Technical Information

Orbipac CPF81/CPF82 and CPF81D/CPF82D

Compact pH/ORP electrodes, analog or with digital Memosens
technology
For installation or immersion in industrial water and wastewater

Application
• Industrial and municipal wastewater treatment
• Water conditioning
• Condensate cleaning

Your benefits
• Suitable for flow and immersion installation
• Suitable for measurement within pH range 0 to 14 pH and
temperature range 0 to 110 °C (32 to 230 °F)
• Analog pH electrodes with or without integrated temperature
sensor, digital pH sensors with integrated temperature sensor
• With patented KNO3 electrolyte bridge for better protection
against electrode poisons like S2- or CN- ions
• Protection guard against damage
• Flat membrane suitable for high flow rates and fibrous media
• Optional integrated preamplifier for low-impedance and
noise-free measuring value transmission
• NPT ¾" threaded connection, top and bottom
Further benefits offered by Memosens technology
• Maximum process safety through contactless inductive signal
transmission
• Data safety through digital data transmission
• Easy handling thanks to storage of sensor-specific data in the
sensor
• Predictive maintenance possible thanks to registration of
sensor load data in the sensor

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Function and system design

Measuring principle pH measurement
The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The membrane
glass of the electrode supplies an electrochemical potential which is dependent upon the pH value of the
medium. This potential is generated by the selective penetration of H+ ions through the outer layer of the
membrane. An electrochemical boundary layer with an electric potential forms at this point. An integrated
Ag/AgCl reference system serves as reference electrode.
The transmitter converts the measured voltage into the corresponding pH value using the Nernst equation.
ORP measurement
The ORP potential is a unit of measurement for the state of equilibria between oxidizing and reducing
components of a medium. ORP potential is measured similarly to the pH value. A platinum electrode is used
instead of pH-sensitive membrane glass. Analog to the pH measurement, an integrated Ag/AgCl reference
system is used as a reference electrode.

Important properties of Maximum process safety

CPF81D/CPF82D The inductive and non-contacting measured value transmission of Memosens guarantees maximum process
safety and offers the following benefits:
• All problems caused by moisture are eliminated.
– The plug-in connection is non-contacting and therefore free from corrosion.
– Measured value distortion from moisture is not possible.
– The plug-in system can even be connected under water.
• The transmitter is galvanically decoupled from the medium. The result: No more need to ask about
"symmetrically high-impedance" or "unsymmetrical" (for pH/ORP measurement) or an impedance
converter.
• EMC safety is guaranteed by screening measures for the digital measured value transmission.
Data safety through digital data transfer
The Memosens technology digitalizes the measured values in the sensor and transfers them to the transmitter
contactlessly and free from interference potential. The result:
• An automatic error message is generated if the sensor fails or the connection between sensor and transmitter
is interrupted.
• The availability of the measuring point is dramatically increased by immediate error detection.
Easy handling
Sensors with Memosens technology have integrated electronics that allow for saving calibration data and
further information such as total hours of operation and operating hours under extreme measuring conditions.
When the sensor is mounted, the calibration data are automatically transferred to the transmitter and used to
calculate the current measured value. Storing the calibration data in the sensor allows for calibration away from
the measuring point. The result:
• Maintenance intervals can be defined based on all stored sensor load and calibration data and predictive
maintenance is possible.
• The sensor history can be documented on external data carriers and evaluation programs at any time. Thus,
the current application of the sensors can be made to depend on their previous history.
• The transmitter does not need to be installed close to the measuring point but can be placed in the control
room.
Communication with the transmitter
Always connect digital sensors to a transmitter with Memosens technology. Data transmission to a transmitter
for analog sensors is not possible.

