11 S Online Lesson 11 2022.5
11 S Online Lesson 11 2022.5
11 S Online Lesson 11 2022.5
The Periodic Table is a vital tool used by chemists to predict the way in which elements react during
chemical reactions. It is a method of classifying elements according to their properties.
It gives the names and symbols for the elements.The modern Periodic Table,was created in 1869
by the Russian chemist, Dmitri Ivanovich Mendeleev.He collected the elements together in a table
that revealed the periodic(repeating) pattern in their properties.In the periodic table, chemical
elements are arranged :
1. in order of increasing atomic number;
2. in relation to the electron configurations(electron structure) of elements;
3. in relation to the similarities in chemical properties of the elements.
Groups and Periods
Groups
The groups are the vertical columns of elements in the Periodic Table.There are eight (8) groups.All
groups are represented by Roman numerals from I to VIII.The group to which an element belongs
depends on the valence electrons of the element.Valence electrons are electrons that are found in
the outer shell of an atom. In other words,all the elements in a group have the same number of
electrons in their outer shell.Group I elements have 1 electron in the outer shell e.g.Lithium,
7 23 39
3Li(2,1),Sodium, 11Na(2,8,1),Potassium, 19K(2,8,8,1).Group VII elements have 7 electrons in the
outer shell e.g.Fluorine,199F(2,7),Chlorine,35.517Cl(2,8,7), Bromine,8035Br(2,8,18,7).Group VIII elements
have full outer shells e.g. Helium,42He(2), Neon, 2010Ne(2,8),Argon,4018Ar(2,8,8).Elements in the same
group have similar chemical properties( i.e.outer valence electrons determine the chemical
properties of an element).
Some of the groups have special names:
a) Group I is called the alkali metals.
b) Group II is called the alkaline earth metals.
c) Group VII is called the halogens.
d) Group VIII is called the noble gases
Periods
The periods are the horizontal rows of elements in the Periodic Table.There are seven periods.
Periods are numbered with ordinary numerals from 1 to 7.The first period contains two elements:
hydrogen, H and helium, He. Periods 2 and 3 each contain eight elements.They are called short
periods.Periods 4 and 5 each contain 18 elements.They are called long periods.
All the elements in a period have the same number of occupied electron shells.The elements in
period 1 have one shell,those in period 2 have two shells ,those in period 3 have three shells and so
on.
Classification of elements using the Periodic table.
Elements can be classified as metals, non metals and metalloids.The zigzag line in the Periodic table
through the groups separates the metals from the non metals. All the metals are on the left and all
non metals are found to the right.The metalloids are found on either side of the line.Metalloids are
elements that have properties of both metals and non metals.Metalloids include silicon,
germanium,arsenic,antimony,selenium and tellurium.
Groups and Periodic trends.
Group trends
Moving down a group, elements gain electron shells.This changes the size of the atoms which in
turn obviously affects both their physical and chemical properties.
Trends within Group I-the alkali metals
Atom Metal Reactivity Melts at...OC Boils at...OC melting and
7
3Li Lithium increases 181 1342 boiling
23
11Na Sodium as atoms get 98 883 points
39
19K potassium larger 63 760 decrease
85
37Rb Rubidium 39 686
As we go down Group I, reactivity increases while melting and boiling points decrease.
Alkali metals react to lose an outer electron and obtain a full outer shell.The further the
electron is from the nucleus, the easier this is.So the bigger the atom, the more reactive
the metal will be.
Meanwhile the melting and boiling points decrease because the attraction between the
atoms gets less strong as the atoms get larger.
The atomic radius increases down the group. As extra electron shells are added in passing down
group I, the outer electrons are further away and increasingly screened (shielded) from the positive
nucleus. As a result they are not held tightly and the atomic radius increases.
Going down the group, the first ionisation energy decreases. There is more shielding between the
nucleus and the outer electrons and the distance between the nucleus and the outer electron
increases and therefore the force of attraction between the nucleus and outer most electrons is
reduced.
