Module Physics. Last
Module Physics. Last
Module Physics. Last
CALORIMETRY
I. OBJECTIVES:
1. To be able to distinguish the various units of heat.
2. To be able to describe specific heat and its cause,
3. To be able to explain how the specific heat of materials are obtained using
calorimetry.
4. To be able to compare and contrast the three common phases of matter and
relate latent heat to phase changes.
Q where:
C= Q- amount of heat, cal, kcal, Btu
m ∆t
m- mass of the substance, g, kg, lb
Δt- change in temperature, Co, Co, Fo
C- specific heat,
cal kcal Btu
, ,
g. Co kg. Co lb. F o
Table 3. Specific Heat Capacities
Aluminum 0.220
Brass 0.094
Copper 0.093
Ethyl alcohol 0.600
Glass 0.200
Gold 0.030
Ice 0.500
Iron 0.113
Lead 0.031
Mercury 0.033
Silver 0.056
Soil (Average) 0.25
Steam 0.480
Steel 0.114
Turpentine 0.420
Zinc 0.092
Water 1.000
Wood (Average) 0.40
Solution.
Given:
Q
m = 200 g C=
m ∆t
ti =20oC Q = m c ∆t
tf = 100oC
cal cal
cHg = 0.033 g.Co Q = m c ∆t = 200 g (0.033 g.Co )(100o C − 20o C)
Q = 528 calories
Sample Problem 9-2.
How much heat is required to:
a) raise the temperature of 10-lb brass from 30oC to 50oC?
b) raise the temperature of 0.80-kg of alcohol from 15oC to its boiling point,
78.2oC?
Solution.
Btu
(a) Given: Q = m c ∆t = 10 lb (0.094 )(122o F − 86o F)
lb.Fo
m = 10 lb. Q = 33.84 Btu
9
ti = 30oC = 5 (30) + 32 = 86o F
9
tf = 50oC = 5 (50) + 32 = 122o F
Btu
cB = 0.094 lb.Fo
kcal
(b) m = 0.80 kg Q = m c ∆t = 0.80 kg (0.600 )(78.2o C − 15o C)
kg.Co
ti = 15oC Q = 30.34 kcal
tf = 78,2oC
kcal
cA = 0.600 kg.Co
ms = 95.58 grams
Sample Problem 9-4.
Suppose that 200 g of copper at 300oC is dropped into 310 g of water at 15oC contained
in a 310 g copper calorimeter cup. Compute the equilibrium temperature.
Solution. The heat lost by the copper must equal the heat gained by water plus the heat
gained by calorimeter cup.
Given:
mcu = 200 g mW = 310 g mc =310 g tmix =?
o
tcu =300 C o
tW = 15 C o
tc = 15 C
cal cal
ccu = 0.093g.Co cW =1.0 g.Co
Heat lost by copper = Heat gained by water + Heat gaine by calorimeter cup
During the phase change, the heat energy goes into the work of breaking and
separating molecules, rather than increasing the temperature. The heat involved in a
phase change is called latent heat.
Latent heat of fusion (Lf) – is the amount of heat which must be added to a unit of mass
of the substance to change it from solid to liquid at melting point.
Btu cal kcal
Lf ice = 144 = 80 = 80
lb g kg
Latent heat of vaporization (Lv) – is the amount of heat which must be added to a unit
mass of the substance at boiling point to change it from liquid to vapor.
Btu cal kcal
Lv water at boiling point = 970 = 540 = 540
lb g kg
For a change in temperature, the amount of heat required is the product of three
factors, mass of the substance, specific heat, and change in temperature.
Q = m c ∆t
For a change of phase, the amount of heat needed is the product of two factors,
mass of the substance and latent heat.
Q =m L
Q1 Q2 Q3 Q4
mi = 2 kg mW = 2 kg
mW = 2 kg mW = 2 kg
ti = -10oC mi = 2 kg 100oC
0oC 100oC
0oC
Let Q1- the amount of heat needed to raise the temperature of ice to its melting point.
kcal
Q1 = mi Ci ∆t = (2 kg ) (0.50 ) [0o C − (−10o C)]
kg. Co
Q1 = 10 kcal
Q2- the amount of heat needed to melt ice at 0oC.
kcal
Q2 = mi Lf = (2 kg ) (80 )
kg
Q2 = 160 kcal
Q3- the amount of heat needed to raise the temperature to its boiling point.
kcal
Q3 = mW CW ∆t = (2 kg ) (1.0 ) [100o C − 0o C]
kg. Co
Q3 = 200 kcal
mi = 20 lb mW = 20 lb
mW = 20 lb mW = 20 lb
ti = 12oF mi = 20 lb 212oF ms = 20 lb
32oF 212oF
32oF 232oF
Let Q1- the amount of heat needed to raise the temperature of ice to its melting point.
Btu
Q1 = mi Ci ∆t = (20 lb ) (0.50 ) [32o F − 12o F]
lb. F o
Q1 = 200 Btu
Q2- the amount of heat needed to melt ice at 32oF.
