Vol-7 (No1) 9Cr Fluage
Vol-7 (No1) 9Cr Fluage
Vol-7 (No1) 9Cr Fluage
Harsh, cold seas require stronger, tougher materials for more durable offshore structures... DW-62L and DWA-62L meet the challenge.
With Ti-B micro-alloyed fine microstructure, DW62L and DWA-62L exhibit unsurpassed notch toughness as shown in Fig. 1 and excellent CTOD values as shown in Table 2.
DW-62L (AWS A5.29 E91T1-Ni2J) and DWA-62L (AWS A5.29 E91T1-G), brand new rutile-based fluxcored wires for CO 2 and 80%Ar/bal.CO 2 shielding respectively, offer excellent notch toughness suitable for low temperature steel of the 500-MPa yield strength class. Both wires provide high notch toughness at 60 or higher by Charpy impact testing and stable fracture at 40 or higher by CTOD testing. As shown in Table 1, both wires contain Ni at around 2% and micro-alloying with Ti and B. This sophisticated chemistry of the weld metal enables fine microstructures even in the as-cast zone or dendritic zonePhoto 1.
Table 1. Typical chemical compositions and tensile properties of DW-62L and DWA-62L weld metals tested per AWS A5.29 Brand C Si Mn Ni Ti B 0.2PS (MPa) TS (MPa) El () Shielding gas DW-62L 0.07 0.29 1.21 2.4 0.06 0.004 545 626 29 CO2 DWA-62L 0.07 0.32 1.33 2.1 0.07 0.005 561 641 27 80Ar/bal.CO2 Brand Figure 1. Charpy impact absorbed energies of weld metals tested by using a 60-mm thick double-V groove joint for DW62L (1.2mm) and an 80-mm thick double-V groove joint for DWA-62L (1.2mm) in vertical welding Table 2. CTOD values of DW-62L and DWA-62L weld metals welded in the vertical position Plate Test temp. thickness () (mm) 60 40 Fracture type Stable fracture Stable fracture CTOD (mm) 0.72 0.63 0.66 0.51 0.49
DW-62L
DWA-62L
80
40
Note: Base metal: Rolled steel of JIS G 3106 SM490A grade Testing method: BSI BS7448-1991 (W = B)
DW-62L
DWA-62L
Photo 1. Ti-B micro-alloyed fine microstructures of the as-cast zone of weld metals of thick plate joints
Diffusible hydrogen testing per JIS Z 3118 resulted in 2.1 ml/100g on average for DW-62L weld metal and 3.9 ml/100g on average for DWA-62L weld metal. Such low diffusible hydrogen enables the use of 100 preheating to prevent cold cracking in thick plate welds.
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Preface
Contents
Masakazu Tojo
General Manager International Operations Dept. Welding Company Kobe Steel, Ltd.
P8 How to prevent unstable arc in GMAW
Technical Highlight
corrosives should also be taken into account for a more precise classification. In general, high-temperature highpressure service requires the component steel materials to contain chromium to improve creep rupture strength and thermal corrosion resistance and molybdenum, vanadium, niobium and tungsten to improve creep rupture strength at elevated temperatures.
Table 1. Power boiler component materials and suitable service temperature ranges Steel type Typical ASTM (ASME) grade A106 A335Gr.P1 A335Gr.P12 A335Gr.P11 A335Gr.P22 (SA213Gr.T23) (SA335Gr.P23) A335Gr.P5 A335Gr.P9 A335Gr.P91 Service temperature () (1) 350-400 400-475 450-550 500-550 520-600 525-600 550-600 600-650 525-600
Steam boilers produce high-temperature high-pressure steam by heating pressurized water in hermetically sealed vessels through the combustion of such fossil fuels as coal, LNG, and oil. Steam boilers are widely used for such applications as power plants, ships, steel mills, textile processes, chemical processes, and oil refineries. Power generation boilers are required to drive turbogenerators in central power stations or they may be used to supply steam for process requirements. A steam power station contains many thousands of welds and the failure of just one can result in a shutdown, so good weld quality is of great importance. This two-part series of articles on welding power generation boilers will begin with Part 1: How to select filler metals. In the next issue the series will continue with Part 2: Essential factors in welding procedure controls.