Trends within Group II-the alkaline earth metals
Elements Melting point in OC Boiling point in OC
Beryllium 1278 2970
Magnesium 649 1107
Calcium 839 1484
Strontium 769 1384
Barium 725 1640
The trend is however not so smooth.Magnesium seems to be out of place for example.But the
overall trend is a decrease from top to bottom.
Why alkaline earth metals are less reactive
When group II metals react they have to give up two outer electrons to obtain a full outer
shell.This is more difficult than losing just one electron,so they are less reactive than group I
metals.But as the atoms get bigger it gets easier to lose the two electrons,so the metals get
more reactive as you go down the group.This was also the trend in group I.Groups I and II share
two trends:increasing reactivity down the group,and an overall decrease in melting and boiling
points as you go down the group.
Group VII-The halogens
The Group VII elements include fluorine,Chlorine,bromine,iodine and astatine. Chlorine, bromine
and iodine are the most common halogens.
Trends within group VII
ATOM ELEMENT Reactivity Melts at...OC Boils at...OC melting and
19
9 F Fluorine(pale yellow gas) decreases -220 -188 boiling
35
17 Cl chlorine(green gas) as atoms get -101 -35 points
80
35Br bromine (red liquid) larger -7 59 increase
127
53I iodine (black solid) 114 184
Melting and boiling points increase down the group because the attraction between
molecules increases .More energy is needed to help them escape from the solid to form
liquid, and from the liquid to form gas.
Reactivity decreases down the group because of size.A halogen atom is able to attract an
extra electron into its outer shell because of the positive charge on the nucleus.(opposite
charges attract).But as the atoms get bigger,their outer shells get further away from the
nucleus.The force of attraction gets less.So the element gets less reactive.
Periodic trends.
The trend in reactivity across period 3
Group I II III IV V VI VII VIII
Element Sodium Magnesium aluminium silicon phosphorus sulphur chlorine argon
Outer 1 2 3 4 5 6 7 8
electrons
Element Metal Metal metal metalloid nonmetal nonmetal nonmetal nonmetal
is..
Reactivity High High high Low Low Low high unreactive
Melting 98 649 660 1410 590 119 -101 -189
O
point/ C
Boiling 883 1107 2467 2355 Ignites 445 -35 -186
point/OC
Oxide Na2O MgO Al2O3 SiO2 P2O5 SO3 Cl2O7 none
formed
Oxide is.. Basic Basic amphoteric Acidic Acidic acidic acidic -
If you look at the properties of the elements across a period of the Periodic Table you will notice certain
trends. For example, there is:
an increase in the number of electrons in the outer energy level of the element. Moving across
the periodic table, elements gain electrons.The number of outer shell electrons increases by 1
each time-like the group number. By argon (group O), the shell is full.
The physical properties of elements such as the melting point (m.p), boiling point (b.p) and
density vary as their atomic numbers (Z) increases across a period from left to right. The melting
and boiling points increase to the middle of the period, then decrease.They are lowest on the
right. However, there are some anomalies to this pattern, such as the high boiling points and
density of aluminium and the very low melting points of chlorine and argon (they are gases at
room temperature).
the atomic radius decreases steadily as the atomic number increases from Group I to Group
VII.The steady increase in nuclear charge pulls all electrons closer to the nucleus.This is
because the nuclear charge becomes increasingly positive as the number of protons in the
nucleus increases.Although the number of electrons also increases,the outer electrons are all
in the same shell.This means that they are attracted more strongly to the nucleus,thus
reducing the atomic radius across a period.
a gradual change from metal to non-metal.Silicon is in between, like a metal in some way and a
non metal in others.It is called a metalloid.
all the elements except argon react with oxygen to form oxides.The ratio of oxygen atoms to
metal atoms in the oxides increases steadily across the period.
the oxides on the left are basic which means they react with acids to form salts.Those on the
right are acidic-they react with alkalis to form salts.Aluminium oxide is in between-It reacts with
both acids and alkalis to form salts.It is called an amphoteric oxide.
The patterns seen across period 3 are seen across other periods too.This recurrence of the same pattern
is called periodicity.
