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Material Safety Data Sheet MSDS# 15-3201

Section 1. Chemical Product and Company Identification

Product name ARMOHIB® CI-31
Material Uses : Surfactant. In Case of Emergency

Supplier/ AKZO NOBEL SURFACE CHEMISTRY LLC CHEMTREC: 800-424-9300

Manufacturer 525 West Van Buren CANUTEC: 613-996-6666
Chicago, IL 60607-3823 Medical/Handling: 914-693-6946
www.surfactants.akzonobel.com Product/Technical: 800-906-9977

Section 2. Hazards Identification

Physical State Liquid.
Color Amber.
Odor Fatty

Emergency Overview WARNING!

CAUSES EYE IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
HARMFUL TO AQUATIC ORGANISMS.
MAY BE HARMFUL TO ENVIRONMENT IF RELEASED IN LARGE AMOUNTS.

Avoid contact with eyes. Do not ingest. Avoid prolonged or repeated contact with skin. Wash
thoroughly after handling. Avoid contact of spilled material and runoff with soil and surface waterways.

Routes of Entry Absorbed through skin. Dermal contact. Eye contact.

See Toxicological Information (section 11)

Section 3. Composition/ Information on Ingredients

Name CAS # % by Weight
proprietary alkoxylated Fatty Amine. salts proprietary proprietary
proprietary alkoxylated Organic acid. proprietary proprietary
Thiourea, N,N'-dibutyl 109-46-6 20-30

Section 4. First Aid Measures

Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 30 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing
contaminated clothing and shoes. Cold water may be used. W ash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention.

Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.

Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

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Medical Conditions Repeated or prolonged exposure is not known to aggravate medical condition.
Aggravated by
Overexposure:

Section 5. Fire Fighting Measures

Flammability of the May be combustible at high temperature.
Product

Flash Points Closed cup: >150°C (302°F).

Products of Combustion These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3
...).
Fire Fighting Media SMALL FIRE: Use DRY chemical powder.
and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire)

Section 6. Accidental Release Measures

Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste
disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of
according to local and regional authority requirements.
Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish
cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system.

Section 7. Handling and Storage

Handling Avoid contact with eyes. Do not ingest. Avoid prolonged or repeated contact with skin. Wash
thoroughly after handling. Avoid contact of spilled material and runoff with soil and surface waterways.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 48°C
(118.4°F).

Section 8. Exposure Controls/ Personal Protection

Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective occupational exposure limits. Ensure that eyewash stations and safety
showers are proximal to the work-station location.

Personal Protection
Eyes Splash goggles.
Body Lab coat.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Hands Gloves.
Feet Suitable protective footwear.

Protective Clothing
(Pictograms)

Personal Protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
Case of a Large Spill a specialist BEFORE handling this product.

Ingredient Name Exposure Limits United States

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proprietary alkoxylated Fatty Amine. Not available.

salts
proprietary alkoxylated Organic acid. Not available.
thiourea, n,n'-dibutyl- Not available.

Section 9. Physical and Chemical Properties

Physical State Liquid.
Color Amber.
Odor Fatty
pH 5.5 [Acidic.]
Melting/Freezing Point -4°C (24.8°F)
Pour Point 0oC
Density 1.042 g/cm3 (25°C / 77°F)
Vapor Pressure <0.1 kPa (<1 mmHg) (at 20°C)
Vapor Density The highest known value is 6.5 (Air = 1) (thiourea, n,n'-dibutyl-).
Solubility Soluble in cold water.
Dispersion Properties See solubility in water.
Physical Chemical Viscosity = 1150 (#3 @ 60 RPM cps)
Comments Surface tension = 43.4 dynes/cm (0.1%), 41.5 dynes/cm (1.0%)
HLB (Davies scale 0-40) = 30.4 (proprietary alkoxylated Fatty Amine. salts)

Section 10. Stability and Reactivity

Stability and Reactivity The product is stable.
Incompatibility with Reactive with OXIDIZING AGENTS, acids.
Various Substances Slightly reactive to reactive with alkalis.
Hazardous Will not occur.
Polymerization

Section 11. Toxicological Information

Toxicity to Animals
Ingredient Name or Product Test Result Route Species
name
proprietary alkoxylated Fatty LD50 580 mg/kg Oral Rat
Amine. salts
proprietary alkoxylated Organic LD50 >5000 mg/kg Oral Rat
acid.
thiourea, n,n'-dibutyl- LD50 350 mg/kg Oral Rat

Special Remarks on thiourea, n,n'-dibutyl-: Fetotoxic in animal.

