Product Safety Information Sheet Date of issue: 12.11.

2020
Product: DrägerSensors™ (classified as UN 2796) Version: 11/2020

Product Safety Information Sheet

Document: 9030375 Date of issue: 12.11.2020

Version: 11/2020 Supersedes: 25.01.2017
Format: DrägerSensors™ (classified as UN 2796)_miscellaneous_PSIS_st_375d.doc Status: released

1. Identification of the substance/preparation and of the company/undertaking

1.1 Identification of the substance or preparation:

Trade name: DrägerSensors™ (classified as UN 2796)
Part nos. : miscellaneous

1.2 Use of the substance/preparation:

Detection of gases, measuring of gas concentrations.

1.3 Company/undertaking name:

Dräger Safety AG & Co. KGaA
Revalstr. 1
D-23560 Lübeck
Telephone number +49 451/882-0
Fax number +49 451/882-2080
Contact for information: Dräger Global EHS Management
Telephone number +49 451/882-6979
Fax number +49 451/882-76979

1.4 Emergency telephone: +49 451/882-2395

1.5 Relevant products:

Part-No. Trade name Part-No. Trade name
6801032 MicroPac H2S 6810030 DrägerSensor® microPac CO
6809105 DrägerSensor® XS EC CO 6810032 DrägerSensor® XS H2S
6809110 DrägerSensor® XS EC H2S 6810034 DrägerSensor® XS O2
6809115 DrägerSensor® XS EC OV 6810200 DrägerSensor® XS CO V
6809120 DrägerSensor® XS CO HC 6810208 DrägerSensor® XS NO V
6809125 DrägerSensor® XS EC NO 6810210 DrägerSensor® XS O2 V
6809130 DrägerSensor® XS EC O2 6810258 DrägerSensor® XS R CO
6809135 DrägerSensor® XS PH3 6810260 DrägerSensor® XS R H2S
6809150 DrägerSensor® XS EC HCN 6810262 DrägerSensor® XS R O2 LS
6809155 DrägerSensor® XS EC NO2 6810365 DrägerSensor® XS 2 CO
6809160 DrägerSensor® XS EC SO2 6810370 DrägerSensor® XS 2 H2S
6809165 DrägerSensor® XS Cl2 6810375 DrägerSensor® XS 2 O2
6809170 DrägerSensor® XS H2O2 6810435 DrägerSensor® H2S
6809180 DrägerSensor® XS EC H2S HC 6810550 Dräger OxyTrace-Sensor (A)
6809185 DrägerSensor® XS H2 6810575 DrägerSensor® XS H2S SR
6809195 DrägerSensor® XS THT 6810740 DrägerSensor® OV1
6809200 DrägerSensor® XS Odorant 6810745 DrägerSensor® OV2
6809522 DrägerSensor® XS EtO 6811125 DrägerSensor® XS NF3
6809535 DrägerSensor® XS PH3 6811360 DrägerSensor® XS ClO2
6809550 DrägerSensor® XS O2 100 6811365 DrägerSensor® XS H2 HC
6809605 DrägerSensor® CO 6812570 DrägerSensor® CO LH
6809610 DrägerSensor® H2S LC 6812730 DrägerSensor® MEC CO
6809615 DrägerSensor® OV 6812735 DrägerSensor® MEC H2S
6809620 DrägerSensor® CO LS 6812740 DrägerSensor® MEC O2
6809625 DrägerSensor® NO LC 6812755 DrägerSensor® MEC NO2
6809630 DrägerSensor® O2 LS 6812760 DrägerSensor® MEC SO2
6809635 DrägerSensor® Hydride 6812770 DrägerSensor® MEC HCN

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

6809640 DrägerSensor® HCl 6812775 DrägerSensor® MEC H2

6809650 DrägerSensor® HCN 6812780 DrägerSensor® MEC OV
6809655 DrägerSensor® NO2 6812785 DrägerSensor® MEC NO
6809660 DrägerSensor® SO2 6813160 DrägerSensor® CO BB
6809675 DrägerSensor® H2O2 HC
6809685 DrägerSensor® H2
6809695 DrägerSensor® PH3/ AsH3
6809705 DrägerSensor® H2O2 LC
6809710 DrägerSensor® H2S HC

2. Hazards identification

2.1 Electrochemical DrägerSensors™ are products which are not subject to identification. The requirements of GHS,
EC regulations 1907/2006 (Reach) and 1272/2008 (GHS/CLP) do not apply to such products. Hence the following
information is purely voluntary.

