JEE Main 31-01-2024 (Evening Shift) : B X at 2 1 1 2 1 1 2 1 0 0 1 1
JEE Main 31-01-2024 (Evening Shift) : B X at 2 1 1 2 1 1 2 1 0 0 1 1
JEE Main 31-01-2024 (Evening Shift) : B X at 2 1 1 2 1 1 2 1 0 0 1 1
Questions
At
(b) L M T 2 −1 1
(c) L M T −2 1 0
(d) L M T 0 −1 1
2. Force between two point charges q and q placed in vacuum at ‘r’ cm apart is F. Force between them when
1 2
(a) F
25
(b) 25F
(c) F
(d) 5F
3. If two vectors A ⃗ and B⃗ having equal magnitude R are inclined at an angle θ, then
∣ ⃗ ⃗∣ –
(a) ∣
A − B = √ 2R sin(
∣
θ
2
)
∣ ⃗ ⃗∣
(b) ∣
A + B = 2R cos(
∣
θ
2
)
∣ ⃗ ⃗∣
(c) ∣
A − B = 2R cos(
∣
θ
2
)
∣ ⃗ ⃗∣
(d) ∣
A + B = 2R sin(
∣
θ
2
)
6. The mass number of nucleus having radius equal to half of the radius of nucleus with mass number 192 is:
(a) 32
(b) 24
(c) 20
(d) 40
7. By what percentage will the illumination of the lamp decease if the current drops by 20%
(a) 56%
(b) 46%
(c) 26%
(d) 36%
A B Y
0 0 0
(a) 1 0 0
0 1 1
1 1 0
A B Y
0 0 0
(b) 1 0 0
0 1 0
1 1 1
A B Y
0 0 0
(c) 1 0 0
0 1 0
1 1 0
A B Y
0 0 0
(d) 1 0 1
0 1 1
1 1 0
9. The measured value of the length of a simple pendulum is 20 cm with 2 mm accuracy. The time for 50
oscillations was measured to be 40 seconds with 1 second resolution. From these measurements, the accuracy
in the measurement of acceleration due to gravity is N%. The value of N is:
(a) 6
(b) 4
(c) 8
(d) 5
10. A body of mass 2 kg begins to move under the action of a time dependent force given by
⃗ ^ 2^
F = (6t i + 6t j) N . The power developed by the force at the time t is given by
(a) (6t
4 5
+ 9t ) W
(b) (9t
5 3
+ 6t ) W
(c) (3t
3 5
+ 6t ) W
(d) (9t
3 5
+ 6t ) W
11. The mass of the moon is times the mass of a planet and its diameter is
1
times the diameter of a planet.
1
144 16
If the escape velocity on the planet is v, the escape velocity on the moon will be:
v
(a) 12
v
(b) 3
v
(c) 4
v
(d) 6
12. The resistance per centimetre of a meter bridge wire is r, with XQ resistance in left gap. Balancing length
from left end is at 40 cm with 25Ω resistance in right gap. Now the wire is replaced by another wire of 2r
resistance per centimetre. The new balancing length for same settings will be at
(a) 20 cm
(b) 10 cm
(c) 80 cm
(d) 40 cm
13. A block of mass 5 kg is placed on a rough inclined surface as shown in the figure. If F ⃗ is the force required
1
to just move the block up the inclined plane and F ⃗ is the force required to just prevent the block from
2
sliding down, then the value of ∣∣F ⃗ ∣∣ − ∣∣F ⃗ ∣∣ is: [use g = 10m/s ]
1 2
2
(a) 5√ 3
N
2
(b) 10 N
(c) 50√–3N
–
(d) 25√3N
14. A small spherical ball of radius r, falling through a viscous medium of negligible density has terminal
velocity ‘v’. Another ball of the same mass but of radius 2r, falling through the same viscous medium will
have terminal velocity:
v
(a) 2
(b) 2v
v
(c) 4
(d) 4v
15. An AC voltage V = 20 sin 200πt is applied to a series LCR circuit which drives a current
). The average power dissipated is:
π
I = 10 sin(200πt +
3
(a) 50W
(b) 173.2W
(c) 21.6 W
(d) 200W
16. In a photoelectric effect experiment a light of frequency 1.5 times the threshold frequency is made to fall on
the surface of photosensitive material. Now if the frequency is halved and intensity is doubled, the number
of photo electrons emitted will be:
(a) Halved
(b) Doubled
(c) Quadrupled
(d) Zero
17. When unpolarized light is incident at an angle of 60 on a transparent medium from air, the reflected ray is
∘
(b) 45 ∘
(c) 60 ∘
(d) 90 ∘
18. A uniform magnetic field of 2 × 10 T acts along positive Y-direction. A rectangular loop of sies 20 cm
−3
and 10 cm with current of 5A is in Y-Z plane The current is in anticlockwise sense with reference to
negative X axis. Magnitude and direction of the torque is:
(a) 2 × 10 N − m along positive Z-direction
−4
(a) 5
(b) 9
(c) 4
(d) 8
20. A gas mixture consists of 8 moles of argon and 6 moles of oxygen at temperature T. Neglecting all
vibrational modes, the total internal energy of the system is:
(a) 21 RT
(b) 27 RT
(c) 29 RT
(d) 20 RT
21. The distance between charges +q and -q is 2l and between +2q and −2q is 4l. The electrostatic potential at
point P at a distance r from center O is −α [ where the value of α is _____. (Use
ql
9
] × 10 V ,
2
r
4πε0
9 2
= 9 × 10 N m C
−2
)
22. A nucleus has mass number A and volume V . Another nucleus has mass number A and volume V . If
1 1 2 2
23. Two circular coils P and Q of 100 turns each have same radius of π cm. The currents in P and R are 1A and
2A respectively. P and Q are placed with their planes mutually perpendicular with their centers coincide.
The resultant magnetic field induction at the center of the coils is √−
x mT , where x = _____.
