This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what

changes have been made to the previous version. Because

it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.

Designation: E694 − 99 (Reapproved 2010) E694 − 18

Standard Specification for

Laboratory Glass Volumetric Apparatus1
This standard is issued under the fixed designation E694; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.

1. Scope
1.1 This specification covers general requirements common to glass volumetric apparatus. Specific dimensions and tolerances
for applicable instruments are given in other specifications as cited throughout this specification. Glass must conform to
Specifications E438 and be calibrated in accordance with Practice E542.
1.1.1 Class A—Each instrument shall be marked with the letter A to signify compliance with applicable construction and
accuracy requirements. Instruments may be marked with an identification marker (serial number) at the option of the manufacturer.
1.1.2 Class B—General purpose instruments are of the same basic design as Class A. However, volumetric tolerances for Class
B instruments shall be within twice the specified range allowed for Class A unless otherwise specified.
1.2 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

2. Referenced Documents
2.1 ASTM Standards:2
iTeh Standards
(https://standards.iteh.ai)
C188 Test Method for Density of Hydraulic Cement
E237 Specification for Laboratory Glass Microvolumetric Vessels (Volumetric Flasks and Centrifuge Tubes)

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E287 Specification for Laboratory Glass Graduated Burets
E288 Specification for Laboratory Glass Volumetric Flasks
E438 Specification for Glasses in Laboratory Apparatus
E542 Practice for Calibration of Laboratory Volumetric Apparatus
E671 Specification for Maximum Permissible Thermal ASTM E694-18
Residual Stress in Annealed Glass Laboratory Apparatus
E675 Specification for Interchangeable Taper-Ground Stopcocks And Stoppers
https://standards.iteh.ai/catalog/standards/sist/7ce12635-11b3-4e22-857b-9527772adf5b/astm-e694-18
E676 Specification for Interchangeable Taper-Ground Joints
E788 Specification for Pipet, Blood Diluting
E911 Specification for Glass Stopcocks with Polytetrafluoroethylene (PTFE) Plugs
E969 Specification for Glass Volumetric (Transfer) Pipets
E1045 Specification for Pipet, Sahli Hemoglobin
E1272 Specification for Laboratory Glass Graduated Cylinders
E1878 Specification for Laboratory Glass Volumetric Flasks, Special Use

3. General Requirements
3.1 Units of Volume—The unit of volume shall be the cubic centimetre (cm3) or, in special cases, the cubic decimetre (dm3) or
cubic millimetre (mm3).
NOTE 1—The term millilitre (mL) is commonly used as a special name for the cubic centimetre (cm3) and, similarly the litre for the cubic decimetre
(dm3) and the microlitre (µL) for the cubic millimetre (mm3), in accordance with the International System of Units (SI).

1
This specification is under the jurisdiction of ASTM Committee E41 on Laboratory Apparatus and is the direct responsibility of Subcommittee E41.01 on
ApparatusLaboratory Ware and Supplies.
Current edition approved July 1, 2010Jan. 1, 2018. Published July 2010January 2018. Originally approved in 1979. Last previous edition approved in 20052010 as
E694 – 99 (2005).(2010). DOI: 10.1520/E0694-99R10.10.1520/E0694-18.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [email protected]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

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 E694 − 18
3.2 Standard Temperature—The standard reference temperature, that is, the temperature at which the article of volumetric
glassware is intended to contain or deliver its nominal volume (nominal capacity), shall be 20°C.
NOTE 2—When it is necessary in tropical countries to work at an ambient temperature considerably above 20°C, and it is not desired to use the standard
reference temperature of 20°C, it is recommended that a temperature of 27°C be adopted.
3.3 Material and Annealing—Volumetric glassware shall be constructed of glass of suitable chemical and thermal properties.
It shall be as free as possible from visible defects and shall conform to Specification E671.
3.4 Limit of Error—On an article having multiple graduation lines, the limit of volumetric error may occur at any graduation
line unless otherwise specified. For example, on a 100-mL graduated cylinder having a limit of error of 61.00 mL, the volume
at 10 mL could range from 9.00 to 11.00 mL.
NOTE 3—The limit of volumetric error specified for any article designed for delivery shall not be less than four times the standard deviation determined
experimentally by an experienced operator from a series of at least twenty replicate determinations of delivered capacity on the same article, carried out
strictly in accordance with the method specified for that article.
3.5 Stability—Vessels provided with a flat base shall stand firmly thereon without rocking when placed on a level surface and,
unless specified otherwise, the axis of the graduated portion of the vessel should be vertical. Except for special cases, vessels shall
not topple when placed empty and without a stopper on a surface inclined at an angle to the horizontal of 15° for sizes 25 cm3or
greater and 10° for vessels less than 25 cm3. Vessels provided with a base that is not circular shall meet this requirement in all
directions.
3.6 Stoppers and Stopcocks:
3.6.1 Stoppers—Glass stoppers should be ground so as to be interchangeable, in which case the ground portions shall be in
accordance with Specification E675. Stoppers of a suitable inert plastics material may be permitted as an alternative to glass. In
such cases, the glass socket into which the stopper fits shall be in accordance with Specification E675. All stoppers shall bear a
proper size identification.

