Cold Bleaching Process - Archroma

LOW TEMPERATURE
BLEACHING
PROCESS
Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

June 2015, Internal, © 2013 Archroma 1/
Low Temperature Bleaching
– New bleaching process for exhaust application at low temperature based on 2
products
– Due to the increasing costs of energy there is a demand to develop new processes
working at low temperature
– With our Low Temperature
p Bleachinggpprocess we offer the possibility
p y to work at 75°c
instead of 95°C in comparison with a classical bleaching
– A first calculation with the one way tool gives us a saving of about 40% in energy
– Both products are GOTS-Oekotex-Community Ecolabel-Bluesign approved

Temperature (°C)
100
95°C
80 30 min
Drain 80°C
10 min
60
5‘ 10 ‘ Dyeing
40
5 ml/l NaOH 36°Be
0.3
0 3 g/l Bactosol SAP liq c
1 ml/l Imerol JSF
0.5 g/l Sirrix NE
0.5 ml/l Stabilizer SOF
20 5 ml/l H2O2 35%
0
0 20 40 60 80 100 120

LLow TTemperature Bl
Bleaching
hi
100
Process comparison
80
Rincing
Rincing
80 95°C
95°C 75°C
75°C Rincing
60
30
30min
min
ii Neutralizing
Neutralizing 40
40min
min 60°C
60°C
60
10
10 min
min
40
40
20 20
0 0
0 20 40 60 80 100 120 0 20 40 60 80 100 120
Wetting Agent Sirrix NE Imerol LTB Sirrix NE

Bactossol SAP liq c Stabilizer LTB Bactossol SAP liq c
Stabilizer
NaOH
NaOH
H2O2
H2O2

Slide
Imerol LTB Wetting washing emulsifying agent

St bili LTB
Stabilizer Bleaching
Bl hi regulator
l t
Bactosol SAP liq c Broad-band catalase for residual peroxide elimination
Sirrix NE liq Strong and flexible universal neutralizing agent

• High wetting power
Imerol LTB liquid

I
Imerol
l LTB Liquid
Li id is
i a strong
t detergent
d t t and
d wetting
tti agentt specially
i ll designed
d i d for
f jet
j t applications.
li ti
•Alkali stable up to 6°Bé

•Nonionic
•Biodegradable
•Strong detergency • No Foaming behaviour
•High emulsification power between 60 and 80°C in order to remove
fatty substances  high absorbency
0 g/l 1 g/l 2 g/l 4 g/l

Sl
Stabilizer LTB liq
q
Specific Bleaching regulator for alkaline peroxide
bleaching of cotton and its components in fibre
blends. Degree of whiteness CIE
80
70
•High degree of whiteness 60
at low Temperature 50
40
•Prevents catalytic damages 30
(complexes heavy metal ions)
20
•Non-foaming
f 10
0
•Biodegradable Other Stabilizer Stabilizer LTB

June 2015, Internal, © 2013 Archroma 10 /
Sl
Temperature (°C)
80
75°C 60°C
40 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
0.3 g/l Bactosol SAP liq c
6.6 %NaOH 36°Be 1.5 g/l Sirrix NE
20 5.6 %H2O2 50%
1%Imerol LTB
2%Stabilizer LTB
0
0 20 40 60 80 100 120
INTRODUCING A BREAKTHROUGH SUSTAINABILITY SERVICE:
ONE WAY

INTRODUCING A BREAKTHROUGH SUSTAINABILITY SERVICE:
ONE WAY
Archroma’s ONE WAY, introduced in October 2012, helps mills and brand owners to develop
innovative textile solutions that are both more ecologically
g y and economically
y sustainable. Our
ultimate aim is to provide a fast, measurable and reliable approach to the selection of
chemical product and process solutions. ONE WAY METHODOLOGY AND TOOLBOX To
help customers meet their sustainability targets in a fast and reliable manner, the ONE WAY
methodology takes a highly systematic approach to the selection of chemicals and production
processes.

ONE WAY Definition / Mission:
Use the most resource
efficient processes Minimize or
possible: minimizing use eliminate water
of materials,, energy,
gy, and air p
pollution.
water, and waste.
Create technologies and Develop, design products &

processes that
th t enhance
h applications
li ti which
hi h contains
t i none‐
biodiversity. hazardous dyes & chemicals

Product selection based on eco-standards requirements
• ONE WAY dyes and chemicals are screened against

more than 15 textiles eco‐standards and criteria
• Instant access to the eco‐profile of almost 600
products in the ONE WAY Selector

Solution selection - based on cost and eco-benefits calculations
• ONE WAY specialists use the ONE

WAY Calculator to assess the cost,
performance and environmental
profile of ONE WAY products and
processes
• The ONE WAY Calculator enables
fast and informed decision‐making
b d on precise d
based data measurement
and analysis
Public or Internal or Strictly Confidential, Presentation title

Philippe Caneva, Business or Service, 00.00.2013 16 /
Process comparison –Classical Bleaching/LTB
Bleaching
- 29%
- 2%
CO2
Time
0% - 39%
Water
W t
Energy
consumption
consumption

