Enz All

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Safety Data Sheet

1. Identification
Product Information. 104437, 116331, 104130
Product Name: EnzAll

Recommended Use. Professional Carpet Cleaning


Uses advised against. Professional Use Only

Supplier. Legend Brands


Chemspec
15180 Josh Wilson Road
Burlington, WA 98233
E-Mail: [email protected]
800-932-3030

Legend Brands
4520 Eastgate Parkway
Mississauga, ON L4W 3W6
800-932-3030

Emergency telephone number. INFOTRAC 1-800-535-5053 (North America)


1-352-323-3500 (International)

2. Hazards Identification
GHS Classification in accordance with 29 CFR 1910.1200
Acute Tox. 4 Inhalation, Eye Dam. 1

GHS Pictograms

Signal Word
Danger

Unknown Acute Toxicity


1.5% of the mixture consists of ingredients of unknown acute toxicity

HAZARD STATEMENTS
Causes serious eye damage.
Harmful if inhaled.
Precautionary Statements - Prevention.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements - Response.
If inhaled: Remove person to fresh air and keep comfortable for breathing.

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Product name.: W.20461 REV_E EnzAll

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
Immediately call a poison center/doctor.
3. Composition/Information on Ingredients

Chemical Name CAS-No. Wt. %


SODIUM TRIPOLYPHOSPHATE 7758-29-4 50-75
Sodium carbonate 497-19-8 10-25
Alcohols, C10-14, ethoxylated 66455-15-0 10-25
Tetrasodium Pyrophosphate 7722-88-5 1.0-2.5
Ethoxylated C12-16 Alcohols 68551-12-2 1.0-2.5
Phosphoric acid 7664-38-2 0.1-1.0

The exact percentage (concentration) of composition has been withheld as a trade secret.

4. First-aid Measures

Description of first-aid measures.


General advice.
Call a physician if irritation develops or persists. Show this safety data sheet to the doctor in attendance.
When symptoms persist or in all cases of doubt seek medical advice.
Inhalation.
Move to fresh air. If symptoms persist, call a physician. Immediate medical attention is required.
Skin contact.
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water. Remove all
contaminated clothes and shoes.
Eye contact.
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Remove contact
lenses, if present.
Ingestion.
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician
immediately. Gently wipe or rinse the inside of the mouth with water.
Symptoms.
See Section 2.2, Label Elements and/or Section 11, Toxicological effects.
Notes to physician.
Treat symptomatically.

5. Fire-fighting Measures
Extinguishing media.
Suitable extinguishing media.
Water spray. Dry powder. Alcohol-resistant foam. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. Carbon dioxide (CO2).
Extinguishing media which shall not be used for safety reasons.
High volume water jet.

Special hazards arising from the substance or mixture.


Hazardous decomposition products formed under fire conditions.

Advice for firefighters.


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)
and full protective gear.

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6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures.


Personal precautions.
Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined areas. Do not
breathe vapors or spray mist.
Advice for emergency responders.
Use personal protection recommended in Section 8.

Environmental precautions.
Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system.
Prevent product from entering drains. See Section 12 for additional Ecological information.

Methods and materials for containment and cleaning up.


Methods for Containment.
Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. Use
personal protective equipment. Remove all sources of ignition.
Methods for cleaning up.
Use personal protective equipment as required.

Reference to other sections.


See section 8 for more information.

7. Handling and Storage

Conditions for safe storage, including any incompatibilities.


Advice on safe handling.
Handle in accordance with good industrial hygiene and safety practice.
Hygiene measures.
See section 7 for more information.
Storage Conditions.
Keep containers tightly closed in a cool, well-ventilated place. Store in original container.

8. Exposure Controls/Personal Protection

Ingredients with Occupational Exposure Limits


Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING

Phosphoric acid 1 mg/m3 3 mg/m3 1 mg/m3 N.E.

TLV = Threshold Limit Value TWA = Time Weighted Average PEL = Permissible Exposure Limit STEL = Short-Term Exposure Limit N.E. = Not Established

Engineering Measures.

Showers, eyewash stations, and ventilation systems.


Personal protective equipment.

Eye/Face Protection.

Safety glasses with side-shields.


Skin and body protection.

Wear suitable protective clothing.


Respiratory protection.

In case of insufficient ventilation wear suitable respiratory equipment.

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Hygiene measures.

See section 7 for more information.

9. Physical and chemical properties.


Information on basic physical and chemical properties.
Physical state Solid
Appearance Powder
Color Off-white
Odor Downey-like
Odor Threshold No Information
pH 10.36
Melting/freezing point., °C (°F) No Information
Flash Point., °C (°F) No Information
Boiling point/boiling range., °C (°F) 86 - 302 (186.8 - 575.6)
Evaporation rate No Information Available
Explosive properties. No Information
Vapor pressure. No Information
Vapor density. No Information
Specific Gravity. (g/cm3) 0.730
Water solubility. Soluble in water
Partition coefficient. No Information
Autoignition temperature.,°C No Information
Decomposition Temperature °C. No Information
Viscosity, kinematic. No Information

Other information.
Volatile organic compounds (VOC) content. <0.2%
Density, lb/gal No Information

10. Stability and Reactivity


Reactivity.
Stable under normal conditions.

