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CHEM EXAM Second Quarter

BSIT (AMA Computer Learning Center)

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What kind of thermodynamic system is coffee held in a cup?

Open system

The equilibrium constant for the formation of hydrogen iodide from hydrogen and iodine is at a certain
temperature.

H2(g) + I2(s) ⇌ 2 HI(g) K = 45

Which of the following is true regarding this equilibrium?

I. The reaction is product favored.

II. The reaction is reactant favored.

III. Equilibrium lies to the right.

IV. Equilibrium lies to the left.

I and III

The higher the number of types of molecules, the higher is the degree of disorder.

True

Twenty grams of ammonium nitrate( NH4NO3 ) is dissolve in 125 grams of water in a coffee cup
calorimeter and the temperature drops from 295 oC to 285 o C. Find the value of q for the calorimeter.

(hint: treat heat capacity of water as the heat capacity of calorimeter and its contents)

-5430 J

Calculate the enthalpy (ΔH) for the process in which 45.0 grams of water is converted from liquid at 10° C
to vapor at 30° C.

126Kj

Which of the following is true for a chemical reaction at equilibrium?

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The rates of the forward and reverse reactions are equal

The lower the concentration of the weak acid decreases the pH of the buffer solution.

False

Predict the entropy change (ΔS) if a liquid substance crystallizes into a solid.

∆S<0

In thermodynamics, an ___process, also called a constant-volume process.

Isochronic

Reactions in which the products can react to form back the reactants are said to be ___.

Reversible

The ____ of a substance is the amount of energy required to raise the temperature of 1 gram of the
substance by 1 degree Celsius.

Specific heat

Calculate ΔG⁰ for a reaction where ΔH⁰ is equal to 36.2 kJ and ΔS⁰ is equal to 123 J/K at 298 K.

-0.45 Kj

A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on it.
What is the heat change of the system?

-30j

What happens to the internal energy of the system if work is done by the system?

Internal energy will decrease

If the reaction quotient Q has a smaller value than the related equilibrium constant, K, __________

The reaction is not at equilibrium, and will make more products at the expense of reactants

If ΔG is 1, the system is at equilibrium.

False

___ is the state at which the concentration ratio of products to reactants is observed to be constant.

Equilibrium

In exothermic reaction, heat is liberated into the surroundings.

True

If ΔG is positive, the reaction is spontaneous in the reverse direction.

True

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If 100 J are required to change the temperature of 10 g of substance B by 5.68 degrees Celsius, what is
the specific heat of substance B?

1.76J/g. C

In thermodynamics, an ___process is a type of thermodynamic process in which the pressure P of a

system remains constant.

Isobaric

Which one of the following thermodynamic quantities is not a state function?

Work

An isometric process, is a thermodynamic process during which the volume of the closed system
undergoing such a process remains constant.

True

An equilibrium that strongly favors products has __________

A value Of K>>1.

Freezing and condensation are examples of exothermic process.

True

A common name for methanol (CH3OH) is wood alcohol. The normal boiling point of methanol is 64.7 o
C and the molar enthalpy of vaporization if 71.8 kJ/mol. The value of ΔS when 2.15 mol of CH3OH (l)
vaporizes at 64.7 o C is ___ J/K.

457

Total change in energy is equal to the sum of the heat and work transferred between the systems and
surroundings.

First lqw of thermodynamics

Predict the entropy change (ΔS) if the temperature of crystal is increased.

∆S will decrease

The increased in internal energy of the system is 80 J and has 70 J of work done on it. What is the heat
change of the system?

-10J

Chemical equilibrium is described as a dynamic process because there is a movement in which the
forward and reverse reactions occur at the same rate to reach a point where the amounts or
concentrations of the reactants and products are unchanging with time.

True

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Calculate the number of kJ necessary to raise the temperature of 80 grams of aluminum from 45 to 65
degrees Celsius. Molar heat capacity of aluminum is 24 J/mole.K.

1.44 Kj

If 25 J are required to change the temperature of 5.0 g of substance A by 2.0 degrees Celsius, what is the
specific heat of substance A?

2.5J/G.C

Non-spontaneous processes are those that do not take place by themselves or is a type of reaction
which cannot occur without the input of work from an external source.

True

A chemical equilibrium may be established by starting a reaction with __________

All of the above

In thermodynamics, an ___process is a type of thermodynamic process in which the temperature T of a

system remains constant.

Isothermal

Melting and vaporization are examples of exothermic process.

False

___ states that regardless of the multiple stages or steps of a reaction, the total enthalpy change for the
reaction is the sum of all changes.

Hess’s law

____ constant tells how far the reaction has proceeded once the equilibrium is reached.

Equilibrium

What happens to the internal energy of the system if work is done on the system?

Internal energy will decrease

The equation that relates enthalpy, temperature and entropy is

Gibss free energy

The ___ is a unit of energy defined as the amount of heat needed to raise the temperature of 1 cm³ of
water by one degree Celsius.

A calorie

The standard enthalpy of formation for a simple substance in its most stable state must be non-zero

False

Which phase of matter has the greatest motion and least orderly arrangement?

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Gas

A reversible reaction has ΔG negative for forward reaction. What will be the sign for the backward
reaction?

Negative

Spontaneous processes are those that can proceed with any outside intervention.

False

The equilibrium constant for the reaction is 10. What will be the value of ΔG?

-5744 J

Determine the change in the standard entropy, ΔS⁰, for the synthesis of carbon dioxide from graphite
and oxygen:

C(s) + O2(g) → CO2(g)

Standard Entropy in J/mol.K for: C= 5.740 O2 = 205.14 CO2=213.74

2.86 J/mol.k

The standard free energy is found to be zero. What is its equilibrium constant?

A photochemical reaction is one of the examples of non-spontaneous reaction.

True

Which of the following is true regarding the concentration of products, for a chemical reaction that is
already at equilibrium, assuming no disruptions to the equilibrium?

The concentrations of products will not change because the forward and reverse rates are equal.

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Downloaded by GHIAN SHEAN MALAZARTE ([email protected])

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