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Data storage CPF81D

The digital sensors are able to store the following system data in the sensor.
• Manufacturing data
– Serial number
– Order code
– Date of manufacture
• Calibration data
– Calibration date
– Calibrated slope at 25 °C (77 °F)
– Calibrated zero point at 25 °C (77 °F)
– Temperature offset
– Number of calibrations
– Serial number of the transmitter used for the last calibration
• Application data
– Temperature application range
– pH application range
– Date of first commissioning
– Maximum temperature value
– Total operating hours
– Operating hours at temperatures above 80 °C (176 °F) and 100 °C (212 °F)
– Operating hours at very low and very high pH values (Nernst voltage below -300 mV, above +300 mV)
– Glass membrane impedance
These system data can be displayed with Mycom S CPM153 and Liquiline M CM42 transmitters.

CPF82D
The digital sensors are able to store the following system data in the sensor.
• Manufacturing data
– Serial number
– Order code
– Date of manufacture
• Calibration data
– Calibration date
– Calibrated offset (operating mode "mV")
– % slope (operating mode "%")
– Number of calibrations
– Serial number of the transmitter used for the last calibration
• Application data
– Temperature application range
– ORP application range
– Date of first commissioning
– Operating hours
These system data can be displayed with Mycom S CPM153 or Liquiline M CM42 transmitters.

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Input
Measured values CPF81, CPF81D: pH value
Temperature
CPF82, CPF82D: ORP potential

Measuring range CPF81/81D

Electrode version LH
pH: 0 to 14 pH
Temperature: 0 to 110 °C (32 to 230 °F)
Electrode version NN
pH: 0 to 14 pH (reduced accuracy for 11 to 14 pH)
Temperature: 0 to 80 °C (32 to 176 °F)

CPF82/82D
ORP potential: -1500 mV to +1500 mV

Caution!
Please note the process operating conditions.

Cable specification CPF81/82 with fixed cable

A BK BK B
Reference
BK BK
pH/ORP
GN
Temperature
WH
Temperature GN
YE
Temperature
GN/YE GN/YE WH
Outer screen YE
BN BN
PM / n. c.*
a0010182-en

Measuring cable
A Fixed cable for CPF81 without temperature sensor and CPF82
B Fixed cable for CPF81 with temperature sensor
* PM is only connected for sensor versions with internal solution ground (CPF81-xxx2xx).

CPF81/82 with TOP68 plug-in head

PM Coax BK Ref.
WH pH
pH/ORP
+ Pt 100 GN Temp
WH Temp.
Screen connection YE Temp.
BN PM
a0003303-en

CPK9 special measuring cable

CPF81D/82D

a0003350

CYK10 Memosens data cable

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Installation
Installation instructions The electrode is suitable for flow and immersion installation.

a0010183 a0010184

Flow installation Immersion installation with Flowfit CYA611

Note!
Make sure to follow the installation instructions in the Operating Instructions of the used assembly.

Environment
Ambient temperature Caution!
Danger of frost damage
Do not use the electrodes at temperatures below 0 °C (32 °F.)

Storage temperature 0 to 50 °C (32 to 122 °F)

Ingress protection Fixed-cable version: IP 67

TOP68 plug-in head: IP 68 (1 m (3.28 ft) water column, 50 °C (122 °F), 168 h)
Memosens plug-in head: IP 68 (10 m (32.8 ft) water column, 25 °C (77 °F), 45 days, 1 M KCl)

Process
Process temperature CPF81/81D
Electrode version LH: 0 to 110 °C (32 to 230 °F)
Electrode version NN: 0 to 80 °C (32 to 176 °F)
CPF82/82D 0 to 80 °C (32 to 176 °F)

Process pressure 0 to 10 bar @ 80 °C (0 to 145 psi @ 176 °F)

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Pressure temperature load

psi bar
curve
145 10
120 8
6
80
50.8
4
3.5
40
2
0 0
0 20 40 60 80 100 110 °C
176 230
32 60 100 140 180 220 °F
a0010185

Glass impedance 150 MΩ @ 25 °C (77 °F )

Minimum conductivity min. 50 μS/cm

Mechanical construction
Design, dimensions
CPF81/82 mm (inch)
mm (inch)
mm (inch)

1 1
1

2 2
2

3 3
3
150 (5.91)
140 (5.51)
150 (5.91)

2 2
2
12.5 (0.49)
23 (0.91)

4 4
4
58.5 (2.3)

Ø 22 (0.87)
Ø 22 (0.87) Ø 22 (0.87)
a0010179 a0010180 a0010181

Fixed-cable version, short shaft, CPF81 with TOP68 plug-in head, Fixed-cable version, long shaft,
protection guard short shaft, flat membrane protection guard
1 Fixed cable 1 TOP68 plug-in head 1 Fixed cable
2 NPT ¾" thread 2 NPT ¾" thread 2 NPT ¾" thread
3 Across flats AF 26 3 Across flats AF 26 3 Across flats AF 26
4 Protection guard 4 Flat membrane 4 Protection guard

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Design, dimensions
CPF81D/82D mm (inch) mm (inch)

35 (1.38)

35 (1.38)
mm (inch)

35 (1.38)
1 1
1

2 2
2

3 3
150 (5.91)

150 (5.91)
3

140 (5.51)
2 2
2
23 (0.91)

12.5 (0.49)
4

58.5 (2.3)
4
4

Ø 22 (0.87) Ø 22 (0.87) Ø 22 (0.87)

a0010174 a0010171 a0010173

CPF82D, short shaft, protection guard CPF81D, flat membrane CPF81D, long shaft, protection guard
1 Memosens plug-in head 1 Memosens plug-in head 1 Memosens plug-in head
2 NPT ¾" thread 2 NPT ¾" thread 2 NPT ¾" thread
3 Across flats AF 26 3 Across flats AF 26 3 Across flats AF 26
4 Platinum ring 4 Flat membrane 4 Protection guard
5 Protection guard

Material Housing, electrode shaft: PPS

pH electrode (in contact with medium): lead-free membrane glass, suitable for process applications
ORP electrode (in contact with medium): platinum ring
Double chamber reference system: KNO3 and KCl/AgCl

Process connection NPT ¾" thread

Integrated preamplifier Design: cast in sensor body

(if ordered) Power supply: via integrated coin cells
Reference potential: reference electrode
Note!
With preamplifier versions, the sensor check function (SCS) of the transmitter is not available and should be
turned off.

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Ordering information
Product structure CPF81 Application range
LH pH 0 to 14, T = 0 to 110 °C (32 to 230 °F)
NN pH 0 to 11, T = 0 to 80 °C (32 to 176 °F)

Version
1 Insertion length 23 mm (0.91") with protection guard
2 Insertion length 12.5 mm (0.51") with flat membrane
3 Insertion length 58.5 mm (2.28") with protection guard

Process connection
1 NPT ¾"
2 NPT ¾" with integrated solution ground

Equipment
A No preamplifier, no Pt 100
B With preamplifier, no Pt 100
C No preamplifier, with Pt 100
D With preamplifier, with Pt 100

Cable connection
2 4.5 m (15 ft) fixed cable
3 9 m (30 ft) fixed cable
4 13 m (45 ft) fixed cable
8 TOP68/ESA plug-in head

CPF81- complete order code

Product structure CPF82 Application range

PA ORP, platinum ring, 0 to 80 °C (32 to 176 °F)

Version
1 Insertion length 23 mm (0.91") with protection guard
3 Insertion length 58.5 mm (2.28") with protection guard

Process connection
1 NPT ¾"

Equipment
A No preamplifier
B With preamplifier

Cable connection
2 4.5 m (15 ft) fixed cable
3 9 m (30 ft) fixed cable
4 13 m (45 ft) fixed cable
8 TOP68/ESA plug-in head

CPF82- complete order code

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Product structure CPF81D Version

7 Basic version

Application range
LH 0 to 14 pH; 0 to 110 °C (32 to 230 °F)
NN 0 to 11 pH; 0 to 80 °C (32 to 176 °F)

Insertion length
1 23 mm (0.91") + electrode guard
2 13 mm (0.51"); flat membrane
3 58 mm (2.28") + electrode guard

Approval
1 Non-hazardous area

CPF81D- complete order code

Product structure CPF82D Version

7 Basic version

Application range
PA ORP, platinum, 0 to 80 °C (32 to 176 °F)

Insertion length
1 23 mm (0.91") + electrode guard
3 58 mm (2.28") + electrode guard

Approval
1 Non-hazardous area

CPF82D- complete order code

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Accessories
Note!
In the following sections, you find the accessories available at the time of issue of this documentation.
For information on accessories that are not listed here, please contact your local service.