Physical and chemical properties of elements
Group I-the alkali metals
Physical properties
The group I elements are highly reactive and do not occur in nature in their elemental form.The
first three elements of group I are lithium,sodium and potassium.All three:
are soft metals that can be cut with a knife.
are so light( low densities ),they float on water.
are silvery and shiny when freshly cut,but quickly tarnish.
have low melting and boiling points compared with other metals.
they are all metals .
they are all conductors of electricity and heat.
they are ductile(drawn into wires) and malleable(bent or hammered into shape).
All alkali metal compounds are soluble in water.
Chemical Properties
1. All the Group I metals are so reactive that they must be stored under oil to prevent reaction
with air or water.
the alkali metals tarnish rapidly in air.
they react vigorously with water at room temperature.The reactions are usually carried out
in a glass trough.Observations are:
i) the metal moves around and floats on the surface of the water.
ii) the reaction produces heat which causes the metal to melt as it reacts.
iii) bubbles of hydrogen gas are given off
iv) the metal rapidly disappears,forming a colourless solution of alkaline metal hydroxide.
The equation for the reaction with sodium is
2Na(s) + 2H2O (l) → 2NaOH (aq) + H2 (g)
Lithium floats and reacts steadily(less vigorously) with water and sodium reacts vigorously
with water. The exothermic reaction melts the metal and the hydrogen released causes it
shoots across the surface of the water.Potassium bursts (ignites) into flames(lilac) when in
contact with water forming potassium hydroxide and hydrogen.Rubdium and caesium
reacts explosively, shattering its glass container.
2. Alkali metals burn in air (oxygen) to form the metal oxides, metal peroxide and superoxides. For
example:
Li(s) + O2(g) → Li2O(s)
4Na(s) + O2(g) → 2Na2O(s) sodium oxide
2Na(s) + O2(g) → Na2O2(s) sodium peroxide
4K(s) + O2(g) → 2K2O(s) potassium oxide
2K(s) + O2(g) → K2O2(s) potassium peroxide
K(s) + O2(g) → KO2(s) potassium superoxide
Lithium burns brightly with crimson flame, sodium burns brightly with yellow flame and
potassium burns brightly with lilac flame.
NOTE:
i) All the Group I metals from sodium to caesium form peroxides.
ii) The Group I metals from potassium to caesium also form superoxides.
3. They burn quickly in chlorine with a bright flame.Potassium burns fastest and sodium
next.White solids are left behind.These solids are potassium, sodium and lithium chlorides.
Example: 2Na(s) + Cl2 (g) → 2NaCl(s)
4. The group I hydroxides and carbonates are both soluble and stable to heat: they melt at high
temperatures.Lithium hydroxide decomposes at around 650OC.
2LiOH(s) → Li2O(s) + H2O (g)
Sodium hydroxide is very soluble in water forming a strongly alkaline solution.The solid
hydroxide is stable to heat: it melts but does not decompose.
NaOH(s) →NaOH (l)
Sodium carbonate is soluble in water and stable to heat: it melts but does not decompose.
Na2CO3(s) → Na2CO3 (l)
Of the Group I carbonates, only lithium carbonate decomposes on heating, giving carbon dioxide
and lithium oxide:
Li2CO3(s) →CO2 (g) + Li2O(s)
However, sodium hydrogecarbonate, NaHCO3, is weakly alkaline in water.It decomposes when
heated:
2NaHCO3(s) →Na2CO3(s) + H2O (g) + CO2 (g)
5. The group I metal oxides are soluble in water.They do not simply dissolve in water,they react
with it.For example,sodium oxide reacts with water to form aqueous sodium hydroxide:
Na2O(s) + H2O (l) → 2NaOH (aq)
Group I metal oxides are ionic, and it is the oxide ion that reacts to form the hydroxide ion:
O2-(s) +H2O (l) → 2OH-(aq)
The resulting solutions are strongly basic because they contain a high concentration of the
aqueous hydroxide ion.
