Contents CLASS-XI

Theory &Questions Explanations

1. Some Basic Concepts of Chemistry Page No. Page No.
2. Structure of Atom 1
3. 19 13
Classification of Elements and Periodicity in Properties 35
4 25
Chemical Bonding and Molecular Structure
50 31
States of Matter /Rationalised Content|
6
71 45
Thermodynamics 90
7. 55
Equilibrium
108 65
8. Redox Reactions
133 81
9 Hydrogen /Rationalised Content) 148 90
10. The s-Block Elements /Rationalised Content|
162 95
11. The p-Block Elements /Rationalised Content)
178 101
12. Organic Chemistry- Some Basic Principles and Techniques 193 107
13. Hydrocarbons
219 123
14. Environmental Chemistry /Rationalised Content) 245 138

CLASS-XII
Theory & Questions Explanations
Page No. Page No.
1. The Solid State (Rationalised Content)
1 142
2. Solutions
23 152
3. Electrochemistry
43 165
4. ChemicalKinetics 62 175
5. Surface Chemistry (Rationalised Content] 82 188
6. General Principles and Processes of Isolation of Elements /Rationalised Content! 100 195
7 The p-Block Elements
(Group 15 to 18) /Rationalised Content) 115 201
8. The d-and f-Block Elements
134 210
9. Coordination Compounds 154 218
10, Haloalkanes and Haloarenes
176 231
11. Alcohols, Phenols and Ethers 197 242
12. Aldehydes, Ketones and Carboxylic Acids 220 254
13. Amines
245 266
14. Biomolecules 268 278
15. Polymers /Rationalised Content| 285 283
16. Chemistry in Everyday Life(Raionalised Contentl 301 287
NEET 2023 Solved Paper 1-10
 CHAPTER

Some Basic Concepts of Chemistry

1
Year Wise Number of Questions Analysis (2023-2014)

Number
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2023 2022 2021 2020 2020 2019 2018 2017 2016 1| 2016| 2015 2015 Re 2014
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Years

Topicwise Number of Questions Analysis (2023-2014)

6
14

13

12 -
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Number
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Topics
 NCERT-PICKS

In a homogeneous mixture, the components

General lntroduction
Chemistry plays a ccntral role in science and is often intertwined
with cach other. Sugar solution and air are the
homogencous mixtures. comexamplpletelyes miofy
with other branches of science. Principles of chemistry are In contrast tothis, in a heterogeneous themixture,
and sugar,comgraiponsist on
is not uniform throughout and sometimes different
applicable in diverse areas, such as weather patterns, functioning
of brain and operation of a computer, production in chemical
industrics ctc. Chemistry provides methods for the isolation
are visible. For example, mixtures of salt
pulses along with some dirt. Components
of lifesaving drugs from natural sources and makes possible In pure substances constituent particles have fixed
synthesis of such drugs. Some of these drugs are cisplatin and
pure substances. Pure substances can further be
composietisoR.of
Coppcr, silver, gold, water and glucose are some
exampl
taxol, which are effective in cancer therapy. The drug AZT
(Azidothymidine) is usedfor helping AIDS patients. To be a good classiconsist
elements and compounds. Particles of an element fied of
chemist and to acept new challanges, one neds to understand oronlymolecules.
one type of particles. These particles may exist as at
the basic concepts of chemistry, which begin with the concept
of matter. Sodium (Na), copper (Cu), silver (Ag), hydrogen
(H),Oxygen
(0), etc. are some examples of elements. Whereas, Hvdm
Matter & Its Classification (H,), nitrogen (N,) and oxygen (0) gases consist of moleu
in which two atoms combine to give their respective molecules
Anything which has mass and occupies space is called matter. When two or more atoms of different elements combine togethe
Everything around us, for example: book, pen, pencil, water, air, in a definite ratio, the molecule of a compound is obtaine
all living beings, etc., is composed of matter. Examples of some compounds are water (H,0), ammonia (NH)
States of Matter: Matter exist in three physical states viz. solid, carbon dioxide (CO,), sugar etc.
liquid and gas. Because of different arrangement of particles,
states of matter exhibit the following characteristics: Measurement of
1. Solids have definite volune and definite shape.
Properties of Matter
2. Liquids have definite volume but do not have definite shape.
They take the shape of the container in which they are The SI system has seven base units and they are listed in the
given Table.
placed.
3. Gases have neither definite volume nor definite shape. They Base Physical Symbol for Name of SI Synbol for
completely occupy the space in the container in which they Quantity Quantity Unit SI Unit
are placed. Length metre m

These three states of matter are interconvertible by changing the Mass m

kilogram kg
conditions of temperature and pressure. Time t second

Solid
heat heat
eliquid cool -Gas Electric current ampere A
cool

Usually a solid changes to a liquid, and the liquid on further

Thermodynarmic T kelvin K
temperature
heating changes to gas (or vapour). But when solid directly Amount of mole mol
changes to the vapour state, the process is called Sublimation. |substance
Classification of Matter: At the macroscopic level matter is Luminous candela
classified as, mixture and pure substances. These are further intensity
classified as,
Matter
The Sl system allows the use of prefixes to indicate the mulaiples
or submultiples of a unit. These prefixes are listed in follow"s
Table.

Mixtures Pure Substances Multiple Prefix Symbol

1015 femto f

Homogeneous
Mixtures Heterogeneous
Mixtures Elements Compounds
10-12 pico
10-9 nano

Classification of matter 106 IMicro

Scne Besic Cocegts of Chemistry

10 milli S. Counting the numbers of object, For example, 2 balls

or 20 eggs, have infinite significant figures. As these are
centi C
exact numbers and can be represented by writing infinite
deci number of zeros after placing a decimal i.c., 2=2.000000 or
10 da 20 - 20.000000
deca
hecto h
Laws of Chemical Combinations
10 kilo
mega M Law of Conservation of Mass: In all physical and chemical
changes, there is no nct change in mass during the process.
109 giga In other words it states that matter can neither be created nor
tera
Destroyed.
peta P Lawof Definite Proportions: Irrespectíiveof the source, a given
compound always contains same elements combined together in
The Si unit of mass is kilogram, However, its fraction named as
Smaller the same proportion by mass. This law is also known as Law of
gran (! kg = 1000 g), is used in laboratories due to the
amount of chemicais used in chemical reactions. definite Composition.
chemistry Law of Multiple Proportions: When two elements combine
In SI svstem, volume has units of m. But again, in masses of one of the
volumes are used. Hence, volume is often to form two or more compounds then the
laboratories, smaller mass of the other element,
units. A common unit, litre (L) which elements which combine with a fixed
denoted in cm² or dm are in the ratio of small whole numbers. For example, water and
volume of liquids.
not an SIunit, is used for measurement of obtained by the
IL=1000 mi. 1000 cm² ldm²
hydrogen peroxide are two compounds which are compounds
combination of hydrogen and oxygen but in both the
°C of oxygen is 16g
There are three common scales to measure
temperature mass ofhydrogen is fixed i.e. 2g whereas, mass ratio
(kelvin). Here, K bears a simple
(degree ceisius), °F (degree fahrenheit) and K related to each and 32g respectively. Means mass of oxygen
scales are
isthe SI unit. The temperatures on two ie. 1:2.
other by the following relationship: Volumes: Gay Lussac in 1808
Gay Lussac's Law of Gaseous
produced in a chemical
°F =9 5 (C)+32. observed that when gases combine or are
volume (at same T and P).
The kelvin scale is related to celsius
scale as follows: reaction they do so in simple ratio by
work of Avogadro in
K=°C + 273.15 This law was explained properly by the
1811.
proposed that equal
Uncertainty in Measurement Avogadro's Law: In 1811, Avogadro
temperature (T) and pressure
volumes of all gases at the same Avogadro made a
of molecules.
or (P)should contain equal numbermolecules.
The uncertainty in the experimental
Significant Figures: mentioning the number distinction between atoms
and
the calculated values is indicated by are meaningful digits
Significant figures
of significant figures. certainty plus one which is estimated or Atomic & Molecular Masses
which are known with
uncertain. very-very small because atoms are
figures: Atomic mass is actually on the
determining the number ofsignificant system atonmic mass is based
Rules for example 421 very small. In the present Carbon-12 is assigned amass
numbers are significant. For carbon-12isotope as the standard.
1. All non-zero significant figures. masses of other atoms
cm, there are three mass unit (amu) and
not significant. of exactly 12 atomic standard.
first non-zero digit are are given relative to
this
2. Zeros preceding to position of decimal point. For
unit is defined as a mass exactly equal
to one
Such zero indicates the figure and 0.0052 One atomic mass
one significant twelfth of mass of one
carbon-12 atom.
exampie in 0.04 has only
figures.
has only two significant significant. Thus, And Iamu = 1.66056 x
1024 g
two non-zero digits are = 1.6736 x 10g
3. Zeros between Mass of an atom ofhydrogen
5.005 has four significant figures. Thus. in terns of amu, the mass
are significant, provided
4. Zeros at the end or right ofa number example, 1.6736x10g
of the decimal point. For
they are on the right side figures. Terminal zeros are not of hydrogen
atom = 1.66056x10g

