Sprayon MSDS

Download as pdf or txt
Download as pdf or txt
You are on page 1of 18

SAFETY DATA SHEET

SC0740000

Section 1. Identification
Product name : WL™740 Zinc-Rich Galvanizing Compound Aerosol
Product code : SC0740000
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.

Manufacturer : Sprayon Products Group


101 W. Prospect Avenue,
Cleveland, Ohio 44115

Emergency telephone : US / Canada: (800) 424-9300


number of the company Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Product Information : US / Canada: (800) 247-3266


Telephone Number Mexico: Not Available

Regulatory Information : US / Canada: (216) 566-2902


Telephone Number Mexico: Not Available

Transportation Emergency : US / Canada: (800) 424-9300


Telephone Number Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 25.1%
(oral), 68.6% (dermal), 68.6% (inhalation)
GHS label elements
Hazard pictograms :

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 1/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 2. Hazards identification
Signal word : Danger
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source. Use
only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash
thoroughly after handling. Pressurized container: Do not pierce or burn, even after use.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. Take off contaminated clothing and wash it before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical
advice or attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice or attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Hazards not otherwise : DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
classified may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 2/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Propane ≥10 - ≤25 74-98-6
Butane ≥10 - ≤25 106-97-8
Lt. Aliphatic Hydrocarbon Solvent ≥10 - ≤25 64742-89-8
Methyl Ethyl Ketone ≤10 78-93-3
n-Butyl Acetate ≤5 123-86-4
Xylene, mixed isomers ≤3 1330-20-7
Ethylbenzene <1 100-41-4
Light Aliphatic Hydrocarbon ≤0.3 64742-47-8
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 3/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In
from the chemical a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel
a considerable distance to a source of ignition and flash back, causing fire or explosion.
Bursting aerosol containers may be propelled from a fire at high speed.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 4/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 5/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 7. Handling and storage
Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name CAS # Exposure limits
Propane 74-98-6 NIOSH REL (United States, 10/2020).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
ACGIH TLV (United States, 1/2021). Oxygen
Depletion [Asphyxiant]. Explosive potential.
Butane 106-97-8 NIOSH REL (United States, 10/2020).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 1/2021).
Explosive potential.
STEL: 1000 ppm 15 minutes.
Lt. Aliphatic Hydrocarbon Solvent 64742-89-8 None.
Methyl Ethyl Ketone 78-93-3 ACGIH TLV (United States, 1/2021).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2020).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
n-Butyl Acetate 123-86-4 NIOSH REL (United States, 10/2020).
TWA: 150 ppm 10 hours.
TWA: 710 mg/m³ 10 hours.
STEL: 200 ppm 15 minutes.
STEL: 950 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 150 ppm 8 hours.
TWA: 710 mg/m³ 8 hours.
ACGIH TLV (United States, 1/2021).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2021).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 6/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2021).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Occupational exposure limits (Canada)
Ingredient name CAS # Exposure limits
Normal propane 74-98-6 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1800 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
1/2021). Oxygen Depletion [Asphyxiant].
Explosive potential.

CA Ontario Provincial (Canada, 6/2019).


Oxygen Depletion [Asphyxiant]. Explosive
potential.
Butane 106-97-8 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 800 ppm 8 hours.
TWAEV: 1900 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
1/2021). Explosive potential.
STEL: 1000 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
Explosive potential.
STEL: 1000 ppm 15 minutes.
Methyl ethyl ketone 78-93-3 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 300 ppm 15 minutes.
8 hrs OEL: 200 ppm 8 hours.
8 hrs OEL: 590 mg/m³ 8 hours.
15 min OEL: 885 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 7/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
1/2021).
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 200 ppm 8 hours.
STEL: 300 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 50 ppm 8 hours.
TWAEV: 150 mg/m³ 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 300 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 300 ppm 15 minutes.
TWA: 200 ppm 8 hours.
n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 200 ppm 15 minutes.
15 min OEL: 950 mg/m³ 15 minutes.
8 hrs OEL: 150 ppm 8 hours.
8 hrs OEL: 713 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 150 ppm 8 hours.
TWAEV: 713 mg/m³ 8 hours.
STEV: 200 ppm 15 minutes.
STEV: 950 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 200 ppm 15 minutes.
TWA: 150 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
CA British Columbia Provincial (Canada,
1/2021).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
15 min OEL: 651 mg/m³ 15 minutes.
15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 434 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2021).
TWA: 100 ppm 8 hours.
STEL: 150 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 150 ppm 15 minutes.
STEV: 651 mg/m³ 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 8/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
8 hrs OEL: 434 mg/m³ 8 hours.
15 min OEL: 543 mg/m³ 15 minutes.
15 min OEL: 125 ppm 15 minutes.
CA British Columbia Provincial (Canada,
1/2021).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 125 ppm 15 minutes.
STEV: 543 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.
Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada,
1/2021). Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Alberta Provincial (Canada, 6/2018).
Absorbed through skin.
8 hrs OEL: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Ontario Provincial (Canada, 6/2019).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.

