Terengganu STPM Trial 2010 Chemistry (W Ans) (74F1C1B0)

Name : ………………………………………………… NRIC : …………………………
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR

962/1 TRIAL
STPM 2010
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN
JABATAN PELAJARAN TERENGGANUJABATANPELAJAR
JABATAN PELAJARANTERENGGANUJABATANPELAJARAN
NEGERI TERENGGANU TERENGGANUJABATANPELAJAR
CHEMISTRY
PAPER 1
One hour and forty-five minutes
Instructions to candidates :
DO NOT OPEN THIS BOOKLET UNTIL YOU ARE TOLD TO DO SO.
There are fifty questions in this paper. For each question, four suggested answers are given. Choose
one correct answer and indicate it on the multiple-choice answer sheet provided.
Read the instructions on the multiple-choice answer sheet very carefully.
Answer all questions.Marks will not be deducted for wrong answers.The total score for this paper is
the number of correctly answered questions.
This question paper consists of 16 printed pages.
http://edu.joshuatly.com/
http://www.joshuatly.com/
STPM 962/1 OTI 2 2010 2 SULIT*(CONFIDENTIAL*)
Section A
Four suggested answers labelled A, B, C and D are given for each question.
Choose one correct answer.
1 Which statement about one mole of a metal is always true?
A It contains the same number of particles as one mole of hydrogen atoms.

B It contains the same number of particles as 1/12 mole of 12C
C It has the same mass as one mole of hydrogen atoms
D It is liberated by one mole of electrons
2 Sodium azide, NaN3, is made for use in car `air bags`. When this compound is heated to
3000oC, it rapidly decomposes into its elements. Which volume of gas , at room temperature
and pressure, would be produced by the decomposition of one mole of sodium azide?
A 24 cm3 C 48 cm3
B 36 cm3 D 72 cm3
3 Which of the following gas cannot be liquefied at room temperature?
Gas Critical Temperature OC

A P 50.0
B Q 12.5
C R 230.0
D S 400.0
4 The successive ionization energies, in kJmol-1, of an element X are given below
870 1800 3000 3600 5800 7000 13200
What is X ?
A 35As C 8O
B 53I D 52Te
5 Gallium has the electronic configuration [Ar] 3d10 4s2 4p1, where [Ar] represents the
configuration of Argon. In which order are the electrons lost in forming the Ga4+ ion?
1st 2nd 3rd 4th

A 3d 4p 4s 4s
B 3d 4s 4s 4p
C 4s 4s 4p 3d
D 4p 4s 4s 3d
STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

Kertas soalan ini SULIT sehingga peperiksaan ini tamat SULIT*(CONFIDENTIAL*)
6 Why is the molecule of BCl3 planar, whereas the molecule of PH3 is pyramidal?
A The boron atom has no d-orbitals available for bonding.

B The boron atom in BCl3 has six electrons in its valency shell, whereas the
phosphorous atom in PH3 has eight.
C The repulsion between chlorine atoms is greater than that between hydrogen atoms
D The covalent radius of chlorine is greater than that of hydrogen.
7 Which of the following statements describes a phenomenon which can be explained by

intermolecular hydrogen bonding?
A The melting points of the Group 1 hydroxides increase with increasing relative
molecular mass.
B The boiling points of the alkanes increase with increasing relative molecular mass.
C Hydrogen chloride forms an acidic solution when dissolved in water.
D Ice has a lower density than water at 0oC.
8 Which of the following statements explains why copper conducts electricity when a potential
difference is applied?
A Copper(II) ions move to the cathode

B The crystal lattice breaks down
C The atoms of copper become ionised
D Bonding electrons in the crystal lattice move
9 A radioactive element has two isotopes, G and H, with half-live of 5 min and 15 min
respectively. An experiment starts with 4 times as many atoms of G as of H.
Radioactive decay is a first-order reaction.
How long will it be before the number of atoms of G left equals the number of atoms of H
left?
A 5 min C 15 min
B 10 min D 20 min
10 For the gaseous reaction: 2X(g) + Y(g) Z(g)
The rate equation is:

Rate = k [X]2[Y]0
If the pressure in the reaction vessel is doubled, but the temperature remains constant by what
factor does the rate of reaction increase?
A 2 C 4
B 3 D 8

11 Which one of the following statements is correct about a reaction for which the equilibrium
constant is independent of temperature?
A The activation energies for both forward and reverse reactions are zero
B The enthalpy change are zero
C Its rate constants do not vary with temperature
D There are equal numbers of moles of reactants and products
12 Which of the following statements could be correct when a little CaCO3 is heated at 800oC in
a closed vessel?
A All the CaCO3 completely decomposed

B The number of moles of CaO and CO2 differs
C Only part of the CaCO3 decomposes no matter how long the compound is heated
D The pressure in the vessel increases slowly as the CaCO3 is heated
13 Identify the solubility product expression for lead (II) chloride.
A [Pb2+]2 [Cl-]2
B [Pb2+]2 [Cl-]
C [Pb2+] [Cl-]2
D [Pb2+] [Cl-]2
[PbCl2]
14 Below is a phase diagram of the mixture of C and D at temperature T. The solution that
contains C and D is an ideal solution.
Vapour
Pressure (atm)
1.0
0 0.5 1
m n o
Mole fraction of C
Which statement is true about the solution which contains C and D?
A Mixture m is a liquid at 1.0 atm.

B Mixture o exists as vapour at 1.0 atm.
C Mixture n boils at temperature T.
D At temperature T, the vapour composition of mixture n contains more C.

15 Which one of the following techniques is most appropriate to analyze the percentage of
alcohol in a blood?
A Column chromatography
B Gas-liquid chromatography
C Paper chromatography
D Thin-layer chromatography
16 The diagram is a set-up for an electrolysis experiment.
platinum
Copper sheet
Dilute H2SO4
What happens at the anode and the cathode?
Anode Cathode
A Copper dissolves Copper is deposited
B Copper is deposited Hydrogen is produced
C Copper is deposited Oxygen is produced
D Hydrogen is produced Copper is deposited
17 An electrolysis is done on a molten compound consisting of the elements Y and Z at a current

of 1.00 A for 1 930 minutes. It is found that 2.07 g of Y is formed at the cathode while 1.60 g
of Z is formed at the anode. Calculate the empirical formula of the compound.
[Relative atomic mass: Y = 207, Z = 80, Faraday’s constant, F = 96 500 C mol-1]
A YZ
B YZ2
C Y2Z
D Y2Z2
18 Which of the following equations represents the enthalpy of atomization of magnesium?
A Mg (s) → Mg (l)
B Mg (s) → Mg (g)
C Mg (l) → Mg2+ (g) + 2e-
D Mg (g) → Mg2+ (g) + 2e-

19 The standard enthalpy of combustion of methanol, carbon and hydrogen is -715 kJ mol-1, -394
kJ mol-1 and -286 kJ mol-1 respectively. What is the standard enthalpy of formation of
methanol in kJ mol-1?
A +35
B -35
C +251
D -251
20 Which of the following reactions involves an electrophilic reagent?
A CH3CH3 + Br2 → CH3CH2Br + HBr