iTeh Standards
3.6.2 Stopcocks—Stopcocks and similar devices shall be designed to permit smooth and precise control of outflow and to
prevent a rate of leakage greater than that allowed in the specification for the article and shall be in accordance with Specification
E675. Stopcocks shall be made from glass or from suitable inert plastics material.
3.7 Graduation Lines: (https://standards.iteh.ai)
3.7.1 Graduation lines shall be clean, permanent lines of uniform vertical thickness. This thickness shall be 0.2–0.6 mm for
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articles not having a scale. On articles having a scale, the specified thickness of the lines shall be 0.2–0.4 mm. All graduation lines
shall lie in planes at right angles to the longitudinal axis of the graduated portion of the article. On articles provided with a flat
base, the graduation lines shall therefore lie in planes parallel to the base.
3.7.2 In general, graduation lines should be confinedASTM
to cylindrical portions of an article’s cross section and should preferably
E694-18
be situated not less than 10 mm from any change in diameter. In special circumstances, preferably for Class B articles only,
https://standards.iteh.ai/catalog/standards/sist/7ce12635-11b3-4e22-857b-9527772adf5b/astm-e694-18
graduation lines may be provided on a parallel side portion of noncircular cross section or on a conical or tapered portion of the
article.
3.7.3 On articles not having a scale, all graduation lines should extend completely around the circumference of the article,
except that a gap, not exceeding 10 % of the circumference, may be permitted. In the case of an article that is restricted as to the
normal direction of viewing in use, the gap should be at the right or left of the normal direction of view.
3.8 Spacing of Graduation Lines—There should be no evident irregularity spacing of graduation lines (except in special cases
where the scale is on a conical or tapered portion of the article and a change of subdivision takes place). The minimum distance,
L, between the centers of adjacent graduation lines shall be not less, in relation to diameter, than that calculated as follows:
L 5 ~0.810.02D ! (1)

where D is the maximum permitted internal diameter of the tube in millimetres (see also Annex A1).
3.9 Length of Graduation Lines (see Fig. 1)—On articles of circular cross section having a scale, the length of the graduation
lines shall be varied so as to be clearly distinguishable and shall be in accordance with the following provisions:
3.9.1 Graduation Pattern I:
3.9.1.1 The length of the short lines should be approximately, but not less than, 50 % of the circumference of the article.
3.9.1.2 The length of the medium lines should be approximately 65 % of the circumference of the article and should extend
symmetrically at each end beyond the end of the short lines.
3.9.1.3 The long lines should extend completely around the circumference of the article, but a gap, not exceeding 10 % of the
circumference, may be permitted (see 3.6).
3.9.2 Graduation Pattern II:
3.9.2.1 The length of the short lines should be not less than 10 % and not more than 20 % of the circumference of the article.
3.9.2.2 The length of the medium lines should be approximately 1.5 times the length of the short lines and should extend
symmetrically at each end beyond the end of the short lines.

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 E694 − 18

FIG. 1 Position of Graduation Lines

3.9.2.3 The long lines should extend completely around the circumference of the article, but a gap, not exceeding 10 % of the
circumference, may be permitted (see 3.6).
3.9.3 Graduation Pattern III:
3.9.3.1 The length of the short lines should not be less than 10 % and not more than 20 % of the circumference of the article.
3.9.3.2 The length of the medium lines should be approximately 1.5 times the length of the short lines and should extend
symmetrically at each end beyond the ends of the short lines.
3.9.3.3 The length of the long lines should be not less than twice the length of the short lines and should extend symmetrically
at each end beyond the ends of the short and medium lines.
3.9.4 In special cases where scales are required on noncircular cross section or conical or tapered portions of an article, the

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requirements of 3.8.1, 3.8.2, or 3.8.3 should be modified appropriately.
3.10 Sequence of Graduation Lines (see Fig. 2):
3.10.1 On articles in which the volume equivalent of the smallest scale division is millilitre (or a decimal multiple or
submultiple thereof): (https://standards.iteh.ai)
3.10.1.1 Every tenth graduation line is a long line;
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3.10.1.2 There is a medium line midway between two consecutive long lines; and
3.10.1.3 There are four short lines between consecutive medium and long lines.
3.10.2 On articles in which the volume equivalent of the smallest scale division is 2 mL (or a decimal multiple or submultiple
thereof):
ASTM E694-18
3.10.2.1 Every fifth graduation line is a long line; and
https://standards.iteh.ai/catalog/standards/sist/7ce12635-11b3-4e22-857b-9527772adf5b/astm-e694-18
3.10.2.2 There are four short lines between two consecutive long lines.
3.10.3 On articles in which the volume equivalent of the smallest scale division is 5 mL (or a decimal multiple or submultiple
thereof):
3.10.3.1 Every tenth graduation line is a long line;
3.10.3.2 There are four medium lines equally spaced between two consecutive long lines; and
3.10.3.3 There is one short line between two consecutive medium lines or between consecutive medium and long lines.

