List of Organic Reagents: I. Reducing Agents
List of Organic Reagents: I. Reducing Agents
List of Organic Reagents: I. Reducing Agents
I. REDUCING AGENTS
C = NOH CH2NH2
RNH2
RNO2
ArN = NAr
ArNO2
azo
azoxy
C = C CH CH
CC CH CH
RX RH
ArX ArH
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R C OH
R Pinacol
7. Alkali metals in
liquid ammonia
(eg. Na in liq.
NH3)
COOH COOH
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8. Aluminium C=O
isopropoxide H C – OH
(aldehyde or
Al (OPri)3
ketone)
9. LiAlH4 in ether
CHO CH2OH
(non hydroxylic
solvent)
CO CHOH
CO2R CH2OH
COCl CH2OH
CONH2 CH2NH2
(RCO)2O RCH2OH
Lactone Diol
Epoxide Alcohol
CN CH2NH2
C = NOH CH2NH2
RNH2
RNO2
ArN = NAr
ArNO2
azo
azoxy
RH
RX
ArH
ArX
C6H5 – CH2 - CH3
C6H5 – CH = CH2
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14. H – Al (iBu)2
R R
Diisobutyl C=O C=O
aluminium RO H
hydride
DIBAL – H R–CN R
C=O
H
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CO CHOH
CO2H CH2OH
CO2R CH2OH
CONH2 CH2NH2
(RCO)2O RCH2OH
Lactone Diol
Epoxide Alcohol
C = C CH CH
CC CH = CH
RX RH
ArX ArH
16. 9 – B.B.N R H
C=C R – CH = CH – CH - R
(B – alkyl – 9 – C
H R |
bora bicyclo) OH
[3.3.1]nonane O
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or alcoholic H – C| C| C O = C– C = C –
solution H (allylic oxidation)
CHO
CH3
20. CrO2Cl2 (etard’s
reagent)
R R
HO R
C=C
21. RCO3H , H3O+ H H R C-C H
H OH
(antihydroxylation)
| |
- C O + - C= O
C OH
22. Pb(OAc)4 C OH
H
C – CH3
OH
CH3
23. NaOH – I2 _ C=O
O + CHI3
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C OH
24. HIO4 (Periodic | |
acid) - C O + - C= O
C OH
C OH
25. Ceric ammonimum | |
nitrate - C O + - C= O
Ce(NH4)2(NO3)6 C OH
C=O
H _ C=O + Cu2O
OH O Red ppt
C
29. Benedict reagent H C=O C=O
(an alkaline R
solution containing C=O
a cupric citrate R
complex ion)
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40. N.B.S
CH2 = CH – CH3
(N bromo CH2 = CH – CH2 Br
(allylic bromination)
succinimide)
OCOR OH OH
COR
+
C6H6 + HCl + CO
CHO
COR
RCOOH
42. Diazo methane
C6H5OH
CH2N2
ROH
RCOOCH3
C6H5OCH3
ROCH3
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REACTANT PRODUCT
REAGENT
R R R H
43. alc. KOH H C-C H C=C
H Cl H R
(major)
R R
44. NaNH2 C=C R – C C - R
H Cl
R
45. NaOH – Br2 C=O RNH2
H2N
46. P2O5 R
(dehydrating C=O R–CN
agent) H2N
47. conc. H2SO4
(dehydrating RCH2 CH2 OH R CH = CH2
agent)
48. Ph3P = CH2 C = CH2
(Wittig reagent) C=O
O Cl
O
49. Cl2, P CH2 C C
CH
OH OH
50. Fe2+ + H2O2 H HO
(Fenton’s reagent)
C OH C OH
C OH C O
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