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    K Bar K K Bar CM Kpa Mol K

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    Fede Carrasco
    The document contains calculations to determine compressibility factors (Z) for the liquid and vapor phases of a substance using reduced temperature (Tr), reduced pressure (Pr) and other properties. Values for Z are calculated using equations of state and solved iteratively, yielding Z1 = 0.041 for the liquid and Z2 = 0.838 for the vapor.

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    K Bar K K Bar CM Kpa Mol K

    Uploaded by

    Fede Carrasco
    4 views2 pages
    The document contains calculations to determine compressibility factors (Z) for the liquid and vapor phases of a substance using reduced temperature (Tr), reduced pressure (Pr) and other properties. Values for Z are calculated using equations of state and solved iteratively, yielding Z1 = 0.041 for the liquid and Z2 = 0.838 for the vapor.

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    Ejercicio resuelto en Mathcad

    Original Title

    EJ14e

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    The document contains calculations to determine compressibility factors (Z) for the liquid and vapor phases of a substance using reduced temperature (Tr), reduced pressure (Pr) and other properties. Values for Z are calculated using equations of state and solved iteratively, yielding Z1 = 0.041 for the liquid and Z2 = 0.838 for the vapor.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    4 views2 pages

    K Bar K K Bar CM Kpa Mol K

    Uploaded by

    Fede Carrasco
    The document contains calculations to determine compressibility factors (Z) for the liquid and vapor phases of a substance using reduced temperature (Tr), reduced pressure (Pr) and other properties. Values for Z are calculated using equations of state and solved iteratively, yielding Z1 = 0.041 for the liquid and Z2 = 0.838 for the vapor.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 2

    w(omega), Tc, Pc, Vc y Zc son sacados de la Tabla B1 Propiedades de especies Puras

    ((e))
    Tc ≔ 430.8 K Pc ≔ 78.84 bar ω ≔ 0.245
    cm 3 ⋅ kPa
    T ≔ ((80 + 273.15)) K T = 353.15 K P ≔ 18.66 bar R ≔ 8314 ⋅ ――――
    mol ⋅ K

    T P
    Tr ≔ ― Pr ≔ ― Tr = 0.82 Pr = 0.237
    Tc Pc

    De la tabla 3.1 de RW

    σ≔1 ε≔0 Ω ≔ 0.08664 Ψ ≔ 0.42748

    α ⎛⎝Tr⎞⎠ ≔ Tr -0.5 α ⎛⎝Tr⎞⎠ = 1.104

    Ψ ⋅ α ⎛⎝Tr⎞⎠ Ω ⋅ Pr
    q ⎛⎝Tr⎞⎠ ≔ ――― β ⎛⎝Tr , Pr⎞⎠ ≔ ――
    Ω ⋅ Tr Tr

    q ⎛⎝Tr⎞⎠ = 6.648 β ⎛⎝Tr , Pr⎞⎠ = 0.025

    Calculo de Z para Liquido


    Valores de prueba

    Z ≔ 0.01
    Restricciones

    ⎛ 1 + β ⎛⎝Tr , Pr⎞⎠ - Z ⎞
    Z ＝ β ⎛⎝Tr , Pr⎞⎠ + ⎛⎝Z + ε ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⋅ ⎛⎝Z + σ ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⎜――――――⎟
    ⎝ ⎛⎝q ⎛⎝Tr⎞⎠ ⋅ β ⎛⎝Tr , Pr⎞⎠⎞⎠ ⎠
    Solver

    Z1 ≔ find ((Z)) Z1 = 0.041

    Z1 ⋅ R ⋅ T cm 3
    V1 ≔ ――― V1 = 64.64 ――
    P mol
    Calculo de Z para Vapor
    Valores de prueba

    Z ≔ 0.9
    Restricciones

    Z - β ⎛⎝Tr , Pr⎞⎠
    Z ＝ 1 + β ⎛⎝Tr , Pr⎞⎠ - q ⎛⎝Tr⎞⎠ ⋅ β ⎛⎝Tr , Pr⎞⎠ ⋅ ――――――
    Z ⋅ ⎛⎝Z + β ⎛⎝Tr , Pr⎞⎠⎞⎠
    Solver

    Z2 ≔ find ((Z)) Z2 = 0.838

    Z2 ⋅ R ⋅ T cm 3
    V2 ≔ ――― V2 = 1318.723 ――
    P mol

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