Chemical Bonding and Molecular Structure

13
Chapter 4
Chemical Bonding and

Molecular Structure
ASSIGNMENT
Single Choice Type Questions

1. Which of the following compound have zero dipole moment?
(1) CH2 = CH — CH2Cl (2) NH3
H— — H
(3) PBr3Cl2 (4) C = C—
—
Cl Cl
2. Which of the following is correct statement?
(1) Only half-filled orbital can participate in hybridisation
(2) Only filled orbital can participate in hybridisation
(3) The orbitals undergoing hybridisation should have almost equal energy
(4) The orbitals undergoing hybridisation must have different energy
3. The compound having bond angle greater than NH3 will be
(1) NCl3 (2) H2O
(3) OF2 (4) NF3
4. The maximum London forces are observed in
(1) N2 (2) SO3
(3) C2H6 (4) CO2
5. More than one type of bond angles are observed in
(1) SF4 (2) XeO4
(3) PCl4+ (4) H3O+
6. Among C2H6, C2H4 and C2F6, what is the correct order of C — C bond length?
(1) C2H6 = C2F6 > C2H4 (2) C2F6 > C2H6 > C2H4
(3) C2H6 > C2F6 > C2H4 (4) C2H4 > C2H6 > C2F6
7. Maximum bond order is of
(1) CN– (2) NO
(3) O2− (4) O2
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8. Which of the following is least ionic?

(1) CuI (2) NaBr
(3) KF (4) CsCl
9. What is the hybridisation of N in SiH3 – NCO?
(1) sp2 (2) sp
(3) sp3d2 (4) sp3
10. If 2s–2p mixing of molecular orbital does not take place in all molecules, then the correct statement is
(1) B2 is paramagnetic and C2 is diamagnetic (2) Both B2 and C2 are diamagnetic
(3) Both B2 and C2 are paramagnetic (4) B2 is diamagnetic and C2 is paramagnetic
11. Number of right angles in XeF5+ will be
(1) 4 (2) 5
(3) 6 (4) Zero
12. d–p bonding is maximum in
(1) XeO2F4 (2) SO32–
(3) H2S (4) XeO4
13. The shape of IF4– and ICl2– ions are respectively
(1) See-saw and bent (2) Square planar and linear

(3) Square planar and bent (4) See-saw and linear
14. d-orbital involved in hybridization of PF2Cl3 is
(1) dxy (2) d z2
(3) dzx (4) d x2 − y2
15. Consider the following statements.

Statement I : Energy of resonance hybrid is less than energy of any single cannonical structure.
Statement II : The cannonical forms have real existence.
Statement III : Resonance stabilizes the molecule.
The incorrect statement(s) is/are
(1) Only I and II (2) Only II and III
(3) Only I (4) Only II
16. In P(CH3)x(CF3)5–x, if value of 'x' is changed from 2 to 3, then polarity of molecule
(1) Changes from polar to non-polar
(2) Changes from non-polar to polar
(3) Remains non-polar
(4) Remains polar
17. Which of the following represents the correct arrangement in the decreasing order of bond dissociation
energy?
+
2  O2  O2  O2
(1) O2– –
(2) O2+  O2  O2–  O22–
(3) O2  O2+  O2–  O22– (4) O2–  O2– +

2  O2  O2
Chemical Bonding and Molecular Structure JEE SCORE for Main-2024 15
18. For which of the following molecule significant   0?

Cl CN
(a) (b)
Cl CN
OH SH
(c) (d)
OH SH
(1) Only (a) (2) (a) and (b)
(3) Only (c) (4) (c) and (d)
19. The species in which the N atom is in a state of sp hybridization is
(1) NO2– (2) NO3–
(3) NO2 (4) NO+2
20. Which of the following species is not paramagnetic?

(1) O2 (2) B2
(3) NO (4) CO
21. Which of the following compounds contain(s) no covalent bond(s)?
KCl, PH3, O2, B2H6, H2SO4
(1) KCl, B2H6, PH3 (2) KCl, H2SO4
(3) KCl (4) KCl, B2H6
22. Match List-I with List -II.

