Stomp+455+CS 000000000030173670 SDS CPA TH en 4-0

Safety data sheet
Page: 1/12
BASF Safety data sheet
Date / Revised: 18.04.2023 Version: 4.0
Product: Stomp 455 CS
(30173670/SDS_CPA_TH/EN)
Date of print: 26.06.2023
1. Substance/preparation and manufacturer/supplier identification
Product name:
Stomp 455 CS
Use: crop protection product, herbicide
Manufacturer/supplier:
BASF (Thai) Limited
23rd Floor, Emporium Tower, 622, Sukhumvit 24 Rd.,
Klongton, Klongtoey, Bangkok 10110, THAILAND
Telephone: +66 2624-1999
Telefax number: +66 2664-9254
E-mail address: [email protected]
Emergency information:
International emergency number:
Telephone: +49 180 2273-112
2. Hazard identification
Classification according to UN GHS 2009
Classification of the substance and mixture:

Skin corrosion/irritation: Cat.3
Skin sensitization: Cat.1B
Reproductive toxicity: Cat.2 (unborn child)
Hazardous to the aquatic environment - acute: Cat.2
Hazardous to the aquatic environment - chronic: Cat.2
Label elements and precautionary statement:
Pictogram:
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Signal Word:
Warning
Hazard Statement:
H316 Causes mild skin irritation.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging the unborn child.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statement:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
Precautionary Statements (Prevention):

P280 Wear protective gloves, protective clothing and eye protection or face
protection.
P261 Avoid breathing mist or vapour or spray.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and
understood.
P272 Contaminated work clothing should not be allowed out of the workplace.
Precautionary Statements (Response):

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P308 + P313 IF exposed or concerned: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
Precautionary Statements (Storage):

P405 Store locked up.
Precautionary Statements (Disposal):

P501 Dispose of contents and container to hazardous or special waste
collection point.
Other hazards which do not result in classification:

See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
3. Composition/information on ingredients
Chemical nature
Substance nature: mixture

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crop protection product, herbicide, capsule suspension (CS)
Hazardous ingredients
pendimethalin
Content (W/W): 38.72 % Acute Tox.: Cat. 5 (oral)
CAS Number: 40487-42-1 Repr.: Cat. 2 (unborn child)
Aquatic Acute: Cat. 1
Aquatic Chronic: Cat. 1
M-factor acute: 100
M-factor chronic: 10
Sulfuric acid magnesium salt (1:1), heptahydrate

Content (W/W): < 20 %
CAS Number: 10034-99-8
4. First-Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water
On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Note to physician:
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, foam, dry powder, carbon dioxide
Specific hazards:
carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides, sulfur oxides, halogenated
compounds, metal oxides
The substances/groups of substances mentioned can be released in case of fire.
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Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying
with water if exposed to fire.
6. Accidental Release Measures

Personal precautions:
Do not breathe vapour/spray.Use personal protective clothing.Avoid contact with the skin, eyes and
clothing.
Environmental precautions:
Do not discharge into drains/surface waters/groundwater.Do not discharge into the subsoil/soil.
Methods for cleaning up or taking up:

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers,
which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and
detergents, observing environmental regulations. Wear suitable protective equipment.
7. Handling and Storage

Handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.
Protection against fire and explosion:

No special precautions necessary. The substance/product is non-combustible. Product is not
explosive.
Storage
Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.
Storage stability:
Storage duration: 60 Months
Protect from temperatures below: -5 °C

Changes in the properties of the product may occur if substance/product is stored below indicated
temperature for extended periods of time.
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time.
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8. Exposure controls and personal protection
Components with occupational exposure limits
No substance specific occupational exposure limits known.
Personal protective equipment

Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Combination filter for
gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN
14387 Type ABEK-P3)
Hand protection:
Suitable chemical resistant safety gloves (EN ISO 374-1) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN ISO 374-1): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures:

The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.
9. Physical and Chemical Properties

Form: liquid
Colour: yellow to brown
Odour: faint odour, nutty
Odour threshold: Not determined due to potential health hazard by inhalation.
pH value: approx. 7 - 9
(21 °C)
(measured with the undiluted
substance)
Melting point: approx. 0 °C