B CH3Br + NaOH → CH3OH + NaBr
C CH3CHCH2 + HBr → CH3CHBrCH3
D CH3COOH + CH2CH2OH → CH3COOCH2CH2 + H2O
21 Which alkenes produce 0.132 g of CO2 and 0.045 g of H2O after complete combustion?
[Relative atomic mass : C = 12, H = 1, O = 16]
B C3H7
C C3H7
C3H7
D CH3 C2H5
\ ⁄
⁄ \
CH3 C2H5

22 Arene molecules are added to petrol to increase the octane number of petrol. Alkane
molecules like heptane can be changed to arene molecules as below.
CH3
H H H H H H H |
| | | | | | |
H—C—C—C—C—C—C—C—H Pt / ∆ + 4H2 (g)
| | | | | | | Pressure
H H H H H H H
Heptane Toluene
(alkane) (arene)
What is the name of this process?
A Catalytic cracking
B Catalytic hydrogenation
C Catalytic reformation
D Thermal cracking
23 The mechanism for the reaction below is best classified as
— Cl
Cl2 — Cl
AlCl3
\
Cl
A an electrophilic addition
B a nucleophilic addition
C an electrophilic substitution
D a nucleophilic substitution
24 Compound Y can react with alcohols and phenols to form ester. Besides, compound Y can
also react with water. Y could be
A CH3COOH
B CH3COCl
C CH3CH2Cl
D
— Cl

25 An organic compound G
(i) decolourises acidified potassium permanganate (VII) and

(ii) forms a yellow precipitate with alkaline iodine solution.
The organic compound G is
A CH3COCH3
CH3
B |
CH3 — C — CH3
|
OH
C
— CHO
D
— CH(OH)CH3
26 An organic compound can react with phosphorous pentachloride with the release of white
fumes. The compound can also be reduced to a primary alcohol.
The compound is likely to be
A CH3COCH3
B C6H5COOH
C CH3COOC6H5
D (CH3)3COH
27. The gases given off when a compound reacts with several reagents are as follows:
Reagent Gas
PCl5 HCl
NaHCO3(aq) CO2
NaNO2/HCl(aq) N2
What is the compound?

A CH3NHCH2COOH
B H2NCH2CH2COOH
C
H2N OH
D O
H2N C OH

28 An organic acid decolourises bromine water. 1.16 g of the acid in aqueous solution requires
20.0 cm3 of a 1.0 mol dm3 sodium hydroxide solution for complete neutralization.
What is the possible structural formula of the acid?
[Relative atomic mass of H is 1.0, C is 12.0, O is 16.0]
A HCOOH.
B HOOCCOOH
C CH2=CHCOOH
D HOOCCH=CHCOOH
29 Which reagent does not react with ethanamine?
A HNO2
B NaOH
C CH3COCl
D CH3CH2Cl
30. GABA is a neuro-transmitter released by red algae which encourages shellfish larvae to settle
on the ocean bed. Its structural formula is H2NCH2CH2CH2COOH. Which reagent reacts only
with the acidic group of GABA?
A HCl
B HNO2
C CH3CH2Cl
D CH3CH(OH)CH3
31 Glycine (2-aminoethanoic acid) is an optically inactive amino acid. Which of the following
compounds is formed not because of the acid-base property of glycine?
A H2NCH2COONa
B CH3OOCCH2NH2
C HOOCCH2NH3Cl
D HOOCCH2NH3OOCCH3
32 The repeating unit of a polymer is shown below. Which of the following statements is not
true of the polymer?
A It is elastic.
B It is thermally stable.
C It can be vulcanised.
D Its monomers are CH=CH2 and CH2 = C(CH3)CH=CH2

33 Which graph most accurately depicts the change in boiling points of the elements from
sodium to chlorine in Period 3?
A B
Boiling point Boiling point
I I I I I I I I I I I I I I
Na Mg Al Si P S Cl Na Mg Al Si P S Cl
C D
Boiling point Boiling point
I I I I I I I I I I I I I I
Na Mg Al Si P S Cl Na Mg Al Si P S Cl
34 The relative molecular mass of aluminium chloride at room temperature is 267. Which of the
following represents the structural formula of aluminium chloride at that temperature?
[Relative atomic mass: Al = 27, Cl = 35.5 ]

35
The diagram above displays the molecule of an organic compound. What is this molecule?
A Silicate
B Silicone
C Kaolin
D Pyrosilicate
36 Germanium has a structure similar to that of diamond.
Which statement about germanium is not true?
A .Germanium is a metalloid
B Germanium is softer than diamond
C Germanium is a poorer conductor of electricity than silicon.
D The Ge — Ge bond length is longer than the C — C bond length..

37
Density
Pressure Ammonia gas
Ideal gas
Pressure
In the graph above, why does the value of density for ammonia gas increase with pressure?
Pressure
A There are hydrogen bonds between ammonia molecules.

B Ammonia gas is difficult to compress.
C There is repulsive force between the molecules when the pressure increases.
D Ammonia gas decomposes when a high pressure is applied.
38 Compound K is an important raw material in the field of agriculture because it can be

oxidised to compound L. Compound L can be used in the making of fertiliser M. What are
probable compounds of K, L and M?
K L M
A NO2 HNO3 NH4NO3
B HNO2 HNO3 KNO3
C NH3 HNO3 Ca(NO3)2
D SO2 H2SO4 BaSO4
39 The reaction between chlorine and aqueous sodium hydroxide can be represented by the
equation.
3Cl2(g) + 6NaOH(aq) → NaC1O3(aq) + 5NaC1(aq) + 3H2O(l)
Which statement is not true concerning the above reaction?
A Dilute NaCl solution is used in the reaction.

B The reaction occurs under warm conditions.
C The chlorine molecule undergoes disproportionation.
D The highest oxidation state of chlorine is found in NaClO3.

40 Which ligand is not a monodentate ligand?

Section B
For questions 41 through 50, one or more of the three numbered statements 1 to 3 may be correct.
Decide whether each of the statements is or is not correct. The responses A to D should be selected
on the basis of the following.
A B C D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2 and 3 are
correct. correct. correct.
41 The vapor pressure of a liquid in a closed container depends on the
1 temperature
2 volume of the vapor
3 the amount of liquid present
42 Silicon carbide has a similar structure to diamond. Which of the following are advantages of
using a silicon carbide ceramic compared with steel?
1 Silicon carbide has a higher melting point

2 Silicon carbide is more resistant to oxidation
3 Silicon carbide is less likely to deform under compression
43 Which of the following in aqueous solution do not considerably change in pH when relatively
small volumes of strong acid or strong alkali are added?
1 A mixture of sodium carbonate and sodium hydrogencarbonate

2 A mixture of sodium ethanoate and ethanoic acid
3 A mixture of sodium sulphate and sodium chloride
44 The energy level diagram for the combustion of methane is given below.
C(s) + 2H2(g) + 2O2(g)
+74.8 kJ mol-1 -393 kJ mol-1

CH4(g) + 2O2(g)
CO2(g) + 2H2(g) + O2(g)
-571.4 kJ mol-1
CO2(g) + 2H2O(l)
Which of the following statements are correct regarding the above reactions?
1 The enthalpy of combustion of methane is +890.0 kJ mol-1

2 The enthalpy of formation of methane is -74.8 kJ mol-1
3 The enthalpy for the reaction H2O(l) → H2(g) + ½ O2(g) is +285.7 kJ mol-1

45 A liquid X decolourises bromine water and reacts with aqueous argentum nitrate. The
precipitate formed is white in colour. X could be
1 CH2 = CHCH2Br
2 — CH2CH2Br
3
— CH = CH2
Br
46 A chemical substance shown below is secreted by the queen bee.
CH3CO(CH2)5CH = CHCO2H
With regards to the above compound structure, which of the following statements are true?
1 It can exist as a cis-trans isomer.

