Chemistry Chapter 10
Chemistry Chapter 10
Chemistry Chapter 10
Introduction:
Acids, bases and salts are three distinct classes in which almost all the organic and inorganic
compounds are classified. A famous Muslim Chemist Jabir Bin Hayan prepared nitric acid
(HNO3 ), hydrochloric acid (HCl) and sulphuric acid (H2SO4 ). In 1787, Lavoisier named binary
compounds of oxygen such as CO2 and SO2 as acids which on dissolution in water gave acidic
solutions. Later on in 1815, Sir Humphrey Davy discovered that there are certain acids which
are without oxygen, e.g., HCl. Davy proved the presence of hydrogen as the main constituent
of all acids. It was also discovered that all water soluble metallic oxides turn red litmus blue,
which is a characteristics of bases. The word acid is derived from the Latin word ‘Acidus’
meaning sour. The first acid known to man was acetic acid, i.e., in the form of vinegar.
We all have a little concentration of hydrochloric acid in our stomach, which helps to break
down the food. Sometimes, the amount of stomach acid becomes too much, which causes
‘acidity’. This uncomfortable feeling is easily treated by taking an alkaline medicine. The alkali
neutralizes the acid, producing a harmless chemical called a salt.
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Table 1.2 Acids and bases are recognized by their characteristic properties, such as:
Acids Bases
1. Acids have sour taste. For example, 1. Bases have bitter taste and feel slippery,
unripe citrus fruits or lemon juice. for example, soap is slippery to touch.
2. They turn blue litmus red. 2. They turn red litmus blue.
3. They are corrosive in concentrated 3. They are non-corrosive except concentrated
form. forms of NaOH and KOH.
4. Their aqueous solutions conduct 4. Their aqueous solutions conduct electric
electric current current.
For example, substances such as HC1, HNO3 , CH3 COOH, HCN, etc., are acids because they
ionize in aqueous solutions to provide H+ ions.
On the other hand, base is a substance which dissociates in aqueous solution to give hydroxide ions
The general ionization of bases take place as follows;
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The substances such as NaOH, KOH, NH4 OH, Ca(OH)2 etc. are bases because these compounds
ionize in aqueous solutions to provide OH ions
Examples of some important acids and bases are given in Table 10.1.
Table 10.2 Acids and Bases
Acids Bases
Hydrochloric acid, HCI Sodium hydroxide, NaOH
Nitric acid, HNO3 Potassium hydroxide, KOH
Sulphuric acid, H2SO4 Calcium hydroxide, Ca(OH)2
Phosphoric acid, H3PO4 Aluminium hydroxide, Al(OH)3
In 1923, the Danish chemist Bronsted and the English chemist Lowry independently
presented their theories of acids and bases on the basis of proton-transfer. According to
this concept:
An acid is a substance (molecule or ion) that can donate a proton (H+) to another substance.
A base is a substance that can accept a proton (H+)from another substance.
For example, HCl acts as an acid while NH3 acts as a base:
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According to Bronsted-Lowry concept, an acid and a base always work together to transfer
a proton. That means, a substance can act as an acid (proton donor) only when another
substance simultaneously behaves as a base (proton acceptor). Hence, a substance can
act as an acid as well as a base, depending upon the nature of the other substance. For
example, H2O acts as a base when it reacts with HCl as stated above and as an acid when
it reacts with ammonia such as:
Such a substance that can behave as an acid, as well as, a base is called amphoteric.
It has been observed that there are certain substances which behave as acids
though they do not have the ability to donate a proton, e.g.,SO3 . Similarly, CaO behaves
as a base but it cannot accept a proton. These observations prove the limitations of
Bronsted-Lowry concept of acids and bases.
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(c) Which of the following behave both as Bronsted acids and Bronsted bases?
Solution
(a) Conjugate base (b) Conjugate acid
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+
The cations (proton itself or metal ions) act as Lewis acids. For example, a reaction between H
+
and NH3 , where H acts as an acid and ammonia as a base.
The product of any Lewis acid-base reaction is a single specie, called an adduct. So, a neutralization
reaction according to Lewis concept is donation and acceptance of an electron pair to form a
coordinate covalent bond in an adduct.