List-I List-II
(A) MO = A – B (I) Dipole moment
(B)  = Q × r (II) Bonding molecular orbital
Nb – Na
(C) (III) Anti-bonding molecular orbital
2
(D) MO = A + B (IV) Bond order
Choose the correct answer from options given below.

(1) (A)-(II), (B)-(I), (C)-(IV), (D)-(III) (2) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
(3) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (4) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
23. Match List-I with List-II.
List-I List-II
(Compound) (Shape)
(A) BrF5 (I) bent
(B) [CrF6]3– (II) square pyramidal
16 JEE SCORE for Main-2024 Chemical Bonding and Molecular Structure
(C) O3 (III) trigonal bipyramidal
(D) PCI5 (IV) octahedral
Choose the correct answer from the options given below.

(1) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) (2) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
(3) (A)-(II), (B)-(IV), (C)-(I), (D)-(III) (4) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
24. In the structure of SF4, the lone pair of electrons on S is in
(1) Equatorial position and there are two lone pair - bond pair repulsions at 90º
(2) Equatorial position and there are three lone pair - bond pair repulsions at 90º
(3) Axial position and there are three lone pair - bond pair repulsion at 90º
(4) Axial position and there are two lone pair - bond pair repulsion at 90º
25. Match List-I with List-II.
List-I List-II
(Molecule) (hybridization shape)
A. XeO3 I. sp3d; linear
B. XeF2 II. sp3; pyramidal
C. XeOF4 III. sp3d3; distorted octahedral
D. XeF6 IV. sp3d2; square pyramidal
Choose the correct answer from the options given below.
(1) A-II, B-I, C-IV, D-III (2) A-II, B-IV, C-III, D-I
(3) A-IV, B-II, C-III, D-I (4) A-IV, B-II, C-I, D-III
Numerical Value Type Questions

26. According to MO theory, number of species/ions from the following having identical bond order is ______.
CN– , NO+ , O2 , O2+ , O22+
27. Among the following species
N2 , N2+ , N2– , N22– , O2 , O2+ , O2– , O22–
the number of species showing diamagnetism is ______.
28. The spin-only magnetic moment value of B +2 species is ______ × 10–2 BM. (Nearest integer)
[Given : 3 = 1.73 ]
29. According to molecular orbital theory, the number of unpaired electron(s) in O2–
2 is ______.
30. Amongst BeF2, BF3, H2O, NH3, CCl4 and HCl, the number of molecules with non-zero net dipole moment is
______.
x
31. The difference between bond orders of CO and NO is , where x = ______. (Round off to the Nearest
2
Integer)
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13

Chemical Bonding and

Single Choice Type Questions

8. Which of the following is least ionic?

(3) H2S (4) XeO4

13. The shape of IF4– and ICl2– ions are respectively

(1) See-saw and bent (2) Square planar and linear

(1) dxy (2) d z2

(3) dzx (4) d x2 − y2

15. Consider the following statements.

(3) O2  O2+  O2–  O22– (4) O2–  O2– +

18. For which of the following molecule significant   0?

(1) NO2– (2) NO3–

(3) NO2 (4) NO+2

20. Which of the following species is not paramagnetic?

(1) KCl, B2H6, PH3 (2) KCl, H2SO4

(3) KCl (4) KCl, B2H6

22. Match List-I with List -II.

(B)  = Q × r (II) Bonding molecular orbital

Choose the correct answer from options given below.

(B) [CrF6]3– (II) square pyramidal

(C) O3 (III) trigonal bipyramidal

(D) PCI5 (IV) octahedral

Choose the correct answer from the options given below.

Numerical Value Type Questions

CN– , NO+ , O2 , O2+ , O22+

27. Among the following species

N2 , N2+ , N2– , N22– , O2 , O2+ , O2– , O22–

the number of species showing diamagnetism is ______.

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