Hydrogen 3%-1

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Safety Data Sheet

Hydrogen Peroxide 3% Min

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Hydrogen Peroxide 3% Min


Synonyms/Generic Names: Peroxide

Product Number: 2753

Product Use: Industrial, Manufacturing or Laboratory use

Manufacturer: Columbus Chemical Industries, Inc.


N4335 Temkin Rd.
Columbus, WI. 53925

For More Information: 920-623-2140 (Monday-Friday 8:00-4:30)


www.columbuschemical.com

In Case of Emergency Call: CHEMTREC - 800-424-9300 or 703-527-3887 (24 Hours/Day, 7 Days/Week)

2. HAZARDS INDENTIFICATION

Hazards Not Otherwise Classified (HNOC): None

Signal Words: Danger

Pictograms:

GHS Classification

Skin irritation Category 2


Eye damage Category 1

GHS Label Elements, including precautionary statements:


Hazard Statements:
H315 Causes skin irritation.
H318 Causes serious eye damage.

Precautionary Statements:
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
P305+P351+P338 lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash it before reuse.

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

Potential Health Effects


Eyes May cause serious irritation.
Inhalation Irritating to the respiratory system. Causes irritation to the respiratory tract.
Skin Irritating to skin. Contact causes redness, burns, itching and pain. Prolonged or repeated
skin exposure may cause dermatitis.
Ingestion Causes irritation and pain.

NFPA Ratings HMIS Ratings


Health 1 Health 1
Flammability 0 Fire 0
Reactivity 0 Reactivity 0
Specific hazard Not Available

3. COMPOSITION/INFORMATION ON INGREDIENTS

EINECS# / Molecular
Component Weight % CAS # Formula
ELINCS# Weight
Hydrogen
3.0-3.5 7722-84-1 231-765-0 H2O2 34.01 g/mol
Peroxide
Water Balance 7732-18-5 231-791-2 H2O 18.00 g/mol

4. FIRST-AID MEASURES

Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention.
Inhalation Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not
breathing, give artificial respiration. Get medical attention.
Skin Flush with plenty of water for at least 15 minutes while removing contaminated clothing
and wash using soap. Get medical attention.
Ingestion Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If
conscious, wash out mouth with water. Get medical attention.
General Advice Get medical advice / attention if you feel unwell. Show this safety data sheet to the
doctor.

5. FIREFIGHTING MEASURES

Suitable (and unsuitable) Product is not flammable. Use water spray, alcohol-resistant foam, dry
extinguishing media chemical or carbon dioxide. Use flooding quantities of water to cool
unopened containers.
Special protective equipment Wear self-contained, approved breathing apparatus and full protective
and precautions for clothing, including eye protection and boots.
firefighters
Specific hazards arising from Emits toxic fumes under fire conditions. (See also Stability and
the chemical Reactivity section).

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, See section 8 for recommendations on the use of personal protective
protective equipment and equipment.
emergency procedures

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

Environmental precautions Prevent spillage from entering drains. Any release to the environment
may be subject to federal/national or local reporting requirements.
Methods and materials for Neutralize spill with sodium bicarbonate or lime. Absorb spill with
containment and cleaning up noncombustible absorbent material, then place in a suitable container
for disposal. Clean surfaces thoroughly with water to remove residual
contamination. Dispose of all waste and cleanup materials in
accordance with regulations.

7. HANDLING AND STORAGE

Precautions for safe handling


See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation.
Wash thoroughly after using. Keep the container closed when not in use.

Conditions for safe storage, including any incompatibilities


Store in a cool, dry, well-ventilated area. Isolate from combustible material. Store in the dark. Store in vented
containers. Keep away from incompatible materials (see section 10 for incompatibilities).

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits Basis Entity


Hydrogen Peroxide 1 ppm (1.4 mg/m3) TWA ACGIH® TLVs®
1 ppm (1.4 mg/m3) TWA OSHA PELs
1 ppm (1.4 mg/m3) TWA NIOSH RELs
TWA: Time Weighted Average over 8 hours of work.
TLV: Threshold Limit Value over 8 hours of work.
REL: Recommended Exposure Limit
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit during x minutes.
IDLH: Immediately Dangerous to Life or Health
WEEL: Workplace Environmental Exposure Levels
CEIL: Ceiling

Personal Protection
Eyes Wear chemical safety glasses with a face shield if splashing is likely to occur.
Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an
approved respirator.
Skin Wear neoprene or nitrile gloves, apron and other protective clothing appropriate to the
risk of exposure.
Other Handle in accordance with good industrial hygiene and safety practices.

