Module Description Thermal Chemistry Spring 20212022

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Module Code: ENGFF021

Module Name: Thermal Chemistry


Module Convenor: Dr Kasturi Muthoosamy
Second Module Convenor: NA
Total Credits: 10
Taught Semesters and Assessment Period: Spring (Default)
Assessed by end of Spring Semester
Session Availability: Taught every year
Module Nature: Elective Module

Summary of Content:
The aim of this module is to establish students’ basic concepts of chemistry kinetic, chemistry equilibrium,
chemistry thermodynamic and organic chemistry in preparation for undergraduate studies in engineering.

Activities:
Activity type Frequency (per week) Duration Timetable
Lecture 1 2 hours Central
Tutorial 1 1 hour Central

Assessment Details:
Assessment Type Percentage Requirement Length
Exam 1 65% Students are required to answer all questions (8 – 2 hours
10 questions) in Part A; and answer 2 out of 3 (or
4) questions in Part B.
Laboratory 15% Students are required to attempt 2 practical 2 hours per session
sessions.
In-class Exam 1 20% Students are required to answer 4 out of 5 1 hour 30 minutes
questions.

Aims:
The aims of the module are to provide students with:
• an introduction to gaseous, liquid and solid states
• a basic understanding of reaction rate, factors affecting the reaction rate and catalysis
• an introduction to reversible reactions and dynamic equilibrium
• an introduction to enthalpy changes and Hess’ Law
• an introduction to alky halides, alcohol, aldehyde and ketones

Recommended Text:
• Whitten, K.W., Davis, R.E., Peck L.M., & Stanley G.G. General Chemistry. 10th ed. Brooks/Cole. 2007. ISBN-
10: 1133610668; ISBN-13: 978-1133610663

References:
• AS Level and A Level Chemistry (2004), B. Ratcliff, H. Eccles, J. Raffan, J. Nicholson, D. Johnson, & J.
Newman, Cambridge University Press (ISBN 0521544718)
• JGR Briggs, Longman A-level Course in Chemistry, Longman, 2005, ISBN 981-4105-08-2.
• Fullick, A. and McDuell B., EDEXCEL AS & A2 Chemistry, Pearson, 2009.

Learning Outcomes:
On completion of this module, the students will be able to:
• describe the basic assumptions of the kinetic molecular theory as applied to an ideal gas
• explain qualitatively in terms of intermolecular forces and molecular size for a gas to approach ideal
behavior and the limitations of its ideality.
• apply the general gas equation pV = nRT in calculations
• apply kinetic-molecular model in describing liquid state, melting, vaporization and vapour pressure
• describe the nature of energy changes that accompany chemical reactions
• define the terms of various enthalpy changes of reactions and standard conditions, bond energy and
lattice energy.
• calculate the enthalpy changes, bond energy and lattice energy from appropriate experimental results
• apply Hess’s law to construct energy cycles, including Born-Haber cycles
• define the terms and calculate the rate of reaction, rate equation, order of reaction, rate constant and
half-life of a reaction
• identify the rate-determining step
• describe the factors affecting the rate of reaction including the role of catalysts and activation energy
involved.
• interpret chemical reactions in terms of equilibria
• describe the response of equilibrium to change
• define and calculate the equilibrium constant and constant expressions such as Kp and Kc
• interpret and use the nomenclature, general formulae and displayed formulae for alkyl halide, alcohols,
aldehydes and ketones
• interpret and use the terminology such as nucleophile, electrophile, free radical, addition, substitution
associated with organic equations.

Lecture outline:
Week
Lesson
Number
1 Chemical kinetics I
Introduction, rate of reaction, rate law expression, 1st order integrated rate law expression, half life,
Arrhenius equation,
2 Chemical kinetics II
reaction rate theories (collision and transition state theories), factors that affect reaction rates,
reaction mechanisms (initial rates), activation energy, examples
3 Chemical Equilibrium I
Introduction, dynamic equilibrium, equilibrium constant, reaction quotient,
4 Chemical Equilibrium II
Le Chatelier's principle, factors that affect equilibria, relationship between Kp and Kc, examples
5 Further organic chemistry-I (Part I)
Alkyl halides, synthesis of alkyl halides, chemical reaction and mechanism of alkyl halides, alcohols
(structure, physical properties, synthesis and chemical reactions)
6 Further organic chemistry-I (Part II)
Alkyl halides, synthesis of alkyl halides, chemical reaction and mechanism of alkyl halides, alcohols
(structure, physical properties, synthesis and chemical reactions)
7 Further organic chemistry-II (Part I)
Introduction, aldehydes and ketones (synthesis, chemical reaction and mechanism), carboxylic acid
(synthesis, chemical reactions and mechanisms), examples
8 Further organic chemistry-II (Part II)
Introduction, aldehydes and ketones (synthesis, chemical reaction and mechanism), carboxylic acid
(synthesis, chemical reactions and mechanisms), examples
9 Chemical thermodynamics
Introduction, thermodynamics terms, enthalpy changes (standard enthalpy changes, standard molar
enthalpies of formation), Hess's law, bond energies, examples
10 Gases (Part I)
Boyle’s Law, Charles’ Law, Combined Gas Law, Avogadro’s law, Ideal Gas Law, Density and Molar
Mass Calculations, Dalton’s Law of Partial Pressures, Gas Stoichiometry, Kinetic Molecular Theory,
Graham’s Law, Behaviour of Real Gases
11 Gases (Part II)
Boyle’s Law, Charles’ Law, Combined Gas Law, Avogadro’s law, Ideal Gas Law, Density and Molar
Mass Calculations, Dalton’s Law of Partial Pressures, Gas Stoichiometry, Kinetic Molecular Theory,
Graham’s Law, Behaviour of Real Gases

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