2 It provides a positive iodoform test.
3 It provides a positive test with Fehling’s solution.
47 What could the product form when the below organic compound is refluxed with excess
aqueous sodium hydroxide?
HOOC — — OCOCH3
1 CH3COONa
2
Na+O- — C — — O-Na+
‫װ‬
O
3
Na+O- — C — — OH
‫װ‬
O

48 Pentaerythritol is an intermediate used in the manufacture of paint and has the structural
formula as follows:
CH2OH
HOH2C C CH2OH
CH2OH
Which statement(s) is/are true of pentaerythritol?
1 It is a monomer for a cross-link polymer.

2 It reacts with SOCl2.
3 It can be dehydrated to an alkene.
49 Which compound(s) and reagent(s) with reaction condition(s) react to form a compound with
halogen atoms attached directly to its benzene ring?
Compound Reagent/Reaction
condition
1 Br2/Fe
2 Cl2/Light
3 I2/NaOH, ∆
50 A metal reacts when heated with dry chlorine and with dry hydrogen chloride to form
different solid products. Which metals behave this way?
1 Iron
2 Lead
3 Magnesium
END OF QUESTION PAPER

CONFIDENTIAL*
Name : ………………………………………………… NRIC : …………………………
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJAR

JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU TRIAL
JABATANPELAJAR
962 / 2
STPM 2010
JABATAN PELAJARAN TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
TERENGGANU
TRIAL STPM 2010
CHEMISTRY TERENGGANU JABATANPELAJAR
JABATAN PELAJARAN ERENGGANUJABATANPELAJARAN
PAPER 2
STRUCTURE AND ESSAY
Two and a half hours
JABATAN PENLAJARAN ERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
Instructions to candidates :
For examiner’s use
Answer all the questions in Section A in the Section Marks Marks
spaces provided. Obtained
Answer any four questions from section B. 1 10
For this section, write your answers on the
2 10
answer sheets provided. Begin each
answer on a fresh sheet of paper. Answers A 3 10
should be illustrated by large, clearly 4 10
labeled diagrams wherever suitable. 40
Answers may be written in either Malay or 5 15
English.
6 15
Arrange your answer in numerical order
and tie the answer sheets to this booklet. B 7 15
8 15
A Data Booklet is provided 9 15
10 15
60
TOTAL 100
This question paper consists of 14 printed pages
STPM 962/2 [Turn over

*This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*
CONFIDENTIAL * 2
Section A (40 marks)

Answer all questions in this section.
1 A real gas X behaves almost like an ideal gas. For n mol of gas X at pressure p, the graph of
volume V versus temperature T is shown below.
V/cm33
Volume V/cm
60
50
40
30
20
10
0
-300 -200 -100 0 100 200
Temperature T/0C
(a) (i) What is the most probable identity of gas X? Explain your answer.
Gas X :
…………………………………………………………………………………………………..
Explanation:
…………………………………………………………………………………………………...
…………………………………………………………………………………………………...
…………………………………………………………………………………………………..
[3 marks]
(ii) On the graph above, sketch and label a graph of variation in volume with
temperature at a lower pressure p’ while other conditions remain constant.
[1 mark]
(iii) At pressure p and temperature 0 oC, a gas Y shows a negative deviation from
an ideal gas. Mark the expected volume of gas Y on the graph above.
[1 mark]
TRIAL STPM 962/2 2010 [Turn over

CONFIDENTIAL * 3
(b) The mass spectrum of naturally occurring magnesium is given below:
Relative abundance
1 1
24 25 26 Relative isotopic
mass
(i) What is the ions that are responsible for the peaks at positions 25.
………………………………………………………………………………………….
[1 mark]
(ii) Deduce the atomic structure of each isotope and calculate the relative
atomic mass of magnesium.
[4 marks]

CONFIDENTIAL * 4
2 (a) Chrome yellow has been used for a long time as a yellow pigment in oil paintings.
SO42- (aq) + 4H+ (aq) + 2e 2H2O(l) + SO2 (g) E0 = +0.17 V
CrO42-(aq) + 8H+(aq) + 3e 4H2O(l) + Cr3+(aq) E 0= +1.33V
(i) By using the standard electrode potentials above, explain why the yellow
colour of the painting exposed to an atmosphere contains sulphur dioxide.
[2 marks]
(ii) Explain why this colour change takes a long time.
………………………………………………………………………………………….
…………………………………………………………………………………………
[2 marks]
(iii) What colour change takes place?
…………………………………………………………………………………………
[1 mark]
(b)
(i) By using this cycle, calculate the lattice energy of lithium chloride.
[2 marks]

CONFIDENTIAL * 5
(ii) Entalphy change of hydration of Li+ ion = -519 kJ mol-1

Entalphy change of hydration of Cl- ion = -364 kJ mol-1
Hence, calculate the enthalpy change of solution for lithium chloride.
[2 marks]
(iii) Comment on the solubility of lithium chloride in water.
………………………………………………………………………………………….
………………………………………………………………………………………….
[1 mark]
3 (a) The amino acid; tyrosine, lysine and glycine are constituents of many proteins.
Their structural formulas are shown below.
O
O O
H2N—CH—C—OH
CH2 H2N—CH—C—OH H2N—CH—C—OH
(CH2)4 H
NH2 Glycine
OH Lysine
Tyrosine
(i) Draw an asterisk on each chiral centre on the above molecules and state the
reagents and conditions to break down proteins into amino acids.
[2 marks]
(i) Amino acids exist as zwitterions in aqueous solution. Draw the zwitterionic
structure of each molecule.
[3 marks]
CONFIDENTIAL * 6
(b) The formula of part of chain of a synthetic polyamide is shown below.
—CH2—O—CO− −CO—O—CH2—CH2—O—CO− −CO—O—CH2—CH2—O—
(i) Identify, draw and give the name for the repeating unit of the polymer.
[2 marks]
(ii) Draw and give the names the structure of two monomers from which the
polymer could be made.
[2 marks]
(iii) Name the type of polymerisation involved.
………………………………………………………………………………………….
[1 mark]
4 (a) A Group 14 element forms a divalent ion that decolourises aqueous acidified
potassium manganate (VII)
(i) Name the element
………………………………………………………………………...………………..
[1 mark]
(ii) Write the equation for the reaction between the ion and acidified
manganate(VII) ion
……………………………………………………………………………………...…..
[1 mark]
(b) Nitrogen exists in the atmosphere as the N2 molecules. Nitrogen is inert.
(i) Explain the inertness of nitrogen.
……...………………….……………………………………...………………………
……...…………………………………………………………...…………………….
[1 mark]
(ii) Give two examples (other than the Haber process) of reactions involving
atmospheric nitrogen.
……...……………………………………………………………...………………….
…….…...…………………………………………………………………...…………
……...…………………………………………………………………………………
CONFIDENTIAL * 7
[2 marks]
(c) In the laboratory, nitrogen is prepared by heating a mixture of ammonium chloride
and sodium nitrate(III).
(i) Write a balanced equation to represent the action of heat on the mixture.
……….…………………………………………………………………………………
[1 mark]
(ii) State the changes in oxidation states of nitrogen in the reaction.
……….………………………………………………………………………...……….
……….………………………………………………………………………………....
[1 mark]
(iii) Nitrogen is also produced by heating solid ammonium nitrate(III).
Explain why this method is considered dangerous.
………………………………………………………………………………………….
[1 mark]
(d) Why is the presence of nitrogen oxides in air polluting?
………..………………………………………………………………………………….………
[1 mark]
(e) Describe how oxides of nitrogen are eliminated from the exhaust gas by the use of a
catalytic converter.
…...……..……………………………….……………………………………………………….
………..………………………………………………………………………………………….
[1 mark]

