OXYGEN
OXYGEN
OXYGEN
OXYGEN
SYNOPSIS - 1
INTRODUCTION:
Oxygen forms 21 % of the air by volume and is very vital for our existence
and the existence of all forms of animals and vegetable life. It is due to
absorption of oxygen, that our respiratory system burns food materials at
controlled rate, to produce heat energy which not only maintains our body
temperature at 37°C, but also helps us to perform various life activities.
Discovery:
Oxygen was discovered by a British chemist Joseph Priestley in 1774. He
heated mercury (II) oxide [HgO by concentrating rays of the sun. He found
out that gas evolved is colourless and odourless, but is chemically active. A
glowing splint gets rekindled when introduced in the gas. Priestly named
this gas “active air”.
Carl Wilhelm Scheele (1777) obtained the Oxygen gas by strongly heating
compounds, such as nitre [KNO3, or mercury (II) oxide in a hard glass test
tube. He named this gas as dephlogisticated air or fire air, as it supported
combustion but itself does not burn.
Lavoisier proved later on, that oxygen is an element. As a matter of fact, it
was Lavoisier who named this gas as oxygen, meaning acid former, because
he believed that oxygen is the constituent of all acids.
Occurrence of Oxygen:
1. Oxygen is the most abundant element occurring on the earth, both in
free, as well as in combined state. As a matter of fact the total weight
of element oxygen on the crust of earth, is as much as the total weight
of all the elements taken together.
2. It occurs both in free state as well as combined state.
Oxygen in Free state:
WORK SHEET - 1
Comprehension Type
Oxygen is the most abundant element occurring on the earth, both in free,
as well as in combined state.
12. Oxygen gas named as active air by:
1) Joseph Priestley2) Scheele 3) Lavoisier 4) Cavendish
13. What is the valency of oxygen?
1) 3 2) 1 3) 2 4) 4
14. The percentage of oxygen in air by volume is:
1) 30% 2) 89% 3) 21% 4) 78%
SYNOPSIS - 2
GENERAL METHODS OF PREPARATION OF OXYGEN:
1. By heating oxides of mercury and silver:
Heating of mercuric oxide [HgO: When mercuric oxide is heated strongly,
it decomposes to form mercury and free oxygen gas.
2HgO(s)
2Hg(l) + O2(g) – t
Observations:
Mercuric oxide is red in colour.
On heating, it blackens and gives off colourless vapours.
A mirror like surface is formed near the cooler parts of the test tube.
A glowing wooden splint bursts into flame, when held in the test tube. It
shows that gas evolved is oxygen.
Heating of silver (I) oxide [Ag 2O: When silver (I) oxide is heated strongly, it
decomposes to form silver metal and oxygen gas.
2Ag2O(s) 4Ag(s) + O2(g) t
Observations:
Silver (I) oxide is brown in colour.
On heating, it leaves behind globules which are silvery in colour.
A glowing wooden splint bursts into flame, when held in the test tube. It
shows, that gas evolved is oxygen.
2. By heating higher oxides of lead:
Heating of red lead oxide (tri lead tetraoxide) [Pb 3O4: On strong heating
red lead oxide decomposes to form lead monoxide [PbO and oxygen gas.
2Pb3O4(s)
6PbO(s) + O2(g) t
Observations:
Red lead is orange red in colour.
The residue is reddish brown when hot and yellow when cold.
If a glowing wooden splint is held in the test tube, it bursts into flame,
thereby showing that gas evolved is oxygen.
A part of residue fuses in glass test tube and stains it yellow.
Heating of lead (IV) oxide (lead dioxide) [PbO 2: On strong heating lead (IV)
oxide decomposes to form lead monoxide [PbO and oxygen gas.
2PbO2(s)
2PbO(s) + O2(g)
Observations: Same as in case of red lead oxide, except that, it is chocolate
brown in colour, before heating.
3. Preparation of Oxygen from hydrogen peroxide: Hydrogen peroxide is a
colourless liquid having 20% of hydrogen peroxide and 80% of water. When
hydrogen peroxide is allowed to trickle over manganese dioxide, it rapidly
decomposes to form water and oxygen gas.
From Water:
This method is followed only at those places, where electricity is very cheap.