stainless steel A312Gr.304H 650-850 Note (1) Ka-ryoku Genshi-ryoku Hatsuden (Fire and Nuclear Power Generation), Vol.51, No.1, January 2000
In response to demands for higher power generation efficiency the steam temperature and pressure of power boilers have been increasing. As the power generation efficiency increases, the consumption of fuels for generating electrical power can be decreased; consequently, the emission of carbon dioxide can be reduced, thereby helping to combat global warming. In this respect, in addition to those shown in Table 1, advanced 9-12Cr ferritic steels enhanced by tungsten in addition to molybdenum, vanadium and niobium have been put into practice. 9Cr-W-V-Nb and 12Cr-W-V-Nb steels are typical of those used for such advanced performance, as they are tailored for the applications to be operated at around 600 with higher allowable stress.
Technical Highlight
Table 2. A selection guide to proper filler metals for heat-resistant low-alloy steels for power boilers
Steel type 0.5Mo Plate A204Gr.A, B, C ASTM (ASME) steel grade Forging Pipe / Tube A209Gr.T1, T1a, T1b A182Gr.F1 A205Gr.T1, T1a, T1b A336Gr.F1 A335Gr.P1 FCAW (1) SMAW CMA-76 (E7016-A1) KOBELCO filler metal GTAW (3) GMAW (2) MGS-M TGS-M (ER80S-G) (ER80S-G) MG-M (ER80S-G) SAW (4) MF-38/ US-40 (F8P6EA3-A3) MF-38/ US-49 (F8P6EG-A4) MF-38/ US-A4 (F8P6EA4-A4) PF-200/ US-511N (F8P2EG-B2)
1-1.25Cr-0.5Mo
2.25Cr-1Mo
A387Gr.22 Cl.1, 2
A199Gr.T11 A213Gr.T11, T12 A234Gr.WP11 A234Gr.WP12Cl.1, 2 A250Gr.T11, T12 A335Gr.P11, P12 A199Gr.T22 A213Gr.T22 A234Gr.WP22Cl.1, 3 A250Gr.T22 A335Gr.P22 (SA213Gr.T23) (SA335Gr.P23) A199Gr.T5 A213Gr.T5, T5b, T5c A234Gr.WP5 A335Gr.P5, P5b, P5c A199Gr.T9 A213Gr.T9 A234Gr.WP9 A335Gr.P9 A199Gr.T91 A213Gr.T91 A234Gr.WP91 A335Gr.P91 A213Gr.T92 A335Gr.P92 SA213Gr.T122 SA335Gr.P122
A182Gr.F22Cl.1, 3 A336Gr.F22Cl.1, 3
A387Gr.5 Cl.1, 2
CMA-96 (E8016-B2) CMB-95 (E7015-B2L) CMB-98 (E8018-B2) CMA-106 (E9016-B3) CMB-105 (E8015-B3L) CMB-108 (E9018-B3) CM-2CW (E9016-G) CM-5 (E8016-B6)
TGS-80B2 (ER80S-B2) TGS-1CM (ER80S-G) TGS-1CML (ER80S-G) MGS-2CM TGS-90B3 DW-91B3 (E91T1-B3/B3M) (ER90S-G) (ER90S-B3) DWA-91B3 MG-2CM TGS-2CM (E91T1-B3M) (ER90S-G) (ER90S-G) TGS-2CML (ER80S-G) MGS-2CW TGS-2CW (ER90S-G) (ER90S-G) MGS-5CM TGS-5CM (ER80S-B6) (ER80S-B6) DW-81B2 (E81T1B2/B2M) DWA-81B2 (E81T1-B2M)
9Cr-1Mo
A387Gr.9 Cl.1, 2
A182Gr.F9 A336Gr.F9
CM-9 (E8016-B8)
9Cr-1Mo-V-Nb
A387Gr.91 Cl.2
A182Gr.F91 A336Gr.F91
PFH-80AK/ US-2CW PF-200S/ US-502 (F7P2EG-B6) MGS-9CM TGS-9CM PF-200S/ (ER80S-B8) (ER80S-B8) US-505 (F7PZEG-B8) MGS-9Cb TGS-90B9 PF-200S/ (ER90S-G) (ER90S-B9) US-9Cb (F10PZTGS-9Cb (ER90S-G) EG-G) MGS12CRS TGS-12CRS PF-200S/ US-12CRS
9Cr-W-V-Nb 12Cr-W-V-Nb
Note (1) DW series wires use CO2 or 75-85Ar/bal. CO2 for shielding, while DWA series wires use only 75-85Ar/bal. CO2 for better impact absorbed energy. (2) MGS series wires use 95-98Ar/bal. O2 or 80-95Ar/bal. CO2 for shielding, while MG series wires use CO2. (3) TGS-XXXL series wires are of low carbon type. (4) MF-38 is a fused type flux, whereas brands indicated with PF and PFH are bonded type fluxes. SAW flux/wire combinations intends to use AC current.