CONFIDENTIAL * 8
Section B [ 60 marks ]
Answer any four questions in this section.
5 (a) The line spectrum of atomic hydrogen in the ultraviolet region of the electromagnetic
spectrum is shown below:
Frequency
(i) Explain why this spectrum consists of lines which are convergence.
[2 marks]
(ii) Using a labeled energy level diagram, show how the line marked Y on the
spectrum is formed.
[2 marks]
(iii) If the frequency of convergence limit in Lyman Series is 3.24  1015 Hz,
calculate the ionisation energy of hydrogen atom in kJmol-1.
[Planck constant, h = 3.99  10-13 kJ s mol-1]
[2 marks]
(iv) Write an equation of ionisation hydrogen atom.
[1 mark]
25
(b) (i) Write the electronic configuration of the isotope of magnesium, Mg2+
12
25
and draw all the orbitals for the Mg2+
12
[4 marks]
(ii) The variation in melting point of the oxides of elements in Period 3 of the
Periodic Table is shown below:
Melting
Point/0C
Na Mg Al Si P S
Explain the variation in melting point in terms of structure and bonding.

CONFIDENTIAL * 9
[4 marks]
6 (a) Diagram below shows the valence and conduction band in a conductor and
semiconductor.
(A) (B)
conductor semiconductor
(i) Give one element for each diagram above.

[2 marks]
(ii) By using the band theory, explain what happened when electrical potential is
applied to the metal.
[3 marks]
(iii) Based on diagram (A) and (B), state which one is lower in electrical
conductivity. Name the process to improve the electrical conductivity.
[2 marks]
(b) Hydrogen peroxide, H2O2 is a strong oxidising agent. It is used as a bleaching agent
for cloth and hair. The structural formula of hydrogen peroxide is HOOH.
(i) Draw the Lewis structure of hydrogen peroxide.

[1 mark]
(ii) State the hybridisation of the oxygen atoms in hydrogen peroxide.
[1 mark]
(iii) Predict the molecular shape of hydrogen peroxide with respect to oxygen
atoms. Draw the molecular structure for hydrogen peroxide.
[3 marks]
(c) The mechanism of the oxidation of iodide ion by hydrogen peroxide in the presence
of acid is suggested below.
slow
- -
H2O2 + I → H2O + IO
fast
+ -
H + IO → HIO
fast
+ -
HIO + H + I → H2O + I2
(i) Write the overall equation for the reaction above. [1 mark]
(ii) Write the rate equation for the reaction above. [1 mark]
(iii) What is the overall order of the reaction above. [1 mark]

CONFIDENTIAL * 10
7 (a) (i) What is meant by dynamic equilibrium? [2 mark]
(ii) For the reversible reaction :
N2(g) + 3H2(g) 2NH3(g)
Ammonia is produced in an equilibrium mixture at temperature of 400 0C and

pressure of 3 x107 Pa, when hydrogen and nitrogen are mixed in the mole ratio of
3:1.Under these conditions, 61 % of nitrogen are converted to ammonia.
At equilibrium, 0.39 mol of nitrogen gas, 1.17 mol hydrogen gas and 1.22 mol of
ammonia are formed.
Calculate the partial pressure equilibrium constant, Kp for the reaction. [3 marks]
(b) (i) A buffer solution is prepared by dissolving 1.0 mol of propanoic acid and
1.0 mol of sodium propanoate in water and the solution is made up to
1.0 dm3. Calculate the pH of this buffer solution. [3 marks]
(The acid dissociation constant, Ka of propanoic acid (CH3CH2COOH) =

1.30 x 10-5 mol dm3.)
(ii) Calculate the pH of the buffer solution when 0.10 mol of barium hydroxide
Ba(OH)2, is added to it. [3 marks]
(c) Two liquids A and B form an ideal mixture. A mixture of 70% of A and 30% of B is
fractionally distilled at a temperature of 373 K, at which temperature of the vapour
pressure of pure A is 48 kPa and of pure B is 36 kPa.
(i) What is the total pressure inside the distillation apparatus. [2 marks]
(ii) What is the composition of the first distillate. [2 marks]
8 (a) State two different substances in everyday or industrial use that contain chlorine.
For each of these substances state its use and explain briefly how the use is related to
the property of the substance.
[6 marks]
(b) Explain the stability trend of the +2 and +3 oxidation states for the transition elements.
[3 marks]
(c) What do you understand by the term transition elements and explain why scandium and
zinc are not transition elements.
[6 marks]
9 (a) (i) Write the mechanism of the reaction when 1-chloropropane is refluxed with
aqueous sodium hydroxide. Name the type of reaction involved.
[3 marks]
(ii) State and explain how the rate of this reaction changes when 1-chloropropane
is replaced by 1-bromopropane.
[3 marks]
(iii) Write the equations to show how you would change 1-chloropropane to
2-chloropropane.