Acids are electron pair acceptors while bases are electron pair donors. Thus, it is evident
that any substance which has an unshared pair of electrons can act as a Lewis base while a
substance which has an empty orbital that can accommodate a pair of electrons acts as Lewis
acid. Examples of Lewis acids and bases are given below:
Lewis acids. According to Lewis concept, the following species can act as Lewis acids:
(i) Molecules in which the central atom has incomplete octet. For example, in BF3 , AICI3 ,
FeCl3 , the central atoms have only six electrons around them, therefore, these can accept an
electron pair.
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(ii) Simple cations can act as Lewis acids. All cations act as Lewis acids since they are
deficient in electrons. However, cations such as Na+, K+, Ca2+ ions, etc., have a very little
tendency to accept electrons. While the cations like H+, Ag+ ions, etc., have a greater
electron accepting tendency therefore, act as Lewis acids.
Lewis bases. According to Lewis concept, the following species can act as Lewis bases:
(i) Neutral species having at least one lone pair of electrons. For example, ammonia,
amines, alcohols etc. act as Lewis bases because they contain a lone pair of electrons:
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Chemical Properties
(i) Reaction with Metals
Acids react explosively with metals like sodium,
potassium and calcium. However, dilute acids (HCl, H2SO4)
react moderately with reactive metals like: Mg, Zn, Fe and Al
to form their respective salts with the evolution of hydrogen
gas.
(aq)
3
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Uses of Acids
1. Sulphuric acid is used to manufacture fertilizers, ammonium sulphate, calcium
superphosphate, explosives, paints, dyes, drugs. It is also used as an electrolyte in lead
storage batteries.
2. Nitric acid is used in manufacturing of fertilizer (ammonium nitrate), explosives, paints,
drugs and etching designs on copper plates.
3. Hydrochloric acid is used for cleaning metals, tanning and in printing industries.
4 Benzoic acid is used for food preservation.
5 Acetic acid is used for flavouring food and food preservation. It is also used to cure
the sting of wasps.
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Uses of Bases
1. Sodium hydroxide is used for manufacturing of soap.
2. Calcium hydroxide is used for manufacturing of bleaching powder, softening of hard water
and neutralizing acidic soil and lakes due to acid rain.
3. Potassium hydroxide is used in alkaline batteries.
4. Magnesium hydroxide is used as a base to neutralize acidity in the stomach. It is also used
for the treatment of bee’s stings.
5. Aluminium hydroxide is used as foaming agent in fire extinguishers.
6. Ammonium hydroxide is used to remove grease stains from clothes.
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1. When acids react with carbonates and bicarbonates, which gas evolves ?
2. Which types of salts produce SO2 gas on reacting with acids?
3. Give the uses of sulphuric acid.
4. Name the gas liberated when alkalies react with ammonium salts.
5. Write down the colours of the precipitates formed by reaction of aqueous
caustic soda with solutions of: copper, zinc and ferric salts.
6. Name an alkali used in alkaline batteries.
Stomach acidity
Stomach secretes chemicals in a regular way to digest food. These
chemicals mainly consist of hydrochloric acid along with other salts. Although,
hydrochloric acid is highly corrosive, but stomach is protected from its effects
because it is lined with cells that produce a base. The base neutralizes stomach
acid. The important function of this acid is to break down chemical bonds of
foods in the digestion process. Thus, big molecules of food are converted into
small ones. It also kills the harmful bacteria of certain foods and drinks.
However, sometimes stomach produces too much acid. It causes stomach
acidity also called hyperacidity. Symptoms of this disease are feeling burning
sensation throughout the gastro intestinal track. These feelings sometimes
extend towards the chest, that is called heart burning.
The best prevention from hyperacidity is:
i) Avoiding over-eating and staying away from fatty acids and spicy foods.
ii) Simple and regular eating, remaining in an upright position for about 45
minutes after taking a meal.
iii) Keeping the head elevated while sleeping.
Process of Etching in Art and Industry:
The process of etching on glass is carried out by using a wax stencil. Stencil is placed
on areas of glass or mirror that are to be saved from acid. The glass or mirror is
dipped into hydrofluoric acid. The acid dissolves the exposed part of the glass thus
etching it. This process has been very dangerous because the acid would damage the
skin and tissue of artist’s body. Although, it is dangerous to deal with acid, yet etching
done with acid is very attractive as compared to using other chemicals.
