Page 1/10

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: CeTePox 1385 H
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the preparation Epoxy resin hardening agent
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
CTP Chemicals and Technologies for Polymers
Stahlstrasse 60
D-65428 Rüsselsheim

Tel.: +49-6142-91850, Fax: +49-6142-918555, Email: [email protected]

· Informing department: see section 16
· 1.4 Emergency telephone number:
Poison Control Center Mainz - 24 h - Emergency Call: +49 (0)6131 19240
GB: Regional Medicines and Poisons Information Centre 844 892 0111
AU: National Poisons Information Network (Australia-wide) 131126

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS05 corrosion

Skin Corr. 1C H314 Causes severe skin burns and eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H332 Harmful if inhaled.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
C; Corrosive
R34: Causes burns.

Xn; Harmful
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.

Xi; Sensitising
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.
(Contd. on page 2)
GB

37.1.4
 Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 1)

· 2.2 Label elements

· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labelling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
trimethylhexane-1,6-diamine
· Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterization: Mixtures
· Description: stabilized amine hardener for epoxy resins
· Dangerous components:
CAS: 100-51-6 Benzyl alcohol 25-50%
EINECS: 202-859-9 Xn R20/22
Index number: 603-057-00-5 Acute Tox. 4, H302; Acute Tox. 4, H332; Eye Irrit.
Reg.nr.: 01-2119492630-38-xxxx 2, H319
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine 25-50%
EINECS: 220-666-8 C R34; Xn R21/22; Xi R43
Index number: 612-067-00-9 R52/53
Reg.nr.: 01-2119514687-32-xxxx Skin Corr. 1C, H314; Acute Tox. 4, H302;
Acute Tox. 4, H312; Skin Sens. 1, H317; Aquatic
Chronic 3, H412
CAS: 25513-64-8 trimethylhexane-1,6-diamine 2.5-10%
EINECS: 247-063-2 C R34; Xn R22; Xi R43
Reg.nr.: 01-2119560598-25-xxxx R52/53
Skin Corr. 1C, H314; Acute Tox. 4, H302;
Acute Tox. 4, H312; Skin Sens. 1A, H317; Aquatic
Chronic 3, H412
(Contd. on page 3)
GB

37.1.4
 Page 3/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 2)
· Additional information For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation
Take affected persons into the open air and position comfortably
Seek medical treatment in case of complaints.
· After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor No particular measures are known - treat according to symptoms.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: Put on breathing apparatus.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Do not allow to enter the ground/soil.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections Clean the accident area carefully.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
The usual precautionary measures for handling chemicals must be observed.
Ensure good ventilation/exhaustion at the workplace.
· Information about protection against explosions and fires: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store only in unopened original containers.
(Contd. on page 4)
GB

37.1.4
 Page 4/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 3)
Provide floor trough without outlet.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· DNELs
100-51-6 Benzyl alcohol
Dermal DNEL - worker 9.5 mg/kg / bw/d (-) (langfristig)
Inhalative DNEL - worker 90 mg/m³ (-) (langfristig)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Inhalative DNEL - worker 20.1 mg/m³ (-)
· PNECs
100-51-6 Benzyl alcohol
PNEC (predicted no effect concentration) 1 mg/l (Frischwasser (freshwater))
0.1 mg/l (Meerwasser (seawater))
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
PNEC (predicted no effect concentration) 0.06 mg/l (Frischwasser (freshwater))
0.006 mg/l (Meerwasser (seawater))
25513-64-8 trimethylhexane-1,6-diamine
PNEC (predicted no effect concentration) 0.0295 mg/l (Frischwasser (freshwater))
0.00295 mg/l (Meerwasser (seawater))
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
· Breathing equipment: Use breathing protection in case of insufficient ventilation.
· Recommended filter device for short term use:

Combination filter A-P2

· Protection of hands:

Plastic gloves

Only use chemical-protective gloves with CE-labelling of category III.

To minimize the wetness in the glove due to perspiration changing of gloves during a shift is
required.
Check the permeability prior to each anewed use of the glove.
(Contd. on page 5)
GB

37.1.4
 Page 5/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 4)
Preventive skin protection by use of skin-protecting agents is recommended.
· Material of gloves
Nitrile rubber, NBR
Fluorocarbon rubber (Viton)
PVC gloves
Recommended thickness of the material: ≥ 0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· As protection from splashes gloves made of the following materials are suitable: PVC gloves
· Not suitable are gloves made of the following materials:
Strong gloves
Leather gloves
· Eye protection:

Tightly sealed safety glasses.

· Body protection: Protective work clothing.

