Chemistry XI STBB MOC 2023

Date: 06-06-2023 Chemistry-XI Time: 3 Hours Max.
Marks: 85
SECTION - A
Q#1 Choose the correct answer for each from given option: Marks: 17
1. The number of carbon atoms in 1 mole of sugar (C12H22O11) are approximately _______.
a) 6 x 1023 b) 24 x 1023 c) 60 x 1023 d) 72 x 1023
Nitrogen has the electronic configuration 1s2 2s2 2 p1x 2 p1y 2 p1z and not 1s2 2s2 2 p2x 2 p1y .
2.
This is determined by _____________________.
Aufbau
a) b) Pauli’s rule c) Hund’s rule d) n + l rule
principle
3. Graphite can conduct electricity in one direction only. With this behavior, it is said to be:
a) Amorphous b) Symmetrical c) Anisotropic d) Polymorphous
Which of the following sample of substances contains the same number of atoms as that
4.
of 20g of calcium:
a) 16g of S b) 20g of C c) 19g of K d) 24g of Mg
5. The shape and hybridization of BCl3 molecule is:

Tetrahedral and Planar trigonal
a) b) Linear and SP c) d) Angular and SP3
SP3 and SP2
6. Which of the following possesses weakest London dispersion forces:

a) Cl2 b) F2 c) Br2 d) I2
7. An example of completely immiscible liquid pair is:

Benzene and Water and Water and Water and
a) b) c) d)
Toluene Phenol Benzene Methanol
If the kelvin temperature of ideal gas increases to double and pressure is reduced to one
8.
half, the volume of gas will:
a) Remains same b) Double c) Reduced to half d) Four time
Balmer series appears in the hydrogen spectrum if electron jump from any appropriate
9.
higher energy orbit to
a) Second orbit b) Third orbit c) Fourth orbit d) Fifth orbit
10. Which is not a colligative property?

Lowering in Elevation in Depression in Atmospheric
a) b) c) d)
vapor pressure boiling point freezing point pressure
11. The molecule which has maximum bond angle is:

a) CS2 b) H2O c) NH3 d) BF3
12. The number of sigma and pi bonds in C2H4 molecule are respectively:
a) 3 and 1 b) 2 and 2 c) 5 and 1 d) 4 and 2
13. The correct Ksp expression of a sparingly soluble salt Li2C2O4 among the following is:
Ksp = [Li+] [C2 Ksp = [Li+]2 [C2 Ksp = [2Li+] [C2 −2
Ksp = [Li+] [C2O 4
a) b) c) d)
O−2
4 ] O−2
4 ] O−2
4 ] ]2
14. A colloidal solution of liquid into liquid is as:

a) Gel b) Foam c) Solution d) Emulsion
15. For Avogadro’s number, this statement is incorrect:

a) It is the number of particles in one mole of any substance
b) Its numerical value is 6.023 x 1023
c) Its value change if temperature increases
d) Its value change if number of moles increases
16. Liquids can form convex meniscus in a narrow glass tube when:
a) Cohesive forces are stronger than Adhesive forces
b) Adhesive forces are stronger than Cohesive forces
c) Cohesive and Adhesive forces are equal in strength
d) None of these
17. The equilibrium of N2(g) + O2(g) ⇌ 2NO(g) (ΔH = +ve) is affected by change in:
Neither
Temperature Both temperature
a) b) Pressure only c) d) temperature nor
only and pressure
pressure
SECTION – B
Attempt any EIGHT questions. Each question carries 5 marks. Marks: 40

Q#2 Calculate the number of moles and molecules in 38g of Carbon Disulphide (CS2).
Q#3 Define pH and pOH of a solution? Also show that pH + pOH = 14.
Q#4 Define solubility product and state Avogadro’s law.
Q#5 What are miscible and immiscible liquids?
Q#6 Define Osmosis and Osmotic pressure.
Q # 7 (a) Define primary cell, secondary cell, and electrochemical series.
Name three major kinds of intermolecular forces in liquid. Explain intermolecular
Q # 7 (b)
forces in HCl.
Q#8 Explain the following with scientific reason:
i. Sigma bond is stronger than pi bond
ii. HF has greater ionic character than HCl
Q#9 Give reason for the following:
Water spilled on the floor evaporate faster than the same amount of water in a
i.
container.
ii. A falling drop of a liquid is spherical.
iii. Evaporation is a cooling process
Q # 10 Name various units of concentration and explain mole fraction.
Q # 11 Write down the electronic configuration of following:
i. Fe (Z = 26)
ii. Br (Z = 35)
iii. Ca (Z = 20)
iv. S (Z = 16)
v. O (Z = 8)
Q # 12 The dipole moment of water is 1.85D but CO2 has zero dipole moment. Why?
Q # 13 Write down the postulate of VSEPR theory.
SECTION – C
Attempt any TWO questions. Each question carries 14 marks. Marks: 28
Describe hydrogen bonding in water. And explain the anomalous behavior of water
Q # 14 (a)
due to hydrogen bonding.
Q # 14 (b) Define unit cell. Draw a diagram to show its axial distances and axial angles.
State Le-Chatelier’s principle. Explain the industrial application of Le-Chatelier’s
Q # 15 (a)
principle using Haber’s process.
Differentiate among True Solution, Colloidal Solution, and Suspension on the basis
Q # 15 (b)
of:
i. Particle Size
ii. Visibility
Q # 16 Draw a molecular orbital diagram of O2 molecule and
a) Write down MO electronic configuration
b) Determine bond order
c) Explain the paramagnetic behavior

Chemistry XI STBB MOC 2023

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Date: 06-06-2023 Chemistry-XI Time: 3 Hours Max.

5. The shape and hybridization of BCl3 molecule is:

6. Which of the following possesses weakest London dispersion forces:

7. An example of completely immiscible liquid pair is:

10. Which is not a colligative property?

11. The molecule which has maximum bond angle is:

14. A colloidal solution of liquid into liquid is as:

15. For Avogadro’s number, this statement is incorrect:

Attempt any EIGHT questions. Each question carries 5 marks. Marks: 40

Attempt any TWO questions. Each question carries 14 marks. Marks: 28

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