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    Mock Che1

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    nassorussi9
    This document contains instructions and content for a mock Form Six chemistry examination for students in the Southern Zone of Tanzania. It consists of two sections, Section A with 6 compulsory questions worth 70 marks total, and Section B with 2 out of 3 questions to answer worth 30 marks total. The examination covers topics including atomic theory, bonding, solutions, equilibrium, organic chemistry, and acid-base reactions. It provides various constants, formulas, and information that may be used in solving the problems.

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    © All Rights Reserved
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    Mock Che1

    Uploaded by

    nassorussi9
    40 views5 pages
    This document contains instructions and content for a mock Form Six chemistry examination for students in the Southern Zone of Tanzania. It consists of two sections, Section A with 6 compulsory questions worth 70 marks total, and Section B with 2 out of 3 questions to answer worth 30 marks total. The examination covers topics including atomic theory, bonding, solutions, equilibrium, organic chemistry, and acid-base reactions. It provides various constants, formulas, and information that may be used in solving the problems.

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    This document contains instructions and content for a mock Form Six chemistry examination for students in the Southern Zone of Tanzania. It consists of two sections, Section A with 6 compulsory questions worth 70 marks total, and Section B with 2 out of 3 questions to answer worth 30 marks total. The examination covers topics including atomic theory, bonding, solutions, equilibrium, organic chemistry, and acid-base reactions. It provides various constants, formulas, and information that may be used in solving the problems.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    40 views5 pages

    Mock Che1

    Uploaded by

    nassorussi9
    This document contains instructions and content for a mock Form Six chemistry examination for students in the Southern Zone of Tanzania. It consists of two sections, Section A with 6 compulsory questions worth 70 marks total, and Section B with 2 out of 3 questions to answer worth 30 marks total. The examination covers topics including atomic theory, bonding, solutions, equilibrium, organic chemistry, and acid-base reactions. It provides various constants, formulas, and information that may be used in solving the problems.

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    © All Rights Reserved
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    of 5

    132/1-Mock Examination 2023

    PRESIDENT’S OFFICE
    REGIONAL ADMINISTRATION AND LOCAL GOVERNMENT
    ADVANCED CERTIFICATE OF SECONDARY EDUCATION EXAMINATION
    FORM SIX MOCK EXAMINATION SOUTHERN ZONE
    (MTWARA AND LINDI)

    132/1 CHEMISTRY 1
    (For Both School and Private Candidates)

    Time: 3 Hours January, 2023

    Instructions

    1. This paper consists of sections A and B with a total of ten(10) questions.


    2. Answer ALL questions in section A and two(2) questions from section B.
    3. Mathematical tables and non-programable calculators may be used.
    4. Cellular phones and any unauthorized materials are not allowed in the
    examination room.
    5. Write your Examination Number on every page of your answer booklet(s).
    6. The following information may be used.
    (a) Universal gas constant, R=8.314JK−1 mol−1 or 0.0821atmdm3 mol−1 .
    (b) Rydberg constant RH = 1.09678 × 107 m−1
    (c) standard pressure =1 atm=760mmHg=1.0× 105 N/m2
    (d) 1 Mass of electron= 9.11 × 10−31 kg
    (e) Density of water= 1g/cm3
    (f) Velocity of light, C= 3.0 × 108 m/s
    (g) Avogadron’s constant =6.022×1023 mol−1
    (h) Planks constant, h= 6.63 × 10−34 Js
    (i) Atomic masses
    H=1, C=12, O=16, N=14, Cl=35.5, Br=80, Na=23.

    This paper consists of five printed pages

    Page1 of 5 acsee0001
    132/1-Mock Examination 2023

    SECTION A (70 MARKS)


    Answer All questions from this section.
    1. (a) Why does hydrogen spectrum have large number of lines despite the fact that
    hydrogen has only one electron. (02 marks)
    (b) Calculate the wavelength of an alpha particle having a mass of 6.7 × 10−25 kg
    moving with a speed of 1000m/s. (04 marks)
    (c) Naijongoro a chemistry teacher at Muungano secondary school told his
    student that “Dalton atomic theory is primitive” support Mr. Naijongoro
    using four points. (04 marks)
    2. (a) Write down the molecules or ions that undergo the following hydridization
    scheme;
    (i) Sp3 d
    (ii) Sp3 d2
    (iii) Sp3 (03 marks)
    (b) CO2 is a non-polar molecule while H2 O is polar molecule. Explain.
    (03 marks)
    (c) Makene a form five student was arguing that double bond is a weaker than
    single bond because double bond has a weak Pi bond. But Anna happened
    to educate Makene that in double bond there are two bonds strong sigma
    bond and weak pi bond while in single bond there is only one bond, which
    is strong sigma bond. Using four points justify that sigma bond is different
    from pi bond. (04 marks)
    3. (a) Define the following
    (i) Ebullioscopic constant
    (ii) Van’t Hoff’s factor
    (iii) Colligative properties (03 marks)
    (b) The vapour pressure of water at 50◦ C is 92.5mmHg. At the same temperature
    a solution containing 9.14g of urea in 150g of water has a vapour pressure of
    90.8mmHg. Determine the molecular mass of urea. (03 marks)
    (c) What is the boiling point of a solution made by dissolving 45.0g of NaCl in
    500g of water (Ebulliscopic constant,kb = 0.512) (04 marks)
    4. (a) Explain the following
    (i) Heat of neutralization
    (ii) Heat of solution (02 marks)
    (b) 1.150g of sucrose was burnt in a bomb calorimeter. If the temperature rose
    from 23.42◦ C to 27.64◦ C and the heat capacity of the calorimeter was