CONFIDENTIAL * 11
[5 marks]
(b) Catalytic cracking is a process where long chained alkanes are broken into mixture of
short chained molecules.
(i) Explain the importance of the catalytic cracking process in industries.
[2 marks]
(ii) State the conditions required for this process.
[2 marks]
10 Five organic compounds, A to E, have the molecular formula of C5H10O. Compounds A, B

and C can react with 2,4-dinitrophenylhydrazine, but not with Fehling’s solution. Only A and
B give a positive iodoform test. A has a higher boiling point than B. Compounds D and E
give a reddish-brown precipitate, P, with Fehling’s solution. D is optically active. Reduction
of E gives a straight chain compound, F.
(a) Based on the information above, identify compounds A to F.
[7 marks]
(b) Identify and name compound P.
[2 marks]
(c) Write the chemical equations for the reactions above, involving different reagents.
[6 marks]
THE END OF THE QUESTIONS

CONFIDENTIAL * 12
DATA BOOKLET

CONFIDENTIAL * 13

CONFIDENTIAL * 14

Name : ………………………………………………… NRIC : …………………………
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA

TRIAL JABATANPELAJA
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU STPM
962/1 2010
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN
JABATAN PELAJARAN TERENGGANU JABATANPELAJA
NEGERI TERENGGANU
JABATAN PELAJARAN TERENGGANUJABATANPELAJARAN
TRIAL EXAMINATIONTERENGGANU 2010 JABATANPELAJA
CHEMISTRY
PAPER 1 & 2
MARKING SCHEME
This answer paper consists of 17 printed pages
TRIAL STPM 2010 2 STPM
STPM CHEMISTRY 962/1

OTI 2 2010
MARKING SCHEME PAPER 1
Question Answer Explanation

No.
1 A
2 B 2NaN3 2Na + 3N2

1 mol 3/2 mol
Volume of N2 = 3/2 x 24
= 36 dm3
3 B To condense a gas at room temperature, its critical temperature must be

higher than the room temperature.
4 D The large difference between the 6th and 7th ionization energies, indicating
that the 6th and 7th electrons are from different principal quantum shells.
Hence, X is a group 16 element, i.e. O or Te. However from the data
booklet, the data do not fit into O. Hence, X is Te
5 D Electron furthest away from the nucleus is removed first. Hence, the
electrons in Ga are removed in the order 4p,4s,4s,3d
6 B B is in Group 13 and P is in Group 15. Bonding with 3 Cl atoms leaves B

with a vacant p orbital (no lone pair) and p with a filled sp3 orbital (no lone
pair). By using VSEPR, BCl3 is trigonal planar and PCl5 is trigonal
pyramidal.
7 D Due to the presence of hydrogen bonding in ice, the H2O molecules take up
an open structure and hence ice becomes less dense than water at 0oC.
8 D In metallic copper, metallic bonds exist. The mobile electron cloud accounts
for the electrical conductivity. In the presence of an electric potential, the
electrons flow from the negative potential to the positive potential.
9 C Let the number of atoms in G and H be 4x and x respectively.

5 min 5 min 5 min
G : 4x 2x x ½x
15 min
H: x ½x
10 C When the pressure is doubled (e.g. by halving the volume), [X] and [Y] are
doubled. Since the reaction is second order with respect to X, therefore, the
rate increases by 4 times.
11 B When the enthalpy change is zero, changing temperature will not shift the
equilibrium. Hence, the equilibrium constant remains unaffected.
12 C At equilibrium, the no.of moles of CaO & CO2 will be the same. Only part of
CaCO3 decomposed. The pressure in the vessel increases gradually and
becomes constant.
Marking scheme TRIAL STPM 2010

No.
13 C PbCl2 Pb2+ + 2Cl-
Ksp = [Pb2+] [Cl-]2
14 B Boiling point of liquid is defined as the temperature at which the vapour
pressure of the liquid is equal to the atmospheric pressure (1 atm). From the
phase diagram (the upper line refers to the liquid while the lower curve
refers to the vapour), the vapour pressure of mixture n is equal to the
atmospheric pressure (1 atm) at temperature T.
Hence, the boiling point of n is T. Mixture m and mixture o do not fall on
any line in the phase diagram at 1 atm. It only shows that the vapour
pressure of mixture m is more than 1 atm at temperature T, while the vapour
pressure of mixture n is less than 1 atm at temperature T.
Vapour
pressure (atm)
liquid
vapour p. of
mixture m at 1.0 w
temp. T vapour
vapour p. of
mixture o
at temp. T
0 0.5 1
m n o
D is more volatile than C. Hence, the vapour composition of mixture n

would contain more D as shown by point w above.
15 B The number of chemicals in blood is large. Only Gas-liquid

chromatography has the required resolution to distinguish between them.
16 A Possible reactions at the anode are :

4OH- (aq) → 2H2O (l) + O2 (aq) + 4e- Eθ = -0.40 V
2+
Cu (s) → Cu (aq) + 2e -
Eθ = -0.34 V
The second reaction with a more positive (less negative) Eθ will occur in
preference to the first reaction.
Possible reactions at the cathode are :

2H+ (aq) + 2e- → H2O (g) Eθ = 0.00 V
Cu2+ (aq) + 2e- → Cu (s) Eθ = +0.34 V
θ
The second reaction with a more positive E value will take place in
preference to the first reaction.
17 B No. of moles of Y produced = 2.07 = 0.010 mole

207

No.
No. of moles of Z produced = 1.60 = 0.020 mole
80
Ratio of Y : Z = 1 : 2
Therefore, Empirical formula = YZ2
18 B The enthalpy of atomization is the heat change when one mole of free
gaseous atoms is produced from its element under standard conditions.
Under standard conditions, magnesium is a solid.
19 D CH3OH + 3O2 → CO2 + 2H2O ∆H = -715

2
∆Hf : a 0 -394 2(-286)
Therefore, (-394) + 2(-286) - a = -715

a = -251 kJ mol-1
Note :
∆H = (sum of heat of formation of products) - (sum of heat of formation of
reactants)
20 C An electrophile is a reagent that attacks centres of rich electron density. For

example, the carbon atoms joined by a double bond.
+
CH3CH = CH2 + HBr → CH3 — CH — CH3 + Br-

+
CH3 — CH — CH3 + Br- → CH3CHBrCH3
21 A No. of moles of CO2 = 0.132 = 0.003

44
No. of moles of carbon atoms = 0.003 moles
No. of moles of H2O = 0.045 = 0.0025

18
No. of moles of hydrogen atoms = 0.0025 x 2
= 0.005 moles
Ratio of C : H = 3 : 5
Hence, empirical formula of the alkene is C3H5
Compound A B C D
Molecular formula C6H10 C9H16 C12H22 C12H22
Empirical formula C3H5 C2H3.6 C3H5.5 C3H5.5
22 C Catalytic reformation is a process whereby alkanes and cycloalkanes are

converted to molecules of arenes (hydrocarbon containing benzene ring) by
means of heat, pressure and a platinum catalyst.

No.
23 C AlCl3 + Cl2 → Cl+ + AlCl4-
Cl+ + —Cl → Cl
+ H+
\
Cl
The Cl+ acts as an electrophile.
24 B Y reacts with water showing that it is an acyl chloride. In fact, acyl chloride
fumes in moist air due to the release of HCl gas.
CH3COCl + H2O → CH3COOH + HCl

CH3COCl + C2H5OH → CH3COOC2H5 + HCl
CH3COCl + C6H5OH → CH3COC6H5 + HCl
25 D OH
|
H — C — CH3
|
D is an alcohol with structure of
Although A (a ketone) also gives a yellow precipitate with alkaline iodine, it

is not oxidized by KMnO4.
B is a tertiary alcohol and is resistant to oxidation.
26 B The release of HCl shows the presence of the —OH group. Reduction to
primary alcohol indicates the presence of —COOH.
PCl5 Reduction
CH3COCH3 No reaction Reduction to secondary alcohol
C6H5COOH C6H5COOH + PCl5 C6H5COOH + 4[H] →
→ C6H5COCl + C6H5CH2OH + H2O
HCl + POCl3 (1o alcohol)
CH3COOC6H5 No reaction O
‫װ‬
C6H5C—O—CH3 + 4[H] →
OH
|
C6H5C—H + CH3OH
|
H
(CH3)3COH HCl liberated Cannot be reduced
27 B (i) The compound must have – C – OH as it reacts with NaHCO3.