0.200 g has three significant point. For example, 400 1.0080 amu
decimal = 1.0078 amu =
significant if there is no but 400. has three significant -16(9O) atom would be
l5.995
significant figure, of oxygen
has onlyone Such numbers Similarly, the mass
four significant figures.
figures and 400.0 has scientific notation. We can express amu. known as
'u', which is
in
are better represented for one significant figure, 4.0x10 'amu' has been replaced by
4x10 present
the number 400 as and 4.00x 10° for three significant At
unified mass.
figures
for two significant
figures.
 0bjective NCERT
Punch
Average atomic mass: it is the sum of the products of fractional
abundances (f) of the isotopes and theit coTesponding mass Eg. Wt, of bases
Molar Mass
Acidity
-Chen'a
number (A ), ie.
Molar Mass
A= EfA,=A, xf +f*A, +. Eq. Wt. of Salts =.
Net Positive or Negative charge
Carbon has the following three isotopes with relative abundance
and massS as shown against each of them.
Isotope Relative Abundance Atomic Mass Empirical &Molecular Formuta)
(%) amn) An empirical formula represents the simplest
98.892 whole
1.108
12

13.00335
ratio of various atoms present in a
molecular formula shows the compound,
whe
exact number of reansu,mbeth:e
2x 1010 14.00317 of atoms present molecule of compound. dif erent
in a a The
From the above data, the average atomic mass molecular formula from empirical tormuBa is given as.Stepsto find
of carbon will Sten Conversion mass per cent to
i: of
COme out to be: grams
(0.98892) (12 u) +(001108) (13.00335 u) +(2 x 10-) (14.00317u) Step 2: Convert into number of moles of each element
=12.011 u Step 3: Divide each of the mole values obtained
MoBecutar Mass: It is the sumn of atomic masses of the smallest number amongst them by tbeabove
present ina molecule. It is obtained by multiplying theelements Step 4: Write down the empirical formula
atomic the numbers after writing the symbolsbyof
mass of each element by the number of its
them together. For example: atoms and by adding
elements
resne mentiorirg
Molecular mass of methane, Step 5: Writing molecular formula
(CH) =(12.011 u) + 4 (1.008 u) = 16.043 u In final step divide molar mass or
relañon between molecular mass and vapour formula mass as,
(moBecular mass) by emoint
density:
Molecula mass = 2 x vapour density Molecular Mass
Molecular mass = Mass of 22.4 Lof vapour of STP Empirical Fornula Mass
V.D= Density of a gas at certain temp. and pressure
Molecular formula =nx Empirical formula
Density of hydrogen at same temp. and pressure or Molecular formula -
(Empirical formula),
Mole Concept and Molar Mass
The mole., (symbol mol), is the SI
Stoichiometric Calculations
Limiting Reagent: The
One mole contains exactly 6.022 14076xof10amount of substance. product is called the limitingreactant
unit that limits the amount oi
This number is the fixed elementary entities. reactant or limiting reagent.
numerical value of the Avogadro Reactants not completely consumed are called excess
constant, N,, when expressed in the unit mol- and is called the lt can be reactant.
Avogadro number. explained by the following example.
In the preparation of
} lmole of atoms
:Gram atomic mass (or lg atom) ammonia:
:6.022 x 10 atoms. N,(g) + 3H,(g) ’ 2NH, (g)
} Imole of
molecules :Gram molecular mass (or lg When one mole of N, reacts with
of NH, are produced. What three moles ofH,, two moles
molecule) would
reacted with three moles of H. ? Would happen if two moles of N,
:6.022 x 10 molecules NH, be formed? Answer is more than two moles of
:22.4 Lat STP given below.
1mole of ionic compound: Gram Before the reaction takes place,
formula mass nitrogen and hydrogen a
present in a l:3 molar ratio. The reaction
6.022 x 102% formula units the balanced equation. One takes place according
Molar mass of H,0= 18.02 g/mol H, to produce two moles of
mole of N. reacts with three
moles o
has been used up, and NH.. At this point, all the hydroge
Important Formulas the reaction stops. One mole of unreacted
nitrogen is left in addition of the
Number of moles = Given Mass twO moles of NH, that häv
been produced by the
Atomic or Molar mass In this reaction, only reaction.
Eq. Wt. of an the hydrogen that
is completely used up. It is
ion/radical =Formula Weight the limiting
total charge of product thatreagent, or the
reagent
can be forned by a determines the amoUn!
occurs
Eq. Wt, of acids Molar Mass only until the limiting reaction. TheByreaçtion
reagent is used contrast, the
reactant that up.
Basicity is
not
completely used up excess
some nitrogen will remain reagent because
unreacted.
Some Basic Concepts of Chemistry

Sometimes in stoichiometric problems, the given quantities of moles of solute

reactants are expressed in units other than moles. In such cases, Molality (m) =
the first step in the solution is to convert cach reactant to nmoles. weight of solvent (in kg)
Then the limiting reagent can be identified. The amount of 4. Molarity (Molar concentration): It is defined as the
product formed in a reaction can be determined from the given number of moles of the solute per liter or per dm² of the
amount of limiting reagent. solution. The unit of molarity is mol liter or mol dm.
Methods of Expressing the Concentration of moles of solute
a Solution Molarity (M) =
volume of solution(L)
The concentration of a solution can be expressed in a number of
ways. The important methods are: Representation Molarity Common name

1. Mass percentage or percent by mass: It is defined as IM 1 Molar solution

the amount of solute in grams present in 100 grams of the 0.5 M or M2 1/2
solution, Semimolar solution