−
[Use μ = 4π × 10 T mA ]
0
−7 −1
24. The magnetic flux ϕ (in weber) linked with a closed circuit of resistance 8Ω varies with time (in seconds) as
ϕ = 5t − 36t + 1. The induced current in the circuit at t = 2s is _____A.
2
25. Light from a point source in air falls on a convex curved surface of radius 20 cm and refractive index 1.5. If
the source is located at 100 cm from the convex surface, the image will be formed at ____ cm from the
object.
26. The time period of simple harmonic motion of mass M in the given figure is π√−−−, where the value of α
αM
5k
is _____.
27. Two identical speres each of mass 2 kg and radius 50 cm are fixed at the ends of a light rod so that the
separation between the centers is 150 cm. Then, moment of inertia of the system about an axis
perpendicular to the rod and passing through its middle point is kg m , where the value of x is _____ .
x
20
2
28. Two blocks of mass 2kg and 4 kg are connected by a metal wire going over a smooth pulley as shown in
figure. The radius of wire is 4.0 × 10 m and Young’s modulus of the metal is 2.0 × 10 N /m . The
−5 11 2
longitudinal strain developed in the wire is . The value of α is ____. [Use g = 10m/s ]
1
απ
2
29. A body of mass ‘m’ is projected with a speed ‘u’ making an angle of 45 with the ground. The angular
∘
momentum of the body about the point of projection, at the highest point is expressed as . The value
√ 2 mu
Xg
of ‘X’ is _____.
30. In the following circuit, the battery has an emf of 2V and an internal resistance of 2
3
Ω . The power
consumption in the entire circuit is _____ W.
(a)
(b)
(c)
(d)
34. Identify structure of 2,3-dibromo-1-phenylpentane.
(a)
(b)
(c)
(d)
α 2 P 2
(a) KP = 3
(2+α) 2
3 1
α 2 P 2
(b) KP = 1
(2+α) 2 (1−α)
1 1
α 2 P 2
(c) KP = 1
(2+α) 2
1 3
α 2 P 2
(d) KP = 3
(2+α) 2
(a)
(b)
(c)
(d)
38. The four quantum numbers for the electron in the outer most orbital of potassium (atomic no. 19) are
(a) n = 4, l = 0, m = 0, s = +
1
(b) n = 2, l = 0, m = 0, s = +
1
(c) n = 4, l = 2, m = –1, s = +
1
(d) n = 3, l = 0, m = 1, s = +
1
2
39. The correct order of reactivity in electrophilic substitution reaction of the following compounds is:
(a) A>B>C>D
(b) B>C>A>D
(c) B>A>C>D
(d) D>C>B>A
Which of the following is/are true about A', B', C' and D'?
A. Order of atomic radii: B' < A' < D' < C'
B. Order of metallic character : B' < A' < D' < C'
C. Size of the element : D' < C' < B' < A'
D. Order of ionic radii : B'+ < A'+ < D'+ < C'+
Choose the correct answer from the options given below :
(a) A, B and D only
(b) A and B only
(c) B, C and D only
(d) A only
42. Identify A and B in the following reaction sequence.
(a)
(b)
(c)
(d)
43. The azo-dye (Y) formed in the following reactions
is Sulphanilic acid + NaNO2 + CH3COOH → X
(a)
(b)
(c)
(d)
44. The fragrance of flowers is due to the presence of some steam volatile organic compounds called essential
oils. These are generally insoluble in water at room temperature but are miscible with water vapour in
vapour phase. A suitable method for the extraction of these oils from the flowers is -
(a) steam distillation
(b) crystallisation
(c) distillation under reduced pressure
(d) distillation
45. Given below are two statements :
Statement I: Group 13 trivalent halides get easily hydrolyzed by water due to their covalent nature.
Statement II: AlCl3 upon hydrolysis in acidified aqueous solution forms octahedral [Al(H2O)6]3+ ion.
In the light of the above statements, choose the correct answer from the options given below :
(a) Statement I is false but statement II is true
(b) Statement I is true but statement II is false
(c) Both statement I and statement II are false
(d) Both statement I and statement II are true
50. A sample of CaCO3 and MgCO3 weighed 2.21 g is ignited to constant weight of 1.152 g. The composition
of mixture is :
(Given molar mass in g mol–1 CaCO3 : 100, MgCO3 : 84)
(a) 1.187 g CaCO3 + 1.187 g MgCO3
(b) 1.023g CaCO3 + 1.023g MgCO3
(c) 1.187 g CaCO3 + 1.023g MgCO3
(d) 1.023g CaCO3 + 1.187 g MgCO3
51. r = k[A] for a reaction, 50% of A is decomposed in 120 minutes. The time taken for 90% decomposition of
A is ______ minutes.
52. If 5 moles of an ideal gas expands from 10 L to a volume of 100 L at 300 K under isothermal and reversible
condition then work, w, is –x J. The value of x is ______.
(Given R = 8.314 J K–1 mol–1)
53. A compound (x) with molar mass 108 g mol–1 undergoes acetylation to give product with molar mass 192 g
mol–1. The number of amino groups in the compound (x) is ______.
56. Number of moles of H+ ions required by 1 mole of MnO – to oxidise oxalate ion to CO is ____.
4 2
57. In the reaction of potassium dichromate, potassium chloride and sulfuric acid (conc.), the oxidation state of
the chromium in the product is (+)_______.
58. From the vitamins A, B1, B6, B, C, D, E and K, the number vitamins that can be stored in our body is
______.
59. A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1Å, then fractional charge on
each atom is ______ × 10–1 esu .
(Given 1D = 10–18 esu cm)
60. The molarity of 1L orthophosphoric acid (H PO ) having 70% purity by weight (specific gravity 1.54 g cm–
3 4
3)is ______M.
