Natural Gas Engineering
Natural Gas Engineering
Natural Gas Engineering
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Petroleum (or crude oil) is a complex mixture of hydrocarbons and other chemicals. The
composition varies widely depending where and how the petroleum was formed.
Source rock refers to rocks from which hydrocarbons have been generated or are capable of
being generated. It contains high total organic carbon (TOC). It has very low permeability. Four
types of source rocks can be found in terms of petroleum generation potentiality. Effective,
active, inactive and spent source rocks. Firstly, a potential source rock can be any rock that
contains sufficient organic matter to generate petroleum. An effective source rock is a potential
source rock which has reached an adequate thermal maturity to generate petroleum. When a
source rock is generating and expelling hydrocarbons either biological or by temperature at the
critical moment, it is called active. An inactive source rock might show petroleum potential but it
stopped generating oil and gas. Finally, a spent source rock reached postmaturity stage and might
generate wet or dry gas, but it cannot generate any oil. Physical, biochemical and geological
processes are behind the creation of a source rock, resulting in the formation of a fine-grained
sedimentary rock rich in organic matter, manly carbon and hydrogen elements. A few phases
need to be taken into account when a source rock is formed such as production, accumulation
and preservation of the organic matter. Thus, the amount and type of organic matter found in a
source rock are subjected to environmental and depositional conditions. Biological activities take
part in the production and transformation of organic matter. On the other hand, depositional
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conditions develop the concentration of the organic matter and finally the post-depositional
conditions preserve it.
Reservoir rock is a rock that has sufficient porosity and permeability to contain accumulations
of oil or gas. It is a place that oil migrates to and is held underground.
Caprock, also known as seal, is any nonpermeable or low permeable formation that may trap oil,
gas or water, preventing it from migrating to the surface. Typical caprocks are compacted shales,
evaporites and tightly cemented sandstones and carbonate rocks.
Petroleum trap is an underground rock formation that blocks the movement of petroleum and
causes it to accumulate in a reservoir that can be exploited.
Petroleum system involves the elements and processes needed so that hydrocarbons can be
generated and accumulated. Thus, a clear definition of it is fundamental in order to comprehend,
locate and analyze a source rock. A petroleum system is composed basically of a source rock,
where hydrocarbons are generated and eventually are expelled and migrate to a reservoir rock,
where oil and gas are accumulated, a seal rock, an impermeable rock which does not allow oil
and gas to go up to the surface, and an overburden rock.
Shale gas is a natural gas (predominantly methane) found in shale rock. Natural gas produced
from shale is often referred to as ‘unconventional’ and this refers to the type of rock type in
which it is found. ‘Conventional’ oil and gas refers to hydrocarbons which have previously
sought in sandstone or limestone, instead of shale or coal which are now the focus of
unconventional exploration. However, the techniques used to extract hydrocarbons are
essentially the same. What have changed are advancements in technology over the last decade
which have made shale gas development economically viable.
Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis,
hydrogenation, or thermal dissolution. These processes convert the organic matter within the
rock (kerogen) into synthetic oil and gas. The resulting oil can be used immediately as a fuel or
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upgraded to meet refinery feedstock specifications by adding hydrogen and removing impurities
such as sulfur and nitrogen. The refined products can be used for the same purposes as those
derived from crude oil.
Oil sands, also known as bituminous sands, are a type of unconventional petroleum deposit. Oil
sands are either loose sands or partially consolidated sandstone containing a naturally occurring
mixture of sand, clay, and water, saturated with a dense and extremely viscous form of petroleum
technically referred to as bitumen (or colloquially as tar due to its superficially similar
appearance).
Coal-bed methane (CBM), also known as coal-seam gas (CSG) or coal-mine methane (CMM)
is a form of natural gas extracted from coal beds.
Inspissated deposits, are heavy hydrocarbons from which the light fraction has been removed.
This situation can occur where an accumulation of liquid oil has been brought to the surface of
the earth by a combination of migration, coupled with uplift and erosion.
