INDIAN PUBLIC SCHOOL VIRAMGAM

કરણ : 1,2,5,6,8,9 ધોરણ-12 Science Date : 11/02/23

કુલ ગુણ : 50 યુિનટ ટે ટ સમય : 1 hr
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [54]

1. Which of the following unit is useful to identify concentration of solution with vapour pressure ?
(A) Mole fraction (B) ppm (C) w/w% (D) Molality
2. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to
(A) low temperature.
(B) low atmospheric pressure.
(C) high atmospheric pressure.
(D) both low temperature and high atmospheric pressure.
3. The unit of ebulioscopic constant is ...........
(A) K kg mol–1 or K (molality)–1 (B) mol kg K–1 or K–1 (molality)
(C) kg mol–1 K–1 or K–1 (molality)–1 (D) K mol kg–1 or K (molality)
4. To prepare 6 normal 1 litre of HCl solution how much volume of 4 normal HCl and 10 normal HCl
solutions are required respectively ?
(A) 0.25 litre and 0.75 litre (B) 0.67 litre and 0.33 litre
(C) 0.82 litre and 0.18 litre (D) 0.5 litre and 0.5 litre
5. If aqueous solution having 1 gram urea is boil at 100.25 degree Celsius. Then solution with same
volume and having 3 gram glucose will boil at .......... temperature.
(A) 100°C (B) 100.5°C (C) 100.25°C (D) 100.75°C
6. Human blood having average osmetic pressure is 7.8 bar at 37°C temperature. So show so what
concentration of aqueous NaCl solution is required in human blood flow ?
(A) 0.16 mole/litre (B) 0.31 mole/litre (C) 0.60 mole/litre (D) 0.45 mole/litre
7.) w1 gm water will be the melting point of a .......... solution containing n mole soluble substance.
1000 × K f × w1 1000 × K f × n 1000 ´ K f ´ w1 1000 × K f × n
(A) 100 + (B) (C) 0 – (D) 0 –
n w1 n w1
8. To produce difference between freezing point and boiling point of a solution by 105.0°C, how much
sucrose should be dissolved in 100 gm of water ?
(Kf = 1.86°C. kg mol–1 and Kb = 0.151°C kg mol–1)
(A) 72 gm (B) 34.2 gm (C) 342 gm (D) 460 gm
9. To obtain 1 mole aluminum from Al2O3, required electricity will be ...........
(A) 1F (B) 6F (C) 3F (D) 2F
10. If standard half cells M, N, O, P and Q are arrange in increasing order then which two half cells gives
maximum cell potential on attaching ?
(A) M and M (B) M and Q (C) M and P (D) M and O
11. What is nernst equation to calculate reduction potential of non standard electrode Zn | Zn2+ ?

d
– 0.059 2+ d– 0.059 é 1 ù
(A) E 2+ =E 2+ – log[Zn ] (B) E Zn 2+ | Zn = E 2+ – log ê 2+ ú
Zn | Zn Zn |Zn 2 Zn | Zn 2 ë Zn û
0.059 0.059
(C) E = E d– + log[Zn 2+ ] (D) E = E d– + log[Zn 2+ ]
Zn 2+ | Zn Zn
2+
| Zn n Zn 2+ | Zn Zn
2+
| Zn 2

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12. What is the ratio of Al, Cu and Na which deposited on cathode bypassing faradic current through
different electrolytes having molten Al2O3 aqueous CuSO4 and molten NaCl solution ?
(A) 3 : 4 : 6 (B) 2 : 1 : 6 (C) 3 : 2 : 1 (D) 2 : 3 : 6
13. Which of the following reaction is possible at anode ?
+ 1
(A) 2H + O2 ® H 2O (B) F2 + 2e– ® 2F–
2
(C) (A) and (B) both (D) 2Cr3+ + 7H2O ® Cr2O72 + 14H+
14.) EoFe+3 | Fe = –0.036 V ; EoFe2+ | Fe = –0.439 V
Fe3+ + e– ® Fe2+
What is the standard electrode potential for above reaction ?
(A) –0.072V (B) 0.385V (C) 0.770V (D) –0.270V
d–
15. When redox reaction stops by achieving equilibrium then what will be true for E cell of following
reaction ?
2+
2Al(s) + 3Cu(aq) ® 2Al(aq)
3+
+ 3Cu(s)

d– 0.059 [Al 3+ ]2 d 0.059 [Al 3+ ]