Btul
Q2 = mi Lf = (20 lb ) (144 )
lb
Q2 = 2880 Btu
Q3- the amount of heat needed to raise the temperature to its boiling point.
Btu
Q3 = mW CW ∆t = (20 lb ) (1.0 ) [212o F − 32o F]
lb. F o
Q3 = 3600 Btu
I. OBJECTIVE
1. To be able to (a) describe the three methods of heat transfer and (b) give practical
and environmental examples of each method.
L L
t’ t
t’ t Q
Q H=
H= T
T
A
Sample Problem10-1.
The outside wall of a brick barbecue pit is 3 inches thick. The inside surface is at 300 oF
and the outside surface is 85oF. How much heat is lost in 1 hour through an area of 1 ft2?
Solution.
Given:
L = 3 inches
t’ = 300oF
t = 85oF
T = 1 hour
A = 1 ft2
Btu.in
k = 5 ft2 .h.Fo
Required: Q
Q k A ∆t
H= =
T L
Btu. in 2 0 0
k T A ∆t 5 2
ft . h. F o (1 h)(1 ft )(300 F − 85 F)
Q= =
L 3 in.
Q = 358.33 Btu
Sample Problem 10-2.
The copper rod having a cross section of 5 cm2 and a length of 50 cm, has one end kept
in contact with boiling water and the other end in contact with ice. Assuming that all the
heat enters at one is transferred by conduction to the other end. Find the amount of ice
melted in ½ hr.
Solution.
Given: 1 m2
A = 5 cm2 x = 5 x 10−4 m2
10000 cm2
t’ = 100oC t = 0oC
1m
L = 50 cm x 100 cm = 0.5 m
Q
H=
T
1 3600 𝑠
Required: mi , T = ℎ𝑟 x = 1800 𝑠
2 1h
Solve for Q:
kcal
k T A ∆t 9.2 x 10−2 m. s. Co (1800 s)(5 x 10−4 m2 )(1000 C − 00 C)
Q= =
L 0.5 𝑚
Q = 16.56 kcal
For mi:
Q = mi Lf
Q 16.56 kcal
mi = = = 0.207 kcal
Lf kcal
80
kg
Q
H= ti
T
10 cm 14 cm
Solution. When two materials of different thermal conductivities and similar cross section
are connected the rate at which heat is conducted through each material must be
constant. For steady flow, the rate of heat through the concrete is equal to the rate of heat
flow through corkboard. Let ti be the temperature at concrete-corkboard interface.
Rate of heat flow through the concrete = Rate of heat flow through the corkboard
HC = HCB
k C A C ∆t k CB ACB ∆t
=
LC LCB
AC = ACB
kcal kcal
(4.1 x 10−4 m. s. Co ) (24o C − t i ) (1 x 10−5 m. s. Co ) [t i − (−200 C)
=
0,14 m 0.10 m
−5
kcal −6
kcal −5
kcalo C −4
kcalo C
−4.1 x 10 t − 1.4 x 10 t = 2.8 x 10 − 9.84 x 10
s. Co i s. Co i s. Co s. Co
kcal kcalo C
−4.24 x 10−5 t = −9.56 x 10 −4
s. Co i s. Co
t i = 22.55𝑜 𝐶
b) The heat flow per unit area per unit time can now be found from
kcal
k C A C ∆t (4.1 x 10−4 m. s. Co ) (24o C − t i )
HC = =
LC 0,14 m
kcal
(4.1 x 10−4 m. s. Co ) (24o C − 22.55o C )
HC =
0,14 m
kcal
HC = 4.25 x 10−3
m2 . s.
or
kcal
(1 x 10−5 m. s. Co ) [t i − (−200 C)
HCB =
0.10 m
kcal
(1 x 10−5 ) [22.5𝑜 C − (−200 C)
HCB = m. s. Co
0.10 m
kcal
HCB = 4.25 x 10−3
m2 . s.
10-2. CONVECTION
Convection is the transmission of heat in liquids and gases. Currents of the liquids
or gas are set up as the warmer portion rises and the colder part descends to take its
place. During the process of heat transfer, a volume of hot fluid (gas or liquid) moves from
one region to another, carrying the internal energy within it. The current is referred to as
convection currents.
ts
tf tf
A
Convection current is a liquid or a gas that absorbs energy at one place and then moves
to another place where it releases heat to a cooler portion of the fluid.
The rate H at which heat is transferred by convection is proportional to the area A
to the difference in temperature Δt between the wall and the fluid.