(Molar mass of H3PO4 = 98 g mol–1)
61. Consider the function f : (0, ∞) → R defined by f (x) = e . If m and n be respectively the number
−|log x|
e
x 1
⎛ ⎞ ⎛ ⎞
Then, the system (A − 3I ) ⎜ y ⎟ = ⎜2⎟ has
⎝ ⎠ ⎝ ⎠
z 3
(a) no solution
(b) exactly two solutions
(c) unique solution
(d) infinitely many solutions
64. Let a variable line passing through the centre of the circle x + y − 16x − 4y = 0, meet the positive co-
2 2
ordinate axes at the points A and B . Then the minimum value of OA + OB, where O is the origin, is equal
to
(a) 18
(b) 12
(c) 20
(d) 24
65. Let (α, β, γ) be the mirror image of the point (2, 3, 5) in the line x−1
=
y−2
=
z−3
. Then, 2α + 3β + 4γ
2 3 4
is equal to
(a) 33
(b) 31
(c) 32
(d) 34
66. The number of ways in which 21 identical apples can be distributed among three children such that each
child gets at least 2 apples, is
(a) 406
(b) 136
(c) 130
(d) 142
− −−−−
(a) √1 + e 6
−−− −−
(b) 3√1 + e 6
−−− −−
(c) 4√1 + e 6
−−− −−
(d) 2√1 + e 6
is equal to
(a) 384
(b) 372
(c) 376
(d) 380
69. Let A (a, b) , B (3, 4) and c (−6, −8) respectively denote the centroid, circumcentre and orthocentre of a
triangle. Then, the distance of the point P (2a + 3, 7b + 5) from the line 2x + 3y − 4 = 0 measured
parallel to the line x − 2y − 1 = 0 is
(a)
17√ 5
(b) 15√ 5
(c) 17√ 5
(d) √5
17
70. x x
2
1
(c) 4π + 25 2
(d) 4π − 20π + 50
2
72. Let f : R → (0, ∞) be strictly increasing function such that lim
f (7x)
= 1 . Then, the value of
f (x)
x→∞
f (5x)
lim [
f (x)
− 1] is equal to
x→∞
(a) 0
(b) 1
(c) 7
(d) 4
(a) 75
(b) 30√– 3
(c) 25√– 3
−−
(d) 15√15
141
(b) √ 221
24
(c) √ 117
42
(d) √ 117
75. The temperature T (t) of a body at time t = 0 is 160° F and it decreases continuously as per the differential
equation = −K (T − 80) , where K is a positive constant. If T (15) = 120 F , then T (45) is equal to
dT
dt
∘
(a) 95° F
(b) 90° F
(c) 80° F
(d) 85° F
76. Let P be a parabola with vertex (2, 3) and directrix 2x + y = 6 . Let an ellipse E :
x
2
+
y2
= 1, a > b,
2 2
a b
of eccentricity 1
√2
pass through the focus of the parabola P . Then, the square of the length of the latus
rectum of E , is
(a) 347
(b)
656
25
(c) 385
(d) 512
25
(d) 14
3
78. Let 2nd, 8th and 44th terms of a non-constant A.P. be respectively the 1st, 2nd and 3rd terms of a G.P. If the
first term of the A.P. is 1, then the sum of its first 20 terms is equal to
(a) 960
(b) 990
(c) 980
(d) 970
79. A coin is biased so that a head is twice as likely to occur as a tail. If the coin is tossed 3 times, then the
probability of getting two tails and one head is
(a) 2
27
(b) 1
27
(c) 2
(d) 1
80. Let the mean and the variance of 6 observations a, b, 68, 44, 48, 60 be 55 and 194, respectively. If a > b ,
then a + 3b is
(a) 180
(b) 200
(c) 210
(d) 190
81. Let A (−2, −1) , B (1, 0) , C (α, β) and D (γ, δ) be the vertices of a parallelogram ABC D. If the point C
lies on 2x − y = 5 and the point D lies on 3x − 2y = 6, then the value of |α + β + γ + δ| is equal to
_____.
82. If lim
2 x
ax e −blog (1+x)+cxe
e
−x
= 1, then 16 (a 2
+ b
2 2
+ c ) is equal to ____.
2
x sin x
x→0
83. A line passes through A (4, −6, −2) and B (16, −2, 4). The point P (a, b, c), where a, b, c are non-
negative integers, on the line AB lies at a distance of 21 units, from the point A. The distance between the
points P (a, b, c) and Q (4, −12, 3) is equal to _____.
84. Let A be a 3 × 3 matrix and det (A) = 2 . If n = det (adj (adj (. . . . . (adj A)))), then the remainder
2024 - times
(x + 3)
n−1
+ (x + 3)
n−2
(x + 2) + (x + 3)
n−3 2
(x + 2) +. . . +(x + 2)
n−1
be α . If
r
n
∑ αr = β
n
− γ
n
, β, γ ∈ N , then the value of β 2
+ γ
2
equals _____.
r=0
86. Let a, b, c be the lengths of three sides of a triangle satisfying the condition
(a + b ) x − 2b (a + c) x + (b + c ) = 0. If the set of all possible values of x is the interval (α, β) ,
2 2 2 2 2
88. Let a⃗ ^ ^ ^
= 3 i + 2 j + k,
⃗ ^ ^ ^
b = 2 i − j + 3kand c ⃗ be a vector such that
2
2 (a ⃗ × b) + 24 j − 6k and (a ⃗ − b + i ) ⋅ c ⃗ = −3. Then |c |⃗ is equal to ___.
⃗ ⃗ ^ ^ ⃗ ^
(a ⃗ + b) × c ⃗ =
89. ∣ π
2
∣
∣
120
3
∫
x sin x cos x
4 4
dx∣ is equal to ____.