mass of solute 0.1 Mor M10 1/10 Decimolar solution

-x100
mass of solute + mass of solvent 0.01M or M/100 1/100 Centimolar solution
2. Mole fraction: This method is used when the solution is
0.001 Mor M/1000 1/1000 Millimolar solution
constituted by mixing two or more components.
Mole Fraction = The ratio of number of moles of one Molarity is dependent on volume and temperature. It decreases
component to the total number of moles of the solution (i.e with increase of temperature, due to increase in temperature the
all the components)
water expands that is why the volume increases hence molarity
Ifa substance 'A' dissolves in substance B and their number decreases.
of moles are n, and n, respectively then the mole fraction of
A(x) and B(x) given as 5. Normality: It is defined as the number of gram equivalents
of solute present per litre of solution. It is denoted by 'N.
XA
nA +ng Or Normality x Volume of solution in litres
= Number of gram equivalents of the solute.
In a binary solution, Relationship between normality and molarity:
Mole fraction of solute + Mole fraction of solvent = 1
Normality = n-factor (acidity or basicity) x Molarity
Mole fraction is independent of temperature. Molality of asolution does not change with temperature
3. Molality: It is defined as number of moles of the solute as it involves masses of the solute and
dissolved in 1 kg of the solvent. It is denoted by 'm'. Its unit
solvent. Normality
and molarity change with temperature because they involve
is mol kg. It is also called molal.
volumes which change with temperature.
 MCQs
NGERT Topic-wise MCQs
9. Which of the following data illustrates the
Uncertainty in Measurement conservation of mass? aw
1. The number of significant figures in value S.041 is I) 56g ofCreacts with 32 g of fOxygen to produce
2) 2 Co, AAgoi
3) 3 4) 4 2) 1.70 g of AgNO, reacts with 100 mL of 0.IM
2. Express the result of (0.582 + 324.65) to the appropriate produce 1.435 g of AgCl and 0.63 gof HNO, HCI
number of significant fgures: 3) 12 gof Cis hcated in vacuum and on cooling,
no change in mass here is
I) 325.24 2) 325.23
3) 325.2 4) 325.232 4) 36g of Sreacts with l6g of 0, to produce 48 gof s%
3. Two students X and Y report the mass of the same substance 10, Two elements X and Y combine in gaseous state to f
XY in the ratio 1:35.5 by mass. The mass of Ythat will L
as 7.0 g and 7.00g respectively, which of the following required to react with 2 g of X is:
statemernt is correct?
) Both are equally accurate 1) 7.1g 2) 3.55 g
3) 71 g 4) 35.5 g
2) X is more accurate thanY
3) Y is more accurate than X 11. 4.4g of an oxide of nitrogen gives 2.24 L of nitrogenand
60 g of another oxide of nitrogen gives 22.4 Lof nitrogen
4) Both are inaccurate scientifically at S.T.P. The data illustrates:
4. The number of significant figures in value of r are: 1) Law of conservation of mass
1) 1 2) 2 2) Law of constant proportions
3) 3 4) 0 3) Law of multiple proportions
5. The corectly reported answer of the addition of 29,4406, 4) Law of reciprocal proportions
3.2 and 2.25 will have significant figures:
12. If law of conservation of mass was to hold true, then 20.8g
1) 3 2) 4
of BaCl,on reaction with 9.8gofH,SO, willproduce 73g
3) 2 4) 5 of HCl and BaSO, equal to:
6. The correctly reported answer of the area of rectangle I) 11.65 g 2) 23.3 g
which is 12.34 cm long and 1.23 cm wide is: 3) 25.5 g 4) 30.6g
1) 15.2 m² 2) 15.2 m 13. The law of conservation of mass holds good for all of the
3) 15.1 cm² 4) 15.17 cm² following except.
7. If an object has a mass of 0.2876 g, then find the mass of 1)) Allchemical reactions
nine such objects: 2) Nuclear reaction
1) 2.5884g 2) 2.5886g 3) Endothermic reactions
3) 2.588 g 4) 2.5 g 4) Exothermic reactions
14. Hydrogen and oxygen combine to form H,0, and H0
the
Laws of Chemical Combinations containing 5.93% and 11.2% hydrogen respectively,
data illustrates:
8. x LofN, at S.T.P. contains 3 x 10 molecules. The number 1) Law of conservation of mass
of molecules in x/2 Lof ozone at S.T.P. will be:
2) Law of Constant proportions
1) 3 x 102 2) 1.5 x 102
3) Law of reciprocal proportions
3) 1.5 x 1024 4) 1.5 x 10!"
4) Law of multiple proportions
 elaale teueu Chesistry

i8, TWo olenents X(of mass l6) and Y (ol ass 14) combine 24, Whieh among the given gascs contain the equal number of
te totn compounds A, B nnd (C. Theatio of different Inolecules Hs that of 16 grams of oxygen?
massos otY which vombine with a fixed mass of Xin A, B I) l6gm of S0,
Aud 'is l:3ES,TN2 parts by näss of Xcombines with 2) 32 grans of S0,
N4 prits (y mass of \Y in B, then in C, l6parts by maSS o 3) 12 gm of0, 4) All
\ willconbine with, 25. One atom of an clement weighs 1.8 × 102 g, its atomic
I) 4 pats by mass ofY 2) 42 parts by nmass ofY hass is
) 70 parts by mmass ofY 4) R4 parts by mass ofY I) 29.9u 2) 18u
3) J08.36 u 4) 154 u
Atomic and Moleeular Masses 2. If H,sO, ioniscs as H,SO, + 2H,0 -’ 2H,0*+ S0}. Then
total number of ions produccd by 0.1 mol H,SO, will be:
io Bonmn has two isotopcs B" and B" whose tolative
) 9.03 x 1021 2) 3.01 x 1022
albundaices are 20% nd 80"% respectively. Atomie woight
of Borm iN 3) 6.02 x 1022 4) 1.8 x 1023
) 0 2) 1| 27, Which of the following will not have a mass of 10 g?
1) 10,$ 4) 10,8 I) 0.l mol CaCO,
17. Insuin contains 34% sulphur by mass. What will be 2) I.51 x 10" Ca² ions
the
minimum nolecular weight of insulin? 3) 0.16 mnol of CO ions
) 94.117u 2) 1884 l 4) 7.525 x 1022 Br atom
) 94| u 4) 976 u 28. g of oxygen contain number of atoms equal to that
2
I8. The holccular nass of glucose (CH,,0) contained by:
1) l60.N u 2) 180.162 u I) 2g of calcium 2) 4 g sulphur
3) 2164 u 4) 134.821 u 3) 9g nitrogen 4) 4 g sodium.
29. A person adds 1.71 gram of sugar
Mole Concept and Molar Masses (C,,H,0,,) in order to
sweeten his tea. The number of carbon atoms added are:
(mol mass of sugar=342).
19. Igatom of nitrogen
represents: I) 3.6 x 1022 2) 7.2 x 1021
) 6.02 10 N, molecules 3) 0.05 4) 6.6 x 1022
2) 22.4 Lof N, at S.T.P 30. The number of atoms present in
3) 0.2L of N, at S.T.P (at. mass =31) are:
0.1 mole of P, 4

4) 28 g of nitrogen I) 2.4 x 1024 atoms

20. Which iscorrect for 10 gof 2)
CaCO?
I) It contains I g atom of carbon
Same as in 0.05 mol of S
3) 6.02x 102 atoms
2) It contains 0.3 g atoms of
Oxygen 4) Same as in 3.1g of
phosphorus
3) It contains 12 g of calcium
3I. Which one contains
4) Itrefcrs to 0.1 g equivalent of maximum number of molecules?
CaCO, 1) 2.5 g molecule ofN,
21. The number of
oxygen atoms present in 14.6 g of 2) 4g atom of nitrogen
magncsium bicarbonate is:
I) 6N, 3) 3.01 x 1024 atoms of
2) 0.6 N, nitrogen
4) 82 g of dinitrogen
3) N 4) Na 32. Out of 1.0 g
22, Which of the
2 dioxygen, 1.0 g (atomic) oxygen and
1.0 g ozone, the maximunm
following has the highest mass? containcd in: number of oxygen atoms are
I) 20 g of sulphur
2) 4 mol of carbon 1) 1.0g of atomic
dioxide oxygen
3) 12 x10 atoms of 2) 1.0 g of ozone
4) |1.2 Lof helium athydrogen
N.TP. 3) 1.0 g of oxygen gas
2.3. If wc assume I/24 th 4) All contain same
number of atoms
part
th part of it as I amu., of mass of carbon instead of 1/12
mass of I mole of a 33. What is the total
I) Remain unchanged substance wilI number of atoms present in 25.0 mg of
2) get doubled camphor, C
C,H,0?
3) Gct halved 4) can't be predicted
1) 9.89 x 1019
2) 6.02 x 1020
3) 9.89 x 1020
4) 2.67 x 102!
S E Rasie oncepts of Chemistry

*. Two ciements X (of mass l6) and Y {of mass I4) combine 24. Which among the given gases contain the tquai nutnber of
to fom compounds A, B and C. The ratio of different molecules as that of l6 grams of oxygen?
masses ofY which combinc with a fixcd mass of Xin A, B } l6gm of SO. 2) 32 gams of S0.
and C is :3:5. if 32 parts by mass of Xcombines with
84 parts by mass of Y in B, then in C, 16parts by mass of 3) 12 gm of O, 4) A!

X will combine with: 25. One atom of an clement weighs 1.8 x 10*g. its atomic
mass is:
) 14 parts by mass of Y 2) 42 parts by mass of Y
3) 70 parts by mass of Y 4) 84 parts by mass of Y ) 29.9 u 2) 18 u
3) I08.36 u 4) 154 u

Atomic and Molecular Masses 26. If HSO, ionises as HSO, + 2H,0 -2H0*+ SO, .Then
totai nunmber of ions produced by 0.i mol H,SO, will be:
16. Boron has two isotopes B° and B' whose relative ) 9.03 x 10! 2) 3.01 x 10
abundances are 20% and 80% respectiveiy. Atomic weight 3) 6.02x 10 4) 1.8 x 10
of Boron is
1) 10 2) 11 27. Which of the following will not have a mass of i0g?
3) 10.5 4) 10.8 ) 0.! mol CaC0,
17,. Insulin contains 3.4% suiphur by mass. What wili be the 2) I.51 x 10Ca ions
minimum molecular weight of insulin? 3) 0.16 moi of CO; ions
1) 94.117u 2) I884 u 4) 7525 x 10 Br aiom
3) 941 u 4) 976 u 28. 2 g of oxygen contain number of atoms cqual to that
18. The molecular mass of glucose (C H,,0,) containod by:
) 160,8 u 2) 180.162 u
I) 2 gof calcium 2) 4g sulphur
3) 216.4 u 4) 134.821 u 3) 9g nitrogen 4) 4g sodium.
29. Aperson adts I.71 gran of sugar (C,,H,0,,)in order to
swocten hts tea. The number of carbon atonns added are:
Mole Concept and Molar Masses (moi mass of sugar 342).
) 3.6 10 2) 7.2 × 10
19, lg-atom of nitrogen represents:
I) 6.02 x 10 N, molecuies 3} 0.05 4) 6.6 10
2) 22.4 LofN, at S.TP 30. The number of atoms present in 0.1 moie of P,
3) 1.2 L of N, at S,T.P {at. mass 31) are:
4) 28 g of nitrogen ) 24 x / stoTIS
20. Which is correct for 10 g of CaCO,? 2) Same as in 0.05 mol of S,
1) Itcontains l g atom of carbon 3) 6.02 * 10atons
2) It contains 0.3 g atoms of oxygen 4) Same as in 3.lg of phosphorus
3) Itcontains 12 g of calciumn 31. Which one contains maximun number of moBecules?
4) Itrefers to 0.l gequivalent of CacO, 1) 2.5 gmolecule of N,
21. The number of oxygen atoms present in 14.6 g of 2) 4g atom of nitrogen
magnesium bicarbonate is: 3) 3.01 x 10 atoms of nitrogen
) 6N, ) 0.6 N 4) 82 g of dinitrogen
3) N, 4) N 32. Out of 1.0 g dioxygen, L.0 g (atomic) oxygen and
2 1.0 g ozone, the maximum number of oxygen atoms are
2?. Which of the foilowing has the highest mass? contained in:
I) 20 g of sulphur I) L0g of atomic OXYgen
2) 4mol of carbon dioxide 2) 1.0gof czone
3) 1?x 0 atoms of hydrogen 3) 1.0 gof oxygen gas
4) 12Lof heliumat N.T.P. 4) All contain same number of atoms
X*. If wc assume 1/24 th part of mass of carbon instead of 1/12 33. What is the total number of atoms present in 25.0 mg ef
th part of it as Iamu, mass of l mole of a substance will
camphor, CH0
Reman unchanged 2) get doubled ) 9.89x10* 2) 6.02 x 10
?} Ciet halved 4) can't be predicted 3) 9.89 x1 4) 2.67x 10:
 Objective NCERT
Punch -

45. Number of moles of

water in 488 gm of Chemistare.ry
34, If N, is Avogadro's mumber, then the number of oxygen
atoms in onc g-equivalent of oxygen is:
2) N,/2
(At. mass of Ba=137)
1) 2 moles 2) 4 moles
BaCl,2H,0
3) 3 moles 4) 5 moles
3) N4 4) 2N,
oi.
35. If224 ml. of a triatomic gas has a mass of lg at 273 K and 46. 23g of sodium willreact with ethyl alcohol to
1 aunpressure, then the mass of onc atom is: 2) 1/2 mole of H,
1) Imole of H,
I) 8.30x 10 2 g 2) 6.24 x 10-21 3) 1mole of O 4) 1mole of NaOH
3) 2.08 x 10g 4) S.54 x 10g 47. One mole of nitrogen gas has volume equal to
36, The rest mass of an electron is 9.11 x 10kg, Molar mass
1) 1litre of nitrogen at S.T.P.
of the ciectron is:
2) 32 litre of nitrogen at S.T.P.
1) 5 x 10 kg mol1 2) 9.11 x 10" kg mol 3) 22.4 litre of nitrogen at S.T.P.
3) 5.5 x 10 ke moi ! 4) 6.02 x 1025 kg mol-! 4) 11.2 litre of nitrogen at S.T.P.
37. A sanple of ammonium phosphate, (NH), PO,, contains 48. 10 grams of each O,, N, and CI, are kept in three
3.18 moles of hydrogen atons. The number of moles of The corect order of arrangment of bottles.
bottles containing
OxVgen atoms in the sampBe is: decreasing number of Molecules.
) 0.26S 2) 0.795
2) C, N, O,
3) 1.06
1).O,, N,, CI,
4) 3.18 4) N,, O, Cl,
3) CI, O, N,
38. 7.5 grams of a gas occupy 5.8 litres of volume at STP, the
gas is:
i) NO Percentage Composition and
2) N,O
3) 0 Empirical &Molecular Formula
4) CO,
39. Which of the following samples Contain the largest number 49. An element A (at wt = 75) and another element B
of atoms? (at. wt. = 25) conbine to form a compound. The compound
J) lg ofCO, 2) 1gofCH, contains 75% A by weight. The formula of the compound
will be
3) 1gofC,H,(g) 4) 1 g of LiF (s)
1) A,B
40. 4.0g of causticsoda (NaOH) (mol mass 40) contains 2) A,B
same 3) AB,
munber of sodum ions as are present in 4) AB
I) 10.6 gofNa,CO, (mol. mass 106) 50. 60 g of acompound on analysis gave 24 g C,4 g H 32
and
2) 58.5 g of NaCI (Formula mass 58.5) g0. The empirical formula of the compound is:
3) 100 ml of 0.5 M Na,SO, (Formula mass 142) 1) C,H0, 2) C,H,0,;
4) Imol of NaN0, (mol. mass 85) 3) CH,0, 4) CH,0
41. Totai nåmber of atoms present in 64 gm of SO, is 51. A compound made of two elements A
andBare found to
contain 25% A (at mass 12.5) and 75%B (at mass 37.5).
l) 2 x 6.02 x 1023 2) 6.02x 1023 The empirical formula of the compound is:
3) 4 x 6.02 × 1g23 4) 3 x 6.02 × 1023 1) AB
42. The total number of protons, electrons and 2) AB,
neutrons in 3) AB,
12gm of,C is 4) A,B
52. An oxide of a metal (M)
1) 1.084 x 102s 2) 6.022 x 1023 contains 40% by mass of oxy
Metal (M) has atomic mass of 24. The
3) 6.022 x 1022 4) 18 the oxide is empirical formula o
43. Number of Ca? and CI ion in 111 g of 1) MO
anhydrous CaCl, 2) MO
are
3) M,O,
1) N,, 2N 4) M,0,
53. 400 mg of capsule contains 100 mg of ferrous fumarate. The
2) 2N, NA
3) N, NA 4) None percentage of Fe present in the capsule is approximately:
44. The maximum volume at
N.T.P. is Occupied by (formula of ferrous fumarate is
1) 12.8 gm of SO, 1) 8.2%
2) 25%
(CHCO0), Fe).
2) 6.02 x 102 3) 16%
molecules of CH, 4) Unpredictable
3) 0.5 mol of NO, 54. The
4) l
percentage of
l) 40
oxygen in NaOH is:
gm-molecule of CO, 2) 60
3) 8
4) 10
Some Basic Concepts of Chemistry
|9|
$$, Asanple of pure compound contains 1.15 g of sodium, 64. Caffeinc has a molccular weight of 194. If it
3.01 x 10* atoms of carbon and 0.l mol of oxygen atom. contains
28.9% by mass of nitrogen, number of atoms of nitrogen
Its empirical formula is one moleculc of caffcine is: in
) Na,CO0, 2) NaCO, I) 4 2) 6
3) Na,CO 4) Na,CO, 3) 2 4) 3
Sb. A hydrocarbon is composed of 759% carbon. The empirical
fomula of the compound is Stoichiometric Calcuiations
1) CH, 2) CH, 65. The moles of O, required for reacting with 6.8 g
ammonia.
3) C,H, 4) CH, (..NH,+..0,-...NO t...H,0) is:
3". Aconpound has 20% of nitrogen by weight. If onc I) 5 2) 2.5
molecule of the compound contains two nitrogen atoms, 3) 1 4) 0.5
the molecular weight of the compound is 66. What mass of CaCl, in grams would be enough to produce
1) 35 2) 70
14.35 gm of AgCl?
3) 140
1) 5.55 g 2) 8.29 g
4) 280
3) 16.59 g 4) 10 g
S8. An alkaloid contains 17.28% of nirogen and its
molecular 67. The mass of 70% H,SO, by mass solution which is
mass is 162. The number of nitrogern atoms present in one for neutralisation of 1 mole of NaOH is: required
moiecuie of aikaloid is
1) 65 2) 98
!) Five 2) Four 3) 70 4) 54
) Three 4) Two 68. If potassium chlorate is 80% pure then 48 g of oxygen
$0. The molecular mass ofa compound having the empirical would be produced from:
formula (C,H0) is 170+5. Find the molecular formula of 1) 153.12gof KCIO, 2) 120 gof KCIO,
the compound.
3) 20 g of KCIO, 4) 90 gof KCIO,
1) CH,0. 2) CH,0, 69. A solution containing 0.1 mole of a metal chloride MCI
3) C,H,0, 4) CH,0, required 500 mL of 0.6 M AgNO, solution for complete
6. A gaseous hydrocarbon on complete combustion gives 3.38 precipitation. The value of x is:
g of CO, and 0.690 g of H,0 and no other products. The 1) 5 2) 4
empirical formula of hydrocarbon is: 3) 3 4) 1
1) CH 70. If 20 g of CaCO0,is treated with 100 mL 20% HCI solution.
2) CH,
3) CH.
The amount of CO, produced is:
4) The data is not complete
1) 22.4 1 2) 8.8 g
61. Empirical formula ofa compound is CH0 and its molecular
mass is 90. The mnolecular formula of the compound is 3) 2.2 g 4) 81
71. The mass of CaCO, required to react with 25 mL of
I) CH0, 2) C,H,0, molar HCI is: 0.75
3) CH,0, 4) CH,0 1) 0.94 g 2) 0.68 g
62. On analysis a certain compound was found to contain 3) 0.76 g 4) 0.52 g
iodine and oxygen in the ratio of 254 g of iodine 72. 2 moles of H,S and 11.2 L of S0,at N.T.P. reacts to form x
(at mass 127) and 80 g oXygen (at mass 16). What is the moles of sulphur. The value of x is:
formula of compound? 1) 1.5 2) 3.5
l) IO 2) I,0 3) 7.8 4) 12.7
3) 1,0, 4) I,0, 73. What weight of HNO, is needed to convert 5 g of iodine
63. 14 g of element X combine with 15g of oxygen. On the into iodic acid according to the reaction,
basis of this information, which of the following is a correct 1, +HNO, ’ HI0, +NO, + H,0
statement 1) 12.4 g 2) 24.8 g
1) The element X could have an atomic weight of 7 3) 0.248g
and its 4) 49.6g
oxide fomula XO
74. The molarity of pure water is:
2) The element X could have an atomic
weight of 14 and 1) 100 M 2) 55.6 M
its oxide formula X,0
3) 50M 4) 18 M
3) The element X could have an atomic weight 7
of and its 75. If0.30 mol of zinc are added to 0.52 mol of HCI, the moles
oxide is X,0 of H, formed are:
4) The element X could have an
atomic weight of 14 and 1) 0.52 2) 0.30
its oxide is XO, 3) 0.26 4) 0.60
 Gbjsctis NGERI

