R E VI E W T E S T- 7

PAPER-1
PAPER CODE : A
Class : XIII (XYZ & CC)
Time : 3 hour Max. Marks : 240
INSTRUCTIONS

1. The question paper contains 60 questions and 16 pages. Each question carry 4 marks and all of them are
compulsory. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.

2. Indicate the correct answer(s) for each question by filling appropriate bubble(s) in your OMR sheet.

3. Use only HB pencil for darkening the bubble(s).

4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

5. For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D

For example if only 'B & D' choices are correct then, the correct method for filling the bubbles is
A B C D

The answer of the question in any other manner (such as putting , cross , or partial shading etc.)
will be treated as wrong.

USEFUL DATA
Atomic Mass: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Ba = 137,
Co = 59, Hg = 200, Pb = 207, He = 4, F=19.
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1.
Take g = 10 m/s2 where ever required.
P A RT- A
Select the correct alternative(s). (One or More than one is/are correct)
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 A parallel plate capacitor of capacitance 200 F is charged by a battery of emf 100 V. The battery is
now disconnected and temperature of the plates is equal to atmospheric temperature. The plates are
now connected by a thin wire of negligible heat capacity. Assume 50% of their stored energy increases
their temperature till the capacitor gets completely discharged and energy equally distributes over the
plates. If thermal capacity of each plate is 0.5 JK–1 and coefficient of linear expansion is 2 × 10–5 °C–1,
percentage increase in the volume of the plates is
(A) 0.001% (B) 0.002% (C) 0.003% (D) 0.004%

Q.2 The graph shown can corrospond relationship between

(quantity quoted first is plotted on y-axis.)
(A) The distance of object from the focus of a convex mirror plotted against the
distance of the image from the same point.
(B) Pressure plotted against temperature for an ideal gas undergoing process P V = constant.
(C) Electric field due to charged conducting sphere plotted against distance from the centre of the
sphere.
(D) The tension in a string plotted against its fundamental frequency.

Q.3 Two small bodies of masses ‘m’ and ‘2m’ are placed in a fixed smooth horizontal
circular hollow tube of mean radius 'r' as shown. The mass ‘m’ is moving with
speed ‘u’ and the mass ‘2m’ is stationary. After their first collision, the time
elapsed for next collision is: (coefficient of restitution e = 1/2)
2r 4r 3r 12r
(A) (B) (C) (D)
u u u u

ROUGH WORK
Q.4 In the figure shown the system is at rest initially. Two persons ‘A’ and ‘B’ of
masses 40 kg each move with speeds v1 and v2 respectively towards each
other on a plank lying on a smooth horizontal surface as shown in figure. Plank
travels a distance of 20 m towards right direction in 5 sec. (Here v1 and v2 are
given with respect to the plank). Then the possible condition(s) can be
(A) v1 = 0 m/s, v2 = 10 m/s (B) v1 = 5 m/s, v2 = 15 m/s
(C) v1 = 10 m/s, v2 = 20 m/s (D) v1 = 2 m/s, v2 = 12 m/s

Q.5 Inside a hollow sphere of mass M, a rod of length R 2 is released from the state of
rest. The mass of the rod is same as that of the sphere. If the inner radius of the
hollow sphere is R then find out its horizontal displacement with respect to earth in
the time in which the rod becomes horizontal.
(A) R/2 (B) R/4 (C) R / 2 2 (D) None

Q.6 In a clock what is the time period of meeting of the minute hand and the second hand
60 59
(A) 59 sec (B) minutes (C) minutes (D) none of these
59 60

Q.7 A bob B of mass 1kg is suspended form the ceiling of a toy train as shown in the
figure. The train oscillates simple harmonically in horizontal direction with angular
frequency =5rad/s and amplitude a=0.1m. What is the ratio of maximum and
minimum tensions in the string AB during the motion (g=10 ms–2 & tan 37°= 3/4 )
(A) 2 (B) 3 (C) 4 (D) 1

Q.8 A stone is dropped from the top of a tall cliff and n seconds later another stone is thrown vertically
downwards with a velocity u. Then the second stone overtakes the first, below the top of the cliff at a
distance given by
2 2 2
g  n ( gn / 2  u )  g  n ( gn  u / 2)   (gn  u ) 
(A)   (B)  (C) g  (D) None
2  (gn  u )  2  (gn  u )  
 (gn  u / 2) 
ROUGH WORK
Q.9 Two particles are projected from the same point with the same speed in the same vertical plane at
different angles with the horizontal. A frame of reference is fixed to one particle. The position vector of

the other particle as observed from the frame is r . Which of the following statements is/are incorrect?