π sin x+cos x
∣ 0
∣
2
,y(
π
4
) = 0 . If y ( π
6
) = α, then e 8α
is equal to
______.
Answer Key
1. B 2. D 3. B 4. B 5. A 6. B
7. D 8. C 9. A 10. D 11. B 12. D
13. C 14. A 15. A 16. D 17. A 18. B
19. B 20. B 21. 27 22. 4 23. 20 24. 2
25. 200 26. 12 27. 53 28. 12 29. 8 30. 3
31. A 32. A 33. C 34. C 35. B 36. C
37. C 38. A 39. B 40. C 41. A 42. D
43. D 44. A 45. D 46. A 47. A 48. C
49. C 50. C 51. 399 52. 28721 53. 2 54. 6
55. 4 56. 4 57. 6 58. 5 59. 0 60. 11
61. A 62. C 63. C 64. B 65. A 66. B
67. D 68. B 69. C 70. B 71. B 72. A
73. A 74. B 75. B 76. B 77. A 78. D
79. C 80. A 81. 32.00 82. 81.00 83. 22.00 84. 7.00
85. 25.00 86. 36.00 87. 66.00 88. 38.00 89. 15.00 90. 9.00
Solutions
1. (B)
2
[B] = L
2 2
x L 1
A = = 2 −2
= −1
tE TML T MT
−1
[A] = M T
2 −1 1
[AB] = [L M T ]
2. (D)
q q
In air F = 1
4π∈ 0
1
r2
2
In medium
1 q q q q
′ 1 2 25 1 2
F = = = 5F
2 2
4π(K∈ 0 ) ′ 4π(5∈ 0 )
(r ) (r)
3. (B)
−−− −−−− −−−− −−−−
The magnitude of resultant vector R = ′
√a 2 + b2 + 2ab cos θ
Here a = b = R
− −−−−−−−−−−−−−−−
Then R = √R + R + 2R cos θ
′ 2 2 2
– −−−− −−−
= R√ 2√ 1 + cos θ
−−−−− −
– 2 θ
= √ 2R√2cos
2
θ
= 2R cos
2
4. (B)
−
− −
− −−−−−−−−
γRT
1.4×8.3×273
v = √ = √ −3
M 32×10
= 314.8541 ≃ 315m/s
5. (A)
2
1 2 B
ε0 E =
2 2μ
0
∵ E = CB and C =
μ ε0
1
6. (B)
R2
R1 =
2
1 1
R0
R 0 (A1 ) 3
= (A2 ) 3
2
1
A1 = A2
8
192
A1 = = 24
8
7. (D)
2
P = i R
2
P int = I R
int
2
P f inal = (0.8 Iint ) R
Pfinal −Pint
% change in power = Pint
× 100 = (0.64 − 1) × 100 = −36%
8. (C)
If A ¯
= 0; A = 1
¯
A = 1; A = 0
¯
B = 0; B = 1
¯
B = 1; B = 0
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
¯ ¯
Y = (A + B ) + (A + B) = (1 + 1) = 0
9. (A)
−
−
ℓ
T = 2π√
g
2
4π ℓ
g = 2
T
Δg Δℓ 2ΔT
= +
g ℓ T
0.2 1
= + 2( )
20 40
0.3
=
20
20
× 100 = 6%
10. (D)
⃗ ^ 2^
F = (6t i + 6t j) N
⃗ ^ 2^
F = ma ⃗ = (6t i + 6t j)
⃗
F ^ 2^
a⃗ = = (3t i + 3t j)
m
t
2
3t ^ 3^
v ⃗ = ∫ a dt
⃗ = i + t j
2
0
⃗ 3 5
P = F . v ⃗ = (9t + 6t ) W
11. (B)
−−−−
2GM
V escape = √
R
−−−−
2GM
V Planet = √ = V
R
−−−−−− −−−−
2GM ×16 1 2GM
V Moon = √ = √
144R 3 R
V Planet V
V Moon = =
3 3
12. (D)
25 X
= . . . . . (i)
rℓ1 rℓ2
25 X
′
= ′
. . . . (ii)
2rℓ 1 2rℓ 2
13. (C)
fK = μmg cos θ
50×√ 3
= 0.1 ×
2
–
= 2.5√ 3N
F 1 = mg sin θ + fK
–
= 25 + 2.5√ 3
F 2 = mg sin θ − fK
–
= 25 − 2.5√ 3
–
∴ F 1 − F 2 = 5√ 3N
14. (A)
Since density is negligible hence Buoyancy force will be negligible
At terminal velocity. M g = 6πηrv
V ∝ (as mass is constant)
1
Now,
′
v r
′
=
v r
′
r = 2r
So, v ′
=
v
2
15. (A)
< P >= I V cos ϕ
20 10 ∘
= × × cos 60
√2 √2
= 50W
16. (D)
f
Since < f i.e. the incident frequency is less than threshold frequency. Hence thee will be no emission of
2
0
photoelectrons.