In using this quick selection guide, the steel type and ASTM (ASME) steel grade can be your guide to an appropriate filler metal brand name or AWS classification. Or, if an exact or equivalent AWS classification is specified by the job specification you may look directly at the appropriate brand of filler metal. New AWS-type brands such as CM-96B9 for SMAW, DW-81B2, DWA-81B2, DW-91B3 and DWA-91B3 for FCAW, and TGS-80B2, TGS-90B3 and TGS-90B9 for GTAW have recently been developed by modifying the chemical compositions of the original brands respectively to help international customers select appropriate filler metals more easily. The welding usability, mechanical properties and crack resistance of such AWS-type brands are comparable to the original brands. For the typical performance of such new AWStype brands, please refer to the special edition of Kobelco Welding Today on filler metals for heat4
resistant low-alloy steels issued last July. However, many filler metals for GMAW, GTAW and SAW are classified with the suffix G or EG G ( stands for General per the AWS standard) because as of their unique chemical compositions developed by Kobe Steel. For such filler metals you can confirm the chemical composition by mill certificate or guaranty of quality supplied from Kobe Steel. When you will have to choose an appropriate filler metal where no exact or equivalent AWS classification is specified for welding a particular grade material that is not included in Table 2, you may follow the following steps. First, confirm the nominal chemical composition, particularly Cr, Mo, W, V and Nb, of the base metal to know the steel type. Second, confirm the minimum tensile strength of the base metal to know the matching filler metal tensile strength. This will suggest the
Technical Highlight
equivalent AWS classification of the filler metal to be chosen in Table 2 for a particular welding process. With respect to filler metals for 9Cr-W-V-Nb and 12Cr-W-V-Nb steels, no AWS classification system is available because they are presently the most advanced filler metals in the power boiler field as detailed below. They have been developed by Kobelcostate-of-the-art s technology, and the application of such advanced steels has been a recent event. In using such filler metals you can confirm the chemical and mechanical properties by mill certificate or guaranty of quality issued by Kobe Steel.
Creep rupture strength is an important property for steam boiler components. Creep rupture, which can have a decisive influence on the lifetime of a boiler, is a phenomenon in which a steel material ruptures as a result of progressive or creeping strain under a stress even below its yield strength when it is kept at a high temperature for long periods. Several types of tungsten-enhanced 9-12Cr steels typically 9Cr-W-V-Nb and 12Cr-W-V-Nb steels specified by ASMEare now drawing attention because they can supersede modified 9Cr-1Mo (9Cr-1Mo-V-Nb) steel in terms of creep rupture strength. They have been applied in the fabrication of steam boilers for many fossil fuel power plants. The applications of such innovative steels include the main steam piping, superheater tubing and reheater tubing Fig. 2.
High-Cr ferritic steels and filler metals are hot topics in the power boiler field
In recent years, greenhouse gasesmainly CO2have been held up as a global environmental problem and moves to reduce such gases have been increasing. In this respect, the reduction of CO2 emitted especially from fossil fuel power plants is being promoted actively for environmental protection. For the reduction of CO 2 emissions at fossil fuel power plants, the improvement of electricity generation efficiency is considered to be imperative. For this purpose, high-temperature highpressure steam must be delivered to the power turbines. The use of such ultra-supercritical pressure steam requires the boiler components to be made from special steel that is durable under such severe steam conditions for a long period of operation. In response to this demand, various types of heat-resistant low-alloy steel have been developed to improve creep rupture strength as shown in Fig. 1.