Other Recommendations
Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.
Have supplies and equipment for neutralization and running water available.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance (physical state, color, etc.) Clear, colorless liquid


Odor No Odor
Odor threshold Not Applicable
pH Not Available
Melting point/freezing point Not Available
Initial boiling point and boiling range Not Available

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

Flash point Not Flammable


Evaporation rate Not Available
Flammability (solid, gas) Not Flammable
Upper/lower flammability or explosive limit Not Explosive
Vapor pressure Not Available
Vapor density Not Available
Specific gravity 1.01-1.02
Solubility (ies) Completely soluble in water
Partition coefficient: n-octanol/water Not Available
Auto-ignition temperature Not Applicable
Decomposition temperature Not Available

10. STABILITY AND REACTIVITY

Chemical Stability Stable


Possibility of Hazardous Reactions Will not occur
Conditions to Avoid Store out of direct light
Incompatible Materials Brass, copper, powdered metals, iron and iron salts, combustible
materials.
Hazardous Decomposition Not Available
Products

11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Skin Not Available
Eyes Not Available
Respiratory Not Available
Ingestion Not Available

Carcinogenicity
IARC 3-Group 3: Not classifiable as to its carcinogenicity to humans (hydrogen peroxide).
ACGIH A3: Confirmed animal carcinogen with unknown relevance to humans (hydrogen
peroxide).
NTP No components of this product present at levels greater than or equal to 0.1% is identified
as a known or anticipated carcinogen by NTP.
OSHA No components of this product present at levels greater than or equal to 0.1% is identified
as a carcinogen or potential carcinogen by OSHA.

Signs & Symptoms of Exposure


Skin Redness, burning, itching and pain.
Eyes Eye burns, pain, watering eyes.
Respiratory Coughing, shortness of breath, burning, coughing, wheezing, laryngitis, headache or
nausea.
Ingestion Causes irritation and pain.

Chronic Toxicity Not Available


Teratogenicity Not Available
Mutagenicity Not Available
Embryotoxicity Not Available
Specific Target Organ Toxicity Eyes, Skin
Reproductive Toxicity Not Available
Respiratory/Skin Sensitization Not Available

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

12. ECOLOGICAL INFORMATION

Ecotoxicity
Aquatic Vertebrate Not Available
Aquatic Invertebrate Not Available
Terrestrial Not Available

Persistence and Degradability Not Available


Bioaccumulative Potential Not Available
Mobility in Soil Not Available
PBT and vPvB Assessment Not Available
Other Adverse Effects Not Available

13. DISPOSAL CONSIDERATIONS

Waste Product or Users should review their operations in terms of the applicable federal/national or
Residues local regulations and consult with appropriate regulatory agencies if necessary
before disposing of waste product or residue.
Product Users should review their operations in terms of the applicable federal/national or
Containers local regulations and consult with appropriate regulatory agencies if necessary
before disposing of waste product container.

The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may
significantly change the characteristics of the material and alter the waste classification and proper disposal
methods.

14. TRANSPORTATION INFORMATION


US DOT Not Dangerous Goods
TDG Not Dangerous Goods
IMDG Not Dangerous Goods
Marine Pollutant No
IATA/ICAO Not Dangerous Goods

15. REGULATORY INFORMATION

TSCA Inventory Status All ingredients are listed on the TSCA Active inventory.
DSL / NDSL All ingredients are listed on the DSL inventory.
California Proposition 65 Not Listed
Massachusetts: Toxic or Hazardous Substance Listed: Hydrogen Peroxide
List, Right to Know
New Jersey: Right to Know Hazardous Listed: Hydrogen Peroxide
Substance List
Pennsylvania: Hazardous Substance List Listed: Hydrogen Peroxide >52%
Rhode Island: Hazardous Substance List Listed: Hydrogen Peroxide
SARA 302 Not Listed
SARA 304 Not Listed
SARA 311 Acute Health Hazard
SARA 312 Acute Health Hazard

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

SARA 313 Not Listed


WHMIS Canada Not Listed

16. OTHER INFORMATION

Revision Date

Created 03/02/2022

Disclaimer: The information provided in this Safety Data Sheet (“SDS”) is correct to the best of our knowledge, information and belief at the
date of publication. The information in this SDS relates only to the specific Product identified under Section 1, and does not relate to its use
in combination with other materials or products, or its use as to any particular process. Those handling, storing or using the Product should
satisfy themselves that they have current information regarding the particular way the Product is handled, stored or used and that the same
is done in accordance with federal, state and local law. WE DO NOT MAKE ANY WARRANTY, EXPRESS OR IMPLIED, INCLUDING
(WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE
INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. WE DO NOT ASSUME

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Columbus Chemical Industries, Inc. Hydrogen Peroxide 3%, 2753

RESPOSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY
WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT.

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