Migration of petroleum refers to the movement of hydrocarbons from source rock into
reservoir rock. There two types of migration:
1) Primary migration: Expulsion of hydrocarbons from the source rock. This process is called
expulsion.
2) Secondary migration: It is any movement in carrier rocks or reservoir rocks outside the
source rock or movement through fractures within the source rock.
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Fig. 1: Evolution of organic matter in source rocks during burial.
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Classification of Hydrocarbons
On the basis of structure, hydrocarbons can be broadly classified into two classes:
1. Open chain hydrocarbons (Aliphatic compounds).
2. Closed chain hydrocarbons (Cyclic compounds).
Hydrocarbons
* The elemental composition of petroleum is carbon from 83 to 87%, hydrogen from 10 to 14%,
nitrogen from 0.1 to 2%, oxygen from 0.05 to 1.5%, sulfur from 0.05 to 6.0% and metals < 0.1%.
The most common metals are iron, nickel, copper and vanadium.
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Fig. 3: Classification of kerogen.
Formation of Kerogen
There are three major phases: 1) Diagenesis, 2) Catagenesis, and 3) Metagenesis.
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Biological activity at the early stage, following by temperature and pressure are responsible for
the physiochemical transformation of organic matter in a sedimentary basin. Higher temperatures
and long period of geological time are involved in the transformation of kerogen into oil and gas.
Thus, increments in burial depth increase temperature and pressure, which along with geological
time play an important role in the organic matter transformation. It should be mentioned that the
amount of hydrocarbons that might be generated in a source rock is exposed to kerogen
composition and concentration, as well as the geothermal gradient evolution during burial
history.
The thermal maturation process, by which organic matter is altered changing its chemical
composition and creating hydrocarbons, can be divided into three consecutively stages,
diagenesis, catagenesis and metagenesis. Diagenesis is the first stage of thermal maturation
process of organic matter. It comprises the natural changes occurring from the moment of
sediment depositions until the first signal of thermal alteration process. Thus, this alteration starts
in the water column, being microbial activity the first process taking place. The temperature, at
which the alteration of organic matter in source rocks takes place, is ranged below 50oC. With
reference to the depth interval, this phase is extended from one hundred to one thousand meters.
In this stage, oxidation along with other chemical process decomposes the material. On the one
hand, anoxic deposition conditions might convert the material from biogenic gas into dry gas.
The term biogenic gas is referred to the gas generated during the degradation of organic matter in
anaerobic conditions by bacterial microorganisms. On the other hand, the increase of temperature
and pH promote the transformation of organic matter into kerogen and bitumen.
Increasing burial depth due to successive sediment depositions, causes increment in pressure and
temperature and the source rock undergoes catagenesis. During this phase, hydrocarbons are
generated at temperatures range from 50 to 150oC and at several kilometers beneath the surface.
As a consequence, a thermal decomposition causes chemical bonds of kerogen brakes down,
creating mostly oil but also gas. A secondary cracking of oil molecules takes place during this
phase due to the increment in temperature, generating wet gas such as methane, ethane, propane
and heavier hydrocarbons.
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The last step in the thermal transformation of kerogen is called metagenesis. Temperature ranges
from 150 to 200oC. In addition, higher burial depth might cause source rock be influenced by
magma and hydrothermal effects. Thus, at this stage, the increment in heat causes chemical
changes within the kerogen, transforming it into methane and a carbon residue. Furthermore, late
methane, or dry gas along with non-hydrocarbons gases such as CO2, N2 and H2S might be
generated as the source rock moves further down.
Source rocks are said to be thermally immature, or potential source rocks, as the rocks have to be
exposed to more heat in order to generate petroleum. Source rocks, which are found at the oil
window, are said to be thermally mature or effective source rocks, as the rocks have been
generating petroleum, or are actively generating it. The last but not the least, source rocks are
said to be thermally postmature, or spent source rocks, as the rocks have entered at the gas
window and have already generated petroleum. Thus, they have consumed all the hydrogen
necessary for further oil and gas generation. On the other hand, it should be mentioned that
maturation process can be also altered due to the influence of heat arising from the crustal
tectonics or igneous bodies.