In addition to the formation of oxygen, hydrogen is also formed as a by-
product, which is collected separately.
The tank is used for the decomposition of water. When heavy current is
passed through acidulated water (water containing sulphuric acid, so as to
make it good conductor of electricity), it decomposes to form hydrogen gas,
which is liberated at cathode (negative pole) and oxygen gas, which is
liberated at anode (positive pole).
2H2O(l )
Electric
current
2H2 (g) O2 (g)
FROM AIR:
(i) Purification of air:
Air generally contains carbon dioxide gas, hydrogen sulphide gas and sulphur
dioxide gas as impurities. In addition to it there are dust particles.
Air is first of all washed by passing it through water, when dust particles are
removed.
The washed air is then passed through dilute caustic soda solution, where
gases like carbon dioxide, sulphur dioxide and hydrogen sulphide are removed.
The purified air, however, contains moisture. The moist air is passed through
pipes, maintained at a temperature below –20°C, where water vapour present
in it freezes and hence, air becomes dry.
The air leaving the cooling pipes, is free from all impurities.
(ii) Liquefaction of air:
The cool air, free from all impurities is compressed to a pressure, 200 times
more than atmospheric pressure. The compression raises the temperature
of air.
The hot compressed air is then passed through cooling tank in which cold
water enters from one end and warm water leaves from other end.
The compressed and cooled air is then passed through a spiral pipe, placed
in a vacuum flask. The end of spiral pipe is provided with a fine jet.
When compressed, air suddenly escapes from jet, its pressure suddenly
falls. Thus, its molecules move wide apart. When the molecules move wide
apart, they need energy. This energy is taken by the molecules from
themselves and hence, their temperature drops.
The air so cooled, is now at a pressure equal to that of atmosphere. This
cooled air rises up and in the process, further cools the incoming compressed
air in spiral tube.
The air is then sucked again by the compression pump and the cycle is
repeated. With every cycle, the temperature of air drops, till it liquefies.
(iii) Fractional distillation of air:
The liquid air mainly consists of nitrogen and oxygen, and is at a temperature
of –200°C.
The boiling point of liquid nitrogen is –195.8°C and that of liquid oxygen is –
183°C.
The liquid is gradually warmed to –195°C, when nitrogen starts boiling off
from the liquid air. The nitrogen gas so formed, is compressed and filled in
steel cylinders.
The liquefied oxygen left behind, is also changed to gas and then filled in
compressed state in steel cylinders.
WORK SHEET - 2
9. The liquid air mainly consists of (H) & (A) , & is at a temperature of (T) .
H A T
1) Carbon Chlorine –100°C
2) Argon Carbon –1000°C
3) Nitrogen Oxygen –200°C
4) Helium Chlorine –500°C
10. 2Na2O2(s) + 2H2O(l) A + B
A B
1) 2NaOH H2
2) 3NaOH 2O2
3) 4NaOH O2
4) NaOH 2O2
11. When water is allowed to trickle drop by drop on sodium peroxide a vigorous
reaction takes place in the cold, forming sodium hydroxide solution and
oxygen gas.
The balanced chemical equation for the above reaction is:
1) NaO2(s) + H2O(l) NaOH + O2. 2) 2NaO2 + H2 Na2O2 + O2.
3) 2Na2O2(s) + 2H2O(l) 4NaOH(aq) + O2(g).
4) Na2O2(s) + 2H2O(l) 2NaOH(aq) + O2(g).
15. Which of the following is correct for heating of red lead oxide?
1) Red lead is orange in colour
2) PbO2 is a chacolate brown colour before heating.
3) The residue is yellowish brown in colour when hot.
4) A glowing wooden splint is held in the test tube it bursts into flame.
16. Which of the following is the correct option, in the steps of purification of
air?
a) Dust particles are removed, washing air by passing through water.
b) In the purified air, moisture is removed by maintaining the temperature
below –200C.
c) When air is passed through dil. caustic soda solution impurities like CO 2,
SO2 and H2S are removed.
