Page 1/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 19.08.2021 Revision: 19.08.2021

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: CeTePox® AM 3218, Komp. A
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Epoxy binder
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
CTP Advanced Materials GmbH
Stahlstrasse 60
D-65428 Rüsselsheim

Tel.: +49-6142-91850, Fax: +49-6142-918555, Email: [email protected]

· Informing department: see section 16
· 1.4 Emergency telephone number:
Poison Control Center Mainz - 24 h - Emergency Call: +49 (0)6131 19240

GB: Regional Medicines and Poisons Information Centre 844 892 0111

AU: National Poisons Information Network (Australia-wide) 131126

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Skin Irrit. 2 H315 Causes skin irritation.
Eye Dam. 1 H318 Causes serious eye damage.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS05 GHS07 GHS09

· Signal word Danger

· Hazard-determining components of labelling:
2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)]bisoxirane
blockiertes Polyisocyanat
1,4-bis(2,3-epoxypropoxy)butane
Triethylene glykol dimethacrylate
Cashew (Anacardium occidentale) Nutshell Extract, Decarboxylated, Distilled
methyl methacrylate
· Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves / eye protection / face protection.
(Contd. on page 2)
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Safety data sheet
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Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 1)
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· Additional information:
EUH205 Contains epoxy constituents. May produce an allergic reaction.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Epoxy resin formulation with a bisphenol-A liquid resin base
· Dangerous components:
CAS: 1675-54-3 2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)] 35-60%
EINECS: 216-823-5 bisoxirane
Index number: 603-073-00-2 Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2,
Reg.nr.: 01-2119456619-26- H319; Skin Sens. 1, H317
xxxx
CAS: 2155840-39-2 blockiertes Polyisocyanat 10-20%
Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4,
H312; Skin Irrit. 2, H315; Skin Sens. 1A, H317
CAS: 2425-79-8 1,4-bis(2,3-epoxypropoxy)butane 10-20%
EINECS: 219-371-7 Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4,
Index number: 603-072-00-7 H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Skin Sens.
Reg.nr.: 01-2119494060-45- 1, H317; Aquatic Chronic 3, H412
xxxx
CAS: 109-16-0 Triethylene glykol dimethacrylate 10-20%
Reg.nr.: 01-2119969287-21- Skin Sens. 1, H317
xxxx
CAS: 8007-24-7 Cashew (Anacardium occidentale) Nutshell Extract, ≤2.5%
EC number: 700-991-6 Decarboxylated, Distilled
Reg.nr.: 01-2119502450-57- Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4,
xxxx H312; Skin Irrit. 2, H315; Skin Sens. 1A, H317
CAS: 80-62-6 methyl methacrylate ≤2.5%
EINECS: 201-297-1 Flam. Liq. 2, H225; Skin Irrit. 2, H315; Skin Sens. 1,
Index number: 607-035-00-6 H317; STOT SE 3, H335
· Additional information For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation
Take affected persons into the open air and position comfortably
Seek medical treatment in case of complaints.
· After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing Seek immediate medical advice.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 2)
· Information for doctor No particular measures are known - treat according to symptoms.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: Put on breathing apparatus.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Do not allow to enter the ground/soil.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· 6.4 Reference to other sections Clean the accident area carefully.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
The usual precautionary measures for handling chemicals must be observed.
· Information about protection against explosions and fires: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store only in the original container.
Keep containers securely closed and dry, store frost-free.
Provide floor trough without outlet.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Additional information about design of technical systems: No further data; see item 7.
· Components with limit values that require monitoring at the workplace:
80-62-6 methyl methacrylate
WEL Short-term value: 416 mg/m³, 100 ppm
Long-term value: 208 mg/m³, 50 ppm
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 3)
· DNELs
1675-54-3 2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)]bisoxirane
Dermal DNEL - worker 8.33 mg/kg / bw/d
Inhalative DNEL - worker 12.25 mg/m³
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane
Dermal DNEL - worker 9.26 mg/kg / bw/d
Inhalative DNEL - worker 1.63 mg/m³
8007-24-7 Cashew (Anacardium occidentale) Nutshell Extract, Decarboxylated, Distilled
Dermal DNEL - worker 0.5 mg/kg / bw/d
Inhalative DNEL - worker 0.88 mg/m³
· PNECs
1675-54-3 2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)]bisoxirane
PNEC (predicted no effect concentration) 0.006 mg/l (Frischwasser (freshwater))
0.0006 mg/l (Meerwasser (seawater))
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane
PNEC (predicted no effect concentration) 0.024 mg/l (Frischwasser (freshwater))
0.0024 mg/l (Meerwasser (seawater))
8007-24-7 Cashew (Anacardium occidentale) Nutshell Extract, Decarboxylated, Distilled
PNEC (predicted no effect concentration) 0.003 mg/l (Frischwasser (freshwater))
0.0003 mg/l (Meerwasser (seawater))
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
· Breathing equipment: Use breathing protection in case of insufficient ventilation.
· Recommended filter device for short term use:

Combination filter A-P2

· Protection of hands:

Plastic gloves

Only use chemical-protective gloves with CE-labelling of category III.

To minimise the wetness in the glove due to perspiration changing of gloves during a shift is
required.
Check the permeability prior to each anewed use of the glove.
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
Recommended thickness of the material:  0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 4)
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Not suitable are gloves made of the following materials:
Strong gloves
Leather gloves
· Eye protection:

Tightly sealed safety glasses.

· Body protection: Protective work clothing.