(A) E cell = log –
(B) E cell = log
2 [Cu2+ ] 2 6 [Cu 2+ ]

d – 0.059 [Al3+ ]2 d – [Al 3+ ]2

(C) E cell = log (D) E cell = 0.059 log
6 [Cu 2+ ]3 [Cu 2+ ]3+
16. At 25°C temperature, if for given unknown half cell has 0.34 Volt potential, then calculate standard
reduction potential for copper : Pt | H2(g)(1 atm) | H+(1 M) | | Cu2+(1 M) | Cu
(A) –0.34 Volt (B) –3.4 Volt (C) +0.34 Volt (D) +3.4 Volt
17. Consider a first order gas phase decomposition reaction given below : A(g) ® B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of
the system increased by x units and became ‘pt’. The rate constant k for the reaction is given as .........
2.303 pi 2.303 pi
(A) k = log (B) k = log
t pi – x t 2pi – pt
2.303 pi 2.303 pi
(C) k = log (D) k = log
t 2 pi + pt t pi + x
18. Which of the following statements is not correct about order of a reaction ?
(A) The order of a reaction can be a fractional number.
(B) Order of a reaction is experimentally determined quantity.
(C) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in
the balanced chemical equation for a reaction.
(D) The order of a reaction is the sum of the powers of molar concentration of the reactants in the rate
law expression.
19. What is the order of following reaction ?
226
86 Ra ¾¾
® 4
2 He + 222
84 Rn
3
(A) Zero order (B) First order (C) order (D) Second order
2
1
20. For gaseous substances having rate of reaction is k[A][B]. If volume of container become than rate
4
becomes ....... times of initial rate.
1 1
(A) (B) 4 (C) 16 (D)
16 8
21. If reactant concentration is increased by 8 times for a certain reaction then rate of reaction becomes
double. Then what is order of reaction ?
1 1
(A) 2 (B) Zero Wish You - All The
(C)Best (D)
3 2
 If reactant concentration is increased by 8 times for a certain reaction then rate of reaction becomes
double. Then what is order of reaction ?
1 1
(A) 2 (B) Zero (C) (D)
3 2
1
22. If for a first order reaction 24 minute is required to decrease the concentration of reactant by then what
8
is the rate constant of reaction ?
1 0.693
(A) minute –1 (B) minute–1
24 24
2.303 æ 1ö 2.303
(C) log ç ÷ minute –1 (D) log(8) minute–1
24 è 8ø 24
23. If one first order reaction is completed by 50% in 1.26 ´ 1014 second then how much time will be taken
by this reaction to complete 100% ?
(A) 1.26 ´ 1015 second (B) 2.52 ´ 1014 second (C) 2.52 ´ 1025 second (D) Infinite time
24. Unit of rate constant for third order of reaction is...
(A) Liter2/(mole)2 s–1 (B) Second–1
(C) (mole/liter)–1 s–1 (D) (liter/mole)2 second
25. Which of the following element can prepare pp-dp type of bond ?
(A) Carbon (B) Nitrogen (C) Phosphorous (D) Boron
26. Which of the following acid can prepare three layered salts ?
(A) H3PO2 (B) H3BO3 (C) H3PO4 (D) H3PO3

27. In preparation of HNO3, NO gas is obtained on oxidation of ammonia. If 2 mole of ammonia is

taken in this reaction then how much mole of NO gas will obtained ?
(A) 2 (B) 3 (C) 4 (D) 6
28. Which of the following is a square planner ?
(A) XeF4 (B) SF4 (C) BF4– (D) [NiCl4]2–

29. Shape and hybridization of xenonoxyfluoride is given as follows, find incorrect set among them.
(A) XeOF2 ® T - shape - sp3d
(B) XeOF4 ® Square pyramidal - sp3d2
(C) XeO2F2 ® Substituted triagonal bipyramidal - sp3d
(D) XeO3F2 ® Octahedral - sp3d