Rank Booster MCOs

10. A+2B +3C AB,C,

1. Light travels with a speed of 3 x i0 m/sec. The distance atoms
travelled by light in l Femto sec is: Reaction of6gofA, 6 12
gofcompound AB,C Ifthe at4mie
) 0.03 mm 2) 0.003 mm &Care4.8
yields 60 &80 amurespectively,the atornic: ma%s
3) 3mm 4) 0.0003 mm 2) 50 arnu
I) 60 amu
2. The molccular formula of a commercial resin used for 4) 120 atnu
3) 90 amu
exchanging ions in water softcning is C,H,So,Na' (mol.
wt 206). What would be the naximum uptake of Ca? ions I1. A100g ofa sample of haenoglobin on analysis Was
cach
If hacmoglobin
by the resin when expressed in mole per gram resin? to contain 9.34% Fe by mass,
has four Fe íons, the molecular mass of haenoglobi iy
2
103 206 (Fe= 56 amu)
2 2) 12735 g
3 4) ) 77(099.,9g
309 412
3) 65882g 4) 96359,9 g
3. 1f 10 molecules are removed from 200 mg CO,, then the 1sL.:
12. What yolume of5 M Na,S0, must be added to 250
number of moles of CO, left are:
l) 2.88 x 103 2) 1,66 x 103
1MBaCl, o produce 10gof Bas0,?
1) 8.58 mL. 2) 6.4 mL
3) 1.66 x 10* 4) 4.54 x103 4) 22 miL
3) 18 mL
4. 1f i ml of water contains 20 drops, then the number of weipk
molecules in a drop of water is: 13. A compound is composed of O and Mn in cqual
2) 1.376 x 1026 ratio, Find the empirical formula of the compound.
1) 6x 1023
1) Mn,0, 2) MnO,
3) I.673 x 102! 4) 4.34 x 1020
3) Mn,0, 4) Mn,0,
5. Ifx g of A(atomic mass 50) contains n atoms, how many
atoms are there in 20x g of elements B: (at wt, 100) 14.1f ísotopic distribution of C-12 and C-14 is 98% ami 2%
respectively, then the number of C-14 atorns in 12 g ef
1) n 2) 1On
carbon is:
3) 20n 4) n/10 2) 3,0! z |(2
l) L,032x 1(22
reactíon
6. Diborane (B,H)can be prepared by the following 3) 5.88 x1G23 4) 6.02 1023
3NaBH, +4BE, ’3NaBF, +2B,H, 15. Sulphuric acid reacts with sodíum hydroxide as follows:
moles of NaBH,
If the reaction hasa 70% yicld, how mnany H,S0, +2NaOH ’ Na,S0, +2H,0
obtain 0.,200
shouid be used with excess BF, in order to
When 1L of 0,1 M sulphuric acid solutíon is allowed t»
mol of B,H,?
2) 0.429 moles rcact with 1L of 0.1 M sodíurm hydroxíde solution, the
1) 0.21 moles
4) 0.175 moles amount of sodiurn sulphate formed is:
3) 0.30O mol
by mass. ) 0.15 g 2) 7.10 g
7. An ore contains I.24% of mineral argentate,beAg,S
processed in 3) 0.025 g 4) 3.55 g
have to
How many grams of this ore would
order to obtain lg of pure solíd silver? 16. X gm of Ag was dissolvcd in HN0. and the solution a
treatcd with cxces% of NaCI, When 2,87 of AgCi w
1) 92,6 g 2) 88.1 g
4) 107.25g precipitated, the value ofx is
3) 101.11g
has density 1.025 g/mL and Ag +2HNO, -’ AgNO, +NO, +H,0
8. An aqueous solution of ethanol this solution: AgNO, + NaC|--’ AgCi +NaNO,
molarity 8 M. Calculate nolality of I) L.08 g
2) 17.12 m 2) 2.16g
) 20.27 n
4) 1.117 n 3) 2.70 g 4) 1.62 g of
3) J2.18 m sample
mixture of CrSO,and 17. The %% loss in weight afer heating a pure
9. Themolar ratio of Cr? to Cr in a both potassium chlorate (M, wt, I22.5) will be
ions in
Cr(S0,), having equal number of sulphate 2KCIO, -2KCI+ 30,
sulphates is
2) 3:2 I) 12.25 2) 24.50
1) 1:3
3) 2:3 4) 3:4 3) 39.18 4) 49.00)
S0Te BasConcepts of Chomistrv