2.2 Classification: n.a.

“Nature of hazard”: n/a
“H314”

2.3 Particular hazards for man and environment:

Improper handling, leaks, destruction of and/or damage to the DrägerSensors™ may release small amounts of caustic
sulphuric acid.

3. Composition/Information on ingredients

3.1 Chemical characterisation (constituent):

not applicable

3.2 Chemical characterisation (preparation):

Electrochemical DrägerSensors™ are products which are not subject to identification. The requirements of GHS,
EC regulations 1907/2006 (Reach) and 1272/2008 (GHS/CLP) do not apply to such products. Hence the following
information is purely voluntary.
Electrochemical DrägerSensors™ are articles which contain small amounts (2-8 ml) of sulphuric acid. The housings consist
of polyethylene, polypropylene and polyamide.

EINECS / Designation acc. to the GHS-

CAS-No. Conc. Unit H-Phrases
ELINCS-No. EC Regulation Pictogram
231-639-5 7664-93-9 Sulphuric Acid <45 % (w/w) GHS05 H314

3.3 Other information:

DrägerSensors™ are articles which are not subject to labelling. The requirements of EC regulations 1907/2006 (Reach)
and 1272/2008 (GHS/CLP) do not apply to such products. Hence, the information in this Product Safety Information
Sheet is purely voluntary!

4. First-aid measures

4.1 After inhalation:

n/a

4.2 After contact with skin:

Wash with plenty of water. Then dab with polyethylene glycol 400.

4.3 After contact with the eyes:

Flush open eye with plenty of water (for at least 15 minutes). Consult ophthalmologist immediately. Danger of corneal
clouding.

4.4 After ingestion:

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

Make victim drink plenty of water (if necessary several litres). Avoid vomiting (danger of perforation). Immediately consult
doctor. Do not attempt to neutralize.

4.5 Information for the doctor:

n/a

5. Fire-fighting measures

5.1 Suitable extinguishing media:

Elektrochemical DrägerSensors™ do not normally burn. Use extinguishing media appropriate to the environment, preferably
water, foam or CO2.

5.2 Extinguishing media which must not be used for safety reasons:
n/a

5.3 Special exposure hazards arising from substances or preparation itself, combustion products, resulting gases:
Thermal decomposition or combustion of the plastic components and ingredients of the electrochemical
DrägerSensors™ may release small amounts of harmful or toxic gases (CO2, CO, SO3 etc.).

5.4 Special protective equipment for fire-fighters:

For fire fighting respiratory protection with a compressed air breathing apparatus is recommended.

6. Accidental release measures

6.1 Personal precautions:

Take care to avoid eye and skin contact with released/leaked electrolyte; use safety goggles. Use protective gloves resistant
to acids.

6.2 Environmental precautions:

Do not discharge electrolyte into the sewer system.

6.3 Methods for cleaning up:

Bind released/leaked electrolyte with suitable absorbent (silica gel) and dispose of correctly. Wash away residues with large
amounts of water.

6.4 Additional information:

n/a

7. Handling and storage

7.1 Handling:
Precautions for safety handling: Closely follow the instructions in the relevant sensor data
sheets/instructions for use when handling electrochemical
DrägerSensors™. This also applies for all calibration activities and
when handling calibration gases. Calibration activities should
always be carried out in areas which are well-ventilated or provided
with an exhausting device. Observe hazard informations.
Information for protection against fire and explosion: Electrochemical DrägerSensors™ are not combustible.