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Yellowish
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Mixture is non-polar/aprotic.
· Change in condition
Melting point/freezing point: Not determined
Initial boiling point and boiling range: >200 °C
· Flash point: >100 °C
· Inflammability (solid, gaseous) Not applicable.
· Decomposition temperature: Not determined.
· Self-inflammability: Product is not selfigniting.
· Explosive properties: Product is not explosive.
· Critical values for explosion:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 23 °C 1.12 g/cm³ (ISO 2811-2)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Fully miscible
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
dynamic at 25 °C: 1.500 mPas (ISO 3219)
kinematic: Not determined.
· 9.2 Other information No further relevant information available.
GB
(Contd. on page 6)

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Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 5)

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions
Reacts with strong oxidizing agents, alkali, amines and acids
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: strong oxidizing agents
· 10.6 Hazardous decomposition products:
none, if stored and handled correctly.
in the event of fire:
toxic gases and vapours

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values that are relevant for classification:
1675-54-3 2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)]bisoxirane
Oral LD50 15,000 mg/kg (rat)
Dermal LD50 23,000 mg/kg (rab)
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane
Oral LD50 1,134 mg/kg (rat)
Dermal LD50 >2,150 mg/kg (rab)
8007-24-7 Cashew (Anacardium occidentale) Nutshell Extract, Decarboxylated, Distilled
Oral LD50 500 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation
Causes serious eye damage.
· Respiratory or skin sensitisation
May cause an allergic skin reaction.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
1675-54-3 2,2'-[(1-methylethyliden)bis(4,1-phenylenoxymethylen)]bisoxirane
Bakterientoxizität (Bacteria toxicity) 100 mg/l (Pseudomonas putida)
Daphnientoxizität (Daphnia toxicity) 1.8 mg/l (Daphnia magna (Wasserfloh)) (EC50(48h))
(Contd. on page 7)
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Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 6)
Algentoxizität (Algae toxicity) 11 mg/l (Scenedesmus capricornutum) (EC50(72h))
Fischtoxizität (Fish toxicity) 2 mg/l (Oncorhynchus mykiss (Regenbogenforelle))
(LC50(96h))
2155840-39-2 blockiertes Polyisocyanat
Daphnientoxizität (Daphnia toxicity) >1,000 mg/l (Daphnia magna (Wasserfloh)) (LL50(48h))
Algentoxizität (Algae toxicity) >1,000 mg/l (Skeletonema costatum) (EL50(72h))
Fischtoxizität (Fish toxicity) >1,000 mg/l (Fisch (fish)) (LL50(96h))
2425-79-8 1,4-bis(2,3-epoxypropoxy)butane
Daphnientoxizität (Daphnia toxicity) 76 mg/l (Daphnia magna (Wasserfloh)) (EC50(24h))
Algentoxizität (Algae toxicity) 160 mg/l (Pseudokirchnerilla subcapitata) (LC50 (72h))
Fischtoxizität (Fish toxicity) 18 mg/l (Goldorfe (orfe)) ((96h))
8007-24-7 Cashew (Anacardium occidentale) Nutshell Extract, Decarboxylated, Distilled
Algentoxizität (Algae toxicity) 1,300 mg/l (Skeletonema costatum) (EC50(72h))
Fischtoxizität (Fish toxicity) >1,000 mg/l (Fisch (fish)) (LL50(96h))
· 12.2 Persistence and degradability No further relevant information available.
· Other information: The product is slightly biodegradable.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Other information bioaccumulation possible
· Ecotoxical effects: Not determined
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Danger to drinking water if even small quantities leak into soil.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
For disposal,local regulations issued by the authorities must be observed.Dispose of liquid
components at a suitable incineration plant. After curing, the product can be disposed of with
household waste.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR/RID/ADN, IMDG, IATA UN3082
· 14.2 UN proper shipping name
· ADR/RID/ADN 3082 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (epoxy resin)
(Contd. on page 8)
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Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 7)

· IMDG ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S. (epoxy resin),
MARINE POLLUTANT
· IATA ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (epoxy resin)
· 14.3 Transport hazard class(es)
· ADR/RID/ADN

· Class 9 (M6) Miscellaneous dangerous substances and

articles.
· Label 9
· IMDG, IATA

· Class 9 Miscellaneous dangerous substances and

articles.
· Label 9
· 14.4 Packing group
· ADR/RID/ADN, IMDG, IATA III
· 14.5 Environmental hazards: Product contains environmentally hazardous
substances: epoxy resin
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR/RID/ADN): Symbol (fish and tree)
· Special marking (IATA): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Miscellaneous dangerous substances
and articles.
· Kemler Number: 90
· EMS Number: F-A,S-F
· Stowage Category A
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR/RID/ADN
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000
ml
· Transport category 3
· Tunnel restriction code (-)
· IMDG
· Limited quantities (LQ) 5L
(Contd. on page 9)
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Safety data sheet
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Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 8)

· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000
ml
· UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN), 9,
III

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category E2 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· National regulations
· Decree to be applied in case of technical fault:
· VOC - CH 0.00 %
· MAL-Code (DK) 5-5
· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

· Reasons for alterations
These data are based on our present knowledge. However, they shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Changes made since last issue dated at the following points:
· Relevant phrases
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
· Department issuing data specification sheet:
CTP Advanced Materials GmbH
Stahlstrasse 60
D-65428 Rüsselsheim
· Contact: [email protected]
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning
the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
(Contd. on page 10)
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Printing date 19.08.2021 Revision: 19.08.2021

Trade name: CeTePox® AM 3218, Komp. A

(Contd. of page 9)
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Skin Sens. 1: Skin sensitisation – Category 1
Skin Sens. 1A: Skin sensitisation – Category 1A
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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