Information applies to the solvent.
Boiling point: approx. 100 °C
Flash point:
No flash point - Measurement made
up to the boiling point.
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Evaporation rate:
not applicable
Flammability (solid/gas): not applicable

Lower explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Ignition temperature: 354 °C (DIN EN 14522)
Thermal decomposition: 235 °C , 900 kJ/kg (DSC (OECD 113))

(onset temperature)
Not a substance liable to self-

decomposition according to UN
transport regulations, class 4.1.
SADT: > 75 °C
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
Vapour pressure: approx. 23 hPa

(20 °C)
Density: approx. 1.18 g/cm3

(20 °C)
Relative vapour density (air):
not applicable
Solubility in water: dispersible

Partitioning coefficient n-octanol/water (log Pow):
not applicable
Viscosity, dynamic: 128 mPa.s (OECD 114)

(20 °C, 100 1/s)
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
10. Stability and Reactivity

Conditions to avoid:
See SDS section 7 - Handling and storage.
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Thermal decomposition: 235 °C, 900 kJ/kg (DSC (OECD 113))

(onset temperature)
Thermal decomposition: Not a substance liable to self-decomposition according to

UN transport regulations, class 4.1.
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.
Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.
Chemical stability:
The product is stable if stored and handled as prescribed/indicated.
Reactivity:
No hazardous reactions if stored and handled as prescribed/indicated.
11. Toxicological Information
Routes of exposure
Acute oral toxicity
Experimental/calculated data:
LD50rat (oral): > 2,000 mg/kg (OECD Guideline 423)
No mortality was observed.
Acute inhalation toxicity
LC50 rat (by inhalation): > 5.2 mg/l 4 h (OECD Guideline 403)
No mortality was observed. An aerosol was tested.
Acute dermal toxicity
LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402)
Assessment of acute toxicity
Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually
nontoxic by inhalation.
Symptoms
Information, i.e. additional information on symptoms and effects may be included in the GHS labeling
phrases available in Section 2 and in the Toxicological assessments available in Section 11.
(Further) symptoms and / or effects are not known so far
Irritation
Assessment of irritating effects:

Not irritating to the eyes. Skin contact causes slight irritation.
Skin corrosion/irritation rabbit: (OECD Guideline 404)
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Serious eye damage/irritation rabbit: (OECD Guideline 405)
Respiratory/Skin sensitization
Assessment of sensitization:
Sensitization after skin contact possible.
Mouse Local Lymph Node Assay (LLNA) mouse: (OECD Guideline 406)
Germ cell mutagenicity
Assessment of mutagenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity
Assessment of carcinogenicity:
individual components.
Information on: pendimethalin

Assessment of carcinogenicity:
In long-term studies in rats the substance induced thyroid tumors. The effect is caused by an animal
specific mechanism that has no human counter part. In long-term studies in mice in which the
substance was given by feed, a carcinogenic effect was not observed.
----------------------------------
Reproductive toxicity
Assessment of reproduction toxicity:

individual components. The results of animal studies gave no indication of a fertility impairing effect.
Developmental toxicity
Assessment of teratogenicity:

Assessment of teratogenicity:
Indications of possible developmental toxicity/teratogenicity were seen in animal studies.
----------------------------------
Specific target organ toxicity (single exposure)
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.
Remarks: The product has not been tested. The statement has been derived from the properties of
the individual components.
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Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:


Assessment of repeated dose toxicity:
No substance-specific organtoxicity was observed after repeated administration to animals. Adaptive
effects were observed after repeated exposure in animal studies.
----------------------------------
Aspiration hazard
Other relevant toxicity information
Misuse can be harmful to health.
12. Ecological Information
Ecotoxicity
Assessment of aquatic toxicity:

Toxic to aquatic life with long lasting effects.
Toxicity to fish:
LC50 (96 h) 20.36 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)
Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
Aquatic plants:
EC50 (72 h) 1.49 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201)
EC10 (72 h) 0.14 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201)
EC50 (7 d) 19.25 mg/l (growth rate), Lemna gibba (OECD guideline 221)
No observed effect concentration (7 d) 1.0 mg/l (growth rate), Lemna gibba (OECD guideline 221)
Mobility
Assessment transport between environmental compartments:


Assessment transport between environmental compartments:
The substance will slowly evaporate into the atmosphere from the water surface.
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Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
----------------------------------
Persistence and degradability
Assessment biodegradation and elimination (H2O):


Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
----------------------------------
Bioaccumulation potential
Assessment bioaccumulation potential:


Bioaccumulation potential:
Bioconcentration factor: 3,300
Based on a weight of evidence, the compound will not bioaccumulate.
----------------------------------
Additional information
Other ecotoxicological advice:

Do not discharge product into the environment without control.
13. Disposal Considerations
Must be sent to a suitable incineration plant, observing local regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.
14. Transport Information

Domestic transport:
UN number or ID number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (PENDIMETHALIN)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known

user:
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Sea transport
IMDG
Packing group: III
Marine pollutant: YES
Special precautions for EmS: F-A; S-F
user:
Air transport
IATA/ICAO
Packing group: III
Special precautions for None known
user:
Further information
Product may be shipped as non-hazardous in suitable packages containing a net quantity of 5 L or
less under the provisions of various regulatory agencies: ADR, RID, ADN: Special Provision 375;
IMDG: 2.10.2.7; IATA: A197; TDG: Special Provision 99(2); 49CFR: §171.4 (c) (2) and also the
Special Provision 375 in Appendix B which is regulated in China "Regulations Concerning Road
Transportation of Dangerous Goods Part 3: Index of dangerous goods name and transportation
requirements" (JT/T 617.3)
15. Regulatory Information
Other regulations
To avoid risks to man and the environment, comply with the instructions for use.
16. Other Information
Vertical lines in the left hand margin indicate an amendment from the previous version.
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The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.

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Safety data sheet

1. Substance/preparation and manufacturer/supplier identification

Use: crop protection product, herbicide

Classification according to UN GHS 2009

Classification of the substance and mixture:

Label elements and precautionary statement:

Precautionary Statements (Prevention):

Precautionary Statements (Response):

Precautionary Statements (Storage):

Precautionary Statements (Disposal):

Other hazards which do not result in classification:

Substance nature: mixture

crop protection product, herbicide, capsule suspension (CS)

Sulfuric acid magnesium salt (1:1), heptahydrate

On contact with eyes:

Special protective equipment:

6. Accidental Release Measures

Methods for cleaning up or taking up:

7. Handling and Storage

Protection against fire and explosion:

Protect from temperatures below: -5 °C

8. Exposure controls and personal protection

Components with occupational exposure limits

No substance specific occupational exposure limits known.

Personal protective equipment

General safety and hygiene measures:

9. Physical and Chemical Properties

Melting point: approx. 0 °C

Flammability (solid/gas): not applicable

Thermal decomposition: 235 °C , 900 kJ/kg (DSC (OECD 113))

Not a substance liable to self-

Vapour pressure: approx. 23 hPa

Density: approx. 1.18 g/cm3

Solubility in water: dispersible

Viscosity, dynamic: 128 mPa.s (OECD 114)

10. Stability and Reactivity

Thermal decomposition: 235 °C, 900 kJ/kg (DSC (OECD 113))

Thermal decomposition: Not a substance liable to self-decomposition according to

Hazardous decomposition products:

11. Toxicological Information

Assessment of irritating effects:

Serious eye damage/irritation rabbit: (OECD Guideline 405)

Germ cell mutagenicity

Information on: pendimethalin

Assessment of reproduction toxicity:

Information on: pendimethalin

Specific target organ toxicity (single exposure)

Assessment of repeated dose toxicity:

Information on: pendimethalin

Other relevant toxicity information

Misuse can be harmful to health.

12. Ecological Information

Assessment of aquatic toxicity:

Assessment transport between environmental compartments:

Information on: pendimethalin

Persistence and degradability

Assessment biodegradation and elimination (H2O):

Information on: pendimethalin

Assessment bioaccumulation potential: