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    Chemistry 2

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    Chemistry 2

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    Chemistry 2

    Uploaded by

    daudimgetamafwele

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    © All Rights Reserved
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    of 3

    PRESIDENT’S OFFICE

    REGIONAL ADMINISTRATOIN AND LOCAL GOVERNMENT


    FORM SIX PRE-MOCK JOINT EXAMINATIONS
    IRINGA, NJOMBE AND MBEYA
    132/2 CHEMISTRY 2
    (For Both School and Private Candidates)
    TIME: 3 HRS OCTOBER, 2020.

    Instructions:
    i. This paper consist of six (6) questions
    ii. Answer any five (5) questions
    iii. Each question carries 20 marks
    iv. Write your examination number on every page of your answer booklet(s)
    v. For calculations the following constants may be used
     1L= 1dm3=1000cm3
     1F=96500coulombs
     Atomic masses: H =1, C =12, O =16, Na =23, Al =27, Cl =35.5, N=14, F = 19 and S =32

    1. (a) Ethanol and water form an azeotropic mixture which boils at 78.2oC of which 95.6% ethanol at
    constant pressure. If the boiling point of pure ethanol and water are 78.5oC and 100oC respectively
    (i) Draw a labelled temperature verses mole fraction diagram of ethanol and water solution
    (04 Marks)
    (ii) How can you separate ethanol azeotropic mixture of ethanol and water?
    (02 Marks)
    (b) At a certain temperature an ideal solution containing benzene and toluene form a vapour pressure
    whose composition is 0.62 benzene. Calculate mole fraction of benzene and toluene. If the vapour
    pressure of pure benzene are 88.2mmHg and 25.5mmHg.(07 Marks)
    (c ) 100cm3 of water contain 10g of an organic compound. Given that the distribution constant of
    between ethoxy ethane and water is 9. Assuming that ethoxy ethane and water are immiscible and
    that is in the same molecular condition in both. What mass of Y is extracted? if the mixture is shaken
    with
    (i) 50cm3 of ethoxyethane
    (ii) 25cm3ethoxy ethane twice.(07 Marks)
    2. (a) Can a nickel spatula be used to stir a solution of copper sulphate. Give reasons to Support your
    answer
    (EQ Ni2+ /Ni = - 0.25V, EQCu2+/Cu = + 0.34V (03 Marks))
    (b) For the Cell, Mg(s) /Mg2+ (1M) // Cu2+ (1M/ Cu (s)

    (EQ Mg2+/Mg = - 2.37V and EQ Cu2+/Cu = + 0.34V) operating to a light bulb


    (i) Identify the cathode and the anode as the current is drawn from it(02 Marks)
    (ii) Write the electrode reactions(04 Marks)
    (iii) Calculate the cell potential.(04 Marks)
    Page 1 of 3
    (c) The reduction potential of Cu2+/Cu and Ag+/Ag electrode are 0.34V and 0.8V respectively.
    Construct a galvanic cell using these EQ values. For what concentration of Ag+ ion the emf of cell at
    25oc be zero. If the concentration of Cu2+ is 0.01M (07 Marks)
    3. (a) Freshly precipitated aluminum and magnesium hydroxide are stirred vigorously in a buffer
    solution containing 0.25M of ammonium chloride and 0.05M of ammonium hydroxide calculate the
    concentration of aluminum and magnesium ion in solution.
    Given that Kb (NH4) H) = 1.8 x 10-5, Ksp Mg (0H)2 = 6 x 10-12Ksp Al(0H)3 = 6 x 10 -32(07 Marks)
    (b) The PH of a 0.IM HCN solution was found to be 5.2. Calculate the value of dissociation
    constant, Ka for this acid.(06 Marks)
    (c) How does dilution with water affect the pH of a butter solution? (03 Marks)
    (d) Calculate solubility of BaSO4 in moldm-3, if its solubility product in water is 1 x 10-10mol2dm-6
    at 25oC (04 Marks)

    4. (a) Briefly explain the following


    (i) Copper metal resists attack of both dilute of both dilute sulphuric acid and hydrochloric
    acid, but reacts with dilute nitric acid.(03 Marks)
    (ii) Nitric acid attack metal but aluminium container are used to transport concentrated nitric
    acid.(03 Marks)
    (iii) Aluminium metal does not reacts with hot water of steam.(03 Marks)
    (iv) Hydrochloric acid should not be used as an acidic medium in redox titration of potassium
    permanganate and iron (II) sulphate.(03 Marks)
    (v) An hydrous aluminum chloride does not conduct electricity but aqueous conducts
    electricity.(03 Marks)
    (b) (i) What are the two factors that helped the classification elements in periodic table(02 Marks)
    (ii) Although ammonia and phosphine are hydrides of group five, ammonia is Lewis base while
    phosphine is not, give reasons (03 Marks)
    5. (a) Indicate the properties needed by a polymer make suitable use in one of the following.
    (i) A fish net (ii) soles of shoes (iii) insulation of an electrical cable.
    Suggest a suitable polymer for each article briefly explain the structure and other features which
    may lead to necessary properties.(06 Marks)
    (b) Indicate the monomers and the polymerisation method which are likely to be used in making each
    of the following commercial polymers
    (i) CH CH2 CH CH2 CH CH2 CH CH2

    (ii) -CF2 - CF2 - CF2 - CF2 - CF2 - CF2-


    (iii) - NH (CH2)5 –C (0) – NH (CH2)5 - C(0) - NH(CH2)5 - (06 Marks)
    (c) (i) Give the structural formulae of hexane - 1,6 - dioic acid and 1,6 – diaminohexane
    (ii) Explain why the pair of molecules in (i) is suitable for polymerization.
    (iii) Give the structural formula of the polymer which might be formed by the pair of molecules
    in (6) (c) (i) above (06 Marks)
    (d) Explain at least two hazard of polymers (02 Marks)
    Page 2 of 3
    6. (a) Equations (including reagents and condition) for the following conversion.
    (i) Butan – 1- 01 tobutan – 2- 01 (3step) (02 Marks)
    (ii) Propanal to propanone (4step) (03Marks)
    (iii) Benzene to benzene carbaldehycle (2 step)(02 Marks)
    (b) Using your knowledge of particular functional group of various type of organic compounds
    predict the products of the reaction of the following

    HO-CH2- -CH2-CO-CH3

    With (i) A warm mixture of iodine and Na0H


    (i) Ethanoyl chloride
    (ii) Acidified K2 Cr207 at only 60 – 80oc
    (iii) H2 and Ni at (a) 140oC (a) 200oC (05 Marks)
    (c) A carbonyl compound (A) was reduced with LiAlH4 to give a compound B. B was dehydrated
    with concentrated sulphuric acid to give one product C (C5H10). 0zonolysis of C gave ethanal
    and compound D (C3H60). D gave a positive iodoform reaction, identify A, B, C and D giving
    their names and Structural formula, explain how you have deduced their Structural formula,
    giving equations for all above reactions (08 Marks)

    Page 3 of 3

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