(A) r is a constant vector

(B) r changes in magnitude and direction with time

(C) the magnitude of r increases linearly with time, its direction does not change

(D) the direction of r changes with time, its magnitude may or may not change depending on the angles
of projection.

Q.10 String #1 is connected with string #2. The mass per unit length in string #1 is 1 and the mass per unit
length in string #2 is 41. The tension in the strings is T. A travelling wave is coming from the left. What
fraction of the energy in the incident wave goes into string #2?

(A) 1/8 (B) 4/9 (C) 2/3 (D) 8/9

Q.11 and Q.12 are together

Q.11 The curve of angle of incidence versus angle of deviation shown has been plotted
for prism. The value of refractive index of the prism used is
3 2
(A) 3 (B) 2 (C) (D)
2 3

Q.12 In the given curve of above question. Find the value of angle i1 in degrees is
(A) 40° (B) 60° (C) 70° (D) 90°

Q.13 A wire has linear resistance  (in Ohm/m). Find the resistance R between points
A and B if the side of the "big" square is d.
d
(A) (B) 2d (C) 2d (D) None
2
ROUGH WORK
Q.14 A solid sphere of mass m, suspended through a string in a liquid as shown. The string has some tension.
Magnitudes of net force due to liquid on upper hemisphere and that on lower hemisphere are FA and FB
respectively. Which of the following is / are true.
(A) Density of material of the sphere is greater than density of liquid
(B) Difference of FB and FA is dependent of atmospheric pressure
(C) FB – FA = mg
(D) FB–FA < mg
Question No. 15 to 17 (3 questions)
Two satellites A and B are revolving around the earth in circular orbits of radius
r1 and r2 respectively with r1 < r2. Plane of motion of the two are same. At
position 1, A is given an impulse in the direction of velocity by firing a rocket so
that it follows an elliptical path to meet B at position 2 as shown. Focal lengths
of the elliptical path are r1 and r2 respectively. At position 2, A is given another
impulse so that velocities of A and B at 2 become equal and the two move
together.
For any elliptical path of the satellite time period of revolution is given by Kepler's planetary law as
r r
T2  r3 where a is semi major axis of the ellipse which is 1 2 in this case. Also angular momentum of
2
any satellite revolving around the Earth will remain a constant about Earth's centre as force of gravity on
the satellite which keeps it in elliptical path is along its position vector relative to the earth centre.
Q.15 When A is given its first impulse at that moment
(A) A, B and earth centre are in same straight line
(B) B is ahead of A angularly
(C) B is behind A angularly
(D) none of these
Q.16 If the two have same mass
(A) A would have more potential energy than B while on their initial circular paths.
(B) A would have more kinetic energy than B while on their initial circular paths.
(C) Relative to Earth's centre, angular momentum of A when it is in elliptical path would be less than
angular momentum of B.
(D) During the whole process angular momentum of B would be more than angular momentum of A.
ROUGH WORK
Q.17 If r2 = 3r1 and time period of revolution for B be T than time taken by A in moving from position 1 to
position 2
3 3 T 2 T 2
(A) T (B) T (C) (D)
2 2 3 3 3
Q.18 A horizontal rod AB which is held by frictionless bearings at its ends, can rotate freely around its horizontal
axis. Two equal masses held in position, as shown, by rigid rods of negligible mass are symmetrically
located relative to the centre of rod. If the system is rotating with angular velocity  in absence of gravity,
then choose the correct alternative(s).