FIG. 2 Length and Sequence of Graduation Lines

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3.11 Position of Graduation Lines (see Fig. 1):
3.11.1 On articles graduated according to Pattern I with vertical scales in accordance with 3.9.1, the ends of the short graduation
lines shall lie on an imaginary vertical line down the center of the front of the article, the lines themselves extending preferably
to the left when the article is viewed from the front in the position of normal use.
3.11.2 On articles graduated according to Pattern II or III, with vertical scales in accordance with 3.9.2 or 3.9.3, the midpoints
of the short and medium graduation lines shall lie on an imaginary vertical line down the center of the front of the article, when
the article is viewed from the front in the position of normal use.
3.12 Two scales are not permitted on the same piece of apparatus. For example, apparatus should not be graduated in both fluid
ounces and millilitres (cubic centimetres). In the case of two units, one of which is an exact multiple of the other, such, for example,
as drams and fluid ounces, there is no objective to having the 8-dr line, 16-dr line, etc., marked respectively, 1 fluid oz, 2 fluid oz,
etc., provided that the two series of numbers are placed on opposite sides of the apparatus and the value of each subdivision is
suitably indicated.
3.13 Figuring of Graduation Lines:
3.13.1 On articles with one graduation line, the number representing nominal capacity may be included with the other
inscriptions and need not be adjacent to the graduation line.
3.13.2 On articles having two or three graduation lines, the numbers representing nominal capacity need not be adjacent to the
lines to which they relate, if some other more suitable method of identification is used.
3.13.3 On articles having one principal graduation line and a small number of subsidiary lines, the number representing the
principal capacity may be included with the other inscriptions as in 3.13.1 provided that the subsidiary graduation lines are suitably
identified.
3.13.4 On Articles Having a Scale:
3.13.4.1 The scale shall be figured so as to enable the value corresponding to each graduation line to be identified readily;
3.13.4.2 The scale should have normally only one set of figures;
3.13.4.3 At least every tenth line shall be figured;
iTeh Standards
3.13.4.4 Figures shall be confined to long graduation lines and should be placed immediately above the line and slightly to the
right of the adjacent shorter graduation lines; and

(https://standards.iteh.ai)
NOTE 4—Where long lines complying with 3.9.2 are used (that is, those lines not extending completely around the article), an alternative scheme of
figuring may be permitted, in which the figure is placed slightly to the right of the end of the long line in such a way that an extension of the line would

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bisect it.
3.13.4.5 Where it is necessary in special cases to use a number relating to a medium or short graduation line, the number should
be placed slightly to the right of the end of the line in such a way that an extension of the line would bisect it.
3.14 Inscriptions:
ASTM E694-18
3.14.1 Every instrument shall bear in permanent legible characters the capacity, the temperature at which it is to be used, the
methodhttps://standards.iteh.ai/catalog/standards/sist/7ce12635-11b3-4e22-857b-9527772adf5b/astm-e694-18
of use (that is, whether to contain or to deliver), and on instruments that deliver through an outflow nozzle, the time
required to empty the total nominal capacity with unrestricted outflow. The inscriptions may be engraved or printed provided such
marking is neat and clear. Grit-blasted serial numbers will be permitted with the same provision. Every instrument shall bear the
name or trademark of the maker. Every Class A instrument may bear the symbol A. Serial numbers may be marked on each
instrument at the option of the manufacturer and detachable parts, such as stoppers, stopcocks, etc., belonging thereto, if not
interchangeably ground, shall bear the same number. Interchangeable ground-glass parts shall be marked on both members with
the proper standard taper symbol and the size designation, in accordance with Specification E676. Fig. 3 illustrates several
arrangements of designating marks that are considered suitable. Marks may be placed elsewhere on apparatus if they are easily
readable and do not interfere with the proper use of the apparatus.
3.14.2 In the case of a special-purpose article of volumetric glassware that is to be graduated for direct reading of capacity when
used with a specific liquid other than water, the specification should also indicate the corresponding capacity when used to disperse
pure water so that the latter can be used for verification.

4. Special Requirements
4.1 Volumetric Flasks—The limiting dimensions for volumetric flasks are given in Specification E288. For flasks smaller than
5-mL capacity, the limits shall be as shown in Specification E237.
4.1.1 Stoppers or Closures—Stoppers may be either glass or plastic as desired by the user and shall conform to Specification
E675. As an alternative, the flasks may have reinforced rims or screw threads for acceptance of cap style closures.
4.1.2 Intermediate Bulb-Style Flasks—The limiting dimensions for bulb style flasks are given in Specification E288.
4.1.3 Dual-Purpose Flask—A flask may be graduated both to contain and to deliver, provided the intention of the different
marks is clearly indicated and provided the distance between the two marks is not less than 1 mm.
4.1.4 Special-Purpose Volumetric Flasks—Certain types of special-purpose volumetric flasks, such as the Engler or Saybolt
viscosity flasks and the Kohlrausch and Stift sugar flasks, while not in conformity with all the special requirements for volumetric
flasks listed in 4.1 because of their specific applications, will be considered Class A if they are in satisfactory conformity with the