In order to evaluate a source rock properly, a differentiation between kerogen types must be
performed. As different types of organic matter have different chemical structures, the
hydrocarbon potential varies. Thus, four types of kerogen are distinguished based on its origin.
Furthermore, the hydrogen, carbon and oxygen content can be used for such classification. Each
type of kerogen can produce or generate different types of petroleum. In earlier times, kerogen
classification used to be made based on its elemental composition. As soon as Rock-eval
pyrolysis was developed, it was found that HI and OI parameters are directly proportional to H/C
and O/C ratios, thus HI and OI replaced them on the Van Krevelen diagram, respectively.
Type I kerogen originates mainly from lacustrine environments, although it can also be
originated from marine environments. It is composed of algae, plankton and other matter which
were reworked by bacteria and microorganisms. It shows high H/C atomic ratio and low O/C
atomic ratio. It is oil-prone, but depending on the thermal maturation phase can also generate
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gas. Type I kerogen is not usual and represents less than 3% of oil and gas reserves in the world,
although it presents high hydrocarbon potential.
Type II kerogen originates in reducing environments from deep marine settings. Remains of
plankton, among others, reworked by bacteria compose this kind of kerogen. It shows high H/C
and low O/C ratios. Type II kerogen can generate mainly oil, but also gas, providing enough
heating and maturation.
Type III kerogen derives from continental plants and contains vegetal debris. It has been
deposited in shallow to deep marine or non-marine environments. It shows low initial H/C ratio
and high initial O/C ratio. This sort of kerogen usually generates dry gas.
Type IV kerogen derives from residual organic matter which might have been altered by
weathering, combustion or biologic oxidation in swamps or soils. It shows very low H/C ratio
and a relatively high O/C ratio. This kind of kerogen is referred as a dead carbon, having no
potential for petroleum generation.
Origin of Petroleum
The origin of petroleum still has uncertainties despite the tremendous researches and studies
devoted to it rather than any other natural substance. There are two different theories for the
origin of petroleum:
1) Inorganic or abiotic theory
2) Organic origin.
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1) Inorganic theory
States that hydrogen and carbon came together under great temperature and pressure, far below
the earth’s surface and formed oil and gas where chemical reactions have occurred. There are
some different theories that describe the inorganic origin of petroleum which include:
a) Metal carbide theory
b) Volcanic theory
c) Earthquake theory
d) Serpentinization theory
2) Organic origin
It is the most widely accepted. The oil and gas are formed from remains of prehistoric plants and
animals. Remains of plants have been transformed to coal and animals to oil and gas. These
remains were settled into seas and accumulated at the ocean floor and buried under several
kilometers of sediments. Over a few million years, the layers of the organic material were
compressed under the weight of the sediments above them. The increase in pressure and
temperature with the absence of oxygen changed the mud, sand, slit or sediments into rock and
organic matter into kerogen. After further burial and heating, the kerogen transformed via
cracking into petroleum and natural gas.
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HYDROCARBON WELL
Oil well: An oil well is a boring in the Earth that is designed to bring petroleum oil hydrocarbons
to the surface.
Gas well: A well that is designed to produce mainly or only gas may be termed a gas well.
Types of Wells
* There are classifications of hydrocarbon wells
Classification I: It depends on the well production:
1) Wildcat well: The first test petroleum well in a new field.
Dry well
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4) Show well: A well found to be incapable of producing either oil or gas in sufficient quantities
to justify completion as an oil or gas well.
5) Development well: A well drilled in a proven producing area for the production of oil or gas.
Classification II: It depends on the method of drilling. There are a number of different types of
wells that can be drilled, and these are described below:
1) Conventional wells: A well location is chosen at top reservoir, and the well is drilled directly
to the target as a vertical well.