Occupational exposure limits (Mexico)


CAS # Exposure limits
Propane 74-98-6 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 1000 ppm 8 hours.
Butane 106-97-8 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 1000 ppm 8 hours.
Methyl Ethyl Ketone 78-93-3 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 200 ppm 8 hours.
STEL: 300 ppm 15 minutes.
n-Butyl Acetate 123-86-4 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 150 ppm 8 hours.
STEL: 200 ppm 15 minutes.
Xylene, mixed isomers 1330-20-7 NOM-010-STPS-2014 (Mexico, 4/2016).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
Ethylbenzene 100-41-4 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 9/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not applicable.
Melting point/freezing point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability : Not available.
Lower and upper explosion : Lower: 0.9%
limit/flammability limit Upper: 10%

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 10/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 9. Physical and chemical properties
Vapor pressure : 101.3 kPa (760 mm Hg)
Relative vapor density : 1.55 [Air = 1]
Relative density : 1.07
Solubility : Not available.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 21.028 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 10768 mg/kg -
Xylene, mixed isomers LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 11/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 11. Toxicological information
Product/ingredient name Result Species Score Exposure Observation
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
mg
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 mg -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 uL -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Skin - Moderate irritant Rabbit - 100 % -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 24 hours 15 -
mg
Sensitization
Not available.
Mutagenicity
Not available.

Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene, mixed isomers - 3 -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Propane Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Butane Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Methyl Ethyl Ketone Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
n-Butyl Acetate Category 3 - Narcotic effects
Xylene, mixed isomers Category 3 - Respiratory tract
irritation

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 12/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 11. Toxicological information
Ethylbenzene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Propane Category 2 - -
Butane Category 2 - -
Lt. Aliphatic Hydrocarbon Solvent Category 2 - -
Methyl Ethyl Ketone Category 2 - -
Xylene, mixed isomers Category 2 - -
Ethylbenzene Category 2 - -
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Xylene, mixed isomers ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1
Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 13/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 11. Toxicological information
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 29324.09 mg/kg
Dermal 17499.14 mg/kg
Inhalation (gases) 106585.66 ppm

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours
Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethylbenzene Acute EC50 4900 µg/l Marine water Algae - Skeletonema costatum 72 hours
Acute EC50 7700 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Light Aliphatic Hydrocarbon Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days

Persistence and degradability


Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 14/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 12. Ecological information
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Methyl Ethyl Ketone - - Readily
n-Butyl Acetate - - Readily
Xylene, mixed isomers - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Xylene, mixed isomers - 8.1 to 25.9 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 15/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 14. Transport information
Additional - Product classified - - Emergency
information as per the schedules F-D, S-
following sections U
of the
Transportation of
Dangerous Goods
Regulations:
2.13-2.17 (Class
2).
ERG No. ERG No. ERG No.
126 126 126
Dependent upon Dependent upon Dependent upon Dependent upon Dependent upon
container size, this container size, this container size, this container size, this container size, this
product may ship under product may ship under product may ship under product may ship under product may ship under
the Limited Quantity the Limited Quantity the Limited Quantity the Limited Quantity the Limited Quantity
shipping exception. shipping exception. shipping exception. shipping exception. shipping exception.

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Transport in bulk according : Not available.
to IMO instruments
Proper shipping name : Not available.

Section 15. Regulatory information


SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
International regulations
International lists : Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 16/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health * 3

Flammability 4

Physical hazards 3

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
ASPIRATION HAZARD - Category 1 Calculation method
History
Date of printing : 2/7/2022
Date of issue/Date of : 2/7/2022
revision
Date of previous issue : 12/20/2021
Version : 13.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 17/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.

Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 18/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US

You might also like