6. All group I sulphates are soluble in water.
They show a gradual change from a gas through a liquid to a solid.The change in physical
state from gas to liquid to solid down the group indicates an increase in melting and
boiling points and density down the group(due to an increase in the strength of
intermolecular forces)
(He,Ne, Ar, Kr, Xe, and Rn) exist in nature as single atoms. For this reason, they are
called monatomic (meaning a single atom) gases.
The Group VIII elements are inorder of increasing atomic number.These elements are all:
i) non metals
ii) colourless gases at room temperature(they occur naturally in air)
iii) monatomic-they exist as individual atoms because their atoms all have a full outer shell of
electrons and do not form covalent bonds with other Group VIII atoms to form diatomic molecules.
Physical Properties
The elements have similar properties because their atoms have full outer electron shells(a
complete octet) except Helium.As a result,they show a great reluctance to combine with any other
elements.The atoms do not interact to form molecules as in the case of O2,N2,H2 etc.They are
therefore the only gases that exist as separate atoms.A full outer electron shell makes an atom
unreactive.The noble gases are unreactive because their atoms already have full outer electron
shells.
The melting and boiling points of the noble gases are extremely low.The boiling points of the noble
gases increase as their atomic number increases down Group VIII.
As you go down Group VIII, the density of the gases increases.The density increases because the
mass of the atoms increases.
ELEMENT SYMBOL M.p./OC B.p./OC
Helium He -272 -269
Neon Ne -249 -246
Argon Ar -189 -186
Krypton Kr -157 -152
Xenon Xe -112 -108
Radon Rn -71 -62
Helium, neon and argon are inert; they do not form compounds.However, Xenon and to a much
lesser extent, krypton form compounds with the highly electronegative elements fluorine and
oxygen.Examples include XeF2, XeF4 and XeF6 together with XeO3 and XeOF2.Compounds of krypton
consists mainly of fluorine such as the colourless solid KrF2.
Helium is obtained by fractional distillation of liquid air.Most commercial helium comes from
natural gas and petroleum.
Argon is the most abundant noble gas (≈ 1%) in the atmosphere.Argon (neon, krypton and xenon)
are separated from the atmosphere by fractional distillation of liquid air.
Radon is a radioactive alpha emitter formed from the radioactive decay of heavy nuclides such as
238
U.
Uses of the noble gases
Because they are unreactive, many of the inert gases are very useful:
1. Helium:
to fill weather balloons and airships because it has very low density and not flammable.
Mixing with oxygen (80% helium and 20% oxygen)to form a gas for divers to breathe.
The reason for this is that if a diver breathes normal air, nitrogen dissolves in the blood
and can cause a dangerous problem called nitrogen narcosis in which the diver has
symptoms similar to drunkenness.
low temperature research because of its low boiling point.
to inflate the tyres of large aircraft.
as a coolant in nuclear reactors.
to provide an inert atmosphere for welding
in the helium – neon laser
2. Neon
This is used in fluorescent lights.When an electric current is passed through neon,
it give off of a bright light(it glows red). The advertising signs in our towns are filled with
neon.
in the helium-neon gas laser
in Geiger – Muller tubes,which are used for the detection of radioactivity.
3. Argon
to fill ordinary light bulbs to prevent the tungsten filament from reacting with oxygen
in the air and forming the oxide.
to provide an inert atmosphere in the arc welding.
in titanium production.
in silicon and germanium zone refining.
4. Krypton
in lamps used in photographic flash units
in stroboscopic lamps
in lamps used in lighthouses.
Krypton is used in lasers,which produce very intense beams of light.Krypton lasers
are used in eye surgery,to prevent bleeding on your retina.The laser is directed to
the points where bleeding might occur.The intense light makes blood clot.
5. Xenon
in fluorescent lights.This works like neon but the light is very bright and much like
daylight.Xenon lights are used in car headlights,but only more expensive cars because
xenon is expensive.Xenon strobe lights are used in discos.
NOTE:
Radon is an inert gas that is radioactive.It is slowly given off by certain rocks such as granite.
Houses built on granite can build up dangerous levels of radon in the room if they are not well
ventilated.If too much radon is breathed in,it can cause lung cancer.