2) Sidetrack wells: A sidetrack may be required if there is an object stuck in the original hole,
which cannot be fished out.
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Fig. 6: Sidetrack well.
3) Horizontal wells: Horizontal wells are wells where the reservoir section is drilled at a high
angle. In a strict sense, these wells are rarely perfectly horizontal, but they tend to be near
horizontal mostly, generally at an angle greater than 80° from vertical.
4) Designer wells: Designer wells are types of high-angle or horizontal wells that have more
than one intended target.
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Fig. 8: Designer wells.
5) Multilateral wells: Multilateral wells are wells that have more than one branch radiating from
the main borehole.
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NATURAL GAS
Natural gas (or fossil gas) is a naturally occurring hydrocarbon gas mixture consisting primarily
of methane. The most common and greatest number of hydrocarbon compounds making up
natural gas deposit is those of paraffin series.
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Second classification: This classification depends on the origin and therefore the natural gases
are divided into three types (Fig. 10).
Natural gases
Based on the methane content, there are two general types of hydrocarbon gases:
1) Biogenic gas (≥95% methane), or dry gas, which was formed by bacterial decay at shallow
depth.
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2) Thermogenic gas (<95% methane), or wet gas, which is a lower quality gas formed at high
temperatures. Wet gas on the other hand contains compounds such as ethane and butane, in
addition to methane.
-70
Biogenic gas
Wetness (%)
Mixing
-60 Low maturity 10-15
M 30-45
To
-50
δ13C1 (‰)
Most oils
-40 TT (m)
Tc
High maturity
-30
M = Mixed TT (h)
To = Thermal oil Humic gas
-20
TT (m) = Thermal marine or mixed
Tc = Thermal condensate
TT (h) = Thermal humic
-10
50 60 70 80 90 100
C1 (%)
Fig. 11: Plot of C1 concentration vs. δ13C1 showing the maturity of natural gas.
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δ13C1
3
C1/C2 C2/C3
2
0
δ13C2- δ13C1 iC4/nC4
-1
-2
-3
δ13-nC4 δ13-iC4
Fig. 12: Gastar diagram.
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Fig. 13: Schematic flow diagram of a typical natural gas processing plant.
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Fig. 14: Natural gas production and delivery.
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HYDROCARBON FLUID CHARACTERISTICS
* Because of reservoir hydrocarbons blend into one another, there are no distinct dividing lines
between the types into which may be divided.
* At high pressure and low temperature, the molecules are attracted more and therefore the crude
oil is formed.
* At low pressure and high temperature, the molecular attraction decreases and the natural gas is
formed.
* There is a positive correlation between temperature and kinetic energy.
Gas phase
Temperature
Fig. 16: Phase diagram of natural gas.
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GAS RESERVOIR
* In general, if the reservoir temperature is above the critical temperature (Tc) the reservoir is
classified a natural gas reservoir.
2) Wet gas reservoir: All mixture stays in vapor state with a small amount of liquid.
3) Gas condensate reservoir: It is also called natural gas liquids. It is a low-density mixture of
hydrocarbon liquids that are present as gaseous components in the raw natural gas.
2) Non-associated gas: They are gases produced as a primary production of natural gas.
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Fig. 17: Associated and non-associated gases.
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PROPERTIES OF NATURAL GAS
* The gas has no definite volume, but affected by pressure and temperature and expands to
completely fill the vacant in which it is placed.
* Knowledge of properties of gases is essential for solving problems in natural gas engineering.
* There are six main properties of natural gas:
1) Apparent molecular weight (Mg).
2) Density (ρg).
3) Specific gravity (γg).
4) Specific volume (Vs).
5) Gas formation volume factor (Bg).
6) Compressibility factor (Z).
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IMPURITIES
* Natural gases contain impurities in varying amounts. This constitutes serious problems.
Therefore, gas treatment required to reduce the impurities to minimum level.
Types of Impurities
1) Carbon dioxide (CO2).