I8. Two oxides of a metal Contain S0% and 40% metal (M)
27, A mctalnitride M,N,contains 28% of
respectively. If the formula of first oxide is MO, the mass of inctal M is:
nitrogcn. The alomic
formula of second oxide will be:
) 24 2) 54
1) MO, 2) MO, 3) 9 4) 87.62
3) M,0 4) M,0, 28. Chlorine can be prepared by reacling HCl with
In an organic compound of molar nass 108 g nmol C, H MnO,. The
reaction is representcd by thc cquation
and Natoms are present in 9:1:3.5 by weight. Molccular
fornmula can be MnO,(g) +4HC\aq.) -’ MnCl, (aq.) +C1,(g) +211,0()
Assuming that the reaction gocs to completion.
1) CHN, 2) C,H,N of conc, HCI solution (36% by mass) is nccded What mass
to produce
3) CH,N, 4) C,HN, 2.5 gC1,?
2R 6.0 x 10° molccules of urca are present in 100 nL of its I) 14.27g 2) 25 g
solution. The molarity of urea solution is 3) 25.21g 4) 30 g
1) 0.00l M 2) 0.01 M 29. 29.2% (w/w) HCIstock solution has a density of 1.25 g
mL'.
The molccular wcight of HCI is 36.5 g mol !. The volume
3) 0.02 M 4) 0.1 M
(Avogadro constant, N, =6.02 ×10* mol) (in mL) of stock solution required to prepare a 200 m
solution of 0.4 M HCl is
2. In the reaction,
1) 16 mL 2) 6l mL
ZAI(s) +6HCl(aq) -’ 2Al"(aq) + 6CI (aq) + 3H,(g),
3) 80 mL 4) 8 mL
I) 6L HC(aq) is consumed for every 3LH,(g)
produced 30. The molality of 1L solution with x% H,SO, (w/v) is
2) 33.6 LH.(g) is produced regardless of
temperature and equal
to 9. The weight of solvent present in the solution is 910 g.
pressure for every mole Al that reacts The valuc ofx is
3) 67.2 LH.(g)at STP is produced for every mole Al that 1) 90 2) 80.3
Teacts
3) 100 4) 95.5
4) 11.2LH(g) at STP is produced for every mole HCI(ag)
consumed 31. The composition of residual mixture will be, if 30 g of Mg
22. 4.4 g of CO, and 2.24 litre of H, at STP are combines with 30 gof O,
mixed in a 1) 40gMgO +20 gO,
container. The total number of molecules present in the 2) 45 gMg0 + 15 gO,
container will be 3) 50 g MgO + 10g 0, 4) 60 g MgO only
1) 6.022 x 1023 32. How many moles of magnesium phosplhate,
2) 1.2044 x 1023
contain 0.25 moles of oxygen atoms? Mg,(PO,), will
3) 2 moles 4) 6.023 × 1024
I) 0.02 2) 3.125 x 10
23, 1g sample of alkaline earth metal react completely with 4.08
gH,SO, and yields an ionic product MSO,. Then find out the 3) 1.25 x 102 4) 4.25 x 10
atomic mass of alkaline earth metal (M)? 33. The atomic weights of two elements A and B are 40 u
and
I) 9 80 u respectively. If x g of A contains y atoms, how many
2) 24
atoms are present in 2x g of B:
3) 40 4) 87
24. A compound contains 36% Cby mass. If each molecule 1) 2) Y
2 4
contains two C atoms the number of moles of the compound 3) y
in its 10 g is: 4) 2y
34. The haemoglobin from red blood corpuscles of most
1) 0.J5 2) 1.5 mammals contain approximately 0.33% of iron
3)150 4) 1500 by mass. The molecular mass of haemoglobin is
25. When a certain amount of octane is burnt 67200g mol, The number of iron atoms in each molecule
completely, of haemoglobin is:
7.04 g of CO, is formed. What mass of H,0 is formed
simultaneously? I) 3 2) 4
1) 3.24 g 2) 6.68 g 3) 2 4) 6
3) 6.48 g 4) 6.16 g 35. 0.8 mole of a mixture of CO and CO, requires Cxactiy
26. A 1.50 g sample of KHCO, having 80% purity is 40 gram of NaOH in solution for complete conversion
strongly
heated. Assuming the impurity to be thermally stable, of all the CO, into Na,CO,, if the mixture (0.8 mole) is
loss in weight of the sample, on heating is:
the completely oxidised to CO,, find further requiredmoles of
NaOH.
1) 26.4 g 2) 2.64 g I) 0.2 2) 0.6
3) 0.264g 4) 0.0264 g 3) 1 4) 1.5
 Objective NCERT Punch

B - pr,1; C’t; D 9,t

6. 3.68 g of a misture of CatO, And
iberate 0,04 mole of co,. The moleMgCO,
is heated to B - 4,t,p; C t;
%of CaCO, nnd 2) A S, ri
MgCO, in the mixture is respectively: 3) A q, P: B p.t; Cp; D p,r,t
) SO%, 500% 2) 60%, 40% BS,p,t;
4) A g 1;
3) 40%, 60% 4) 30%, 70% of ferric alum,
17. An element is found in nature in two
isotopic torns wilh
44. How 11tany
moles
Fe,(SO,),24H,0 can be made from
(NH,) ofSO,Fe
the sample
mass mumbers (A--) and (A + 3). If the average ntomie containing 0.0056 g of it?
mass of the eBenent is found to be A, then the relative 1) 104 mol
2) 0.5 x 104 mol
abundaoe of the heavier isotope in the nature will bc. 4) 2 x 104 mol
) S6.6% 3) 0.33 x 10 4 mol
2) 75°% on treatment wíth
3) 25o 45. I gram of a carbonate (M,CO,) CXCesS
4) 33.3%
produccs
HCI 0.01186 mole of CO,. The molar mo
I8, 0.S mol of potassium femocyaide contains carbon equal
to: (Fomula of potassium ferocyanide is
M,CO, (in g mol ) is
K,[Fe(CN),]. I) 118.6 2) 11.86
2) 36 g 3) 1186 4) 84.3
3) 18g 4) 3.6 g
46. Suppose the elements X and Y combine to form
39, MaSS of 0.224 litre of hydrogen gas at 273 K and 1 compounds XY, and X,Y,. When 0.1 mole of XY, weich.
atm
(assuming ideal behaviour) is 10g and 0.05 mole of X,Y, weighs 9 g, the atomic weiehe
2) 0.2 g of X and Y are
3) 0.02g 4) 0.002 g 1) 40, 30 2) 60, 40
40. 0.07S grams of a hydrocarbon occupy 22.4 mL. of volume at 3) 20, 30 4) 30, 20
STP. The empirical fomula of the hydrocarbon is CH. The
molecular formuia of hydrocarbon is 47. Concentrated aqucous sulphuric acid is 98% H,SO, by
mass and has a density of 1.80 g mL-!. Volume of acid
) CH, 2) C,H, required to make once litre of 0. 1 M H,SO, solution is
3) C,H, 4) CH, 1) 11.10 mL 2) 16.65 mL
41.0.16 g of dibasic acid required 25 ml of N/10 NaOH for 3) 22.20 mL 4) 5.55 mL
compBete neutralization. Molecular weight of acid is: 48. The following substances are present in different containers
) 32 2) 64
()) One gram atom of nitrogen
3) 128 4) 256
(ii) One mole of calcium
42. Which of the following molarity valucs of ions in a (iii) One atom of silver
aqueous soBution of 5.85% wiv NaCl, S.55% wiv CaCl,
and 6% wir NaOH are corect [Na = 23, Cl = 35.5, (iv) One mole of oxygen molecules
Ca = 40,0 = 16] (v) 10* atoms of carbon
) [C=2M (vi) One gram of iron.
2) (OH]= 1.5 M
3) [Ca]=0.5 M 4) All of these The correct order of increasing masses (in grams) is/are
43. Match the column: 1) (ii)<(iv) < (i) <()
Column-I
2) (ii)< (vi) < (iv)<(ii)
Column-II
A. Imole (NH,), CO, p. Moles of carbon atom
3) (vi) < (v)<()< (iv)
is less than 1 4) (2) and (3) both are
correct
B. 0.5 mole NH, CONH, q. Mass of oxygen is 49. Consider the following statements:
greater than 16 g in () A balanced chemical reaction
should
C. Imole CH,N
sample
r. At least two
conservation of mass on either side. follow law
elements (iü) 2 moles of H,(g) and 3 moles of O,(g) produce 3
have same nunmber of
atoms in given sample moles of water.
D. Imole C,N, s. Number of neutrons
(ii) Equal wt. of carbon and oxygen are taken to produce
and protons are same Co,, then O, is limiting
L,
The above statements i), reagent.
(ii), (iii) respectively are
Moles of nitrogen atom
is greater than and equal (T=True, F= False)
to 1 1) TTT
2) FTF
3) FFF
4) TFT
Some Basic Concepts of Chemistry
|13|
50. How many molecules of HCI gas will be produced by 53. Mole fraction of acetic acid in an aqucous sample is 0.1.
reacting 112 LofH, (0 °C, 1atm) with 213 g of C1,? The molality of the solution is
1) 3.61 x 1024 2) 6.13 x 1023 ) 7.16 mnol kg
3) 6.13 x 1024 4) 1.63 x 1024 2) 1.67 mol kg
51. 20 mL of 0.4 MAgNO, (molar mass = 170 g) is rcacted 3) 6.17 mol kg
with 15 mL of 0.6 M BaCl, (molar mass = 208.4 g). The 4) 5.25 nol kg!
mass of AgCl(molar mass = 143.5 g) produced is 54. Molarity of H,SO, (density 1.8 g/mL) is 18 M. The molality
l) 11.48g 2) 18.14g of this H,SO, is:
3) 14.18g 4) 1.148 g 1) 36 2) 200
52. 85 g CaCO, (limestone sample), on heating produces 3) 500 4) 18
exactly the same amount of CO, which converts 30g of 55. 1.5 moles of each of XY, and XY, if weigh 96 g and 120
MgO to MgCO,. The percentage purity of limestone sample g respectively. The atomic masses of X and Y respectively
are
1) 80% 2) 82.4% 1) 4,8 2) 8, 16
3) 88.24% 4) 84.8% 3) 32, 16 4) 32,64