7.2 Storage:
Requirements for storage and containers: Electrochemical DrägerSensors™ must be stored under the
conditions stated in the sensor data sheets (Oxygen Sensors: -
20°C - +40 °C; PAC Sensors: -40 °C - +40 °C; XS, Polytron
Sensors: 0 °C - +30 °C) and in their original packaging. Observe
the use-by date indicated on the packaging.
Information on storage together with other materials: n/a
Further information on storage conditions: n/a
Storage class: LGK: 8, 10-13 respectively (VCI-Concept)

7.3 Certain application: n/a

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

8. Exposure controls/Personal protection

8.1 Exposure limit values:

With normal handling of the DrägerSensors™ there should be no exposure to contents. However, if exposure does occur,
keep exposure as low as possible and follow the national exposure limits for the relevant chemicals.

EC, Land CAS-No. Description of material Type Content Unit

D 7664-93-9 Sulphuric acid former MAK* 0,1 E** mg/m³
**measured
*German TLV; as inhalable
recommendation fraction of
dust

8.2 Exposure controls:

Additional information on plant design: Handling according to the Instructions for Use.

8.2.1 Occupational exposure controls:

General protection and hygiene measures:
With normal handling of the DrägerSensors™ there should be no exposure to contents. However, if exposure does
occur, keep exposure as low as possible and follow the national exposure limits for the relevant chemicals.

Personal protection:
8.2.1.1 Respiratory protection:
Not necessary when handled according to the Instruction for use.

8.2.1.2 Hand protection:

With normal handling of the DrägerSensors™ there should be no exposure to contents. In case of accidents
use suitable protective gloves made from PE/ PP, Latex, butyl or nitrile rubber. Please observe the glove
manufacturers instructions on permeability and rupture times as well as the specific workplace conditions.
Prophylactic skin protection is recommended. Wash hands before breaks and after work.

8.2.1.3 Eye protection:

Not necessary when electrochemical DrägerSensors™ are handled correctly. Use safety goggles if
electrolyte is released from the DrägerSensors™.

8.2.1.4 Skin protection:

Prophylactic skin protection is recommended. Wash thoroughly after handling. Skin care.

8.2.2 Environmental exposure controls:

n/a

9. Physical and chemical properties

9.1 General information:

Form: n/a
Colour: colourless
Odour: odourless

9.2 Important information about the protection of health, safety and the environment: Method (67/548/EEC):
Solubility: n/a
pH-value: n/a
Boiling point: n/a
Melting point: n/a
Flame point: n/a
Inflameability: n/a
Explosion limits:
lower: n/a
upper: n/a
Ignition temperature: n/a

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

Vapour pressure: n/a

Mass density: n/a
Further information: see relevant sensor data sheet and section 2/3

9.3 Other information

n/a

10. Stability and reactivity

General information:
n/a

10.1 Conditions to be avoided:

n/a

10.2 Materials to be avoided:

n/a

10.3 Hazardous decomposition products:

n/a
Possibility of a dangerous exothermic reaction: If acid released from the DrägerSensors™ mingles
with water or bases.
Dangerous products of decomposition at contact with water: n/a

10.4 Further information:

n/a

11. Toxicological information

11.1 Toxicity tests:

Classification-relevant LD/LC50-values: n/a

11.1.1 Specific symptoms in animal studies: n/a

11.1.2 Irritant/corrosive effects: n/a

11.1.3 Sensitization:
n/a

11.1.4 Subacute and chronic toxicity:

Experiments: n/a
Species: n/a

11.1.5 Carcinogenic, mutagenic and reproductive toxic effects:

n/a

11.1.6 Further information:

n/a

11.2 Effects on human body/Experiments made in practice:

n/a
after inhalation:
n/a
after ingestion:
n/a
after eye contact:
n/a
after skin contact:
n/a

11.3 Additional toxicological information:

n/a

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

Further information:
n/a

12. Ecological information

12.1 Ecotoxicity:
n/a

12.2 Mobility:
n/a

12.3 Persistence and degradability:

Biological decompositionability: n/a
Behaviour in purification plants: n/a

12.4 Bioaccumulative potential:

n/a

12.5 Other adverse effects:

Electrochemical DrägerSensors™ contain electrolytes which are classified in WGK 1 [German water hazard class]