(A) The angular momentum of system about point O is along axis of rotation.
(B) The reaction force at bearings is upwards at A & downwards at B.
(C) The reaction force at bearings is downwards at A & upwards at B.
(D) There would be no reaction forces at bearings.
Q.19 If wedge is moving with acceleration a as shown in the figure and friction coefficient
between two blocks is  then value of net force on m is
(A) ma (B) 2 ma (C) mg – ma (D) zero
Q.20 In two experiments with a continuous flow calorimeter to determine the specific heat capacity of a liquid,
an input power of 60 W produced a rise of 10 K in the liquid. When the power was doubled, the same
temperature rise was achieved by making the rate of flow of liquid three times faster. The power lost to
the surroundings in each case was
(A) 20 W (B) 30 W (C) 40 W (D) 120 W

ROUGH WORK
Q.21 The solubility of H2 (g) and CO (g) in molten KNO3 / NaNO3 is given by
log10 (S H ) = – 5.4 – 768 (T/K)–1
2

log10(SCO) = – 6 – 980(T/K)–1
where S is the solubility in mole cm–3 bar–1. Based on above write up- identify the correct statement(s)
among the following. {Assume S° and H° do not vary with 'T'}
o o
(A) H solution [CO(g)] > H solution [H2(g)] (at 500 K)
o
(B) Ssolution [CO(g)] > Sosolution [H2(g)] (at 500 K)
(C) At very high temperature the process CO (g) + solvent  CO (solution)
becomes spontaneous process in standard conditions
(D) A 500 K the molar enthalpy of solution of H2(g) is 14.7 kJ/mole.

Q.22

(I) (II) (III) (IV)

(V) (VI)

A and B are respectively.

(A) I and II (B) II and IV (C) V and VI (D) I and III

Q.23 For which of the following dn configuration of octahedral complex (es), can not exist in both high spin
and low spin forms.
(A) d3 (B) d5 (C) d6 (D) d8

ROUGH WORK
Q.24 For the reaction
1
CO(g) + O (g) CO2(g)
2 2
using data given in table find out incorrect statement(s) among the following.

H of (kJ / mole ) S(J / Kmole )

CO (g)  110  197
O 2 (g ) 0  205
CO 2 (g )  395  213

Assume vibration modes of motion do not contribute to heat capacity at low temperature.
(A) H° > U° for the reaction at 298K.
1
(B) In standard state condition, the reaction CO(g) + O (g) CO2(g)
2 2
attain equilibrium at very high temperature.
d (  H )
(C) At low temperature = – ive
dT
(D) In a CO, O2 fuel cell electrical energy obtained by cell > | H ocombustion [CO (g) ]|

Q.25 Which of the following will give three different compounds on ozonolysis

(A) (B) (C) (D)

Q.26 Potassium chromate solution is added to aqueous solutions of metal nitrate. The Yellow precipitate thus
obtained are insoluble in acetic acid. These are subjected to flame test, flame colour of individual ppt.
is/are
(A) Lilac (B) Apple green (C) Crimson red (D) Blue

ROUGH WORK
Q.27 A compound 'A' transform by two parallel first order paths
1
A (g) k
1 (min )
 2B (g) k1 = 6.93 × 10–3 min–1
1
A (g) k 2 (min )
  C (g) k2 = 6.93 × 10–3 min–1
If reaction started with pure 'A' with conc. 0.1 mol/L in a closed container with initial pressure 2 atm.
What is the pressure (in atm) developed in container after 50 minutes from start of experiment.
(A) 1.25 (B) 0.75 (C) 1.50 (D) 2.50


Q.28 + PhN 2 Cl–  ? H
3O


Final product is a mixture containing:

(A) (B) (C) (D)

Q.29 Which of the following aqueous solution of cation(s) give(s) white ppt with NaOH and NH4OH solution
and formed ppt. is/are further completely dissolved in one of the excess reagent.
(A) Cd2+ (B) Cr3+ (C) Sn2+ (D) Bi3+

Q.30 True statements regarding SN1 reaction is/are

(A) Perfect racemisation is observed
(B) Only Walden inversion is observed
(C) Total retention of configuartion is observed
(D) None of these

ROUGH WORK
Q.31 CO 32 and HCO 3 can be distinguished by
(A) Phenolphthalein (B) MgCl2 solution (C) HgCl2 solution (D) KCl solution

SOCl
Q.32 2  (A)

Major product (A) is:

(A) (B) (C) H2C = CH2 (D)

Q.33

Which of the following options is/are correct regarding ‘P’ among the following
(A) O3 (B) excess Cl2 water (C) conc. HNO3 (D) HCl

Q.34 Which of the following is the chain termination step during photochlorination of ethane:
 