1) c, a and b 2) a,c and b 3) a,b,c 4) b,c,a
17. In the liquefaction of air, compression of air require the pressure of:
1) 20 times more than atmospheric pressure
2) 200 times less than atmospheric pressure
3) 200 times more than atmospheric pressure
4) 40 times more than atmospheric pressure
Comprehension Type
Writeup-1:
Hydrogen peroxide is a colour less liquid having 20% of hydrogen peroxide
and 80% of water.
When water is allowed to trickle drop by dron on sodium peroxide a vigorous
reaction takes place in the cold.
22. The catalyst used in decomposition of hydrogen peroxide is:
1) Nickel 2) Platinum
3) Manganese dioxide 4) Palladium
23. The chemical formula of sodium peroxide is:
1) NaO 2) NaO2 3) Na2CO3 4) Na2O2
24. What are the two compounds formed when sodium peroxide with water?
1) NaOH 2) O2 3) H2O2 4) Both 1 and 2
Writeup-2:
When mercuric oxide is heated strongly it, decomposes to form mercury and
free oxygen gas. In the same way silver oxide is heated strongly it decomposes
to form silver metal and oxygen gas.
25. Name a liquid that can be used for the preparation of oxygen in laboratory.
1) NaCl 2) Pb3O4 3) H2O2 4) Ag2O
26. Name a solid which on coming in contact with water produces oxygen gas.
1) H2O2 2) Na2O2 3) KClO3 4) PbO2
27. On strong heating lead (IV) oxide decomposes to form lead monoxide and
oxygen gas
Which of the following is a balanced chemical equation
for the above reaction?
1) 2Pb3O4(s)
6PbO(s) + O2(g) – 2) Pb3O4(s)
6PbO(s) + H2(g) t
3) 2PbO2(s)
2PbO(s) + O2(g) 4) 2Pb(s) + O2
PbO(s) + O2(g)
SYNOPSIS - 3
PHYSICAL PROPERTIES OF OXYGEN:
Nature: It is colourless, odourless and tasteless gas.
Vapour density: It is slightly heavier than air. Its vapour density is 16,
whereas that of air is 14.4. It is because of its higher vapour density, that
amount of oxygen on higher altitudes decreases.
Solubility: Under laboratory conditions, oxygen is practically insoluble in
water, e.g., 100 cm 3 of water will dissolve only 4 cm3 of oxygen after a
prolonged interval of time.
Liquefaction: Under high pressure and low temperature, oxygen can be
liquefied. The liquid oxygen is slightly blue in colour and has a boiling point
–183°C.
CHEMICAL PROPERTIES OF OXYGEN:
Combustibility: Oxygen is an incombustible gas, but it supports combustion.
When a glowing splinter is taken in the jar of oxygen, it rekindles.
Action with litmus: Oxygen neither turns moist blue litmus red, nor red
litmus blue and hence, is neutral towards litmus i.e., it is neither acidic
nor basic in character.
Oxidising properties: Oxygen is a very active element. It reacts with most of
the metals (exception is gold, silver and platinum), non-metals and
compounds containing carbon to form their respective oxides.
Oxidation of Non-metals:
Action with hydrogen: When two volumes of hydrogen and one volume of
oxygen are electrically sparked, they react with blinding flash and loud
explosion, to form water.
However, if a mixture of two volumes of hydrogen and one volume of oxygen,
under pressure are passed through a pipe with a very small hole and the
mixture is ignited, it burns with intense hot blue flame, commonly called
oxy-hydrogen flame.
2H2(g) + O2(g) 2H2O(l) + t
Electric
Spark
Action with nitrogen: When equal volumes of nitrogen and oxygen are
electrically sparked, they react to form nitric oxide gas. However, reaction
is reversible and only 2% gases react.
Electric spark
N2 (g) O2 (g) ‡ˆ ˆˆ ˆˆ ˆˆ300
ˆˆ ˆˆ ˆˆ ˆ†
C
ˆˆˆˆ 2NO(g) t
Action with carbon: When red hot charcoal is taken in the jar containing
oxygen, it starts glowing with a yellowish glow and gives off bright sparkles
to form carbon dioxide gas.
C(s) O2 (g) CO2 (g) t
Products: Carbon dioxide gas
Colour of flame: Bright yellow
Effect on litmus solution: Blue to red.
The reaction is exothermic. The presence of carbon dioxide can be shown by
adding a few drops of limewater to gas jar, where it turns milky.