12.6 Additional information:

n/a

13. Disposal considerations

13.1 Product (recommendations):

Utilized and exhausted electrochemical DrägerSensors™ must not be disposed of as household waste. They must be
disposed of in accordance with local waste disposal regulations or by hiring an appropriate disposal company. Disposal is
regulated by federal and state waste disposal laws and the corresponding regulations or other national regulations.
Dräger Safety AG & Co. KGaA takes back expired and exhausted electrochemical DrägerSensors™ and ensures correct
recycling or disposal after separating off usable materials (a charge is made to cover costs).
Waste category: EWL (European waste list): 160215*
Waste designation: Hazardous components removed from discarded equipment.
Obligation to prove correct disposal: yes

13.2 Not cleaned packaging material (recommendations):

The disposal of plastic containers and flexible packages is possible by EWL 150102, and fibre board boxes by EWL 150101.

14. Transport information

14.1 Road transport ADR/RID and GGVSEB (cross-border/domestic):

UN-No.: 2796 Class: 8 Packing group: II
Name: Sulphuric Acid Classification code: C1
Remarks: Electrochemical DrägerSensors™ should always be shipped in combination packaging according to E2 or
LQ (1L). Then they are only subject to the provisions of Chaps. 3.4 or 3.5 of ADR/GGVSEB.

14.2 Marine transport IMDG-Code/GGVSee:

UN-No. 2796 Correct technical name: Sulphuric Acid
Class: 8 Sub risk: n/a Packing group: II
EmS-No.: n/a MFAG: n/a
Marine pollutant: n/a
Remarks: n/a

14.3 Air transport ICAO-TI and IATA-DGR:

UN-No. 2796 Proper shipping Name: SULPHURIC ACID
Class 8 Sub risk: ./. PG: II
Remarks: Electrochemical DrägerSensors™ could be shipped in "Excepted Quantities" according to Code E2.

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Product Safety Information Sheet Revision date 25.01.2017 Date of issue: 26.01.17
Product: DrägerSensors™ (classified as UN 2796) Version: 25.01.2017

14.4 Transport/further information:

Dräger recommends that the option of air shipment in "Excepted Quantities" (E2) should be used.

15. Regulatory information

15.1 Labelling according to EC Regulations:

Hazardous symbols and indicators of danger for dangerous substances and preparations: No labelling necessary
Hazardous components to be indicated on label: contains: n/a

H-Phrases:
n/a
P-Phrases (recommendation):
P102 Keep out of reach of children.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

15.2 National regulations:

Additional classification acc. to GefStoffV Annex II No. (only if differing from EC classification): n/a
Restrictions of occupation: n/a
Statutory order on hazardous incidents: n/a
Water pollution class: nwg
Information according 1999/13/EC about limitation of emissions of volatile organic compounds (VOC-guideline):
Further regulations, restrictions, and prohibition regulation:
(such as principles of industrial medicine and health and safety regulations)
Instruction Sheet BG-Chemie (Chemical Professional Association):
M 004 Corrosive and irritant substances
BGI 595 Corrosive and irritant substances

16. Other information

Use of the substance / preparation:

See section 1.2; additional information in the Instruction for use.

Relevant H-Phrases:
H314 Causes severe skin burns and eye damage.

Comments:
n. a.; n/a, ./. : not applicable
MAC: Maximum allowable concentration
COD: Chemical oxygen demand
BOD: Biochemical oxygen demand
EWL: European waste list
VOC: Volatile organic compounds
VCI: Verband der Chemischen Industrie e.V. (Association of the German chemical industry)
WGK: German water hazard class

Further information:
The above information represents our current state of experience and describes the product only with respect to safety
requirements. The manufacturer makes no representation and assumes no liability for any direct, incidental or consequential
damages resulting from its use. It is the responsibility of the customer to test whether the product is suitable for the purpose
intended by the customer.

Data sheet issued by: Global EHS Management

Contact: Dr. Michaela Schatz; [email protected]

Changes to preceding version: In section 1 and 16.

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