(ii) The compound must be a primary amine as it gives off N2 with HNO2
RNH2 + HNO2 → ROH + N2 + H2O

No.
(iii) The compound must have –OH or –COOH group as it reacts with PCl5
forming white fumes, HCl.
28 D Decolourises bromine water → alkene
Number of moles of NaOH = 0.02
Number of moles of acid = 1.16
Mr
0.02
If acid is monobasic → ——– = 1
1.16
Mr
→ Mr = 58 ≠ Mr of (C)
I f acid is dibasic = 0.02 = 2
1.16
Mr
→ Mr = 116 = Mr of (D)
29 B Ethanamine, CH3CH2NH2, is a base. Hence it doesn’t react with alkali.
30 D –COOH is the acidic group. It can react with an alcohol.
31 B Glycine, NH2CH2COOH, has a base and acid group.

The acid group reacts with NaOH forming structure A.
The base group can react with HCl forming structure C.
The base group can also react with CH3COOH forming structure D.
B is formed when the acid group reacts with alcohol forming an ester by the
condensation process
32 B The polymer is a addition copolymer. Its monomers are
Since the polymer has a double bond, it is elastic and can be vulcanised. It is
not thermally stable.
33 D The boiling point of the elements increases from Na to Al as the strength of

the metallic bond increases. It reaches its maximum in Si which a giant
covalent molecule with strong covalent bonds. However, P, S and Cl are
simple covalent molecules with weak van der Waals forces attraction
between molecules resulting in low boiling points.
The boiling point of S is higher than those of P and Cl because the S
molecule is larger than the P4 and Cl2 molecules. As the van der Waals
forces in S8 are larger, the larger point of S8 is higher.

No.
34 D At room temperature, aluminium chloride exists as a dimer, Al2Cl6. The
availability of vacant orbitals in aluminium allows the aluminium ion to
receive a lone pair of electrons from chlorine to form dative bonds.
35 D Silicone is a type of organosilicon polymer. It contains Si—O bonds. The

structure of silicone is as follows.
(R is an alkyl group such as CH3, C2H5).
36 C Germanium is a better conductor of electricity than silicon.
Electrical conductivity/Ohm-1 m-1

Si 2.52 x l0-4
Ge 1.45
37 A When pressure increases, NH3 molecules are close to one another. Therefore,
more hydrogen bonds form between molecules of NH3. As such ammonia
shows deviation from ideality.
38 C NH3 (that is, K) is a very important raw material in the manufacture of
fertilisers.
When NH3 is oxidised (Ostwald’s Process) and dissolved in water, nitric
acid, HNO3 (that is, L) is produced.
[0] [0]
NH3(g) → NO(g) → NO2(g)
4NO2(g) + 2H2O(l) + O2(g) → 4HNO3(aq)
Nitric acid is reacted with Ca(OH)2 to form the fertiliser Ca(NO3)2
(that is, M).
2HNO3 + Ca(OH)2 → Ca(NO3)2 + 2H2O
39 A Chlorine gas that reacts and not dilute NaCl solution. In fact, NaCl is
produced in the reaction. Therefore, dilute NaC1 solution is not used in the
reaction.
40 D Ethanedioate ions are bidentate ligands.
41 A(1) The vapor pressure of a liquid in a closed container depends on the

temperature, not the volume of the vapor nor the amount of liquid present.
42 D(1,2,3) Having a diamond structure with strong covalent bonds between Si and C
atoms, SiC has a high melting point, is resistant to corrosion and less likely
to deform under compression. Its physical properties are similar to those of
diamond.
43 B(1,2) A buffer solution does not considerably change pH when a relatively small
volumes of strong acid and strong alkali are added. It usually contains a
mixture of a weak acid and its conjugate base, or a weak base and its
conjugate acid. A mixture of sodium sulphate nad sodium chloride has no
buffering capacity.

No.
44 C ∆Hformation of CH4 : C(s) + 2H2(g) → CH4(g) ∆H = -74.8 kJ mol-1
H2O(l) → H2(g) + ½ O2(g) ∆H = ½ (+571.4)
(2 and 3)
= +285.7 kJ mol-1
The heat of combustion is always exothermic.
C + 2H2 + 2O2 -393.4 CO2 + 2H2 + O2
+74.8 -571.4
CH4 + 2O2 a CO2 + 2H2O
Therefore, a = 74.8 – 393.4 – 571.4 = -890.0 kH mol-1
45 A Decolourisation of bromine water indicates the presence of the C = C double

bond. Formation of a white precipitate with aqueous argentum nitrate shows
(1 only)
that the chlorine atom is not bonded directly to the benzene ring.
46 B This molecule does not give a positive reaction with Fehling’s solution
(1 and 2) because it is not an aldehyde. This molecule has a group
O
‫װ‬
CH3 —C —, thus it will provide a positive iodoform. This molecule exists
as a cis-trans isomer.
H H H COOH
\ ⁄ \ ⁄
C=C C=C
⁄ \ ⁄ \
CH3CO(CH2)5 COOH CH3CO(CH2)5 H
cis trans
47 B O O
(1 and 2) ‫װ‬ ‫װ‬
HO — C — — O— C — CH3 + 3NaOH →
O O
‫װ‬ ‫װ‬
Na+O- — C — — O-Na+ + Na+O- — C — CH3 + 2H2O
48 B It can form cross-link polymers, similar to the formation of bakelite from

phenol and methanal. The – OH group reacts with SOCl2. It cannot be
dehydrated to alkene when heated with concentrated sulphuric acid because
the C atom with the OH is bonded to the C atom without a H atom, thus H2O
cannot be formed.
49 A The reaction is an electrophilic substitution reaction of the aromatic nucleus.
50 A In dry chlorine, 2Fe(s) + 3C12(g) —, 2FeCl3(s)

In dry hydrogen chloride, Fe(s) + 2HC1(g) — FeC12(s) + H2(g)
END OF MARKING SCHEME
Name : ………………………………………………… NRIC : …………………………

962/1&2
JABATAN
TRIAL STPM
PELAJARAN TERENGGANUJABATANPELAJARAN TERENGGANU JABATANPELAJA
JABATAN PELAJARAN
TERENGGANU
TRIAL STPM 2010
CHEMISTRY
PAPER 1 & 2
MARKING SCHEME
This answer paper consists of 19 printed pages
Trial stpm 2010 9 STPM
STPM CHEMISTRY 962/1