⇒Current = 0
17. (A)
By Brewster’s law
18. (B)
⃗ ⃗
M = iA
^
= 5 × (0.2) × (0.1) (− i )
= 0.1 (−^
i)
⃗ ⃗ ^ −3 ^
τ ⃗ = M × B = 0.1 (− i ) × (2 × 10 ) ( j)
−4 ^
= 2 × 10 (−k ) N − m
19. (B)
(m1 −m2 )g g
a = =
(m1 +m2 ) 8
8m1 − 8m2 = m1 + m2
7m1 = 9m2
m1 9
=
m2 7
20. (B)
U = nC V T
⇒ U = n1 C V 1 T + n2 C V 2 T
3R 5R
⇒ 8 × × T + 6 × × T = 27RT
2 2
21. (27)
9
⃗ r⃗
Kp . 9×10 (6qℓ)
∘
V = = cos(120 )
3 2
r r
qℓ
9 2 −2
= − (27) ( ) × 10 N m c
2
r
⇒ α = 27
22. (4)
For a nucleus
Volume: V = 4
3
πR
3
R = R 0 (A) 3
4 3
V = πR A
4 0
V2 A2
⇒ = = 4
V1 A1
23. (20)
μ N i1 μ ×1×100
0 0 −3
BP = = = 2 × 10 T
2r 2π
μ N i2 μ ×2×100
0 0 −3
BQ = = = 4 × 10 T
2r 2π
−−−−−−−−
2 2
B net = √B + B
P Q
− −
= √ 20 mT
x = 20
24. (2)
dϕ
ε = −( ) = 10t − 36
dt
At t = 2, ε = 16V
ε 16
i = = = 2A
R 8
25. (200)
μ μ μ −μ
2 1 2 1
− =
v u R
1.5 1 1.5−1
− =
v −100 20
v = 100cm
26. (12)
2k.k 5k
k eq = + k =
3k 3
−
−−
keq
Angular frequency of oscillation (ω) = √
m
−−
−
5k
(ω) = √
3m
−−
−
Period of oscillation (τ ) =
2π
ω
= 2π√
3m
5k
−−−
12m
= π√
5k
27. (53)
2 2 2
I = ( mR + md ) × 2
5
2 2
2 1 3 53 2
I = 2( × 2 × ( ) + 2 × ( ) ) = kg − m
5 2 4 20
X = 53
28. (12)
2m1 m2 80
T = ( )g = N
m1 +m2 3
2 −10 2
A = πr = 16π × 10 m
Strain = Δℓ
ℓ
=
F
AY
=
T
AY
80
3 1
= −10 11
=
16π×10 ×2×10 12π
α = 12
29. (8)
2 2
u sin θ
L = mu cos θ
2g
3 1
= mu ⇒ x = 8
4√ 2 g
30. (3)
4
R eq = Ω
3
2
V 4
∴ P = = = 3W
R eq 4/3
31. (A)
(A) Mn2O7 is green oil at room temperature.
(B) V2O4 dissolve in acids to give VO2+ salts.
(C) CrO is basic oxide
(D) V2O5 is amphoteric it reacts with acid as well as base.
32. (A)
S1: S8 + 12 OH⊖ → 4S2– + 2S2O32– + 6H2O
S2: ClO4⊖ cannot undergo disproportionation reaction as chlorine is present in it’s highest oxidation state.
33. (C)
34. (C)
2, 3-dibromo -1-phenylpentane
35. (B)
A(g) ⇌ B(g) + (g) C
t = teq (1 – α), α, α
2
α
α (1−α)
2
PB = . P, PA = . P , PC = .P
α α α
(1+ ) (1+ ) (1+ )
2 2 2
2
PB .P
C
KP =
PA
3 1
α 2 P 2
KP = 1
(2+α) 2 (1−α)
36. (C)
Gatterman-Koch reaction
37. (C)
38. (A)
2 2 6 2 6 1
19K 1s , 2s , 2p , 3s , 3p , 4s .
Outermost orbital of potassium is 4s orbital
n = 4, l = 0, m = 0, s = + . 1
39. (B)
–CH3 shows +M and +I .
–Cl shows +M and –I but inductive effect dominates.
–NO2 shows –M and –I.
Electrophilic substitution α −M and −I
1
α + M and +I
Hence, order is B > A > C > D.
40. (C)
(A) All group 16 elements form oxides of the EO2 and EO3 type where E = S, Se, Te or Po.
(B) SO2 is reducing while TeO2 is an oxidising agent.
(C) The reducing property increases from H2S to H2Te down the group.
(D)
41. (A)
In general along the period from left to right, size decreases and metallic character decrease.
In general down the group, size increases and metallic character increases.
B' < A'(size) C' > A'(size)
D' < C'(size) D' > B'(size)
B' < A' (metallic character)
D' < C' (metallic character)
B'+ < A'+ (size)
D'+ < C'+ (size)
∴ C statement is incorrect.
42. (D)
43. (D)
44. (A)
Steam distillation technique is applied to separate substances which are steam volatile and are immiscible with
water.
45. (D)
In trivalent state most of the compounds being covalent are hydrolysed in water. Trichlorides on hydrolysis in
water form tetrahedral [M(OH)4]– species, the hybridisation state of element M is sp3.
In case of aluminium, acidified aqueous solution forms octahedral [Al(H2O)6]3+ ion.
46. (A)
47. (A)
AgCl < CoCl2 < BaCl2 < KCl (ionic character)
Reason: Ag+ has pseudo inert gas configuration.
48. (C)
[Cr(H2O)6]3+ Contains Cr3+ : [Ar] 3d3 : t2g3eg0
[Fe(H2O)6]3+ Contains Fe3+ : [Ar] 3d5 : t2g3eg2
[Ni(H2O)6]2+ Contains Ni2+ : [Ar] 3d8 : t2g6eg2
[V(H2O)6]3+ Contains V3+ : [Ar] 3d2 : t2g2eg0
49. (C)
[Ni(CO)4], diamagnetic, sp3 hybridisation, number of unpaired electrons = 0
[NiCl4]2–, paramagnetic, sp3 hybridisation, number of unpaired electrons = 2
50. (C)
Δ
100
= moles of CaO formed
∴ weight of CaO formed = × 56 x
100
84
= moles of MgO formed
∴ weight of MgO formed=
2.21−x
× 40
84
2.21−x x
⇒ × 40 + × 56 = 1.152
84 100
51. (399)
r = k[A]
So, order of reaction = 1
t1/2 = 120min
For 90% completion of reaction
2.303 a
⇒ k = log( )
t a−x
0.693 2.303 100
⇒ = log
t 1/2 t 10
∴ t = 399 min.
52. (28721)
It is isothermal reversible expansion, so work done negative
V2
W = –2.303 nRT log( V1
)
10
)
= –28720.713 J
≡ –28721 J
53. (2)
Gain in molecular weight after acylation with one –NH2 group is 42.