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10.2 pH SCALE
+
Concentration of hydrogen ion [H ] in pure water is the basis for the pH scale. Water
is a weak electrolyte because it ionizes very slightly into ions in a process called auto-
ionization or self-ionization;
A new equilibrium constant known as ionic product constant of water ‘Kw’ is used instead of
product of equilibrium constant and [H2O]. Therefore,
As we know, one molecule of water produces one H+ ion and one OH ion on dissociation so
As it is difficult to deal with such small figures having negative exponents, so it is convenient
to convert these figures into a positive figure using a numerical system. It is taking the
common (base-10) logarithm of the figure and multiplying it with -1. ‘p’ before a symbol
means’ negative logarithm of the symbol. So ‘p’ before H means negative logarithm of [H+].
Therefore, pH is the negative logarithm of molar concentration of the hydrogen ions. That
is,
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With reference to this equation, a scale develops according to the molar concentration of
H+ ions that is called pH scale. It ranges from 0 to 14. According to this scale, pH of water is
calculated as:
Similarly
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Uses of pH
(i) It is used to determine acidic or basic nature of a solution.
(ii) It is used to produce medicines, culture at a microbiological particular
concentration of H+ ion.
(iii) It is used to prepare solutions of required concentrations necessary for
certain biological reactions.
10.2.1 Indicators
Indicators are the organic compounds. They have different colours in acidic and alkaline
solutions. Litmus is a common indicator. It is red in acidic solutions and blue in alkaline
solutions.
Each indicator has a specific colour in acidic medium which changes at a specific pH to
another colour in basic medium. For example, phenolphthalein is colourless in strongly
acidic solution and red in strongly alkaline solution. It changes colour at a pH of about
9. This means phenolphthalein is colourless in a solution with pH less than 9. If the pH is
above 9, phenolphthalein is red as is shown in figure 10.2 .
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figure 10.2.
Measuring pH of a Solution
(i) Universal Indicator
Some indicators are used as mixtures. The mixture indicator gives different colours at different
pH values. Hence, it is used to measure the pH of a solution. Such a mixed indicator is called
Universal Indicator or simply pH indicator. The pH of solution can be measured by dipping a
piece of Universal Indicator paper in the solution. The pH is then found by comparing the colour
obtained with a colour chart as shown in figure 10.3.
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Problem 10.2
A solution of hydrochloric acid is 0.01M. What is its pH value?
Solution: Hydrochloric acid is a strong acid so it ionizes completely.
That is:
So, its solution also contains 0.01M H ions, i.e., 10 2M.
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Problem 10.3
Find out the pH and pOH of 0.001M solution of KOH?
Solution: Potassium hydroxide solution is a strong base. It ionizes completely such that one
mole of KOH gives one mole of OH ions.
Problem 10.4
Find the pH of 0.01M sulphuric acid?
Solution: Sulphuric acid is a strong dibasic acid. It ionizes completely and its one mole
produces 2 moles of hydrogen ions as presented in equation.
Therefore, 0.01M sulphuric acid will produce 2 x 0.01M hydrogen ions. Hence, hydrogen
ions concentration is
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They have a wide area for working ranging from basic research in laboratories
to analytical research in industries. They work in almost all industries including
manufacturing, pharmaceuticals, healthcare, forensics and public protection -
where they test air, water, industrial waste, drugs and food to make sure they
are safe. They ensure the quality of the products in industry.
10.3 SALTS
Salts are ionic compounds generally formed by the neutralization of an acid with a base.
Salts are made up of positive ions (cations) and negative ions (anions). A cation is metallic ion
derived from a base, therefore, it is called basic radical. While anion is derived from an acid,
therefore, it is called acid radical.
A salt gets its name from the names of the metal and the acid as shown in Table 10.4.
10.3.1 Preparation
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Calcium chloride It is used for de-icing roads in winter, as a drying agent of chemical
(CaCI2) reagents and as freezing agent.
Calcium oxide It is used as drying agent for gases and alcohol and in steel making, water
(CaO) Quick lime treatment and other chemicals like slaked lime, bleaching powder, calcium
carbide. For purification of sugar, a mixture of CaO and NaOH called soda
lime is used to remove carbon dioxide and water vapours from air.
Calcium sulphate Gypsum is used as fertilizer, to prepare plaster of Paris which is used for
(CaSO4. 2H2O) making statues, casts, etc.
Potassium
It is used as fertilizer and for the manufacture of flint glass.
