1. A series of tests were performed on a simple salt to determine its composition. Flame and chloride tests indicated the presence of strontium.
2. Further analysis found the salt contained chloride as the acid radical based on silver nitrate and chromyl chloride tests.
3. The salt was identified as strontium chloride based on formation of a white precipitate with ammonium sulfate, confirming the basic strontium radical.
1. A series of tests were performed on a simple salt to determine its composition. Flame and chloride tests indicated the presence of strontium.
2. Further analysis found the salt contained chloride as the acid radical based on silver nitrate and chromyl chloride tests.
3. The salt was identified as strontium chloride based on formation of a white precipitate with ammonium sulfate, confirming the basic strontium radical.
1. A series of tests were performed on a simple salt to determine its composition. Flame and chloride tests indicated the presence of strontium.
2. Further analysis found the salt contained chloride as the acid radical based on silver nitrate and chromyl chloride tests.
3. The salt was identified as strontium chloride based on formation of a white precipitate with ammonium sulfate, confirming the basic strontium radical.
1. A series of tests were performed on a simple salt to determine its composition. Flame and chloride tests indicated the presence of strontium.
2. Further analysis found the salt contained chloride as the acid radical based on silver nitrate and chromyl chloride tests.
3. The salt was identified as strontium chloride based on formation of a white precipitate with ammonium sulfate, confirming the basic strontium radical.
1. Colour: Colour of Colourless Absence of copper, nickel the salt is noted and manganese salts. 2. Smell: Smell of the No characteristic smell Absence of ammonium or salt is noted acetate salt 3. Action of heat: No characteristic Absence of ammonium, A pinch of salt in observation. carbonate, zinc etc., the dry test tube is heated. 4. Flame test: A pinch of salt is Crimson red colour flame. Presence of strontium salt. taken in a watch glass and made into a paste with Conc. HCl. Introduce the paste into luminous part of the flame. 5. Ash test: To the pinch of salt No characteristic coloured Absence of Aluminium, taken in a test tube, ash. Zinc and Magnesium few drops of cobalt nitrate solution is added. A filter paper is soaked into the solution and burn it until it turns into ash. Dry tests: 1. Dil HCl test: To the No brisk effervescence is Absence of carbonate. pinch of salt taken seen. in a test tube, few drops of Dil. HCl is added. 2. Conc. H2SO4 test: Colourless gas which Presence of Chloride. To the pinch of salt gives dense white fumes taken in a test tube, with a glass rod dipped in few drops of Conc. ammonium hydroxide is H2SO4 is added and formed. heated slightly. 3. MnO2 test: To a Greenish yellow gas Presence of chloride. pinch of a salt in which turns starch iodide the test tube add paper blue is fomed. half a pinch of MnO2 and then add few drops of conc. H2SO4 and heat. 4. Chromyl chloride test: To the pinch of salt taken in a test tube, a pinch of potassium Yellow orange vapours. dichromate and few drops of Conc. Presence of chloride is H2SO4 is added and confirmed. then heated gently.
The vapours are
allowed to pass through a solution Yellow precipitate is containing NaOH, formed. dil. Acetic acid and lead acetate solution. 5. Copper turning No red brown fumes. Absence of nitrate. test: To the pinch of salt taken in a test tube, add copper turnings and Conc. H2SO4 and heated. 6. Ferric chloride test: No red precipitation. Absence of acetate. To the pinch of salt taken in a test tube, add few ml of neutral ferric chloride solution and heated. 7. Ester test: To a No characteristic Absence of acetate. pinch of salt add observation. few mL of ethyl alcohol and few drops of conc. H2SO4 and warm heat it gently. Preparation of original salt solution (OS): To a pinch of salt taken in a test tube add 20 mL of distilled water and shaken well.
Experiment Observation Inference
1. Silver nitrate test: Curdy white precipitate Presence of chloride is To a part of OS, which is soluble in excess confirmed. add few drops of of ammonium hydroxide silver nitrate solution is obtained. solution. 2. Barium chloride No characteristic Absence of sulphate. test: To a part of observation. OS add BaCl2 solution. 3. Lead acetate test: No characteristic Absence of sulphate. To a part of OS, observation. add lead acetate solution. 4. Brown ring test: To No characteristic Absence of nitrate. a part of OS, add observation. twice the part of freshly prepared ferrous sulphate solution and then add Conc. Sulphuric acid slowly along the inner sides of the test tube. 5. To the part of OS, No characteristic Absence of phosphate. add Conc. HNO3 in observation. excess and allow it to boil until all the vapours get evolved. Then cool the content slowly and add ammonium molybdate reagent. 6. To the part of OS, No characteristic Absence of phosphate. add dil. HCl and observation. heat and cool it. Then add magnesia mixture to the content. Basic radical Analysis - Group Analysis 1. Zero Group radical: No characteristic Absence of zero group To a pinch of salt observation. radical – Ammonium. taken in a test tube, few drops NaOH solution is added and heated. 2. To a part of OS, No White precipitate. Absence of I group radical add dil. HCl. – Lead. 3. To a part of OS, No black precipitate. Absence of II group add dil. HCl and radical – Copper. YAS solution. 4. To a part of OS, No gelatinous white Absence of III group add NH4Cl and precipitate. radical – Aluminium NH4OH solution. 5. To a part of OS, No characteristic Absence of IV group add NH4Cl, precipitate. radical. NH4OH and YAS solution. 6. To a part of OS, White precipitate is Presence of V group add NH4Cl, obtained. radicals. NH4OH and (NH4)2CO3 solutions.
Confirmatory test: For nickel radical:
Experiment Observation Inference To a part of OS add White precipitate is Presence of Strontium ammonium sulphate formed. radical is confirmed. solution.
Result: 1. The given acid radical is chloride. 2. The given basic radical is strontium. 3. So, the given simple salt is Strontium chloride.