Chemical stability.
Stable under recommended storage conditions.

Possibility of hazardous reactions.


None known based on information supplied.

Conditions to Avoid.
Direct sources of heat.

Incompatible Materials.
None known based on information supplied.

Hazardous Decomposition Products.


Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

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Product name.: W.20461 REV_E EnzAll

11. Toxicological Information


Information on toxicological effects.
Acute toxicity.
Product Information
No Information
The following values are calculated based on chapter 3.1 of the GHS document.
ATEmix (oral) 18,482.6 mg/kg
ATEmix (dermal) 14,300.0 mg/kg
ATEmix (inhalation - dust/mist) 3.93 mg/l
Component Information.
CAS-No. Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
7758-29-4 SODIUM TRIPOLYPHOSPHATE 0.000 N.I. 0.000 (Gas/Mist)
497-19-8 Sodium carbonate 0.000 2002 0.8 mg/l Guinea pig (Dust)
66455-15-0 Alcohols, C10-14, ethoxylated 0.000 N.I. 0.000 (Gas/Mist)
7722-88-5 Tetrasodium Pyrophosphate 0.000 N.I. 0.000 (Gas/Mist)
68551-12-2 Ethoxylated C12-16 Alcohols 0.000 N.I. 0.000 (Gas/Mist)
7664-38-2 Phosphoric acid 0.000 2740 mg/kg 0.000 (Gas/Mist)
Rabbit
N.I. = No Information
Skin corrosion/irritation.
SKIN IRRITANT.
Eye damage/irritation.
No Information
Respiratory or skin sensitization.
No Information
Ingestion.
No Information
Germ cell mutagenicity.
No Information
Carcinogenicity.
No Information
Reproductive toxicity.
No Information
Specific target organ systemic toxicity (single exposure).
No Information
Specific target organ systemic toxicity (repeated exposure).
No Information
Aspiration hazard.
No Information
Primary Route(s) of Entry
No Information

12. Ecological Information


Toxicity.
79.82500 % of mixture consists of components of unknown hazards to the aquatic environment.
Ecotoxicity effects.
Toxicity to daphnia and other
Chemical Name Toxicity to algae Toxicity to fish aquatic invertebrates
LC50 96 h Lepomis macrochirus
Sodium carbonate EC50 48 h Daphnia magna 265
- 300 mg/L, LC50 96 h Pimephales
497-19-8 mg/L
promelas 310 - 1220 mg/L

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Product name.: W.20461 REV_E EnzAll

Persistence and degradability.


No data are available on the product itself.

Bioaccumulative potential.
Discharge into the environment must be avoided.

Mobility in soil.
No information

Other adverse effects.


No information

13. Disposal Considerations

Waste Disposal Guidance.


Disposal should be in accordance with applicable regional, national and local laws and regulations.
No Information

14. Transport Information

DOT No Information

IMDG No Information

IATA No Information

15. Regulatory Information


International Inventories:
TSCA Complies
DSL Complies
EINECS/ELINCS -
ENCS -
IECSC -
KECI -
PICCS -
AICS -
NZIoC -
TCSI
TSCA United States Toxic Substances Control Act Section 8(b) Inventory.
DSL Canadian Domestic Substances List.
EINECS/ELINCS European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances.
ENCS Japan Existing and New Chemical Substances.
IECSC China Inventory of Existing Chemical Substances.
KECL Korean Existing and Evaluated Chemical Substances.
PICCS Philippines Inventory of Chemicals and Chemical Substances.
AICS Australian Inventory of Chemical Substances.
NZIoC New Zealand Inventory of Chemicals.
TCSI Taiwan Chemical Substance Inventory

U.S. Federal Regulations:

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Product name.: W.20461 REV_E EnzAll

SARA SECTION 313:


This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372: .

No Sara 313 components exist in this product.


TOXIC SUBSTANCES CONTROL ACT 12(b):
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:.

No TSCA 12(b) components are present in this product.

CALIFORNIA PROPOSITION 65 CARCINOGENS

No Proposition 65 Carcinogens exist in this product.


CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

No Proposition 65 Reproductive Toxins exist in this product.

16. Other Information


Revision Date: 10-17-2022 Supersedes Date: 5/3/2019
Reason for revision: No Information
Datasheet produced by: Regulatory Department

HMIS Ratings:
Health: 3 Flammability: 0 Physical Hazard: 0 Personal Protection: X

NFPA Ratings:
Health: 3 Flammability: 0 Instability: 0 Physical & Chemical: -

Notice: Constituents of this product include crystalline silica which, if inhalable, may cause silicosis, a form of progressive
pulmonary fibrosis. Inhalable crystalline silica is listed by IARC as a group I carcinogen (lung) based on sufficient evidence in
occupationally exposed humans and sufficient evidence in animals. Crystalline silica is also listed by the NTP as a known human
carcinogen. Constituents may also contain asbestiform or non-asbestiform tremolite or other silicates as impurities, and above de
minimus exposure to these impurities in inhalable form may be carcinogenic or cause other serious lung problems.

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The
information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may
not be valid for such material used in combination with any other material or in any process, unless specified in the text.

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