Figure 1. Transition of heat-resistant low-alloy steel for power boilers in conjunction with improvement of creep rupture strength [Ref. 1]
Technical Highlight
superior high temperature strength and workability. However, in response to the demand for higher creep strength materials for high-temperature high-pressure power boilers, low-C 2.25Cr-W-V-Nb steel has also been developed by alloying with tungsten and optimizing the content of other alloying elements. This W-enhanced 2.25Cr steel offers superior creep rupture strength that is almost double that of conventional 2.25Cr-1Mo steel and almost the same as that of modified 9Cr-1Mo steel. It also offers better weldability due to its low carbon content. The piping and tubing of low-C 2.25Cr-W-V-Nb steel for steam boilers including supper heater tubes can be welded by using Kobelco filler metals tailored for this steel. Table 4 shows typical chemical and mechanical properties of the filler metals for individual welding processes. Such excellent properties are provided by the weld metal of fine bainitic microstructure as shown in Photo 1.
Table 4. Typical weld metal chemical and mechanical properties of low-C 2.25Cr-W-V-Nb steel filler metals Welding process Brand SMAW CM-2CW GTAW TGS2CW GMAW (1) MGS2CW SAW PFH-80AK/ US-2CW
SAW PF-200S/ US-12CRS 0.09 0.15 0.99 0.007 0.003 0.37 0.98 0.14 10.74 0.23 0.19 0.03 1.77 0.02 624 781 22 70 37
C (wt) 0.06 Si 0.38 Mn 0.72 P 0.005 S 0.003 Cu 0.01 Ni 0.48 Co 1.56 Cr 9.49 Mo 0.20 V 0.29 Nb 0.03 W 1.50 N 0.05 0.2YS (MPa) 648 TS (MPa) 768 El () [4D] 26 RA () 64 vE0 (J) 40 Creep rupture 2650 3915 1670 2635 time (2) (hr) PWHT (hr) 7408 7408 7408 7458 Note (1) Shielding gas: 95Ar/bal. CO2 (2) Testing temperature and stress: 650, 98MPa
MGS12CRS 0.07 0.31 0.93 0.005 0.004 0.01 0.50 1.50 9.54 0.40 0.29 0.04 1.60 0.04 619 745 27 62 47
C (wt) 0.05 0.02 0.05 0.03 Si 0.40 0.42 0.33 0.14 Mn 0.79 0.48 1.02 0.90 P 0.006 0.004 0.005 0.007 S 0.003 0.003 0.004 0.006 Cu 0.02 0.10 0.14 0.23 Ni 0.03 0.01 0.47 0.02 Cr 2.43 2.27 2.23 2.23 Mo 0.13 0.52 0.10 0.11 V 0.20 0.32 0.24 0.20 Nb 0.015 0.026 0.035 0.015 W 1.69 1.20 1.96 1.88 0.2YS (MPa) 565 467 656 548 TS (MPa) 652 578 727 628 El () [4D] 20 31 21 23 RA () 70 84 64 74 vE0 (J) 105 205 38 39 Creep rupture 1728 2857 2032 2579 time (2) (hr) PWHT (hr) 7152 7152 7152 7152 Note (1) Shielding gas: 80Ar/bal. CO2 (2) Testing temperature and stress: 600, 129MPa
Technical Highlight
lower alloy base metal in normal applications. For a quick guide to recommended Kobelco brands for joining dissimilar metals, refer to Table 5. For instance, carbon steel can readily be joined to 2.25Cr-1Mo steel by using either a carbon steel or 1.25Cr-0.5Mo steel filler metal; however, carbon steel filler metals are usually selected except where carbon migration must be minimized. Likewise, 2.25Cr-1Mo steel can be joined to 9Cr-1Mo-V-Nb steel by using a 2.25Cr-1Mo filler metal. In contrast, Cr-Mo steel and austenitic stainless steel are joined with a high Cr-Ni stainless (e.g., E309) or, where carbon migration and thermal stress are important factors, nickel alloy (e.g., ENiCrFe-1) filler metal. Carbon migration is a metallurgical phenomenon in which carbon diffuses from the lower-Cr metal to the higher-Cr metal to form a decarburized zone in the former metal and a carburized zone in the later metal by PWHT and exposure to high temperatures during service. Carbon migration is believed to cause adverse effects on the bending properties and creep rupture strength of the dissimilar metal joint.
Reference [1] F. Masuyama. Development in Environmentally Compatible MaterialsHeat Resistant Materials for Ultra-Supercritical Pressure Boilers. Journal of the Japan Welding Society, Vol. 70, No. 8, p.20-25. 2001.
(1)(2)
Photo 2. Fabrication of superheater tube bundles for steam boilers (Photo: Nagasaki Kogyosho Co., Ltd., Japan)
Table 5. A quick guide to proper filler metals for welding dissimilar metal joints for general applications Base metal Type 304 stainless steel LB-52 (E7016) TGS-50 (ER70S-G) LB-52 (E7016) TGS-50 (ER70S-G) LB-52 (E7016) TGS-50 (ER70S-G) LB-52 (E7016) TGS-50 (ER70S-G) LB-52 (E7016) TGS-50 (ER70S-G) Mild steel
0.5Mo
1.25Cr-0.5Mo
2.25Cr-1Mo
5Cr-0.5Mo
9Cr-1Mo 9Cr-1Mo-V-Nb
NC-39 (E309), NC-39L (E309L), TGS-309 (ER309), TGS-309L (ER309L) NIC-703D (ENiCrFe-3), NIC-70A (ENiCrFe-1), TGS-70NCb (ERNiCr-3) CMA-76 (E7016-A1) TGS-M (ER80S-G) CMA-76 (E7016-A1) TGS-M (ER80S-G) CMA-76 (E7016-A1) TGS-M (ER80S-G) CMA-76 (E7016-A1) TGS-M (ER80S-G) CMA-96 (E8016-B2) TGS-80B2 (ER80S-B2) CMA-96 (E8016-B2) TGS-80B2 (ER80S-B2) CMA-96 (E8016-B2) TGS-80B2 (ER80S-B2) CMA-106 (E9016-B3) TGS-90B3 (ER90S-B3) CMA-106 (E9016-B3) TGS-90B3 (ER90S-B3)
Note: (1) This table is a guide to recommended filler metals matching the lower-alloy steels in various dissimilar metal joints, excepting for Type 304 steel. Other types of filler metals may be needed where a specific requirement is imposed.
9Cr-1Mo 9Cr-1Mo-V-Nb
5Cr-0.5Mo
2.25Cr-1Mo
1.25Cr-0.5Mo
0.5Mo
Note: (2) Preheating and postweld heat treatment for dissimilar Cr-Mo steels should be sufficient to the higher-alloy steel; however, the PWHT temperature should be lower to avoid damage to the lower-alloy steel and minimize the carbon migration. Type 304 stainless steel should not be preheated or postweld heat-treated to avoid sensitization.
A wire ring with an excessive diameter can cause an irregular electrical contact between the contact tip and the wire, thereby causing an unstable arc.
In automatic gas metal arc welding (GMAW) with robots and exclusive-use automatic systems you may adjust the wire straightener in order to deliver the welding wire as straight as possible from the contact tip and thus facilitate better wire tracking onto the welding line. This method, however, can have an adverse effect on the regular electrical contact between the contact tip and the wire, thereby causing an unstable arc. This is a typical cause of unstable arc, even though the wire feeding is smooth. The tip-to-wire irregular electrical contact can occur where the contact pressure of the wire onto the contact tip is insufficient. The wire-to-tip contact pressure is predominantly affected by the diameter of the wire ring (Fig. 1).
Figure 2. Frequency of unstable arcs as a function of wire ring diameter (D) when passing through the contact tip (Wire diameter: 1.2mm)
An unstable arc caused by tip-to-wire irregular electrical contact can also cause fusion at the interface between the contact tip and wire, which can damage the inside surface of the contact tip and markedly increase the wire feeding resistance, thereby damaging the wire surface at the wire feeding roller. Therefore, this electrical trouble can cause subsequent wire feeding trouble. To prevent such multiple troubles, when irregular electrical contact causes seriously unstable arcs or arc cutting, you should not only renew the contact tip, but also remove all the wire extended from the wire pressure roller to the welding torch through the conduit. Take preventive measures against the irregular electrical contact before restarting welding.
Unstable arc can also be caused by an excessively long or small diameter welding cable due to a voltage drop.
GMAW power sources are designed so that they perform best when the welding cable, which has a specified diameter according to the rated welding current, is extended 5-10m long in general. Therefore, the use of a cable that is either longer or thinner can cause poor arc stability due to a voltage drop. In order to overcome this trouble, increase the output terminal voltage or use a thicker thus lower electrical resistancewelding cable to compensate the voltage drop. When a long welding cable is spiraled during use, the arc can become more unstable because of an increase of inductance of the welding cable. This is why a long welding cable should be kept straight in use.
Figure 1. Wire ring diameter where the wire is fed out of the contact tip
As the wire ring diameter increases, the wire-to-tip contact pressure decreases; consequently, more unstable arcs can occur as shown in Fig. 2. Therefore, the diameter must be controlled small enoughnormally 600 mm or smallerby adjusting the wire straightener and pressure roller of the wire feeder to maintain stable wire-to-tip contact pressure. In addition, as shown in Fig. 2, the use of a loose contact tip having an excessively large inside diameter over the wire diameter or being worn out causes more unstable arcs.
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Kobe Welding of Tangshan is built in Tangshan City which lies about 200 km east of Beijing. Execute all the obligations imposed by industry, thereby contributing to the progress of social and economical prosperity in order to achieve peace and happiness for people, states the board outside the front gate of KWTfactory. s
All the executives of KWT celebrate the inauguration of the factory by pulling open a decorative paper ball put on the ceiling, expecting a prosperous future for the company.
Thus, KWT has taken its first step as the 9th overseas business hub of the Welding Company of Kobe Steel, Ltd. and is endeavoring to join the other great brother companies fulfilling KOBELCO international slogan s QTQ(Quality Products, Technical Support, and Quick Delivery). With respect to Quality Products especially, each and every one of the employees is ready to work creatively in order to supply materials and services reflecting local input and responding to the expectations of customers in China. In fact, many customers have already evaluated our products highly, recognizing our uncompromising attitude for quality. For Technical Support, will provide kind and we helpful advice that is easy to understand. And we will seek to achieve Quick Delivery, keeping our by promises for the most convenient delivery time.
As you all may know, the 2008 Olympic Games will be held in the capital city Beijing, which is near Tangshan, the home of KWT. We expect a great expansion of demand in China, where the whole country is booming in tandem with the construction boom for the Olympic Games. With KWT at the forefront, the KOBELCO GROUP is determined to grasp this business opportunity securely and to supply welding consumables and services to as many customers as possible, and in this way contribute to the development of industries of China. We should be very happy if foreign enterprises already existing in China and those who plan to establish businesses in China will remember that KOBELCO is in China as in many other countries. KWT will continue its efforts to live up to all of your expectations.
Bulletin
Prior to the Exhibition, at the Symposium, Welding for Automobiles, held from November 24 to 26, Mr. R. Suzuki, a KSL researcher, made a presentation on the recent trends in MAG welding technologies for thin plates, which drew much attention from the audience. All through the exhibition period, there was a constant flow of visitors, letting us understand the active demand of the Chinese market.
Technical presentation by Mr. R. Suzuki, a researcher of the Technical Development Dept. of KSL, on a state-of-the-art gas metal arc welding process suitable for sheet metal welding in automobile fabrication (Beijing Essen)
KWT and KSL will strive in their advertising and publicity activities to comply with this brisk demand in the Chinese market. The next Beijing Essen is scheduled to be held in Beijing in November 2004. The KOBELCO Group is determined to respond to expectations of customers the world over, let alone customers in China. Our challenge is to realize Whenever you see the arc, KOBELCO is here, there and everywhere.
MG-51T spools exhibited by KWT at Beijing Essen (left)
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