    Page2 of 5 acsee0001
    132/1-Mock Examination 2023

    4.9KJ◦ C−1 , what was the heat of combustion of sucrose (C12 H22 O11 ) in
    KJ/md? (04 marks)
    (c) Calculate the heat of formation of ethyl alcohol (C2 H5 OH) if the heat of
    combustion of ethyl alcohol is -1380.7KJ/mol and the heats of formation of
    CO2(g) and H2 O(l) are -393.9KJ/mol and -286KJ/mol respectively.
    (04 marks)
    5. (a) Aluminium oxide is said to be amphoteric. Explain this fact by aid of
    chemical equation. (03 marks)
    (b) Iron (III) carbonate never exists. Explain this statement. (01 marks)
    (c) Explain the following with the aid of chemical reaction if applicable.
    (i) MgCl2 · 6H2 O when heated can never give anhydrous MgCl2
    (ii) CuCl2 solution is acidic to litmus paper
    (iii) Fe3 O4 is called mixed oxide. (06 marks)
    6. (a) Explain these concept
    (i) Dynamic equilibrium.
    (ii) irreversible reactions (03 marks)
    (b) At 773K, the reaction between gaseous nitrogen and hydrogen to form
    ammonia gas has a KC = 6.0 × 10−2 dm6 mol−2 . Compute the value of Kp for
    this reactions. (03 marks)
    (c) A mixture of CO and steam consisting of 0.25 mol each constituent is placed
    in 500ml flask and the mixture heated up to 900K. The reaction equations is
    CO(g) +H2 O(g) CO2(g) +H2(g) . What is the composition of the equilibrium
    mixture at this temperature if the KC for this reaction is 1.56? (04 marks)
    7. (a) (i) Catenation
    (ii) Isomerism
    (iii) Mesomerism (03 marks)
    (b) Give the IUPAC name of the following organic compounds
    CH3
    (i) CH3 C CH3
    CH3
    CH2 CH3
    (ii) CH3 CH2 CH2 C CH2 CH3
    CH3
    (iii) H C ≡ C CH CH CH3
    (iv) CH3 C C CH3 (04 marks)
    Cl Br
    Page3 of 5 acsee0001
    132/1-Mock Examination 2023

    (c) Show the product and mechanism of the following reactions


    H2 SO4
    (i) CH2 CH2 +H2 O −−− −−→
    180◦ C
    (ii) CH3 CH CH2 +HCl −→ (03 marks)

    SECTION B (30 MARKS)


    Answer two (2) questions in this section.

    8. (a) (i) By using the chemical equation explain why tertiary haloalkane can not
    undergo SN2 reaction.
    (ii) Benzene is more reactive than Nitrobenzene while methylbenzene is more
    reactive than benzene. Explain this observation. (04 marks)
    (b) Explain which substituent entered in the benzene ring first
    OH

    (i)
    NO2
    OH

    Cl
    (ii)

    CH3
    NH2

    (iii) (03 marks)

    COOH
    COOH

    (c) Convert CH3 CH3 to in not more than three steps. (03 marks)

    (d) From the scheme below identify the molecules V, W, X, Y and Z.

    Page4 of 5 acsee0001
    132/1-Mock Examination 2023

    Cl2 KOH(alcoh)
    CH2 CH2 V W

    Na(dry ether) AlCl3


    Z Y X
    C 6 H6 CH3 CH2 Cl

    (05 marks)
    9. (a) The soil of Mjimwema has very low pH due to waste from factories, acid rain,
    over application of ammonium fertilizer and leaching of basic cations. What
    do we call this phenomenon? Explain three (3) effects of the phenomenon.
    (04 marks)
    (b) Mzee Juma was telling Mzee Ally that do not waste money to buy UREA,
    DAP and NPK just use animal dungs will give the same results. As a chemist
    educate Mr.Juma and Mr.Ally the different between artificial fertilizer and
    Natural fertilizer by giving three (3) points. (03 marks)
    (c) 50 g of oven dry soil was shown to have 4meqCa2+ , 2meq Na+ , 3meq Mg2+ ,
    1meq H+ , 2.5meq Al3+ , 1meq Na− and 1.5meq K+ at their exchange sites
    (i) calculate the percentage base saturation of the soil.
    (ii) Calculate the mass of magnesium in 150g of soil
    (iii) Explain the nature of the soil (09 marks)
    10. (a) Predict the major product(s) for each of the following reactions
    H2 SO4
    (i) (CH3 )2 CHCH CH2 −−− −−→ A
    H2 O
    Hg(OH)2 NaBH4
    (ii) CH3 CH2 CH CH2 −−−−−−−→ B −−−−−→ C
    H2 O
    BH3 ,THF H2 O2
    (iii) (CH3 )2C CH CH2 −−−−−−−→ D −−− −→ E (05 marks)
    NaOH
    H
    (b) When 1, 2-dibromodecane was treated with potassium hydroxide in aqueous
    ethanol, it yielded a mixture of three isomeric compounds of molecular
    formula C10 H19 Br. Each of these compounds was converted to dec-1-yne on
    reaction with sodium amide in dimethyl sulphoxide. Identify the three
    compounds. (06 marks)
    (c) Explain briefly the preparation of acetylene (ethyne) by
    (i) pyrolysis of natural gas.
    (ii) Action of water on calcium carbide. (04 marks)

    Page5 of 5 acsee0001

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