(A) CH 3  CH 2  Cl  CH3–CH2–Cl
 
(B) CH 3  CH 2  CH 3  CH 2  CH3CH2CH2CH3

 
(C) Cl Cl  Cl2
 
(D) Cl H HCl

ROUGH WORK
Q.35 Which of the following properties show a similar trend on moving from Li to Cs within the group
(A) Ionic mobility in aqueous solution (B) Reactivity towards water
(C) Solubility of Bromide salt (D) Thermal stability of Carbonate salt

Q.36 Which of the following statements is / are true :

(A) Major part of energy needed for the heterolysis of C–X bond in SN1 reaction mechanism is obtained
by the solvation of X– by the polar protic solvent.
(B) Greater solvation of attacking nucleophile & poor solvation of transition state promotes the reaction
by SN2 mechanism.
(C) Increase in the no. of phenyl ring at C of C–X causes a shift in mechanism from SN2 to SN1.
(D) Allyl & benzyl halides undergo SN2 reactions as they are primary halides which do not give SN1
reaction.

Q.37 Which of the following statement is incorrect.

(A) O2 is paramagnetic, O3 is also paramagnetic
(B) O2 is paramagnetic, O3 is diamagnetic
(C) B2 is paramagnetic, C2 is also paramagnetic
(D) Different observation is found in their bond length when NO NO+ and CO  CO+

Q.38 In the given reaction

C7H12 (A) HBr



(A) is:

(A) (B)

(C) (D)

ROUGH WORK
Q.39 Choose the correct statement.
(A) BaCl2 + AcOH + K2CrO4  yellow ppt
(B) BaCO3 (s) + K2CrO4  yellow ppt
(C) BaCO3 (s) + K2CrO4 + AcOH  No ppt.
(D) SrCO3(s) + K2CrO4 + AcOH  No ppt.

Q.40 Which of the following will give same product with HBr in presence & absence of peroxide
(A) ethene (B) 1-butene (C) 2-butene (D) isobutene

ROUGH WORK
Q.41 Point A lies on the line y = 2x and the sum of its abscissa and ordinate is 12. Point B lies on the x-axis and
the line AB is perpendicular to the line y = 2x. Let 'O' be the origin. The area of the triangle AOB is
(A) 20 (B) 40 (C) 60 (D) 80

Q.42 Suppose f (x) = sin x and g (x) = 1 – x . Which of the following composite functions have the same
range?
(A) fog (B) gof (C) fof (D) gog

Q.43 Given the vectors


u  2 î  ˆj  k̂

v  î  ĵ  2k̂

w  î  k̂
  
If the volume of the parallelopiped having – c u , v and c w as concurrent edges, is 8 then 'c' can be
equal to
(A) 2 (B) – 2 (C) 4 (D) can not be determined

Q.44 Let A = the number of ways of selecting a committee of 5 from a group of 9 persons.
B = the number of permutations of the word PRELEPCO taken all at a time.
C = the number of ways in which 8 people can be arranged in a line if two particular people must
stand next to each other.
AB
The value of equals
C
(A) 63 (B) 126 (C) 360 (D) none

100
3 3i
Q.45 If 349(x + iy) =   
 and x = ky then the value of k equals (x, y  R)
 2 2 
1 1
(A) 3 (B) – 3 (C) (D) –
3 3
ROUGH WORK
Q.46 Let x, y be reals satisfying sin x + cos y = 1 and sin y + cos x = – 1. Then which of the following must
be correct?
(A) sin(x + y) = 0 (B) cos(x – y) = 0 (C) cos(x + y) = 1 (D) cos 2x = cos 2y

Q.47 Two points A(x1, y1) and B(x2, y2) are chosen on the graph of f (x) = ln x with 0 < x1 < x2. The points
C and D trisect line segment AB with AC < CB. Through C a horizontal line is drawn to cut the curve at
E(x3, y3). If x1 = 1 and x2 = 1000 then the value of x3 equals
(A) 10 (B) 10 (C) (10)2/3 (D) (10)1/3

Q.48 Suppose f is a differentiable real function such that f (x) + f '(x)  1 for all x, and f (0) = 0, then the
largest possible value of f (1), is
(A) e–2 (B) e–1 (C) 1 – e–1 (D) 1 – e–2