Q
H= = h A t
T
where:
H- rate of heat flow by convection
Q- amount of heat
T- time
A- area
t- change in temperature
h- convection coefficient
Geometry kcal
h,
m2 .s.Co
4 ∆
Pipe diameter, d (1.0 𝑥 10−3 ) √ 𝑑𝑡
t’=116
o
C h = (4.24 𝑥 10−4 ) 4√∆𝑡
4
t=35oC t=35oC = (4.24 𝑥 10−4 ) √116 − 35
kcal
= 1.272 𝑥 10−3
m2 .s.Co
T=1 h =3600 s
A=6m2
The quantity of heat transferred from each wall can be found by solving for Q,
Q
H= = h A ∆𝑡
T
Q = h A T ∆t
kcal
Q = (1.272 x 10−3 2 o ) (6 m2 )(3600 s)(116o C − 35o C)
m .s.C
Q = 2225.5 kcal
Since there are two walls, the total heat transferred,
Q = 2225.5 kcal (2)
Q = 4451 kcal
4 ∆
t’=94oC
ℎ = (1.0 𝑥 10−3 ) √ 𝑑𝑡
t=23oC
4 (94−23)
h=5 m
ℎ = (1.0 𝑥 10−3 ) √ 0.08
T=1 h=3600 s
kcal
ℎ = 5.46 𝑥 10−3
m2 .s.Co
Area of a pipe:
𝐴 = 𝜋 d ℎ = 𝜋 ( 0.08 𝑚)(5 𝑚) = 1.26 m2
The quantity of heat released to the air by convection,
Q = h A T ∆t
kcal
Q = (5.46 𝑥 10−3 2 o ) (1.26 m2 )(3600 s)(94o C − 23o C)
m .s.C
Q = 1758.4 kcal
10-3. RADIATION
Radiation is the transmission of energy in the form of electromagnetic waves
originating at the atomic level. Electromagnetic waves exist either in the form of light,
radio, x-rays and gamma rays. The electromagnetic waves travel at a given velocity, the
same as the measured speed of light (3 x 108 m/s) and require no medium for their
passage. Blackbody is said to be a perfect absorber of radiation, and accordingly it is the
best radiator.
Radiation differs from conduction and convection is that radiation requires no
material medium for the transmission of the heat energy.
For example: The heat from the sun reaches the earth by means of radiation.
11. CURRENT AND RESISTANCE
I. OBJECTIVES:
1. To be able to (a) summarize the basic features of a battery and (b) explain how
a battery produces a direct current in a circuit, (c) define electric current.
2. To be able to (a) define electrical resistance and explain what is meant by an
ohmic resistor, summarize the factors that determine the resistance and (c) calculate the
effect these factors in simple situations
3. To be able to (a) define electrical power, (b) calculate the power delivery of simple
electric circuits, and (c) explain joule heating and its significance.
E r
As long as the internal chemical action maintains a potential difference across the
terminals, current is supplied to a circuit. The battery is said to deliver current to a circuit.
Alternatively, we say that the circuit (or its components) draws current from the battery.
Because electrons can flow only in one direction in such a circuit, from negative (-)
terminal (cathode) to the positive (+) to the positive (+) terminal (anode), this is called
direct current (dc).
Electric current (I) in a wire is defined as the net amount of charge (q) that passes a
cross sectional area of the wire per unit time, that is
𝑞
I=
𝑡
where:
q- magnitude of a charge, coulomb
t-time, seconds
coulomb
I- current, = Ampere
sec
The combination of units is called Ampere(A), in honor of French physicist Andre Ampere
(1775-1836) an early investigator of electrical and magnetic phenomena.
q 4 coulombs
I= = = 2 Amperes
t 2s
11-2. RESISTANCE AND OHM’S LAW
The fact that a wire carrying current can become hot, it is evident that the work done
be the applied force in producing the current must be accomplished some opposition or
resistance (R).
Resistance (R) of a wire or other object is a measure of the potential difference (V)
that must be impressed across the current of one ampere to flow through it. The unit of
resistance is ohm (Ω).
Ohm’s law is not a fundamental law in the sense that Newton’s law of gravitation, or
the first and second law of thermodynamics are. There is no law that states that materials
must have a constant resistance. It is an extremely useful generalization that applies to a
wide range of materials, particularly metals, unless otherwise specify, assume the
resistors are ohmic (a resistor that has constant resistance)
Ohm’s law states,” The current flowing in a conductor is directly proportional to the
potential difference and inversely proportional to the resistance of the circuit.”
E
I=
R
where:
E- potential difference, Volt (V)
R- resistance, Ω
I- current, V/Ω or Ampere (A)
Sample Problem 11-2.
What is the potential difference in an electric circuit with a current of 15 A and a resistance
of 4Ω?
Solution.
Given:
I = 15 A
R=4Ω
Required: E
E = I R = (15 A) (4)
E = 60 V
E 120 𝑉
I= = = 4.5 𝐴
R 26.7 Ω
Sample Problem 11-4.
A load of 10 Ω was connected to a 12-V battery. The current drawn was 1.18 A. What is
the internal resistance of the battery?
Solution.
Given:
R = 10 Ω
E = 12 V
I = 1.18 A
Required: r (internal resistance of the battery)
E
I=
r +R
I (r + R) = E
I r + IR = E
E − IR 12 − (1.18 A)( 10 Ω)
r= =
I (1.18 A)
r = 0.17 Ω