Action with sulphur: When burning sulphur (in deflagrating spoon) is
introduced in the jar of oxygen, it burns with beautiful blue flame forming a
mixture of sulphur dioxide and sulphur trioxide.
2S (s) + 3O2 (g)
2SO3 (g) + t (In traces)
S (s) + O2 (g)
SO2(g) + t (Main reaction)
Products: Sulphur dioxide and traces of sulphur trioxide.
Colour of flame: Brilliant blue
Effect on litmus solution: Blue to red and then gets bleached.
Effect on dichromate solution: Orange to green.
The presence of sulphur dioxide can be shown, by adding a few drops of
acidified potassium dichromate solution (K2Cr2O7 solution) to the gas, where
it turns green.
Action with phosphorus: When burning phosphorus (in deflagrating spoon)
is introduced in the jar of oxygen, it burns with brilliant white flame,
forming dense white fumes of phosphorus pentoxide.
4P(s) + 5O2(g)
2P2O5(s) + t
Products: Phosphorus pentoxide
Colour of flame: Bright white and dense white fumes.
Effect on litmus solution: Blue to red.
OXIDATION OF METALS:
Action with potassium: When slightly warm potassium is taken in a jar of
oxygen (by means of deflagrating spoon), it catches fire and burns with lilac
flame to form potassium oxide.
4K(s) + O2(g)
2K2O(s) + t
Products: Potassium oxide
WORK SHEET - 3
A B
1) SO2 SO 3
2) SO2 SO 2
3) SO3 SO 3
4) 2SO3 SO 2
1) 3 O2 2 O3 - t
Silent electric
disch arg e 2) 4 P + 5O2 2 P2O5 + t
17. Element ‘A’ is silvery white metal which burns with golden yellow flame.
The oxide is basic in nature. Element ‘A’ is:
1) Carbon 2) Nitrogen 3) Sodium 4) Oxygen
18. Carbon monoxide burns with ______ producing intense heat in the atmosphere
of Oxygen, to form CO2 gas.
1) Red luminous flame 2) Pale blue non-luminous
3) Yellow flame 4) No flame
19. The chemical formula of Tri-ferric tetraoxide is:
1) Fe 2O3 2) Fe 3O4 3) Fe(OH)2 4) Fe(OH)3
20. 3 Fe (s) + 2 O2 (g) ‘X’ . What is ‘X”?
1) CuO 2) Fe 3O4 3) Fe(OH)2 4) MgO
21. 2 Cu (s) + O2 (g) “A” + t
In the above reaction product “A” is:
1) Copper (I) oxide 2) Copper (II) oxide
3) Copper (III) oxide 4) Copper (IV) oxide
22. Which of the following metal form a peroxide?
1) Potassium 2) Sodium 3) Calcium 4) Magnesium
Comprehension Type
Writeup-1:
Oxygen is colourless, odourless and taste less gas.
34. The valency of oxygen is:
1) 4 2) 1 3) 3 4)2
35 The boiling point of liquid oxygen is:
1) 183°C 2) –183°C 3) 180°C 4) 120°C
36. The amount of oxygen on higher attitudes is:
1) Increases 2) Decreases
3) Increases and decreases 4) Neither decreases nor increases
Writeup-2:
In oxidation of metals, when warm potassium is taken in a jar of oxygen, it
catches fire and burns with lilac flame to form potassium oxide
37. Potassium oxide __________ in nature.
1) Acidic 2) Basic 3) Neutral 4) None
38. The colour of flame of sodium metal is:
1) Golden yellow flame 2) Dazzling white
3) Lilac flame 4) Brick flame
39. What is product formed when iron reacts with oxygen?
1) Ferrous oxide 2) Triferric tetroxide
3) Diferric tetroxide 4) None
SYNOPSIS - 4
OXIDATION PROPERTIES OF OXYGEN:
Action with sulphur dioxide: When two volumes of sulphur dioxide gas and
one volume of oxygen are passed over heated platinized asbestos or vanadium
pentoxide at 450°C they react to form sulphur trioxide.
WORK SHEET - 4
Comprehension Type
Writeup-1:
All hydrocarbons burn in oxygen, to form carbon dioxide gas steam. The
reactions are exothermic and a lot of heat and light is liberated.
18. Methane gas reacts with oxygen gas to form a:
1) Carbon dioxide gas 2) Hydrogen gas
3) Oxygen gas 4) Carbon monoxide gas
19. 2C4H10 (g) + 13 O2 (g) 8 CO2 (g) 10H2O (g) + t
In the above reaction is:
1) Exothermic reaction 2) Endothermic reaction
3) Heat liberation 4) Both 1 and 3
20. Hydrogen sulphide gas burns in oxygen to form:
1) Sulphur trioxide 2) Sulphur dioxide
3) Carbon disulphide 4) Hydroxide
Writeup-2:
Hydrocarbons burn in oxygen to form carbon dioxide gas and steam.
21. The chemical formula of ethylene is:
1) CH4 2) C2H6 3) C2H2 4) C2H4
22. The chemical formula of butane is:
1) C4H8 2) C4H9 3) C4H10 4) C6H6
23. What are the two products formed when carbon disulphide burns in oxygen?
1) Carbon dioxide 2) Sulphur dioxide
3) Carbon monoxide 4) Both 1 and 2
SYNOPSIS - 5
TESTS FOR OXYGEN:
It turns alkaline pyrogallol solution brown.
It rekindles glowing wooden splinter.
When mixed with nitric oxide, it forms reddish brown colour of nitrogen
dioxide.
USES OF OXYGEN:
General Uses:
21% of the air by volume is oxygen. It is absolutely essential for the respiration
of all living beings.
Artificial respiration is resorted to only when there is not sufficient supply
of oxygen in air, such as at high altitudes; during fire fighting; under sea or
in space. Thus, oxygen is used for artificial respiration by:
Firemen during fire fighting
Aviators during high altitude flying
Astronauts in space ships
Divers and submariners under water
Miners during deep mining
Climbers during high altitude climbing
Liquid oxygen, under the trade name LOX, is used to burn rocket fuel in
space.
MEDICAL USES:
Carbogen: It is a mixture of 5% carbon dioxide and 95% oxygen. It stimulates
natural breathing. It is given to the patients suffering from asthma or for
reviving patients from drowning or gas poisoning.
Anaesthesia: A mixture of nitrous oxide (N2O) and oxygen is used in surgical
operations.
INDUSTRIAL USES:
For cutting and welding purposes: When oxygen and hydrogen are made to
burn in a specially designed torch, they form a flame, having a temperature
of 2800°C. However, if instead of hydrogen, acetylene gas is used, the
temperature is 3300°C.
The oxy-hydrogen flame or oxy-acetylene can easily melt most of metals
and hence, are used for welding purposes.
In the iron and steel industry: Instead of air, the oxygen is used in blast
furnace for the manufacture of iron, because it can produce more heat than
oxygen, diluted by nitrogen. Moreover, it saves heat energy, which is
otherwise carri ed by
non-reacting nitrogen. Similarly, in the manufacture of steel we use oxygen
for removing impurity of carbon present in cast iron, in the form of carbon
dioxide.
In explosives: In mining industry large amount of explosives are required.
Cartridges made of one part of coal dust, one part of petroleum jelly and
eight parts of liquid oxygen are used for blasting rocks.
In chemical industry: Oxygen is extensively used in the manufacture of
sulphuric acid from sulphur dioxide and nitric acid from ammonia.
WORK SHEET - 5
Comprehension Type
Oxygen is used in blast furnace for the manufacture of iron, because it can
produce more heat than diluted by nitrogen
13. The chemical name of rust is:
1) Iron oxide 2) Iron II oxide
3) Hydrated Iron III oxide 4) Iron
14. Which of the following is not essential condition for burning but essential
for rusting?
1) Oxygen 2) Moisture 3) Heat 4) Pressure
15. Prevents rusting of lower parts of a ship or bridges:
1) Greasing 2) Tar 3) Plastic coating 4) Tin-plating
16) A-1
B-5
C-2
D-4
6) 2 7) 1 8) 2 9) 3 10) 3
6) 2 7) 4 8) 4 9) 1 10) 2
6) 4 7) 1 8) 2 9) 1 10) 4