Total increase in molecular weight = 84
∴ Number of amino group in x = =2
84
42
54. (6)
55. (4)
Conductivity (S m–1)
2.1 × 103, 1.2 × 10, 3.91, 1 × 103
are conductors at 298.15K
1 × 10–16 Insulator at 298.15 K
1.5 × 10–2, 1 × 10–7
Semiconductor at 298.15 K
Therefore, number of conductors is 4.
56. (4)
2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O
∴ Number of moles of H+ ions required by 1 mole of MnO4– to oxidise oxalate ion to CO2 is 8
57. (6)
K2Cr2O7(s) + 4KCl(s) + 6H2SO4 conc. → 2CrO2Cl2(g) + 6KHSO4 + 3H2O
This reaction is called chromyl chloride test.
Here oxidation state of Cr is +6.
58. (5)
Vitamins A, D, E, K and B12 are stored in liver and adipose tissue.
59. (0)
μ = 1.2 D = q × d
⇒ 1.2 × 10–10 esu Å = q × 1Å
∴ q = 1.2 × 10–10 esu
60. (11)
Specific gravity (density) = 1.54 g/cc.
Volume = 1L = 1000 ml
Mass of solution = 1.54 × 1000 = 1540 g
% purity of H2SO4 is 70%
So weight of H3PO4 = 0.7 × 1540 = 1078 g
Mole of H3PO4 = 1078
98
= 11
Molarity = = 11 11
1 L
61. (A)
f : (0, ∞) → R
−|log x|
f (x) = e e
1
; 0 < x < 1
− ln x
1 e
f (x) = = {
|ln x| 1
e
; x ⩾ 1
ln x
e
1
⎧ 1
= x; 0 < x < 1
⎨ x
⎩ 1
; x ⩾ 1
x
Let A = ⎢ x2 y2 z2 ⎥
⎣ ⎦
x3 y3 z3
1 2
⎡ ⎤ ⎡ ⎤
Given A ⎢ 0 ⎥ = ⎢0⎥ . . . . (1)
⎣ ⎦ ⎣ ⎦
1 2
x1 + z 1 2
⎡ ⎤ ⎡ ⎤
∴ ⎢ x2 + z 2 ⎥ = ⎢ 0 ⎥
⎣ ⎦ ⎣ ⎦
x3 + z 3 2
∴ x1 + z 1 = 2 . . . . (2)
x2 + z 2 = 0 . . . . (3)
x3 + z 3 = 0 . . . (4)
−1 −4
⎡ ⎤ ⎡ ⎤
Given A ⎢ 0 ⎥ = ⎢ 0 ⎥
⎣ ⎦ ⎣ ⎦
1 4
−x1 + z 1 4
⎡ ⎤ ⎡ ⎤
∴ ⎢ −x2 + z 2 ⎥ = ⎢ 0 ⎥
⎣ ⎦ ⎣ ⎦
−x3 + z 3 4
⇒ −x1 + z 1 = −4 . . . (5)
−x2 + z 2 = 0 . . . . (6)
−x3 + z 3 = 4
0 0
⎡ ⎤ ⎡ ⎤
Given A ⎢ 1 ⎥ = ⎢2⎥
⎣ ⎦ ⎣ ⎦
0 0
y1 0
⎡ ⎤ ⎡ ⎤
∴ ⎢ y2 ⎥ = ⎢ 2 ⎥
⎣ ⎦ ⎣ ⎦
y3 0
∴ y1 = 0, y2 = 2, y3 = 0
y1 = 0, y2 = 2, y3 = 0
z 1 = −1, z 2 = 0, z3 = 3
3 0 −1
⎡ ⎤
∴ A = ⎢ 0 2 0 ⎥
⎣ ⎦
−1 0 3
x −1
⎡ ⎤ ⎡ ⎤
∴ Now (A − 3I ) ⎢ y ⎥ = ⎢ 2 ⎥
⎣ ⎦ ⎣ ⎦
z 3
0 0 −1 x −1
⎡ ⎤⎡ ⎤ ⎡ ⎤
∴ ⎢ 0 −1 0 ⎥⎢ y ⎥ = ⎢ 2 ⎥
⎣ ⎦⎣ ⎦ ⎣ ⎦
−1 0 0 z 3
−z 1
⎡ ⎤ ⎡ ⎤
⎢ −y ⎥ = ⎢ 2 ⎥
⎣ ⎦ ⎣ ⎦
−x 3
⇒ t = 1 ± 1.73
So no solution
64. (B)
(y − 2) = m (x − 8)
⇒ x -intercept
−2
⇒ ( + 8)
m
⇒ y -intercept
⇒ (−8m + 2)
−2
⇒ OA + OB = + 8 − 8m + 2
m
′ 2
f (m) = − 8 = 0
2
m
2 1
⇒ m =
4
−1
⇒ m =
2
−1
⇒ f ( ) = 18
2
⇒ Minimum = 18
65. (A)
−
−→
∵ P R⊥ (2, 3, 4)
−
−→
∴ P R. (2, 3, 4) = 0
(α − 2, β − 3, γ − 5) . (2, 3, 4) = 0
⇒ 2α + 3β + 4γ = 4 + 9 + 20 = 33
66. (B)
After giving 2 apples to each child 15 apples left now 15 apples can be distributed in 15+3−1
C2 =
17
C2 ways
17×16
= = 136
2
67. (D)
3
x −3x+1
f (x) = e
3
′ x −3x+1 2
f (x) = e ⋅ (3x − 3)
3
x −3x+1
= e .3 (x − 1) (x + 1)
For f ′
(x) ⩾ 0
P (2b + 4, a + 2)
3
∴ P (2e + 4, 2)
3 −3
(2e +4)+2e −4 −−−−−
d = = 2√1 + e 6
√ 1+e−6
68. (B)
6 6 6 8
C m + 2 ( C m+1 ) + C m+2 > C3
7 7 8
C m+1 + C m+2 > C3
8 8
C m+2 > C3
∴ m = 2
And n−1
P3 :
n
P4 = 1 : 8
(n−1)(n−2)(n−3)
1
=
n(n−1)(n−2)(n−3) 8
∴ n = 8
n n+1 8 9
∴ P m+1 + Cm = P3 + C2
9×8
= 8 × 7 × 6 +
2
= 372
69. (C)