2) Oxygen (O2).
3) Nitrogen (N2).
4) Hydrogen sulfide (H2S).
5) Sulfur compounds.
6) Water (H2O).
7) Helium (He).
8) Mercury (Hg).
9) Dust.
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* The presence of H2O will reduce the area available for gas flow.
* When the temperature of the natural gas falls below a certain limit allows the water and gas
molecules and form a solid phase know as hydrates.
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GAS RESERVE
* The gas reserve applied to the prospect gas in the reservoir. Generally, means the future
production of gas which can be expected from the reservoir.
* Often the word reserve is used to denote ultimate recovery.
Gas Volumetrics
* Gas volumetrics is a static measurement based on a geologic model that uses geometry to
describe the volume of gas in the reservoir.
* Two main techniques are commonly employed in gas volumetrics, namely:
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1) The volumetric method: The gas volume is calculated using the following equation:
Where:
Gi = initial gas in place
Vs = sand volume
Φ =Porosity
Swi = water saturation
Bg = gas formation volume factor
2) The material balance method: The gas volume is calculated using the following equation:
Gi = GP + GR
Where:
Gi = initial gas in place
GP = produced gas
GR = remaining gas
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GAS METERING
* The common method of measuring the gas produced is by metering the volume of the stream
of gas flowing in the pipeline.
* Since the volume of gas is a function of pressure and temperature, then normally measured at
international standard conditions (14.7 psia and 520 oR).
2) Elbow meter: A device used to measure the flow rate of a gas through a pipe. An elbow
meter is a pipe with a right-angle bend, and flow rate is gauged by sensors that measure the
difference in pressure between the inner and outer angle of the bend.
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3) Sonic meter: A Sonic Meter, also known as an ultrasonic flow meter, is a type of flow
measurement equipment that measures the velocity of a fluid flowing inside a pipeline by
transmitting ultrasonic sound waves across the pipeline.
4) Rotameter: A rotameter is a device that measures the volumetric flow rate of gas in a closed
tube. It belongs to a class of meters called variable area meters, which measure flow rate by
allowing the cross-sectional area the gas travels through to vary, causing a measurable effect.
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5) Orifice meter: An orifice meter is basically a type of flow meter used to measure the rate of
flow of gas, using the differential pressure measurement principle. It is the most common
technique of gas measurements in pipeline. The gas flow rate is calculated using the following
equation:
Q = K(D*Pf)0.5
Where:
Q = gas flow rate
K = orifice constant
D = the differential pressure across the orifice
Pf = flowing pressure
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DETERMINING THE STATIC AND FLOWING PRESSURES OF A GAS
WELL
* The ability of the reservoir to deliver a certain quantity of gas depends both on the inflow
performance relationship and the flowing-bottom-hole pressure. The flowing bottom-hole
pressure on its part depends on the separator pressure and the configuration of the piping system.
* In order to determine the deliverability of the total well system, it is necessary to calculate all
the parameters and pressure drops. Static and flowing pressures are what I’m really concerned
about, and methods for determining pressure drops in tubing for single-phase gas flow and for
multiphase gas-liquid flow. Inflow and outflow performance curves must be determined. Well,
the static and flowing pressure at the formation must be known in order to predict the
productivity or absolute open flow potential of gas wells. The preferred method is to measure the
pressure with a bottom-hole pressure gauge. It is often impractical or too expensive to measure
static or flowing bottom-hole pressures with bottom-hole gauges. However, for many problems,
a sufficiently pressure and temperature, formation temperature, and well depth. The static
pressure is equal to the weight of the column of gas. In the case of flowing wells, the gas column
weight and friction effects must be evaluated and summed up.
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* There are several ways to determine the pressure either static or flowing.
3) Annular Flow
* In most instances, gas wells are produced through tubing. Occasionally, however, a well may
be produced through the casing-tubing annulus. The tubing flow equations may be used for
annular flow, provided proper account is taken of the flow diameter variable.
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