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Yellowish
· Odour: Amine-like
· Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: > 200 °C
· Flash point: > 100 °C
· Ignition temperature: 350 °C
· Self-inflammability: Product is not selfigniting.
· Danger of explosion: Product is not explosive.
· Critical values for explosion:
Lower: 1.2 Vol %
Upper: 13.0 Vol %
· Density at 23 °C 1.0 g/cm³ (ISO 2811-2)
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix
· Viscosity:
dynamic at 25 °C: 30-70 mPas (ISO 3219)
· 9.2 Other information No further relevant information available.
GB
(Contd. on page 6)

37.1.4
 Page 6/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 5)

SECTION 10: Stability and reactivity

· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions Reacts with acids, alkalis and oxidizing agents
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: strong oxidizing agents
· 10.6 Hazardous decomposition products:
none, if stored and handled correctly.
in the event of fire:
toxic gases and vapours

* SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
100-51-6 Benzyl alcohol
Oral LD50 1040 mg/kg (mou)
1230 mg/kg (rat)
1040 mg/kg (rbt)
Dermal LD50 2000 mg/kg (rbt)
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Oral LD50 1030 mg/kg (rat)
Dermal LD50 1840 mg/kg (rab)
>2000 mg/kg (rat)
25513-64-8 trimethylhexane-1,6-diamine
Oral LD50 910 mg/kg (rat)
Dermal LD50 1280 mg/kg (rab)
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye: Strong caustic effect.
· Sensitization: Sensitization possible by skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation
of esophagus and stomach.

* SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
100-51-6 Benzyl alcohol
Algentoxizität (Algae toxicity) 79 mg/l (Scenedesmus quadricauda) (EC50(3h))
640 mg/l (Alge Scenedesmus sp.) (EC50(96h))
(Contd. on page 7)
GB

37.1.4
 Page 7/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 6)
Bakterien-Toxizität (Bacteria toxicity) >658 mg/l (Pseudomonas putida) (EC50(16h))
71.42 mg/l (Photobacterium phosphoreum)
(EC50(0,5h))
400 mg/l (Pseudomonas putida) (EC50(0,5h))
Daphnientoxizität (Daphnia toxicity) 400 mg/l (Daphnia magna (Wasserfloh)) (EC50(24h))
Fischtoxizität (Fish toxicity) 460 mg/l (Pimephales promelas) (LC50(96h))
645 mg/l (Goldorfe (orfe)) (LC50(96h))
10 mg/l (Lepomis macrochirus) (LC50 (96h))
2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine
Algentoxizität (Algae toxicity) >50 mg/l (Scenedesmus subspicatus) (ErC50(72h))
Bakterien-Toxizität (Bacteria toxicity) 1120 mg/l (Pseudomonas putida) (EC10(18h))
Daphnientoxizität (Daphnia toxicity) 23 mg/l (Daphnia magna (Wasserfloh)) (EC50(48h))
Fischtoxizität (Fish toxicity) 110 mg/l (Leuciscus idus) (LC50(96h))
25513-64-8 trimethylhexane-1,6-diamine
Algentoxizität (Algae toxicity) 29.5 mg/l (Scenedesmus subspicatus) (EC50(72h))
Bakterientoxizität (Bacteria toxicity) (static) 89 mg/l (Pseudomonas putida) (EC50(17h))
Daphnientoxizität (Daphnia toxicity) 31.5 mg/l (Daphnia magna (Wasserfloh)) (EC50(24h))
Fischtoxizität (Fish toxicity) 174 mg/l (Leuciscus idus) (LC50(48h))
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects: Not determined
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into soil.
Harmful to aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
For disposal,local regulations issued by the authorities must be observed.Dispose of liquid
components at a suitable incineration plant. After curing, the product can be disposed of with
household waste.
· European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU)
OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES,
SEALANTS AND PRINTING INKS
08 02 00 wastes from MFSU of other coatings (including ceramic materials)
08 02 99 wastes not otherwise specified
(Contd. on page 8)
GB

37.1.4
 Page 8/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 7)

· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN2735
· 14.2 UN proper shipping name
· ADR 2735 AMINES, LIQUID, CORROSIVE, N.O.S.
(ISOPHORONEDIAMINE)
· IMDG, IATA AMINES, LIQUID, CORROSIVE, N.O.S.
(ISOPHORONEDIAMINE)
· 14.3 Transport hazard class(es)
· ADR

· Class 8 (C7) Corrosive substances.

· Label 8
· IMDG, IATA

· Class 8 Corrosive substances.

· Label 8
· 14.4 Packing group
· ADR, IMDG, IATA III
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Corrosive substances.
· Kemler Number: 80
· EMS Number: F-A,S-B
· 14.7 Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Excepted quantities (EQ): E1
· Limited quantities (LQ) 5L
· Transport category 3
· Tunnel restriction code E
· UN "Model Regulation": UN2735, AMINES, LIQUID, CORROSIVE, N.O.S.
(ISOPHORONEDIAMINE), 8, III
GB
(Contd. on page 9)

37.1.4
 Page 9/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 8)

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labelling:
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Benzyl alcohol
trimethylhexane-1,6-diamine
· Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· National regulations
· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Changes made since last issue dated 09.02.2011 at the following points: *
· Relevant phrases
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H412 Harmful to aquatic life with long lasting effects.
R20/22 Harmful by inhalation and if swallowed.
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
(Contd. on page 10)
GB

37.1.4
 Page 10/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 03.09.2013 Revision: 03.09.2013

Trade name: CeTePox 1385 H

(Contd. of page 9)
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
· Department issuing data specification sheet:
CTP Chemicals and Technologies for Polymers GmbH
Stahlstraße 60
D-65428 Rüsselsheim
· Contact:
Mr. Dr. U. Prinz
([email protected])
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organization
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
GB

37.1.4