A (a, b) , B (3, 4) , C (−6, 8)
⇒ a = 0, b = 0 ⇒ P (3, 5)
⇒ x = 3 + r cos θ, y = 5 + r sin θ
where tan θ =
1
∣ −17√ 5 ∣ 17√ 5
⇒ r = =
∣ 7 ∣ 7
70. (B)
x
2
2 −t
f (x) = ∫ (|t| − t ) e dt
−x
2
′ 2 −x
⇒ f (x) = 2. (|x| − x ) e . . . (1)
2
x
1
−t
g (x) = ∫ t 2 e dt
0
2
′ −x
g (x) = xe (2x) − 0
2 2 2
′ ′ −x 2 −x 2 −x
f (x) + g (x) = 2xe − 2x e + 2x e
0
2
x = t
√α
α
−t −t √
⇒ ∫ e dt = [−e ]
0
0
−1
(log (9) )+1
e
= −e
1
⇒ 9 (f (x) + g (x)) = (1 − )9 = 8
9
71. (B)
−1
a = sin (sin 5) = 5 − 2π
and b = cos
−1
(cos 5) = 2π − 5
2 2 2 2
∴ a + b = (5 − 2π) + (2π − 5)
2
= 8π − 40π + 50
72. (A)
f : R → (0, ∞)
f (7x)
lim = 1
f (x)
x→∞
∵ f is increasing
∴ f (x) < f (5x) < f (7x)
f (x) f (5x) f (7x)
∵ < <
f (x) f (x) f (x)
f (5x)
1 < lim < 1
f (x)
x→∞
f (5x)
∴ [ − 1]
f (x)
⇒ 1 − 1 = 0
73. (A)
z1 + z2 = 5
3 3
z1 + z2 = 20 + 15i
3 3
z1 + z2 = 125 − 3z 1 . z 2 (5)
⇒ 3z 1 z 2 = 25 − 4 − 3i
⇒ 3z 1 z 2 = 21 − 3i
⇒ z1 . z2 = 7 − i
2
⇒ (z 1 + z 2 ) = 25
2 2
⇒ z1 + z2 = 25 − 2 (7 − i)
⇒ 11 + 2i
2
2 2
(z 1 + z2 ) = 121 − 4 + 44i
4 4 2
⇒ z1 + z2 + 2(7 − i) = 117 + 44i
4 2
⇒ z1 + z2 = 117 + 44i − 2 (49 − 1 − 14i)
4 4
⇒ ∣
∣z1 + z2 ∣∣ = 75
74. (B)
x+4 y−4 z−3
L2 = = =
3 2 0
∣ x 2 −x 1 y −y z2 −z1 ∣
2 1
∣ ∣
∣ 2 −3 2 ∣
∣ ∣
S.D. =
∣ 3 2 0 ∣
∴
∣ ⃗ ⃗
∣n1 ×n2 ∣
∣
∣ 5 −5 −7 ∣
∣ ∣
∣ 2 −3 2 ∣
∣ ∣
∣ 3 2 0 ∣
=
∣ ⃗ ⃗
∣n1 ×n2 ∣
∣
141
=
∣ ^ ^ ^∣
−4 i +6 j +13k
∣ ∣
141
=
√ 16+36+169
141
=
√ 221
75. (B)
dT
= −k (T − 80)
dt
T t
dT
∫ = ∫ −K dt
(T −80)
160 0
T
[ln|T − 80|] = −kt
160
= 90
76. (B)
Slope of axis = 1
2
1
y − 3 = (x − 2)
2
⇒ 2y − 6 = x − 2
⇒ 2y − x − 4 = 0
2x + y − 6 = 0
4x + 2y − 12 = 0
α + 1.6 = 4 ⇒ α = 2.4
β + 2.8 = 6 ⇒ β = 3.2
⇒ + 2
= 1 . . . (1)
2
a b
2 2
Also 1 − b
a
2
=
1
2
=
b
a
2
=
1
2
2 2
⇒ a = 2b
Put in (1) ⇒ b
2
=
328
25
2 2 2
2b 4b 2 1 328 656
⇒ ( ) = × b = 4 × × =
a a
2 2 25 25
77. (A)
4
∣ (x−4)
2 ∣
Area = ∣∫ [(4x − x ) −
2
3
] dx∣
∣1 ∣
3 4
∣ (x−4) ∣
Area =
2 3
4x x
∣ − − ∣
3
∣ 2 9 ∣1
64 64 4 1 27
= ∣
∣( − − + − )∣
∣
2 3 2 3 9
⇒ (27 − 21) = 6
78. (D)
1 + d, 1 + 7d, 1 + 43d are in GP
2
(1 + 7d) = (1 + d) (1 + 43d)
2 2
1 + 49d + 14d = 1 + 44d + 43d
2
6d − 30d = 0
d = 5
20
S20 = [2 × 1 + (20 − 1) × 5]
2
= 10 [2 + 95]
= 970
79. (C)
Let probability of tail is 1
80. (A)
a, b, 68, 44, 48, 60
Mean = 55 a > b
Variance = 194 a + 3b
a+b+68+44+48+60
= 55
6
⇒ 220 + a + b = 330
∴ a + b = 110 . . . . (1)
Also,
2
(x i−x̄ )
∑ = 194
n
2 2 2 2 2 2
⇒ (a − 55) + (b − 55) + (68 − 55) + (44 − 55) + (48 − 55) + (60 − 55) = 194 × 6
2 2
⇒ (a − 55) + (b − 55) + 169 + 121 + 49 + 25 = 1164
2 2
⇒ (a − 55) + (b − 55) = 1164 − 364 = 800
2 2
a + 3025 − 110a + b + 3025 − 110b = 800
2 2
⇒ a + b = 800 − 6050 + 12100
2 2
a + b = 6850 . . . . (2)
γ+1 β−1
and
α−2 δ
= =
2 2 2 2
⇒ α − γ = 3 . . . . (1) , β − δ = 1 . . . . (2)
3γ − 2δ = 6 . . . . (3)
⇒ 2α − β = 5 . . . . . (4)
|α + β + γ + δ| = 32
82. (81.00)
2 3 2 3
2 x x x x
a (1 + x + + + … . .) − b (x − + − … … .)