Chronic Effects on
Humans

Acute Effects Skin May cause sensitization by skin contact. Moderately irritating to the skin.

Acute Effects Eyes Severely irritating to the eyes.

Special Remarks on :
Other Toxic Effects on proprietary alkoxylated Fatty Amine. salts: Skin and Eyes based on data for: (similar material)
Humans proprietary alkoxylated Organic acid.: Skin and Eyes based on data for: (similar material)

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Section 12. Ecological Information

Ecotoxicity
Ingredient Name or Product name Species Period Result
proprietary alkoxylated Fatty Amine. Trout (LC50) 96 hour(s) 24 mg/l
salts Algae. (EC50) 96 hour(s) 3.9 mg/l
Biodegradability and proprietary alkoxylated Fatty Amine. salts: 11% @ 28 day(s) CBT; 26% @ 112 day(s) CBT
Ecotoxicity Remarks

Products of Degradation These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...), sulfur oxides
(SO2, SO3...).

Section 13. Disposal Considerations

Waste Information Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Consult your local or regional authorities.

Section 14. Transport Information

Regulatory UN Proper shipping name Class Packing Label Additional information
Information number Group
DOT Not - - - Remarks
Classification regulated. 172.102 (c) Special Provision 146:
This material may be shipped as a
- Class 9, because it has been
designated as such by another
Compentent Authority. For transport
by ground or rail in North America,
this material is not regulated for
transport.

TDG Not - - - -
Classification regulated.
-

IMDG Class UN 3082 ENVIRONMENTALLY 9 III Marine pollutant

HAZARDOUS SUBSTANCE, Marine pollutant (P)
LIQUID, N.O.S. (Quaternary
9
alkyamine ethoxylate). Marine
pollutant (Quaternary
alkyamine ethoxylate)

IATA-DGR UN 3082 ENVIRONMENTALLY 9 III -

Class HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (Quaternary
9
alkyamine ethoxylate)

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Section 15. Regulatory Information

HCS Classification Toxic
Irritating material

U.S. Federal Regulations TSCA: All intentionally present components are listed on the TSCA inventory.
DSL: All intentionally present components are listed on the DSL.
TSCA 5(a)2 final significant rules: No products were found.
CERCLA: Hazardous substances.: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: ARMOHIB® CI-31
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: ARMOHIB® CI-31:
Immediate (Acute) Health Hazard
SARA 313 Form R Reporting Requirements
No products were found.
SARA 313 Supplier Notification
No products were found.

State Regulations No products were found.

California prop. 65: No products were found.

WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA DSL: proprietary alkoxylated Fatty Amine. salts; proprietary alkoxylated Organic acid.;
thiourea, n,n'-dibutyl-

Component EC Number EC Status EC Annex

European Union proprietary alkoxylated Fatty Amine. proprietary proprietary proprietary
salts
proprietary alkoxylated Organic acid. proprietary proprietary proprietary
thiourea, n,n'-dibutyl- 203-674-6 Not available. Not available.

Other International Lists Australia (NICNAS): proprietary alkoxylated Fatty Amine. salts; proprietary alkoxylated Organic
acid.; thiourea, n,n'-dibutyl-

China IECSC:: proprietary alkoxylated Fatty Amine. salts; proprietary alkoxylated Organic acid.;
thiourea, n,n'-dibutyl-

Japan (MITI): proprietary alkoxylated Fatty Amine. salts; thiourea, n,n'-dibutyl-

Korea (TCCL): proprietary alkoxylated Fatty Amine. salts; proprietary alkoxylated Organic acid.;
thiourea, n,n'-dibutyl-

Philippines (RA6969): proprietary alkoxylated Fatty Amine. salts; thiourea, n,n'-dibutyl-

Section 16. Other Information

Hazardous Material Health 2 National Fire Fire Hazard
Information System Fire Hazard 1 Protection 1
(U.S.A.) Physical Hazards 0 Association Health 2 0 Reactivity

Personal Protection
(U.S.A.) Specific Hazard

Other Information Armohib® is a registered trademark of Akzo Nobel or affiliated companies and is registered in one or
more countries including the United States.

Validation Date 9/11/2013. Validated by Elitania Perez

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Previous Validation Date 5/20/2011. Print Date 9/11/2013.

Phone Number 312-544-7038

Notice to Reader
The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed
to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good
faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency
of such information and/or suggestions or as to the product’s merchantability or fitness for any particular purpose, or that any suggested
use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent.
Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing
with other products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the
date on this document is more than three years old, call to make certain that this sheet is current.