MHT-CET 2023 Question Paper - Chemistry

12th May 2023 (Shift – I)

1. Find [OH–] if a monoacidic base is 3% ionised 9. Which among the following compounds
in it’s 0.04 M solution. exhibits +2 oxidation state of oxygen?
(A) 3.1  10–2 mol L–1 (A) H2O (B) SO2
(B) 4.5  10–3 mol L–1 (C) OF2 (D) H2O2
(C) 9.0  10–2 mol L–1 10. Identify substrate A in the following reaction.
(D) 1.2  10–3 mol L–1 A  AgOH 
i) moist Ag 2 O
 CH 3CH 2 N  CH 3 2  CH 2  CH 2

ns
ii) 

2. Calculate Δ Go for the reaction (A) Diethyldimethyl ammonium halide

Mg (s)  Sn aq  
 Mgaq   Sn (s) if E ocell is 2.23V (B) Ethyltrimethyl ammonium halide
(C) Diethyldimethyl ammonium hydroxide
(A) –430.4 kJ (B) 215.2 kJ (D) Ethyltrimethyl ammonium hydroxide

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(C) 645.6 kJ (D) –860.8 kJ
11. What volume of CO2(g) at STP is obtained by
3. If lattice enthalpy and hydration enthalpy of KCl complete combustion of 6g carbon?
are 699 kJ mol–1 and –681.8 kJ mol–1

at
(A) 22.4 dm3 (B) 11.2 dm3
respectively. What is the enthalpy of solution of (C) 5.6 dm 3
(D) 2.24 dm3
KCl?
(A) 8.20 kJ mol–1 (B) 10.25 kJ mol–1 12. Identify the chiral molecule from the following.
(C) 13.80 kJ mol –1
(D) 17.20 kJ mol–1
lic (A) 2-Iodopropane
(B) 2-Iodo-2-methylbutane
4. Which of the following compounds does not (C) 2-lodo-3-methylbutane
undergo Williamson’s synthesis? (D) 3-Iodopentane
(A) C2H5 – Cl
ub
(B) CH3 – CH – CH2 – Cl 13. Calculate the time needed for reactant to
decompose 99.9% if rate constant of first order
CH3 reaction is 0.576 minute–1
(C) C6H5 – Cl (A) 8 minute (B) 12 minute
P

(C) 16 minute (D) 20 minute

(D) CH3 – CH2 – CH2 – Cl
14. What is the number of moles of sp3 hybrid
5. What is the expression for solubility product of
carbon atoms in one mole of 2-Methylbut-2-ene
silver chromate if it’s solubility is expressed as
et

(A) Four (B) Three

S mol L–1 ?
(C) Two (D) One
(A) 2S2 (B) 3S3
3
(C) 4S (D) 27S4 15. Identify major product A in following reaction.
rg

3-Bromo-2-methylpentane  alc.KOH

A
6. Which from following is a non-ferrous alloy? 

(A) Nickel steel (B) Chromium steel (A) 2-Methylpentan-3-ol

(C) Stainless steel (D) Brass (B) 2-Methylpent-2-ene
Ta

(C) 4-Methylpent-3-ene
7. What are the number of octahedral and (D) 4-Methylpentan-3-ol
tetrahedral voids in 0.3 mole substance
respectively if it forms hcp structure? 16. For reaction,
(A) 1.8066  1023 and 3.6132  1023 1
CO g   O2 g  
 CO2 g 
(B) 3.6132  1023 and 1.8066  1023 2
(C) 6.022  1023 and 12.044  1023 Which of the following equations is correct at
constant T and P?
(D) 12.044  1023 and 6.022  1023
(A) ΔH < ΔU (B) ΔH > ΔU
8. Calculate the molar mass of an element having (C) ΔH = ΔU (D) ΔH = 0
density 7.8g cm–3 that forms bcc unit cell. 17. Identify the example of zero-dimensional
[a3.NA = 16.2 cm3 mol–1] nanostructure from following.
(A) 63.18 g mol–1 (B) 61.23 g mol–1 (A) Nanotubes (B) Fibres
(C) 59.31 g mol–1 (D) 65.61 g mol–1 (C) Thin films (D) Quantum dots
1
 
MHT-CET 2023 Question Paper - Chemistry
12th May 2023 (Shift – I)
18. What is pH of solution containing 50 mL each 27. Calculate osmotic pressure of solution of
of 0.1 M sodium acetate and 0.01 M acetic acid 0.025 mole glucose in 100ml water at 300K.
(pKa CH3COOH = 4.50) [R = 0.082 atm dm3 mol–1 K–1]
(A) 2.5 (B) 3.5 (C) 4.5 (D) 5.5 (A) 1.54 atm (B) 2.05 atm
(C) 6.15 atm (D) 3.08 atm
19. Calculate amount of methane formed by
liberation of 149.6 kJ of heat using following 28. Which from following is a neutral ligand?
equation. (A) Aqua (B) Sulphato
Cs   2H 2 g  
 CH 4 g  ΔH = –74.8 kJ/mol (C) Carbonato (D) Bromo
29. How many isomers of C4H11N are tertiary amines?
(A) 16g (B) 24g
(A) One (B) Two
(C) 32g (D) 48g
(C) Three (D) Four
20. Which from following polymers is used to 30. Which element from following exhibits

ns
obtain tyre cords? diagonal relationship with Mg?
(A) Nylon 6 (B) Polyacrylonitrile (A) Be (B) Li (C) Na (D) B
(C) Bakelite (D) Terylene
31. Identify the good conductor of electricity from

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21. Electrolytic cells containing Zn and Al salt following band gap energy values of solids
solutions are connected in series. If 6.5g of Zn is
deposited in one cell calculate mass of Al Solid E gap
deposited in second cell (molar mass : Zn = 65, A 5.47 eV

at
Al = 27) by passing definite quantity of electricity? B 0.0 eV
(A) 2.4g (B) 2.1g C 1.12 eV
(C) 2.7g (D) 1.8g
lic D 0.67 eV

22. What type of glycosidic linkages are present in (A) A (B) B (C) C (D) D
cellulose? 32. Identify the product obtained when ethoxybenzene
(A)  - 1, 6 (B)  - 1, 4 reacts with hot and concentrated HI.
(C)  - 1, 6 (D)  - 1, 4 (A) Ethyl iodide and Phenol
ub
(B) Ethyl alcohol and Phenol
23. Calculate the rate constant of first order reaction (C) Ethyl alcohol and Iodobenzene
if half life of reaction is 40 minute. (D) Ethyl iodide and Iodobenzene
(A) 1.733  10–2 minute–1
33. Identify thermosetting polymer from following.
P

(B) 1.951  10–2 minute–1

(A) Urea formaldehyde resin
(C) 1.423  10–2 minute–1 (B) Polythene
(D) 1.256  10–2 minute–1 (C) Polystyrene
et

24. Identify product ‘B’ in following sequence of (D) Polyvinyls

reactions. 34. Which from following phenomena is inversely
Ba  OH 
 proportional with adsorption?
2n Propanone 
2
 A   nB
rg

 H2O
(A) Critical temperature of gas
(A) 4-Hydoxy-4-methylpentan-2-one (B) Surface area of adsorbent
(B) 2-Methylpentan-3-one (C) Temperature of process
(C) 2-Methylpent-2-en-4-one (D) Pressure of gas
Ta

(D) 4-Methylpent-3-en-2-one
35. Calculate the frequency of blue light having
25. Identify rate law expression for wavelength 440nm.
2NO(g) + Cl2(g)  2NOCl(g) if the reaction is (A) 6.82  1014 Hz
second order in NO and first order in Cl2. (B) 7.5 1014 Hz
(A) Rate = k [NO]2 [Cl2] (C) 4.0 1014 Hz
(B) Rate = k [NO] [Cl2] (D) 5.26 1014 Hz
(C) Rate = k [NO]2 36. Which from following elements is NOT
(D) Rate = k [Cl2] radioactive?
26. Which among the following solutions has (A) At (B) Po (C) Rn (D) Ar
minimum boiling point elevation? 37. Which from following is strongest reducing
(A) 0.1m NaCl (B) 0.2m KNO3 agent?
(C) 0.1m Na2SO4 (D) 0.05m CaCl2 (A) K (B) Al (C) Mg (D) Ag
22
 
MHT-CET 2023 Question Paper - Chemistry
12th May 2023 (Shift – I)
38. What is the numerical value of spin only 47. Which of following pairs is an example of
magnetic moment of copper in +2 state? isoelectronic species?
(A) 0.0 (B) 1.73 (A) O– – ; Na+ (B) O– – ; F
++
(C) 2.78 (D) 4.4 (C) K ; Ca (D) Ar ; Al+3
39. Identify the element having highest density from 48. Which from following compounds is obtained
following. when anisole is heated with dilute sulfuric acid?
(A) O (B) S (C) Se (D) Te (A) Phenol and ethanol
40. What is the shape of AB4E type of molecule (B) Phenol and methanol
according to VSEPR? (C) Pyrogallol and methanol
(A) See saw (D) Phloroglucinol and ethanol
(B) Bent 49. Calculate molality of solution of a nonvolatile
(C) Trigonal pyramidal

ns
solute having boiling point elevation 1.89K if
(D) T shade boiling point elevation constant of solvent is
41. The molecular formula of hexachlorobenzene is 3.15K kg mol–1.
(A) C6H6Cl6 (B) C6Cl6 (A) 0.4m (B) 0.8m

io
(C) C6H5Cl (D) C6H6Cl (C) 0.6m (D) 0.3m

42. What is the value of specific rotation exhibited 50. What type of following phenomena does the
by fructose molecule? Cannizzaro reaction exhibits?

at
(A) +52.7o (B) –92.4o (A) Nucleophilic addition
(C) +66.5 o
(D) –40.3o (B) Elimination
(C) Disproportionation
43. Which of the following reactions is Rosenmund
reduction?
lic (D) Decomposition
(A) R – C – Cl  H2
P d  BaSO4
 R – CHO + HCl
O
ub
(B) R  CN 
SnCl2 .HCl
H2 O
 R  CHO  NH4 Cl
Zn  Hg ,Conc.HCl
(C) R  CHO  
 RCH3  H 2 O
P

i) H2 N  NH2 , 
(D) R – C – R 
ii) KOH, HO  CH2  CH2  OH

O R – CH2 – R
44. Which from following complexes contains only
et

anionic ligands?
(A) Tetraamminedibromoplatinum (IV)
bromide
rg

(B) Potassiumtrioxalatoaluminate (III)

(C) Pentaaquaisothiocyanatoiron (III) ion
(D) Pentaammineaquacobalt (III) iodide
Ta

45. A hot air balloon has volume of 2000 dm3 at

99oC. What is the new volume if air in balloon
cools to 80oC?
(A) 2428.9 dm3 (B) 2656.9 dm3
3
(C) 2814.9 dm (D) 1897.8 dm3
46. Identify the product obtained in following
reaction.
n CH3MgI + H2O 
dry ether
 product
(A) n MgI and n CH4
n
(B) C2 H 6
2
(C) n CH3OH and n MgI
(D) n CH4 and n MgI(OH)
3