2! 3! 2 3
2 3
x x
+cx(1−x+ − +…….)
x! 3!
lim sin x
3
x→0 x ⋅
x
b 2 b c 3
(c−b)x+( −c+a)x +(a− + )x +……
2 3 2
= lim = 1
3
x→∞ x
b
c − b = 0, − c + a = 0
2
b c 3 3
a − + = 1 a = b = c =
3 2 4 2
2 2 2 9 9 9
a + b + c = + +
16 4 4
2 2 2
16 (a + b + c ) = 81
83. (22.00)
x−4 x+6 z+2
= =
12 4 6
x−4 y+6 z+2
6
= 2
= 3
= 21
7 7 7
6 2 3
(21 × + 4, × 21 − 6, × 21 − 2)
7 7 7
= (22, 0, 7) = (a, b, c)
−−−−−−−−−−−−
∴ √ 324 + 144 + 16 = 22
84. (7.00)
|A| = 2
2024
(n−1)
adj (adj (adj. . . . . (a))) = |A|
2024 times
2024
2
= |A|
2024
2
= 2
2024 674 674
2 2 2022
2 = (2 ) 2 = 4(8) = 4(9 − 1)
2024
⇒ 2 ≡ 4 ( mod 9)
⇒ 2
2024
≡ 9m + 4, m ← even
3m
9m+4 3
2 ≡ 16.(2 ) ≡ 16 ( mod 9)
≡ 7
85. (25.00)
n−1 n−2 n−3
(x + 3) + (x + 3) (x + 2) + (x + 3)
2 n−1
(x + 2) + … … . +(x + 2)
n−1 n−2 n−3 2 n−1
∑ αr = 4 + 4 × 3 + 4 × 3 …… + 3
2 n−1
n−1 3 3 3
= 4 [1 + + ( ) … . +( ) ]
4 4 4
n
3
1−( )
n−1 4
= 4 × 3
1−
4
n n n n
= 4 − 3 = β − γ
β = 4, γ = 3
2 2
β + γ = 16 + 9 = 25
86. (36.00)
2 2 2 2 2
(a + b )x − 2b(a + c)x + b + c = 0
2 2 2 2 2 2
⇒ a x − 2abx + b + b x − 2bcx + c = 0
2 2
⇒ (ax − b) + (bx − c) = 0
⇒ ax − b = 0, bx − c = 0
√ 5 −1 √ 5 +1
⇒ < x <
2 2
√ 5 −1 √ 5 +1
⇒ α = ,β =
2 2
2 2
(√ 5 −1) +(√ 5 +1)
2 2
12 (α + β ) = 12 ( ) = 36
4
87. (66.00)
R = {(3, 2) , (6, 4) , (9, 6) , (12, 8) , . . . (99, 66)}
n (R) = 33
∴ 66
88. (38.00)
⃗ ⃗ ^ ^
(a ⃗ + b) × c ⃗ = 2(a ⃗ × b) + 24 j − 6k
^ ^ ^ ^ ^ ^ ^ ^
(5 i + j + 4k ) × c ⃗ = 2(7 i − 7 j − 7k ) + 24 j − 6k
∣ ^ ^ ^∣
i j k
∣ ∣
^ ˆ ˆ
∣ 5 1 4 ∣ = 14 i + 10 j − 20k
∣ ∣
∣x y z∣
ˆ ˆ ˆ ˆ ˆ ˆ
⇒ i (z − 4y) − j(5z − 4x) + k (5y − x) = 14 i + 10 j − 20k
2x + 3y − 2z = −3
∴ x = 5, y = −3, z = 2
2
|c |⃗ = 25 + 9 + 4 = 38
89. (15.00)
π
2
x sin x⋅cos x
∫ 4
dx
4
sin x+cos x
0
π
sin x⋅cos x 2 2
= ∫ 4
(x − (π − x) ) dx
4
sin x+cos x
0
π
2 2
sin x⋅cos x(2πx−π )
= ∫ 4 4
sin x+cos x
0
π π
2 2
2 2
2
2
π sin x cos x
= − ∫ 4
dx
2 sin x+cos x
4
0
π
2
2
π sin x cos xdx
= − ∫ 2
2 1−2sin x×cos x
2
0
π
2
2
π sin 2x
= − ∫ 2
dx
2 2−sin 2x
0
π
2
2
π sin 2x
= − ∫ dx
2 2
1+cos 2x
0
Let cos 2x = t
90. (9.00)
2 dx 2y 2
sec x + e tan x + tan x = 0
dy
2 dx dt
(Put tan x = 1 ⇒ sec x = )
dy dy
dt 2y 2
+ e × t + t = 0
dy
dt 2 2y
+ t = −t . e
dy
1 dt 1 −2y
+ = −e
2
dy t
t
1 −1 dt du
(Put = u = )
t 2
t dy dy
−du 2y
+ u = −e
dy
du 2y
− u = e
dy
− ∫ dy −y
I. F . = e = e
−y −y 2y
ue = ∫ e × e dy
1 −y y
× e = e + c
tan x
π
x = , y = 0, c = 0
4
π
x = ,y = α
6
– −α α
√ 3e = e + 0
2α
–
e = √3
8α
e = 9