Chemistry 2022 AKTU

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Subject Code: KAS102

0Roll No: 0 0 0 0 0 0 0 0 0 0 0 0 0
BTECH
(SEM I) THEORY EXAMINATION 2021-22
CHEMISTRY
Time: 3 Hours Total Marks: 100

Note: 1. Attempt all Sections. If require any missing data; then choose suitably.
SECTION A
1. Attempt all questions in brief. 2 x 10 = 20
Qno. Question Marks CO
2+ 2-
a. Which species out of H2, H2 and H2 are paramagnetic and why? 2 1
Why Lithium exists as diatomic while beryllium remains as
b. 2 1
monoatomic?
How will you distinguish between benzene and anthracene by UV
c. 2 2
spectroscopy?
How many vibrational modes are there in a linear and non-linear
d. 2 2
molecule having n number of atoms?
e. Why Iron Nail present on the door undergoes corrosion? 2 3
f. What is salt bridge? Mention its function in an electrochemical cell. 2 3
.in
What is the difference between Gross calorific value and Net calorific
g. 2 4
value of a fuel?
Temporary hardness is removed by boiling. Write chemical reactions in
ld
h. 2 4
support of your answer.
or
i. What is Bio-degradable polymers? Discuss their importance. 2 5
Define functionality. What is the minimum functionality required for a
j. 2 5
w
compound to act as monomer?

SECTION B
er
2. Attempt any three of the following:

pp
Draw the Molecular Orbital diagram of NO. Calculate the bond order
a. 10 1
and predict the magnetic behaviors of NO, NO+, NO- .
To
Illustrate Finger print region in IR spectroscopy. Two Isomers I and II

of the molecular formula C3H6O give I.R. absorption band near 3550
b. 10 2
cm-1 and 1717 cm-1 respectively. Assign structural formula to A and B
consistent with their IR absorption bands.
Define Phase, Component and Degree of freedom with examples. Also
outline the salient features of the phase diagram of water system
c. 10 3
highlighting the name of system (areas, curves and points), phase in
equilibrium and degree of freedom in each case.
What are Resins? How hard water can be purified by Ion exchange
d. 10 4
resins? Compare its merits and demerits over lime –soda process.
Give preparation, properties and applications of following polymer:
e. 10 5
(i) Buna-S (ii) Dacron (iii) Nylon 6 (iv) Neoprene
SECTION C
3. Attempt any one part of the following:
What are the Anisotropic crystals? How they are classified on the basis
a. 10 1
of temperature? Also mention their important applications.
Discuss preparation, properties, structure and applications of an allotrope
b. 10 1
of carbon having truncated icosahedron geometry.
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Subject Code: KAS102
0Roll No: 0 0 0 0 0 0 0 0 0 0 0 0 0
BTECH
(SEM I) THEORY EXAMINATION 2021-22
CHEMISTRY

Discuss the quantum theory of Raman Spectroscopy. What technological
advances have enabled the routine use of Raman Spectroscopy? How the
a. 10 2
Stokes, anti-Stokes and Rayleigh lines appear in the Raman
Spectroscopy?
Discuss electronic transitions involved in UV- visible spectroscopy.
Illustrate, the effect of polar solvent on n - π* transition in acetone. Also
b. 10 2
describe Absorption and Intensity shift in the UV spectroscopy with the
help of examples.

What is battery? Differentiate between primary and secondary batteries.
a. Explain the construction and working of secondary battery by taking an 10 3
.in
account of Lead Storage battery.
Outline the mechanism involved in Electrochemical theory of corrosion.
b. 10 3
How corrosion is prevented by anodic and cathodic inhibitors?
ld
or
With the help of neat sketch, explain continuous cold Lime soda process
w
for softening of hard water. Also write the chemical reactions involved.
Calculate the quantity of lime (74% pure) and soda (90%pure) for
er
a. 10 4
softening 50,000 liters of water containing the following salts:
Mg(HCO3)2 =50mg/L, MgCl2 =6ppm,Ca(HCO3)2 =81 mg/L,CO2 =44
pp
ppm, Na2SO4 =10oFr, HCl=73mg/L, Al2(SO4)3 =57 mg/L.

With the help of a neat diagram, explain the construction and working of
To
bomb calorimeter.
A sample of coal contain C=80%, H=15% and ash=5%. The following
data were obtained when the above coal was tested in bomb calorimeter:
Weight of coal burnt=0.98 g
Weight of water taken=1000 g
b. 10 4
Water equivalent of bomb and calorimeter= 2500 g
Rise in temperature=2.5˚C
Fuse wire correction =8.0 cal
Acid correction= 50.0 cal
Cooling correction=0.02 ˚C
Calculate gross and net calorific values of the coal.

Write short notes on:
a. 10 5
(i) Polymer Blends (ii) Preparation and applications of Grignard reagent
What are conducting polymers? Classify conducting polymers and
b. 10 5
mention their important applications.
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Printed Page: 1 of 2

Subject Code: KAS102

Time: 3 Hours Total Marks: 100

compound to act as monomer?

2. Attempt any three of the following:

Illustrate Finger print region in IR spectroscopy. Two Isomers I and II

4. Attempt any one part of the following:

5. Attempt any one part of the following:

ppm, Na2SO4 =10oFr, HCl=73mg/L, Al2(SO4)3 =57 mg/L.

7. Attempt any one part of the following:

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