30. How many hydrogen atoms are attached with oxygen in phosphoric acid ?
(A) Two (B) Three (C) Five (D) Four
31. What is the oxidation product of sodium borohydride with iodine ?
(A) B2H6 (B) Sodium hydroxide (C) HI (D) I3–

32. Which of the following has same number of s and p bond ?

(A) HCO3– (B) XeO4 (C) (CN)2 (D) CH2(CN)2

33. Which of the following cannot prepare MF36– ions ?

(A) In (B) Ga (C) B (D) Al
34. Helium is used in ballons because....
(A) it is radioactive. (B) it more reactive than H2.
(C) it is incombustible. (D) it is lighter then H2.
35. ……… does not give Cannizzaro reaction.
CHO
(A) (B) CHO (C) HCHO (D) CH3CHO
CH3

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36. In clemmensen reduction, carbonyl compound react with…..
(A) Zn(Hg) + HCl (B) Na(Hg) + HCl (C) Zn(Hg) + HNO3 (D) Na(Hg) + HNO3

37. Which of the following is not true for Tollen's reagent ?

(A) Tollen's reagent only react with ketone compounds.
(B) Tollen's reagent is a solution of ammoniated silver nitrate solution.
(C) Tollen's test is a test of aldehyde compound.
(D) In Tollen's test Ag+ of Tollen's reagent is reduced to Ag.
40%
H2SO4 Isomerisation
38. CH3 – C º CH A CH3 – C – CH 3
1%
HgSO4 O
Structure of ‘A’ and type of isomerism in the above reaction are respectively.
(A) Prop-1-en-2-ol, metamerism (B) Prop-1-en-1-ol, tautomerism
(C) Prop-2-en-2-ol, geometrical isomerism (D) Prop-1-en-2-ol, tautomerism
39. The reagent which does not react with both, acetone and benzaldehyde ?
(A) Sodium hydrogen sulphite (B) Phenyl hydrazine
(C) Fehling’s solution (D) Grignard reagent

40. Which product is formed when the compound CHO is treated with concentrated aqueous
KOH solution ?
O
+ ||
+
(A) KO CHO (B) CHO – OK + CH2OH

O O
+ || + + || + +
(C) KO C – OK+ + KO OK (D) C – KO + OK

P2O5 , D
41. CH3COOH ¾¾¾¾® P, then what is P in the reaction ?
(A) CH3CH2OH (B) (CH3CO)2O (C) CH3CHO (D) CH3COOC2H5

42. Among the following which reaction is not true for the production of butanoic acid ?
Tollens
(A) CH3CH2CH2CHO ¾¾¾¾¾
® CH CH CH COOH
3 2 2
reagent
CrO – H SO
(B) CH3 CH2 CH2CH2OH ¾¾¾¾¾¾¾
3 2 4¾
® CH3CH2CH2COOH
Jones reagent

3 ® H O+
(C) CH3 CH2 CH2 CONH2¾¾¾¾ CH3CH2CH2COOH
D
H O+
(D) CH3 CH2CH2CH2 Cl ¾¾¾¾
3 ® CH CH CH COOH
3 2 2

43. Which of the following compounds undergo aldol condensation ?

(A) H – CHO (B) –CO – CH3 (C) –CHO (D) –CO–

1.dil. NaOH
44. Ethanal + Benzaldehyde ¾¾¾¾¾¾® X
2. D; – H2O
identify product “X”.
(A) 3-phenyl prop-2-enal (B) 3-phenyl propanal
(C) 3-phenyl prop-2-enol (D) 2-phenyl prop-2-enal
45. Which of the following is strong base in presence of aqueous medium ?
(A) CH3NH2 (B) NC – CH2NH2 (C) (CH3)2NH (D) C6H5 – NH – CH3

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46. In ..... Hoffmann bromide reaction is observed.
(A) ArNH2 (B) ArCONH2 (C) ArNO2 (D) ArCH2 NH2