Q.49 Let S be a set consisting of first five prime numbers. Suppose A and B are two matrices of order 2 each
with distinct entries  S. The chance that the matrix AB has atleast one odd entry, is
(A) 0 (B) 20% (C) 80% (D) 96%

Q.50 A curve is represented parametrically by the equations x = t + eat and y = – t + eat when t  R and
a > 0. If the curve touches the axis of x at the point A, then the coordinates of the point A are
(A) (1, 0) (B) (1/e, 0) (C) (e, 0) (D) (2e, 0)

Q.51 Suppose g (x) = 2x + 1 and h (x) = 4x2 + 4x + 5 and h (x) = (fog)(x). The area enclosed by the graph
of the function y = f (x) and the pair of tangents drawn to it from the origin, is
(A) 8/3 (B) 16/3 (C) 32/3 (D) none

        
Q.52 Suppose a vector V satisfies ( V · V) V = 169 V and 4 ( V ·î ) = 3 ( V · ĵ) = ( V ·k̂ ) where ( V ·î ) >0
  
then ( V ·î ) + ( V · ĵ) + ( V · k̂ ) equals
(A) 16 (B) 19 (C) 21 (D) 23

ROUGH WORK
 1
Q.53 Suppose the function gn(x) = x2n + 1 + anx + bn (n  N) satisfies the equation  (px  q ) g n ( x ) dx = 0
1
for all linear functions (px + q) then
3
(A) an = bn = 0 (B) bn = 0; an = –
2n  3
3 3 3
(C) an = 0; bn = – (D) an = ; bn = –
2n  3 2n  3 2n  3

Q.54 Suppose f : R  R is a differentiable function satisfying f (x + y) = f (x) + f (y) + xy(x + y) for every
x, y  R. If f ' (0) = 0 then which of the following hold(s) good?
(A) f is an odd function
(B) f is a bijective mapping
(C) f has a minima but no maxima
(D) f has an inflection point

Q.55 Consider the parabola y2 = 4x and the ellipse 2x2 + y2 = 6, intersecting at P and Q. Which of the
following hold(s) good?
(A) The two curves are orthogonal.
(B) The area enclosed by the parabola and the double ordinate, common to ellipse and parabola is 4/3.
(C) The common double ordinate is the latus rectum of the parabola.
(D) If tangent and normal at the point P on the ellipse intersect the x-axis at T and G respectively then
area of the triangle PTG is 4.

Q.56 Triangle ABC has BC = 1 and AC = 2. The maximum possible value of the angle A is
   
(A) (B) (C) (D)
6 4 3 2

ROUGH WORK
Q.57 Let the equation of a line in the Cartesian plane is Ax + By + C = 0 where A, B, C  R and A2 + B2  0.
If the corresponding equation on the complex plane is  z   z    0 where  is complex and  is
real, then the correct statement(s) is/are
A  Bi
(A)  = and  = C (B) If    the line is parallel to imaginary axis.
2

(C) If    = 0 line is parallel to real axis. (D) slope m of the line is i.


x
2
t
Q.58 Let f (x) =  e dt and h (x) = f 1 g(x) , where g (x) is defined for all x, g'(x) exists for all x, and
1
g (x)  0 for x > 0. If  h'(1) = e and g'(1) = 1, then the possible values which g(1) can take
(A) 0 (B) – 1 (C) – 2 (D) – 4

x 2 y2
Q.59 P and Q are two points on the upper half of the ellipse 2  2 = 1. The centre of the ellipse is at the
a b
origin 'O' and PQ is parallel to the x-axis such that the triangle OPQ has the maximum possible area. A
point is randomly selected from inside of the upper half of the ellipse. The probability that it lies outside
the triangle, is
 1 2  1  1  1
(A) (B) (C) (D)
 2 2 4

Q.60 A square OABC is formed by line pairs xy = 0 and xy + 1 = x + y where 'O' is the origin. A circle with
centre C1 inside the square is drawn to touch the line pair xy = 0 and another circle with centre C2 and
radius twice that of C1, is drawn to touch the circle C1 and the other line pair. The radius of the circle
with centre C1 is
2 2 2 2 2 1
(A) (B) (C) (D)

3 2 1  
3 2 1  
3 2 1  3 2

ROUGH WORK