
3. Excess adhesive can be dissolved with Loctite cleanup In case Henkel would be nevertheless held liable, on whatever legal ground,
solvents, nitromethane or acetone. Henkel’s liability will in no event exceed the amount of the concerned delivery.
In case products are delivered by Henkel Colombiana, S.A.S. the following
Loctite Material SpecificationLMS disclaimer is applicable:
LMS dated March-03, 2003. Test reports for each batch are The information provided in this Technical Data Sheet (TDS) including the
recommendations for use and application of the product are based on our
available for the indicated properties. LMS test reports include knowledge and experience of the product as at the date of this TDS. Henkel is,
selected QC test parameters considered appropriate to therefore, not liable for the suitability of our product for the production processes
specifications for customer use. Additionally, comprehensive and conditions in respect of which you use them, as well as the intended
controls are in place to assure product quality and applications and results. We strongly recommend that you carry out your own
prior trials to confirm such suitability of our product.
consistency. Special customer specification requirements may Any liability in respect of the information in the Technical Data Sheet or any other
be coordinated through Henkel Quality. written or oral recommendation(s) regarding the concerned product is excluded,
except if otherwise explicitly agreed and except in relation to death or personal
Storage injury caused by our negligence and any liability under any applicable mandatory
Store product in the unopened container in a dry location. product liability law.
Storage information may be indicated on the product container In case products are delivered by Henkel Corporation, or Henkel Canada
Corporation, the following disclaimer is applicable:
labeling. The data contained herein are furnished for information only and are believed to
Optimal Storage: 2 °C to 8 °C. Storage below 2 °C or be reliable. We cannot assume responsibility for the results obtained by others
greater than 8 °C can adversely affect product properties. over whose methods we have no control. It is the user's responsibility to
determine suitability for the user's purpose of any production methods mentioned
Material removed from containers may be contaminated during herein and to adopt such precautions as may be advisable for the protection of
use. Do not return product to the original container. Henkel property and of persons against any hazards that may be involved in the handling
Corporation cannot assume responsibility for product which and use thereof. In light of the foregoing, Henkel Corporation specifically
has been contaminated or stored under conditions other than disclaims all warranties expressed or implied, including warranties of
merchantability or fitness for a particular purpose, arising from sale or use
those previously indicated. If additional information is required, of Henkel Corporation’s products. Henkel Corporation specifically
please contact your local Henkel representative. disclaims any liability for consequential or incidental damages of any kind,
including lost profits. The discussion herein of various processes or
Conversions compositions is not to be interpreted as representation that they are free from
(°C x 1.8) + 32 = °F domination of patents owned by others or as a license under any Henkel
Corporation patents that may cover such processes or compositions. We
kV/mm x 25.4 = V/mil recommend that each prospective user test his proposed application before
mm / 25.4 = inches repetitive use, using this data as a guide. This product may be covered by one or
µm / 25.4 = mil more United States or foreign patents or patent applications.
N x 0.225 = lb Trademark usage
Except as otherwise noted, all trademarks in this document are trademarks of
N/mm x 5.71 = lb/in Henkel Corporation in the U.S. and elsewhere. ® denotes a trademark registered
N/mm² x 145 = psi in the U.S. Patent and Trademark Office.
MPa x 145 = psi
N·m x 8.851 = lb·in Reference 1.4
N·m x 0.738 = lb·ft
N·mm x 0.142 = oz·in
mPa·s = cP

For the most direct access to local sales and technical support visit: https://www.henkel-adhesives.com