47. IUPAC name of NH2

(A) Benzenamine (B) Aniline (C) (A) and (B) both (D) Amino benzene
48. Which of the following is limitation of Gabriel phthalimide synthesis ?
(A) It cannot form pure primary amines. (B) Primary aromatic amine can't be form.
(C) This method is expensive and take long time. (D) All of above
49. Which product is obtained on reaction of methyl amine with HNO2 followed by hydrolysis ?
(A) Ethanamide (B) Ethanol (C) Methenal (D) Ethenoic acid
50. What is obtained on acetylation of aniline ?
(A) p-amino acetophenone (B) o-amino acetophenone
(C) N-acetyl aminobenzene (D) Paracetamol
51. Bromobenzene is obtained on heating of benzene diazonium chloride with Cu2Br2 + HBr. This reaction
is known as .........
(A) Carbyl amine (B) Elimination (C) Sandmeyer (D) Diazotization

52. Name of SO2Cl reactant is ?

(A) Tollen's reagent (B) Grignard reagent (C) Schiff reagent (D) Hinsberg reagent
53. What is correct order of halide amine ?
(A) R – I > R – Br > R – Cl (B) R – Cl > R – Br > R – I
(C) R – Br > R – I > R – Cl (D) R – I < R – Br > R – Cl
54. On reduction of which of the following compound produce secondary amine by LiAlH 4 ?
(A) Ethanamide (B) Ethyl isocynide (C) Nitro ethane (D) Ethane nitrile

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 INDIAN PUBLIC SCHOOL VIRAMGAM
કરણ : 1,2,5,6,8,9 ધોરણ-12 Science Date : 11/02/23
કુલ ગુણ : 50 યુિનટ ટે ટ સમય : 1 hr

Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que Universal_QueId

1. A Chap 2 S10 1 QP22P11B1212_P1C2S10Q1
2. B Chap 2 S10 2 QP22P11B1212_P1C2S10Q2
3. A Chap 2 S10 3 QP22P11B1212_P1C2S10Q3
4. B Chap 2 S10 4 QP22P11B1212_P1C2S10Q4
5. C Chap 2 S10 5 QP22P11B1212_P1C2S10Q5
6. B Chap 2 S10 7 QP22P11B1212_P1C2S10Q7
7. D Chap 2 S10 8 QP22P11B1212_P1C2S10Q8
8. A Chap 2 S10 9 QP22P11B1212_P1C2S10Q9
9. C Chap 3 S11 1 QP22P11B1212_P1C3S11Q1
10. B Chap 3 S11 2 QP22P11B1212_P1C3S11Q2
11. A Chap 3 S11 4 QP22P11B1212_P1C3S11Q4
12. D Chap 3 S11 6 QP22P11B1212_P1C3S11Q6
13. D Chap 3 S11 7 QP22P11B1212_P1C3S11Q7
14. C Chap 3 S11 8 QP22P11B1212_P1C3S11Q8
15. C Chap 3 S11 5 QP22P11B1212_P1C3S11Q5
16. C Chap 3 S11 3 QP22P11B1212_P1C3S11Q3
17. B Chap 4 S11 1 QP22P11B1212_P1C4S11Q1
18. C Chap 4 S11 2 QP22P11B1212_P1C4S11Q2
19. B Chap 4 S11 4 QP22P11B1212_P1C4S11Q4
20. C Chap 4 S11 5 QP22P11B1212_P1C4S11Q5
21. C Chap 4 S11 6 QP22P11B1212_P1C4S11Q6
22. D Chap 4 S11 7 QP22P11B1212_P1C4S11Q7
23. D Chap 4 S11 8 QP22P11B1212_P1C4S11Q8
24. A Chap 4 S11 10 QP22P11B1212_P1C4S11Q10
25. C Chap 7 S10 1 QP22P11B1212_P1C7S10Q1
26. C Chap 7 S10 2 QP22P11B1212_P1C7S10Q2
27. A Chap 7 S10 3 QP22P11B1212_P1C7S10Q3
28. C Chap 7 S10 4 QP22P11B1212_P1C7S10Q4
29. D Chap 7 S10 6 QP22P11B1212_P1C7S10Q6
30. B Chap 7 S10 5 QP22P11B1212_P1C7S10Q5
31. A Chap 7 S10 7 QP22P11B1212_P1C7S10Q7
32. B Chap 7 S10 8 QP22P11B1212_P1C7S10Q8

