Sprayon MSDS
Sprayon MSDS
Sprayon MSDS
SC0740000
Section 1. Identification
Product name : WL™740 Zinc-Rich Galvanizing Compound Aerosol
Product code : SC0740000
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 1/18
SC0740000 WL™740 Zinc-Rich Galvanizing Compound Aerosol SHW-85-NA-GHS-US
Section 2. Hazards identification
Signal word : Danger
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source. Use
only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash
thoroughly after handling. Pressurized container: Do not pierce or burn, even after use.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
doctor. Do NOT induce vomiting. Take off contaminated clothing and wash it before
reuse. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical
advice or attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice or attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Hazards not otherwise : DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
classified may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.
Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 2/18
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Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Propane ≥10 - ≤25 74-98-6
Butane ≥10 - ≤25 106-97-8
Lt. Aliphatic Hydrocarbon Solvent ≥10 - ≤25 64742-89-8
Methyl Ethyl Ketone ≤10 78-93-3
n-Butyl Acetate ≤5 123-86-4
Xylene, mixed isomers ≤3 1330-20-7
Ethylbenzene <1 100-41-4
Light Aliphatic Hydrocarbon ≤0.3 64742-47-8
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.
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Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
Specific hazards arising : Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In
from the chemical a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel
a considerable distance to a source of ignition and flash back, causing fire or explosion.
Bursting aerosol containers may be propelled from a fire at high speed.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
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Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
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Section 7. Handling and storage
Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
Date of issue/Date of revision : 2/7/2022 Date of previous issue : 12/20/2021 Version : 13.01 6/18
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Section 8. Exposure controls/personal protection
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2021).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2020).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Light Aliphatic Hydrocarbon 64742-47-8 ACGIH TLV (United States, 1/2021).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Occupational exposure limits (Canada)
Ingredient name CAS # Exposure limits
Normal propane 74-98-6 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1800 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
1/2021). Oxygen Depletion [Asphyxiant].
Explosive potential.
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Section 8. Exposure controls/personal protection
1/2021).
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 200 ppm 8 hours.
STEL: 300 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 50 ppm 8 hours.
TWAEV: 150 mg/m³ 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 300 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 300 ppm 15 minutes.
TWA: 200 ppm 8 hours.
n-butyl acetate 123-86-4 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 200 ppm 15 minutes.
15 min OEL: 950 mg/m³ 15 minutes.
8 hrs OEL: 150 ppm 8 hours.
8 hrs OEL: 713 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 150 ppm 8 hours.
TWAEV: 713 mg/m³ 8 hours.
STEV: 200 ppm 15 minutes.
STEV: 950 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 200 ppm 15 minutes.
TWA: 150 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
CA British Columbia Provincial (Canada,
1/2021).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
15 min OEL: 651 mg/m³ 15 minutes.
15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 434 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2021).
TWA: 100 ppm 8 hours.
STEL: 150 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 150 ppm 15 minutes.
STEV: 651 mg/m³ 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
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Section 8. Exposure controls/personal protection
Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
8 hrs OEL: 434 mg/m³ 8 hours.
15 min OEL: 543 mg/m³ 15 minutes.
15 min OEL: 125 ppm 15 minutes.
CA British Columbia Provincial (Canada,
1/2021).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 125 ppm 15 minutes.
STEV: 543 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.
Petroleum refining, hydrotreated light distillate 64742-47-8 CA British Columbia Provincial (Canada,
1/2021). Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Alberta Provincial (Canada, 6/2018).
Absorbed through skin.
8 hrs OEL: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
CA Ontario Provincial (Canada, 6/2019).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapour) 8 hours.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
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Section 8. Exposure controls/personal protection
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not applicable.
Melting point/freezing point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability : Not available.
Lower and upper explosion : Lower: 0.9%
limit/flammability limit Upper: 10%
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Section 9. Physical and chemical properties
Vapor pressure : 101.3 kPa (760 mm Hg)
Relative vapor density : 1.55 [Air = 1]
Relative density : 1.07
Solubility : Not available.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): <20.5 mm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 21.028 kJ/g
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
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Section 11. Toxicological information
Product/ingredient name Result Species Score Exposure Observation
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
mg
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 mg -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 uL -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Skin - Moderate irritant Rabbit - 100 % -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 24 hours 15 -
mg
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene, mixed isomers - 3 -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Propane Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Butane Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Methyl Ethyl Ketone Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
n-Butyl Acetate Category 3 - Narcotic effects
Xylene, mixed isomers Category 3 - Respiratory tract
irritation
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Section 11. Toxicological information
Ethylbenzene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Propane Category 2 - -
Butane Category 2 - -
Lt. Aliphatic Hydrocarbon Solvent Category 2 - -
Methyl Ethyl Ketone Category 2 - -
Xylene, mixed isomers Category 2 - -
Ethylbenzene Category 2 - -
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Xylene, mixed isomers ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1
Light Aliphatic Hydrocarbon ASPIRATION HAZARD - Category 1
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
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Section 11. Toxicological information
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Xylene, mixed isomers - 8.1 to 25.9 low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Packing group - - - - -
Environmental No. No. No. No. No.
hazards
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Section 14. Transport information
Additional - Product classified - - Emergency
information as per the schedules F-D, S-
following sections U
of the
Transportation of
Dangerous Goods
Regulations:
2.13-2.17 (Class
2).
ERG No. ERG No. ERG No.
126 126 126
Dependent upon Dependent upon Dependent upon Dependent upon Dependent upon
container size, this container size, this container size, this container size, this container size, this
product may ship under product may ship under product may ship under product may ship under product may ship under
the Limited Quantity the Limited Quantity the Limited Quantity the Limited Quantity the Limited Quantity
shipping exception. shipping exception. shipping exception. shipping exception. shipping exception.
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Transport in bulk according : Not available.
to IMO instruments
Proper shipping name : Not available.
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Section 16. Other information
Hazardous Material Information System (U.S.A.)
Health * 3
Flammability 4
Physical hazards 3
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
ASPIRATION HAZARD - Category 1 Calculation method
History
Date of printing : 2/7/2022
Date of issue/Date of : 2/7/2022
revision
Date of previous issue : 12/20/2021
Version : 13.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
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