Match the Columns MCQs

1. Match the following:
1) (a)-(i) (b)-(ii) (C)-(iii) (d)-(iv)
Column-I Column-I
(a) 88 gof CO, (i)|0.25 mol
2) (a)-(iv) (b)-(ii) (c)-(ii) (@)-i)
(b)|6.022 x1023 (ii) 2 mol 3) (a)-(iv) (b)-(ii) (c)-() (d)-<ii)
molecules of H,0 4) (a)-(ii) (b)-(1) (c)-(ii) (d)-(iv)
(c) 5.6 litres of 0, at (iii) 1mol 4. Match the following
STP
Column-I Column-II
(d) 96 g of O, (iv)6.022 x 10 molecules
(e) 1 mol of any gas (v)3 mnol (a) mega (i) 10
1) (a)-(i) (b)-(iv) (c)-(ii) (d)-(ii) (e)-(v)
(b)peta (ii) 10-12
(c) pico (1i) 1015.
2) (a)-(i) (b)-(ü) (c)-(i) (d)-(v) (e)-(iv)
3) (a)-(v) (b)-(i) (c)-(ii) (d)-(iv) (e)-i) (d) giga (iv) 10
4) (a)-(ii) (b)-(v) (c)-(ii) (d)-(i) (e)-(iv) 1) (a)-(i) (b)-(ii) (c)-(i) (d)-(iv)
2. Match the following physical quantities with units 2) (a)-(iv) (b)-(i) (c)-(ii) (d)-(i)
Physical quantity Unit
3) (a)-(iv) (b)-(ii) (c)-(i) (d)-(i)
(a) Molarity ()mol kg
4) (a)-(ii) (b-(i) (c)-(i) (d)-(iv)
(b) Molality (iü) mol L-1
5. Match the following
(c) Mol fraction (iiin) Unit less
(d) Mole (iv) Mol Column-I Column-Il
(Symbol) (Unit)
1) (a)-(i) (b)-(ii) (c)-(ii) (d)-(iv)
(a) Newton (i) Kgm² see2
2) (a)-(i) (b)-(i) (c)-(iv) (d)-(ii)
3) (a)-i) (b) Joule (ii) Kg msec?
(b)-(i1) (C)-(iv) (d)-(ji)
4) (a)-(ii) (b)-{i) (c)-(ii) (d)-(iv) (c) Acceleration (ii) | m sec?
3. Match the following: (d) Mass (iv) kg
Column-I Column-II
1) (a)-(i) (b)-(i) (c)-(i) (d)-(iv)
(a) Element (i)20 carat gold
2) (a)-(i) (b)-) (C)-(i1) (d-(iv)
(b)|Compound (ii) lodized common salt
(c) Homogeneous mixture (ii) Silica 3) (a)-(i) (b)-(i) (c)-(ii) (d)-(iv)
(d)| Heterogeneous mixture (iv) Radium 4) (a)-(ü) (b)-(iii) (c)-(i) (d)-(iv)
 Correct & inoorrect MCQS
correet statement:
I. ldentify the incorrect statement from the following f, Choose the 16,043 u
Moleeular maS# of methane is
|) Ghucose is not apure substance, )
of waler is24.0 u,
2) Water, ammonia, sugar, CO, are compounds. 2) Molecular naSA u.
of glucOse 0s 324.68
3) H, and O, are gases whereas the compound formed by 3) Molecular maSs ammonía is 36,0 u.
of
their combination ie., water is aliquid, used as ire 4) Molecular ina8%
regarding moles Ís not corrcct y
extinguisher. 7. Whieh statement
amoutof substance
4) Sodium, copper, silver, hydrogen are elemontA. ) The mole is the SI unitof
contains exactly !2,044 t
2. Identify the incorrect statement from tho following. 2) One mole of asubstance
1) The nmultiple of prefix f'ennto is 10!5 elementary entities.
contain 6.022x 102 to
2) The multiple of prefixpico is 10-12 3) I mol of hydrogen atom8
3) The multiple of prefix nano is 10-* 4) The mass of one mole of a substance in grams is callod
4) The multiple of prefix micro is 10-4 its molar mass.

3. Which statement regarding mass and weight is not correct ? 8, Which amongst the following statements is not corree
1) Mass of a substance is the amount of matter present about the given reaction ?
in it. CH, (g) + 20, (g) -’ CO, (g) +2 H,O (g)
2) Weight is the force exerted by gravity on an object. I) One mole of CH,(g) reacts with twO moles of 0.(2) o
3) The SI unitof mass is kilogram. give onc mole of CO,(g)and two moles of H,0(g).
4) Mass of a substance may vary from one place to another 2) One molecule of CH() reacts with 2 molecules of
while weight of a substance is constant. O,(g) to give one molecule ofCO,(g) and 2 molccules
4. The incorrect statement regarding significant figuros is: of H,O(g).
1) There are three significant figures in 285 cm. 3) 22.7 L of CH, (g) reacts with 45,4 L of 0, (g) to give
2) There are two significant figures in 0.25 mL. 22.7 Lof Co,(g) and 45.4 Lof H,0(g)
3) There are threc significant figures in 0.03 4) 16g of CH, (g) reacts with 32 g of O, (g) togive 44 g
4) There are four significant figurcs in 2.005. of CO, (g) and 18 g of H,0(g).
9. Choose the incorrect statement about molarity :
5. Select the incorrect statement regarding laws of chemical
combination : I) Molarity is defined as the number of moles of the solute
1) According to law of conservation of mass, matter can present in Ilitre of the solution.
neither be created nor be destroyed 2) Molarity is denoted by symbol M.
2) According to law of definite proportions, a given 3) IM NaOH means 1 mol of NaOH present in I
litre o1
compound always contains exactly the same proportion the solution.
of elements by weight. 4) Molarity is independent on temperature.
3) According to law of multiple proportions, if two I0. ChoOse the correct statement/s :
clements can combine to form more than one compound,
A. 0.22 g of CO, contains 0.005
the masses of one element that combine with a fixed moles
mass of the other clement, are in the ratio of small B. 320 mg of SO, contains
0.005 moles
whole numbers. C. 560 mg of SO,
contains 0.005 moles
4) According to Gay Lussac's law, equal volumes of all D. 0.085gof NH,
gases at the same temperature and pressure should
contains 0.005 moles
1) A, B and C
contain cqual numbcr of molccules 2) Only C
3) A, B and D
4) B, C and D
Ssnse Rasie Cucepts of Chenústry

Statement Based MCQs

Direetions: These questions consist of two statements cach, Statement-U: Equal wcights of different substances
printed as Statement- and Statement-I1. While answering contain the same number of constituent particles.
these qucstions, you arc roquired to choosc any onc of the 5. Statement-: Molality, molc fraction and mass fraction
following four respoNses. change with temperature.
1) Both Statement-I and Stantement-11I are correct, Statement-li: Molarity and Normality do not change with
2) Both Statement-B and Statement-ll are incorrect. temperature.
3) Statement-I is ecorrect & Statement-I is incorrect. 6. Statement-1: Air is a homogencous mixture.
4) Statcment-l is incorrect & Statement-1l 0s correct. Statement II: The components of air completely mix with
cach other and its composition is uniformn throughout.
Stwiheut-1: The mathematical approach to obtain the 7.
amount of the products or reactants is called stoichiomctry. Statement-I: Mass of a substance is constant where as its
1fmnt-t: The stoichiometric calculations arc derived weight may vary from one place to another.
from chemical cquations. Statement-II: Weight changes due to change in earth's
gravity.
Niement-i: A certain clement X, forms three binary 8. Statement-I: Matter can neither be created nor be
compounds with Chlorine containing 59.68%, 68.95% and
74.75% Chlorine respectively. These data illustrate the law destroyed.
of multiplc proportions. Statement-II: In all physical and chemical changes, the
total mass of the reactants is never equal to the total mass
$tafement -li: According to law of multiple proportions,
the relative amounts of an element combining with some of the products.
fixed amount of a second elcement in a series of compounds 9. Statement-I: Molality of a solution depends upon
are the ratios of snall whole numbers. temperature.
Stateent-: 32 gof 0, and 48 g of O, have same number Statement-II: Molarity of a solution depends upon
of atomns. temperature.
10. Statement-1: One mole is the amount of a substance that
5ratemeat-il: Number of moles in 32g of O, and 48 g of contains as many particles or entities as there are atoms in
0, are different.
exactly 12 g of the 12C isotope.
4. Stutement-i: Equal moles of different substances contain Statement-II: One mole of different substances contain
same number of constituent particles. different number of entities.