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33. C Chap 7 S10 9 QP22P11B1212_P1C7S10Q9
34. C Chap 7 S10 10 QP22P11B1212_P1C7S10Q10
35. D Chap 12 S9 1 QP22P11B1212_P2C12S9Q1
36. A Chap 12 S9 2 QP22P11B1212_P2C12S9Q2
37. A Chap 12 S9 3 QP22P11B1212_P2C12S9Q3
38. D Chap 12 S9 4 QP22P11B1212_P2C12S9Q4
39. C Chap 12 S9 5 QP22P11B1212_P2C12S9Q5
40. B Chap 12 S9 6 QP22P11B1212_P2C12S9Q6
41. B Chap 12 S9 7 QP22P11B1212_P2C12S9Q7
42. D Chap 12 S9 8 QP22P11B1212_P2C12S9Q8
43. B Chap 12 S9 9 QP22P11B1212_P2C12S9Q9
44. A Chap 12 S9 10 QP22P11B1212_P2C12S9Q10
45. C Chap 13 S9 1 QP22P11B1212_P2C13S9Q1
46. B Chap 13 S9 2 QP22P11B1212_P2C13S9Q2
47. C Chap 13 S9 3 QP22P11B1212_P2C13S9Q3
48. B Chap 13 S9 4 QP22P11B1212_P2C13S9Q4
49. C Chap 13 S9 5 QP22P11B1212_P2C13S9Q5
50. C Chap 13 S9 6 QP22P11B1212_P2C13S9Q6
51. C Chap 13 S9 7 QP22P11B1212_P2C13S9Q7
52. D Chap 13 S9 8 QP22P11B1212_P2C13S9Q8
53. A Chap 13 S9 9 QP22P11B1212_P2C13S9Q9
54. B Chap 13 S9 10 QP22P11B1212_P2C13S9Q10

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 INDIAN PUBLIC SCHOOL VIRAMGAM
કરણ : 1,2,5,6,8,9 ધોરણ-12 Science Date : 11/02/23
કુલ ગુણ : 50 યુિનટ ટે ટ સમય : 1 hr
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [54]

1.

//X
 Ans : (A)
2.

//X
 Ans : (B)
3.

//X
 Ans : (A)
4.

//X
 Ans : (B)
5.

//X
 Ans : (C)
6.

//X
 Ans : (B)
7.

//X
 Ans : (D)
8.

//X
 Ans : (A)

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9.

//X
 Ans : (C)
10.

//X
 Ans : (B)
11.

//X
 Ans : (A)
12.

//X
 Ans : (D)
13.

//X
 Ans : (D)
14.

//X
 Ans : (C)
15.

//X
 Ans : (C)
16.

//X
 Ans : (C)
17.

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//X
 Ans : (B)
18.

//X
 Ans : (C)
19.

//X
 Ans : (B)

20.

//X
 Ans : (C)
21.

//X
 Ans : (C)

22.

//X
 Ans : (D)
23.

//X
 Ans : (D)
24.

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//X
 Ans : (A)
25.

//X
 Ans : (C)
26.

//X
 Ans : (C)
27.

//X
 Ans : (A)
28.

//X
 Ans : (C)
29.

//X
 Ans : (D)
30.

//X
 Ans : (B)
31.

//X
 Ans : (A)
32.

//X
 Ans : (B)
33.

//X
 Ans : (C)
34.

//X
 Ans : (C)
35.

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//X
 Ans : (D)
36.

//X
 Ans : (A)
37.

//X
 Ans : (A)

38.

//X
 Ans : (D)
39.

//X
 Ans : (C)

40.

//X
 Ans : (B)

41.

//X
 Ans : (B)
42.

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//X
 Ans : (D)
43.

//X
 Ans : (B)

44.

//X
 Ans : (A)
45.

//X
 Ans : (C)
46.

//X
 Ans : (B)

47.

//X
 Ans : (C)
48.

//X
 Ans : (B)
49.

//X
 Ans : (C)
50.

//X
 Ans : (C)
51.

//X
 Ans : (C)

52.

//X
 Ans : (D)
53.

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//X
 Ans : (A)
54.

//X
 Ans : (B)

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