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    65bc787665022d00198279d3 - ## - Amines Short Notes

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    Imdadullah Akbar
    The document discusses the preparation and chemical reactions of various amine compounds including alkyl amines, aniline, alkyl cyanides, nitrobenzene, and nitroalkanes. Common preparation methods include reaction of alkyl halides with ammonia or amines. Typical reactions include substitution, elimination, oxidation, reduction, and other organic reactions.

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    65bc787665022d00198279d3 - ## - Amines Short Notes

    Uploaded by

    Imdadullah Akbar
    8 views7 pages
    The document discusses the preparation and chemical reactions of various amine compounds including alkyl amines, aniline, alkyl cyanides, nitrobenzene, and nitroalkanes. Common preparation methods include reaction of alkyl halides with ammonia or amines. Typical reactions include substitution, elimination, oxidation, reduction, and other organic reactions.

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    65bc787665022d00198279d3_##_Amines Short Notes

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    The document discusses the preparation and chemical reactions of various amine compounds including alkyl amines, aniline, alkyl cyanides, nitrobenzene, and nitroalkanes. Common preparation methods include reaction of alkyl halides with ammonia or amines. Typical reactions include substitution, elimination, oxidation, reduction, and other organic reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    8 views7 pages

    65bc787665022d00198279d3 - ## - Amines Short Notes

    Uploaded by

    Imdadullah Akbar
    The document discusses the preparation and chemical reactions of various amine compounds including alkyl amines, aniline, alkyl cyanides, nitrobenzene, and nitroalkanes. Common preparation methods include reaction of alkyl halides with ammonia or amines. Typical reactions include substitution, elimination, oxidation, reduction, and other organic reactions.

    Copyright:

    © All Rights Reserved
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    of 7

    CHAPTER

    13 Amines

    Preparation of Alkyl Amines


    Chemical Reactions of Amines
    O
    H2O Cl—C—Cl R–N=C=O
    R–NH3 OH (–2 HCl) (Alkyl isocyanate)
    O
    O
    CH3—C—OH CHCl3+alc.KOH
    R–NH3 O—C—CH3 Hoffmann R–NC
    n (Pungent smell)
    Carbyl amine rx

    R–NH3 Cl HCl CH3–CH=O/HÅ CH3–CH=N–R


    (Schiff’s Base)

    R–NH3 AuCl4 HAuCl4 Cl–N=O


    R–NH2 R–Cl
    Tilden reagent
    NO2
    HO NO2 Na(Metal)   1
    NO2 R  N H Na  H 2 
    2
    NO2
    R–NH3 O NO2
    Picric acid CH3CH2–Cl
    NO2 R–NH–CH2CH3
    (–HCl)
    O
    O
    –2
    R–NH3 2 SO4 H2SO4 CH3–C–Cl
    R–NH–C–CH3
    (–HCl)
    O
    O
    –2 Ph–C–Cl
    D H2PtCl6 R–NH–C–Ph
    Pt metal RNH3 2PtCl4 (–HCl)

    (Chloro platinate method) used in Cl


    deterimantion of molecular weight CH3MgCl
    CH4+Mg
    of amine. NHR

    Br2 + KOH
    Halogenation R–NH–Br

    42 NEET (XII) Module-4 PW


    Reactions for Formation of Aniline

    Chemical Reactions of Aniline


    
    N H 3 Cl
    —

    HCl

    NH—R
    —

    R—X
    –HX
    O
    O
    NH2 —C—Cl
    —NH—C —
    –HCl
    Aniline

    O–CH— /HÅ
    —N=CH—
    (–H2O)

    Cl
    Cl C=O —N=C=O
    (–2HCl)

    N C=
    —

    CHCl3/alc. KOH

    P
    W Amines 43
    Benzene Diazonium Chloride is used in the Synthesis of Following Aromatic Compounds

    H3PO2 or C2H5OH

    Balz

    44 NEET (XII) Module-4 PW


    Preparation Methods and Chemical Reactions of Alkyl Cyanide

    Preparation Methods and Chemical Reactions of Alkyl Isocyanide

    AgCN H3O
    CH3—Cl CH3NH2+HCOOH

    H2/Pd
    CH3—NH—CH3
    reduction
    CH3—N= C
    P2O5 Na/EtOH
    CH3—NH—C—H Methyl CH3—NH—CH3
     reduction
    isocyanide
    O
    O3/
    CH3—N=C=O+O2

    CHCl3 2HgO
    CH3—NH2 CH3—N=C=O+Hg2O
    alc. KOH
    (MIC)

    P
    W Amines 45
    Preparation Methods and Chemical Reactions of Nitrobenzene

    Conc.HNO3

    –
    N2Cl

    NH

    rearranged
    Conc.H2SO4

    46 NEET (XII) Module-4 PW


    Preparation Methods and Chemical Reactions of Nitroalkanes

    NaOH/
    Nef reaction

    P
    W Amines 47

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