Assertion & Reason MCQs

Directions: These questions consist of two statements 3. Assertion: The number of significant figures in 1502 cm is
each, printed as Assertion and Reason. While answering two.
these questions, you are required to choose any one of the Reason: All non-zero digits are significant and zeroes lie
following four responses. between any two non-zeroes will be significant.
1) Both Assertion and Reason are True and the 4. Assertion: The ratio by volume of NH,: HCI:NH,Cl is
Reason is a correct explanation of the Assertion. 1:1:1inthe reaction
2) Both Assertion and Reason are True but Reason is NH,(g) +HCI(g) -’ NH,C()
not a correct explanation of the Assertion. Reason: Gay Lussac's law deals with gaseous reactants
3) Assertion is True but the Reason is False. and products only.
4) Assertion is False but Reason is True. 5. Assertion: 64 g of SO, and 80g of SO, will occupy same
volume at NTP.
!. swertian: 1 mole of anygas occupies 22.4 lit at NTP.
Reason:lmole of any gas occupies 22.4 lit at NTP.
Reson: Volume of gas depends on temperature, pressure
and nature of gas. 6. Assertion: The empirical mass of ethene is half of its
molecular mass.
2. Asversion: The no. of Oxygen atoms present in 16 g of
OXygen and 16 g of 0, is same. Reason: The empirical formula represents the simplest
whole number ratio of various atoms present in a
Reasgn; Both these species represents 1 g atom of oxygen. compound.
 Objective NCERT Punch

7. ANsertion: Onc atomic mass unit is defined as one tweltth Combustion of 16 g of methane gives Chemistry
of the mass of one carbon-12 atonm.
9. Assertion:
Water.
combustion of methane, water is
18gof
Reason: Carbon-12 isotope is the most abundant isotope of Reason: In the one of the
carbonand has bcen chosen as standard. products. amu represents a mass cqual to 166 x 10 21
8. ANsertion: Signiicant figures for 0.200 is 3 wherens for 10. ANsertion:
200 it is 1, kg.Renson: I amu represents the actual mass ot one atom of
Reason: Zero at the end or right of anumber are significant
provided they are not onthe right sicde of the decinnal point. carbon-12.

NCERT Exemplar MCQs

molecules
1. Two students perfommed the same experiment separutely 1) 12.044 x 1020
and each one of them recorded two readings of mass which 2) 6.022 x 102 molccules
are given below. Coreet reading of mass is 3.0 g. On the 3) 1x 1025 molecules
basis of given data, mark the corroct option out of the 4) 12,044 x 1023 molecules
following statements: carbon dioxide?
8. What is the mass per cent of carbon in
Students Readings 2) 27.27%
1) 0.034%
) (i) 3) 3.4% 4) 28.7%
3.01 2.99
2.95
9. The empirical formula and molccular mass of a compound
B 3.05
are CH,0 and l80 g respectively. What will be the
I) Results of both the students are neither accurate nor molecular formula of the conmpound?
precise 1) CHO, 2) CH,0
2) Results of student A are both precise and accurate 3) C,H,0. 4) C, H,0,
3) Results of student B are neither precise nor accurate 10. If the density of a solution is 3.12 g mL, the mass of
4) Results of student B are both precise and accurate 1.5 mL solution in significant figures is:
2, What will be the molarity of a solution, which contains I) 4.7g 2) 4680 x 10 g
5.85 g of NaCl (s) per 500 mL? 3) 4.680 g 4) 46.80 g
1) 4 mol L-! 2) 20 mol L-!
4) 2 mol L!
I1. Which of the following statements about a compound s
3) 0.2 mol L! incorrect?
3. If 500 mL of a 5 M solution is diluted to 1500 mL, what 1) A molecule of a compound has atoms of different
will be the molarity of the solution obtained? elements
1) 1.5 M 2) 1.66 M
2) A compound cannot be separated into its constituent
3) 0.017M 4) 1.59 M elements by physical methods of separation
4. The number of atoms present in one mole of an element is 3) A compound retains the physical properties of i5
equal to Avogadro number. Which of the following element constituent elements
contains the greatest number of atoms? 4) The ratio of atoms of different elements in a comnpou
2) 46 g Na is fixed
1) 4g He
3) 0.40g Ca 4) 12 g He 12. Which of the following statements is correct about
reaction given below?
5. If the concentration of glucose (CH,,0,) in blood is
0.9 gL, what will be the molarity of glucose in blood? 4Fe(s) + 30,(g) ’ 2Fe,0,(g)
2) 50 M 1) Total mass of iron and oxygen in reactants =total mass
l) 5M of iron and OXygen in product therefore it followslaw
3) 0.00S M 4) 0.5 M
of
6. What will be the molality of the solution containing
conservation
of mass
product,
2) Total mass of of
18.25 g of HClgas in 500g of water? reactants = total mass
0.1 m 2) 0.05 m therefore, law of multiple proportions is followedoneof
1) 3)
3) 0.5 m 4) 1m Amount of Fe,0, can be increased bytaking any
the reactants (iron or oxygen) in excess
102 atoms/ anount
7. One mole of any substance contains 6.022 x 4) Amount of Fe,0, produced will decrease if thetakenin
moBecules. Number of molecules of H,SO, present in of any one of the reactants (iron or is
100 mL of 0.02 MH,SO, solution is: excesS
oxygn))
Some Basic Concepts of Chemistry

13. Which of the following statements indicates that law of 3) When magnesium burns in Oxygen, the amount of
muBtipie proportion is being followed? magnesium taken for the reaction isequal to the anount
1) Sample of carbon dioxide taken from any source will of magnesium in magnesium oxide formed
aiways have carbon and oxygen in the ratioi:2
2) Carbon forns two Oxides namely C0, and C0, where 4) At constant temperature and pressure, 200 mL of
masses of exvgen which combine with fixed mass of hydrogen will combine with I00 mL oxygen to produce
carton are in the simpie ratio 2: 200mL. of water vapour

Past 5 Years MCQs

i. What mass of 95% pure CaC0, will be required to 4. One mole of carbon atom weighs 12g, the number of atoms
neutralise sO ml of 0.S M HCI solution according to the in it is equal to. (2029 Covid)
following resction? (2022) (Mass of carbon-12 is 1.9926 × 10 g)
CaC0 2HCICaCl,tCOt 2H,Oo 1) 6.022x 102 2) 12 × 102
[Calcalate upto second place of decimal point] 3) 6.022 x 1023 4) 12 x 123
1) 9.50 g 5. The number of moles of hydrogen moiecules required to
2) 1.25 g produce 20 moles of ammonia through Haber's process is
3) 1.32 g (2919)
4) 3.66 g 1) 10 2) 20
3) 30 4) 40
. An organic compound contains 78% (by wt.) carbon and
6. A mixture of 2.3 g formic acid and 4.5 g oxalic acid is
renaining percentage of hydrogen. The right option for the
empirical formula of this compound is: [Atomic wt. of C is treated with concentration H,SO,. The evoBved gaseous
12, His 1] mixture is passed through KOH pellets. Weight (n g) of
(2021)
I) CH 2) CH,
the remaining product at STP wil be (2018)
1) 1.4 2) 3.0
3) CH, 4) CH 3) 4.4 4) 2.8
3. Which one of the followings has maximum number of 7. Inwhich case is number of molecules of water maximum?
atoms? (2020)
(2018)
1) lg of Mg(s)[Atomic mass of Mg 24) 1) 18mL of water
2) 1gof0,(g) [Atomicmass of O = 16] 2) 0.18 g of water
3) ig ofLi(s) [Atomic mass of Li =7] 3) 10 mol of water
4) lgofAgls) [Atomic mass of Ag=108] 4) 0.00224 L of water vapours at l atm and 273K