Environment

Slide
Neutralization
A d
And
Peroxyde
Eli i ti
Elimination
Sirrix NE liquid is a strong neutralizing agent. Its synergetic
association of organic acids allows a perfect adjusting of the
desired pH on the whole range. With Acetic Acid
Neutralized surface
NaOH
 Core neutralization
Acetate blocking
 No blocking buffer buffer zone
 Phosphorus and Nitrogen free With Sirrix NE liq.
 Biodegradable
 Low COD / BOD Neutralized core

Sirrix NE liquid Built‐in Ecology
Neutralization test on a continuous washing machine with automatic pH regulation:
Set: pH 4
4.0
0
Consumption with Acetic Acid 80%: 15 g/kg
Consumption with Sirrix NE liq.: 11 g/kg
COD BOD5
A ti A
Acetic Acid
id 80% 850 mg/g
/ 650 mg/g
/
Sirrix NE liq. 330 mg/g 230 mg/g
COD and BOD5 per kg of material :

COD BOD5
A ti A
Acetic Acid
id 80% 12 75 g/kg
12.75 /k 9 75 g/kg
9.75 /k
Sirrix NE liq. 3.63 g/kg 2.53 g/kg

Bactosol SAP liq c
Temperature (°C)
Fast action
i
80
75°C 60°C
40 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
0.35 % Bactosol SAP liq c
6.6 %NaOH 36°Be Sirrix NE to pH 7.0
20 5.6 %H2O2 50%
1%Imerol LTB
2%Stabilizer LTB
0
0 20 40 60 80 100 120
Slide
Applications
Knitwear
Yarn Packages
Towel

Cotton 100% 230 kg LR:1/6.5
LR:1/6 5
Temperature (°C)
80
75°C 60°C
40 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
20 5.6 %H2O2 50%
1%Imerol LTB
2%Stabilizer LTB
0
0 20 40 60 80 100 120
Slide
Cotton 100% 230 kg LR:1/6.5

l h
Cotton/Lycra 95%/5%
Temperature (°C)
80
75°C 60°C
40 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
20 5.6 %H2O2 50%
1%Imerol LTB
2%Stabilizer LTB
0
0 20 40 60 80 100 120
Slide
Low Temperature Bleaching (Italy)
Cotton/Lycra 95%/5%

l h
Yarn 100 % Cotton
Temperature (°C)
80
75°C 60°C
40 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
20 5.6 %H2O2 50%
1%Imerol LTB
2%Stabilizer LTB
0
0 20 40 60 80 100 120
Slide
l h
Yarn 100 % Cotton
Degree of Whiteness CIE: 60,5
Absorbency: 110 mm

LTB and
F ll hit
Fullwhite

LTB Bleaching and OBA in one step
Temperature (°C)
80
75°C
40 min
60
0.8% Leucophor BSB liq.

40
Material 10’
10
6.0% H2O2 50% Sirrix NE to pH 6.0

20
4.0% NaOH 48
48°Bé
Bé
1.0% Imerol LTB
2.0% Stabilizer LTB
0
0 20 40 60 80 100 min

LTB Bleaching and OBA in 2 steps
Temperature(°C)
80
75°C
75 C
60 min 70°C
30 min
60
4 g/l Arostit BLN gr.
1 % Leucophor BMF liq.
40 3 g/l Sulphate de NA 10’
1 3% Si
1.3% Sirrix
i NE
7.0% H2O2 50%

20 4.0% NaOH 48°Be
1.0 % Imerol LTB
2.0% Stabilizer LTB
0
0 20 40 60 80 100 120 140 160 180
LTB Bleaching on Viscose
Viscose‐Viscose/Lycra
Viscose/Lycra
Temperature (°C)
80
75°C 60°C
30 min 10 min
60 Drain
5‘ 10 ‘ Dyeing
40
3,5% Soda ash 0.5 g/l Sirrix NE
20 5,0 %H2O2 35%
1%Imerol LTB
0,5%Stabilizer LTB
0
0 20 40 60 80 100 120
Slide
LTB Bleaching on Viscose
Viscose‐Viscose/Lycra
Viscose/Lycra
Degree of Whiteness CIE: 77,0


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LOW TEMPERATURE

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

– Both products are GOTS-Oekotex-Community Ecolabel-Bluesign approved

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Wetting Agent Sirrix NE Imerol LTB Sirrix NE

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Imerol LTB Wetting washing emulsifying agent

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Imerol LTB liquid

•Alkali stable up to 6°Bé

0 g/l 1 g/l 2 g/l 4 g/l

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Create technologies and Develop, design products &

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

• ONE WAY dyes and chemicals are screened against

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

• ONE WAY specialists use the ONE

Public or Internal or Strictly Confidential, Presentation title

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

COD and BOD5 per kg of material :

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Degree of Whiteness CIE: 60,5

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

0.8% Leucophor BSB liq.

6.0% H2O2 50% Sirrix NE to pH 6.0

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

7.0% H2O2 50%

Degree of Whiteness CIE: 77,0

Philippe Caneva, Textile Specialities Business, Prod. Mgmt. Pretreatment EMEA

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