Nitrate (KNO3)
Neutralization Reaction
A reaction between an acid and a base is called a neutralization reaction. It produces a
salt and water. A few balanced chemical reactions are given here:
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Acid Rain
Acid rain is formed by dissolving acidic air pollutants like
oxides of sulphur and nitrogen by rain water. As a result pH of
the rain water decreases, i.e., it becomes acidic. When this acid
rain falls down, it damages animals, plants, buildings, water
bodies and even soil.
Key Points
• Strong acids or bases ionize completely in water while weak acids and bases ionize partially.
• According to Arrhenius concept, acids produce H+ ions in aqueous solution while bases
produce OH- ions in aqueous solution.
• According to Bronsted-Lowry concept, acid are proton donor and bases are proton acceptor,
so this concept is applicable to non-aqueous solutions.
• A substance that can behave as an acid as well as base depending upon the nature of other
substances is called amphoteric.
• According to Lewis concept; acids are electron pair acceptors and bases are electron pair
donors.
• The product of any Lewis acid base reaction is a single specie called adduct.
• “p” scale is the conversion of very small figures into positive figures by taking the common
logarithm of the small figure and multiplying it with-1.
• pH scale is the negative logarithm of concentration of hydrogen ions.
• A substance having pH less than 7 is acidic while a substance having pH more than 7 is
basic. A substance of pH 7 is called neutral.
• Salts are ionic compounds made up of metallic cation and non-metallic anion.
• Different methods for the preparation of soluble and insoluble salts have been discussed.
• Normal salts are made up of cations of strong bases and anions of strong acids.
• Acidic salts are made up of cations of weak bases and anions of strong acids.
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Short Questions
1. Name three common household substances having
a. pH value greater than 7
b. pH value less than 7
c. pH value equal to 7
2. Define a base and explain that all alkalies are bases, but all bases are not alkalies.
3. Define Bronsted-Lowry base and explain with an example that water is a Bronsted-Lowry
base.
4. How can you justify that Bronsted-Lowry concept of acid and base is applicable to non-
aqueous solutions?
5. Which kind of bond is formed between Lewis acid and a base?
6. Why H+ ion acts as a Lewis acid?
7. Name two acids used in the manufacture of fertilizers.
8. Define pH. What is the pH of pure water?
9. How many times a solution of pH 1 will be stronger than that of a solution having pH 2?
10. Define the followings:
i. Normal salt ii. Basic salt
11. Na2SO4 is a neutral salt while NaHSO4 an acid salt. Justify.
12. Give a few characteristic properties of salts.
13. How are the soluble salts recovered from water?
14. How are the insoluble salts prepared?
15. Why is a salt is neutral, explain with an example?
16. Name an acid used in the preservation of food.
17. Name the acids present in:
i. Vinegar ii. Ant sting
iii. Citrus fruit iv. Sour milk
18. How can you justify that Pb(OH)NO3 is a basic salt?
19. You are in a need of an acidic salt. How can you prepare it?
20. Which salt is used to prepare plaster of Paris?
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Extensive Questions:
1. Define an acid and a base according to Bronsted-Lowry concept and justify with
examples that water is an amphoteric compound.
2. Explain the Lewis concept of acids and bases.
3. What is auto-ionization of water? How is it used to establish the pH of water?
4. Define a salt and give the characteristic properties of salts.
5. Explain with examples how are soluble salts prepared?
6. Give the characteristics of an acidic salt.
7. Give four uses of calcium oxide.
8. You are having a strong acid (HNO3) and strong base (NaOH) on mixing
i. What type of salt you will have?
ii. What type of reaction will it be?
iii. Will it be soluble or insoluble salt?
iv. If it is soluble, how will it be recovered?
9. Explain why:
i. HC1 forms only one series of salts.
ii. H2SO4 forms two series of salts.
iii. H3PO4 form three series of salts.
Give necessary equations.
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Numericals
1. Calculate the pH and pOH of 0.2 M H2SO4?
2. Calculate the pH of 0.1 M KOH?
3. Calculate the pOH of 0.004 M HNO3?
4. Complete the following Table.
Solution [H+] [OH] [pH] [pOH]
(i) 0.15 M HI
(ii) 0.040 M KOH
(iii) 0.020 M Ba(OH)2
(iv) 0.00030 M HClO4
(v) 0.55 M NaOH
(iv) 0.055 M HCl
(vii) 0.055 M Ca(OH)2
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