TRIAL/ OTI 2 2010
MARKING SCHEME PAPER 2
SECTION A ( Structured Question )
QUESTION SUGGESTED ANSWERS SUGGESTED

NO MARKS
1(a)(i) Gas X is hydrogen // 1
Gas X is helium Any one
Explaination:The molecular size of H2 (or atomic size for He) is small 1
Hence only weak intermolecular van der Waals forces occur//exert no
force of attraction between particles. 1
1(a)(ii)
1(a)(iii) Volume
V/cm3
60
50
40
30
(iii) Y
20
1+1
10
00 -300 -200 -100 0 100 200

TemperatureT/0C
25
1(b)(i) Mg+
1
1(b)(ii) No of protons = 12
Number of neutrons = 12, 13 and 14 respectively. 1
1
( 2 or 3 answer
Ar of magnesium = correct)
1
= 24.3
1
Total 10 marks
Marking scheme trial stpm2010http://edu.joshuatly.com/


NO MARKS
2(a)(i)
2CrO42-(aq) + 16H+(aq) + 6e 8H2O(l) + 2Cr3+(aq) E 0= +1.33V
6H2O(l) + 3SO2(g) 3SO42-(aq) + 12H+(aq) + 6e E 0= -0.17V
2-
2CrO42-(aq) + 4H+(aq) + 3SO2(g) 2H2O(l) + 3SO4 (aq) + Cr3+(aq)
1+1
∆ E 0= +1.16V
Sulphur dioxide reduces chromate(VI) to chromium ion
2(a)(ii) Concentration of sulphur dioxide in the air is very low,hence low rate of
1+1
reaction.
2(a)(iii) Yellow to green 1
2(b)(i) -409 = (+159) + (+520) + (+121) + (-346) + ∆H6

1+1
:. Lattice energy (∆H6) = -845 kJmol-1
2(b)(ii) Enthalpy change of solution
= - Lattice energy + Enthalpy change of hydration

1+1
= -(-845) + (-519) + (-364)
= -38kJmol-1
2(b)(iii) Lithium chloride is expected to dissolve readily in water because the

1
dissolving process is exothermic.
Total 10 marks


NO MARKS
O O
3(a)(i)
H2N—CH—C—OH
* H2N—CH—C—OH
*
CH2 (CH2)4
NH2
1
Lysine
OH
Tyrosine
Boiling with a dilute mineral acid such as hydrochloric acid
1
OR
Boiling with an aqueous solution of an alkali such as sodium hydroxide
3(a)(ii) O O
O
+ -
1
H3N—CH—C—O +
H3N—CH—C—O -
+
H3N—CH—C—O-
+
CH2 (CH2)4
H
1
NH2
Glycine
+
Lysine
OH 1
Tyrosine
3(b)(i) 1
―—CO− −CO—O—CH2—CH2—O—―
n +
Terylene/Polyester/Dacron 1
3(b)(ii)
HOOC− −COOH 1
Benzene-1,4-dioic acid
HO—CH2—CH2— NH—OH 1
Ethane-1,2-diol
3(b)(iii) Condensation polymerisation 1
TOTAL 10 marks


NO MARKS
4(a)(i) Tin / Stanum 1
4(a)(ii) 5Sn2+ + 2MnO4 -- + + 16H+ → 2Mn2+ + 5Sn4+ + 8H2O 1
4(b)(i) High heat of atomization / high bond energy of the N≡N bond 1
4(b)(ii) Nitrogen fixation by bacteria 1
Production of nitrogen oxides by car engine or lightning 1
4(c)(i) NH4Cl(s) + NaNO2(s) → N2(g) + NaCl(s) + 2H2O(l) 1

4(c)(ii) From -3(in NH3) and +3(in NO2--) to zero(in N2) 1
4(c)(iii) The reaction is explosive 1
4(d) It contributes to acid rain 1
4(e) Oxides of nitrogen are reduced to nitrogen 1
Total 10 marks

SECTION B

NO MARKS
5(a)(i) Lines occur because the atoms have fixed energy levels and 1
transitions between an upper energy level and lower one cause
emission of light;
The series of lines corresponds to transitions from higher energy 1
levels to energy level of n = 1; or
The energy levels get closer together as the energy increases, so 1
the lines converge.
5(a)(ii) n=∞
Energy
n=5
n=4
n=3
n=2
n=1
Labelled the energy axis and the energy level n =1,2,3 ….. 1
Draw the energy levels closer together with increasing the value
of n.
1
An arrow from n=3 to n=1
5(a)(iii) E = hf = (3.99  10-13)  (3.24 1015) 1
= 1.29  103 kJ mol-1 1
5(a)(iv) H(g) → H+(g) + e 1
5(b)(i) y
25
Mg2+ : 1s2 2s2 2p6 1 + 1
x 12
z 2s
y y y
2
x or x or x
z z z
2px 2py 2pz
5(b)(ii) Na2O, MgO and Al2O3 ionic oxides with ionic bond. 1
Al2O3 has a lower melting point than MgO because it has an 1
ionic bond with covalent character.
SiO2 has a giant covalent structure with strong covalent 1
bonds.
SO2 have simple molecular structures with weak van der 1
Waals forces between the molecules.
Total 15 marks


NO MARKS
6(a)(i) A( conductor) - Iron/ Zinc/Copper or any metal. 1
B(Semiconductor) - Silicon/Germanium/Boron 1
6(a)(ii) When an electrical potential is applied to the metal,
the valence electrons jumps to the conduction band 1
and free to move in the conduction band, 1
Metal can conduct electricity/metal are good conductors of 1
electicity.
.. ..
6(b)(i) H–O–O–H 1
.. ..
6(b)(ii) sp3 1
6(b)(iii) V-shaped/bent/bend or see the diagram 1
Because of the presence of 2 lone pairs and 2 bond pairs of 1
electrons on an oxygen atom /shown in diagram
1
H–O
O–H
6(c)(i) H2O2 + 2H+ + 2I- → 2H2O + I2 1
6(c)(ii) Rate = k[H2O2][I-] 1

6(c)(iii) The overall order of the reaction is second order 1
Total 15 marks
Dynamic equilibrium is the stage where the rate of the forward
7(a)(i) reaction is equal to the rate of the reverse reaction, and the amount 1
of substances does not change with time.
7(a)(ii) N2(g) + 3H2(g) 2NH2(g)At

At eqm(mol) 0.39 1.17 1.22
Total number of moles = 0.39 + 1.17 + 1.22 = 2.78 mol 1+1
Partial pressure of NH3

= 1.22 X 3 X 107 = 1.32 x 10 7 Pa
2.78
Pressure of N2(g) + H2(g)
= ( 3 x 107 - 1.32 x 107) = 1.68 x 10 7 Pa 1+1+1
Therefore Partial pressure of N2(g)

= 1.68 x 107 x ¼ = 0.42 x 107 Pa
Therefore Partial pressure of H2
= ¾ x (1.68 x 107 ) = 1.26 x 107 Pa
Therefore Kp = (1. 32 x 107 )2
(0.42 x 107) x (1.26 x 107)3 1
-14 -2
= 2.07 x 10 (Pa)