Transmitters Liquiline M CM42

• Modular two-wire transmitter, stainless steel or plastic, field or panel instrument,
• various Ex approvals (ATEX, FM, CSA, Nepsi, TIIS),
• HART, PROFIBUS or FOUNDATION Fieldbus available
• Ordering acc. to product structure, see Technical Information (TI381C/07/en)
Liquisys M CPM223/253
• Transmitter for pH and ORP, field or panel-mounted housing,
• HART or PROFIBUS available
• Ordering acc. to product structure, see Technical Information (TI194C/07/en)
Mycom S CPM153
• Transmitter for pH and ORP, one or two channel version, Ex or non-Ex,
• HART or PROFIBUS available
• Ordering acc. to product structure, see Technical Information (TI233C/07/en)

Assembly Immersion assembly Dipfit W CYA611

• For sensor immersion in basins, open channels and tanks, PVC
• Ordering acc. to product structure, see Technical Information TI166C/07/en

Buffer solutions pH
High-quality buffer solutions of Endress+Hauser - CPY20
The secondary buffer solutions have been referenced to primary reference material of the PTB (German Federal
Physico-technical Institute) and to standard reference material of NIST (National Institute of Standards and
Technology) according to DIN 19266 by a DKD (German Calibration Service) accredited laboratory.

pH value
A pH 2.00 (accuracy ± 0.02 pH)
C pH 4.00 (accuracy ± 0.02 pH)
E pH 7.00 (accuracy ± 0.02 pH)
G pH 9.00 (accuracy ± 0.02 pH)
I pH 9.20 (accuracy ± 0.02 pH)
K pH 10.00 (accuracy ± 0.05 pH)
M pH 12.00 (accuracy ± 0.05 pH)

Quantity
01 20 x 18 ml (0.68 fl.oz) only buffer solutions pH 4.00 and 7.00
02 250 ml (8.45 fl.oz)
10 1000 ml (0.26 US gal)
50 5000 ml (1.32 US gal) canister for Topcal S

Certificates
A Buffer analysis certificate

Version
1 Standard

CPY20- complete order code

ORP
Technical buffer solutions for ORP electrodes
• +220 mV, pH 7.0, 100 ml (3.4 fl.oz.); order no. CPY3-0
• +468 mV, pH 0.1, 100 ml (3.4 fl.oz.); order no. CPY3-1

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Measuring cables CPK9 special measuring cable

• For sensors with TOP68 plug-in head, for high-temperature and high-pressure applications, IP 68
• Ordering acc. to product structure, see Technical Information (TI118C/07/en)
CYK10 Memosens data cable
• For digital sensors with Memosens technology
• Ordering according to product structure, see below
CYK10 product structure
Certificates
A Standard, non Ex
G ATEX II 1G EEx ia IIC T6/T4

Cable length
03 Cable length: 3 m (9.8 ft)
05 Cable length: 5 m (16 ft)
10 Cable length: 10 m (33 ft)
15 Cable length: 15 m (49 ft)
20 Cable length: 20 m (66 ft)
25 Cable length: 25 m (82 ft)
88 ... m length
89 ... ft length

Ready-made
1 Wire terminals

CYK10- complete order code

Endress+Hauser 11
Instruments International

Endress+Hauser
Instruments International AG
Kaegenstrasse 2
4153 Reinach
Switzerland

Tel.+41 61 715 81 00
Fax+41 61 715 25 00
www.endress.com
[email protected]

TI191C/07/en/07.08
Printed in Germany / FM+SGML 6.0 / DT
71078186