NO MARKS
7(b)(i) PH = -lg Ka + lg [CH3CH2COO-] 1

[CH5CH2COOH]
= -lg 1.30 x 10-5 + lg 1.0
1.0
= 4.89
7(b)(ii) 0.1 mol of Ba(OH)2 produces 0.2 mol of OH- ions 1+1+1
0.2 CH3CH2COOH + OH- → CH3CH2COO- + H2O
[CH3CH2COOH] after reaction = 1.0-1.2
= 0.8 mol dm-3
-
[CH3CH2COO ] after reaction = 1.0 + 0.2
= 1.0 + 0.2 mol dm-3
pH = -lg 1.30 + lg 1.2

0.8
= 4.89 + 0.176
= 5.07
7(c)(i) PA = XA.P0A 1+1+1

= 70 X 48 kPa
100
= 33.6 kPa
PB = XB. P0B
= 30 X 36 kPa
100
= 10.8 kPa
:. Total pressure = 33.6 kPa + 10.8 kPa
= 44.4kPa
7(c)(ii) From Dalton’ s Law 1+1

XA vapour = 1- 0.757 = 0.243
Percentage of A in Vapour phase
= 0.757 x 100%
(0.757 + 0.243)
= 75.7%
Percentage of B in Vapour phase

= 100 - 75.7
= 24.3%
:. The composition of the first distillate is 75.7% of A and 24.3%
of B
Total 15 marks


NO MARKS
8(a) -Sodium chlorate (NaOCl) 1
-It is used as a household bleach 1
-The OCl - ion is an oxidising agent 1
-Chlorofluoro carbons (CCl2F2) 1
-It is used as a propellant in aerosol cans 1
-It is chemically inert and easily liquidified 1
8(b) -Going across the first transition series, the +2 oxidation 1

state becomes more stable compared to the +3 oxidation
state 1
-This is because the third electron removed from the inner
3d 1
subshell that is closer to the nucleus
-As the nuclear charge increases, the ionisation energy also
increases
8(c) An element which forms at least one stable ion where the d
orbitals are partially filled 2
-Scandium forms only Sc3+ 1
-where the d orbitals are empty 1
-Zinc forms only Zn2+ 1
-where the d orbitals are fully filled 1
Total 15 marks
9(a)(i) H CH3CH2 - H
HO: + CH3CH2―C―Cl
-
HO― C ― Cl CH3CH2―C―OH + Cl-
1+1
H H H H
1m 1m
Bimolecular nucleophilic substitution (SN2) 1
9(a)(ii)
The rate of reaction increases because the breaking of C-Br 1
bond needs less energy than that of C-Cl bond. This is due to 1
the length of C-Br bond is less than the C-Cl bond length
1
making it weaker and easier to break.
9(a)(iii) reflux
CH3CH2CH2Cl + NaOH CH3CH2CH2OH + NaCl 1+1
CH3CH2CH2OH conc. H2SO4 CH3CH= CH2 1+1

180°C
CH3CH=
*correct CH2 + HCl
equation, CH3CHClCH
1m; correct reagents and conditions,
3 1m 1
9(b)(i)
Catalytic cracking is used to provide extra petrol and as a 1
source of alkenes for the manufacture of many
petrochemicals. 1
9(b)(ii)
Catalytic cracking is carried out at 450°C using the catalysts 1
silicon (IV) oxide and aluminium oxide. 1
TOTAL 15 MARKS


NO MARKS
10(a) A: CH3COCH2CH2CH3 1
B: CH3COCH(CH3)2 1
1
C: CH3CH2COCH2CH3
D: CH3CH2 CH2CH3
1+1
C C
H CH3 H3C H
CHO CHO
E: CH3CH2CH2CH3CHO 1
1
F: CH3CH2CH2CH2CH2OH
10(b) P is Cu2O, copper (I) oxide 1+1
10(c) NO2
i) CH3COCH2CH2CH3 + H2NNH― ―NO2 →

1+1
CH3 NO2
CH3CH2CH2C=NNH― ―NO2 + H2O
ii) CH3COCH(CH3)2 + 3I2 + NaOH → CHI3 + 1+1
CH(CH3)2COO-Na+ + 3HI
iii) CH3CH2CH2CH3CHO + 2Cu2+ + 5OH- → Cu2O + 1+1
3H2O + CH3CH2CH2CH3COO-
TOTAL 15 MARKS


Terengganu STPM Trial 2010 Chemistry (W Ans) (74F1C1B0)

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Terengganu STPM Trial 2010 Chemistry (W Ans) (74F1C1B0)

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Name : ………………………………………………… NRIC : …………………………

JABATAN PELAJARANTERENGGANUJABATANPELAJARAN TERENGGANUJABATANPELAJAR

DO NOT OPEN THIS BOOKLET UNTIL YOU ARE TOLD TO DO SO.

Read the instructions on the multiple-choice answer sheet very carefully.

This question paper consists of 16 printed pages.

1 Which statement about one mole of a metal is always true?

A It contains the same number of particles as one mole of hydrogen atoms.

3 Which of the following gas cannot be liquefied at room temperature?

Gas Critical Temperature OC

4 The successive ionization energies, in kJmol-1, of an element X are given below

870 1800 3000 3600 5800 7000 13200

1st 2nd 3rd 4th

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

A The boron atom has no d-orbitals available for bonding.

7 Which of the following statements describes a phenomenon which can be explained by

A Copper(II) ions move to the cathode

Radioactive decay is a first-order reaction.

10 For the gaseous reaction: 2X(g) + Y(g) Z(g)

The rate equation is:

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

A All the CaCO3 completely decomposed

13 Identify the solubility product expression for lead (II) chloride.

Which statement is true about the solution which contains C and D?

A Mixture m is a liquid at 1.0 atm.

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

16 The diagram is a set-up for an electrolysis experiment.

What happens at the anode and the cathode?

17 An electrolysis is done on a molten compound consisting of the elements Y and Z at a current

18 Which of the following equations represents the enthalpy of atomization of magnesium?

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

20 Which of the following reactions involves an electrophilic reagent?

A CH3CH3 + Br2 → CH3CH2Br + HBr

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

What is the name of this process?

23 The mechanism for the reaction below is best classified as

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

(i) decolourises acidified potassium permanganate (VII) and

The organic compound G is

What is the compound?

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

[Relative atomic mass of H is 1.0, C is 12.0, O is 16.0]

29 Which reagent does not react with ethanamine?

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

[Relative atomic mass: Al = 27, Cl = 35.5 ]

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

36 Germanium has a structure similar to that of diamond.

Which statement about germanium is not true?

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

A There are hydrogen bonds between ammonia molecules.

38 Compound K is an important raw material in the field of agriculture because it can be

A NO2 HNO3 NH4NO3

B HNO2 HNO3 KNO3

C NH3 HNO3 Ca(NO3)2

D SO2 H2SO4 BaSO4

3Cl2(g) + 6NaOH(aq) → NaC1O3(aq) + 5NaC1(aq) + 3H2O(l)

Which statement is not true concerning the above reaction?

A Dilute NaCl solution is used in the reaction.

STPM 962/1 OTI 2 2010 [Lihat sebelah(Turn over

40 Which ligand is not a monodentate ligand?