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    D 6000

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    (1) This document provides a material safety data sheet for D-6000 Black Developer used in Toshiba copiers. (2) The main ingredients are iron oxide, manganese oxide, magnesium oxide, polyester resin, and carbon black. Excessive inhalation of the toner may irritate the respiratory tract. (3) In case of accidental release, vacuum or sweep up the spilled toner and transfer to a sealable waste container. Maintain adequate ventilation and protective equipment is not required under intended use.

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    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    D 6000

    Uploaded by

    [email protected]
    81 views6 pages
    (1) This document provides a material safety data sheet for D-6000 Black Developer used in Toshiba copiers. (2) The main ingredients are iron oxide, manganese oxide, magnesium oxide, polyester resin, and carbon black. Excessive inhalation of the toner may irritate the respiratory tract. (3) In case of accidental release, vacuum or sweep up the spilled toner and transfer to a sealable waste container. Maintain adequate ventilation and protective equipment is not required under intended use.

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    d6000

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    (1) This document provides a material safety data sheet for D-6000 Black Developer used in Toshiba copiers. (2) The main ingredients are iron oxide, manganese oxide, magnesium oxide, polyester resin, and carbon black. Excessive inhalation of the toner may irritate the respiratory tract. (3) In case of accidental release, vacuum or sweep up the spilled toner and transfer to a sealable waste container. Maintain adequate ventilation and protective equipment is not required under intended use.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    81 views6 pages

    D 6000

    Uploaded by

    [email protected]
    (1) This document provides a material safety data sheet for D-6000 Black Developer used in Toshiba copiers. (2) The main ingredients are iron oxide, manganese oxide, magnesium oxide, polyester resin, and carbon black. Excessive inhalation of the toner may irritate the respiratory tract. (3) In case of accidental release, vacuum or sweep up the spilled toner and transfer to a sealable waste container. Maintain adequate ventilation and protective equipment is not required under intended use.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
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    of 6

    MATERIAL SAFETY DATA SHEET

    Date of Preparation Date of Revised : February 15, 2005 :


    MSDS

    : D6000KAJ1W Page 1 of 6

    SECTION 1

    CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


    : : : : : : D-6000 Black Developer Toshiba Copiers, e-STUDIO 520, 600, 720 and 850 Toshiba TEC Corporation 2-17-2, Higashigotanda, Shinagawa-ku, Tokyo, 141-8664, Japan +81-3-6422-7753 (1) Toshiba TEC Corporation, Mishima Works 6-78 Minami-cho, Mishima-shi, 411-8520 Japan

    Product Name Used for Company Name Address Telephone Number Manufacturer Name

    Contact

    : (1) Toshiba America Information Systems, Inc. Emergency Telephone. No. : +1-800-424-9300 For calls within the U.S. only. (2) Toshiba of Canada Limited Telephone. No. : +1-905-405-3500 For calls within Canada only. (3) Toshiba TEC Germany Imaging Systems GmbH Telephone. No. : +49-2131-1245-0 (European Headquarter) (4) Toshiba (Australia) Pty, Ltd. Telephone. No. : +61-2-98873322

    SECTION 2

    COMPOSITION/INFORMATION ON INGREDIENTS
    CAS No. 1309-37-1 1344-43-0 1309-48-4 ------1333-86-4 ------wt.% 65-75 20-25 1-4 2-6 <1 Trade Secret

    INGREDIENT(S) Iron oxide Manganese oxide Magnesium oxide Polyester resin Carbon black

    SECTION 3

    HAZARDS IDENTIFICATION
    : If used as intended, the product does not present acute or chronic health hazard. : This product is not classified as flammable or combustible. It will burn in case of fire. Avoid contact with strong oxidizers such as chromate, bromate and nitrates. : Inhalation, dermal contact, incidental ingestion

    Emergency Overview Physical Hazards

    Routes of Exposure

    MATERIAL SAFETY DATA SHEET


    Product Identity
    : D-6000

    Black Developer

    MSDS : D6000KAJ1W

    Page 2 of 6
    : Excessive inhalation may cause irritation of the nose, throat and respiratory tract. Eye Contact : Non-irritant. Dermal Contact : Non-irritant, non-sensitiser. Ingestion : Not currently known. Chronic Effects : See Section 11 Supplemental Health Information. Carcinogenicity : See Section 11 Supplemental Health Information. Reproductive/Developmental : Not identified. Target Organs : Prolonged breathing of high concentrations may cause adverse effects on the respiratory system. Signs and Symptoms of Exposure : Prolonged exposure to dusts of this product may irritate the respiratory system. Medical Conditions Aggravated by Exposure to This Product : Respiratory disorders, such as asthma, may be aggravated by prolonged exposure to high concentrations of this product. Inhalation

    SECTION 4
    Eye Contact Skin Contact Ingestion Inhalation

    FIRST AID MEASURES


    : Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, call a physician. : Wash with soap and water. Wash clothing before reuse. If irritation occurs or is persistent, seek medical attention. : Dilute stomach contents with several glasses of water. : Remove from exposure area to fresh air immediately. Contact a physician if there is any difficulty in breathing or other signs of distress.

    SECTION 5 FIRE FIGHTING MEASURES


    General Hazard : Product will not burn in case of fire. Flash Point : Not applicable Flammable Limits : Not applicable Autoignition Temperature : Not applicable Flammability classification : Not applicable Extinguishing Media : Foam, halon, carbon dioxide, dry chemical & water fog. Unusual Fire & Explosion Hazard : Combustible powder. Dust of this product at sufficient concentrations can form explosive mixtures with air. Fire Fighting Procedures : None Hazardous Combustion Products : Carbon monoxide, carbon dioxide and smoke.

    SECTION 6
    Spills or Leaks

    ACCIDENTAL RELEASE MEASURES


    : Vacuum-clean spilled toner and carefully transfer into sealable waste container. If no vacuum-cleaner is available, sweep slowly to minimize generation of dust during clean-up. Residue can be removed with soap and cold water.

    MATERIAL SAFETY DATA SHEET


    Product Identity
    : D-6000

    Black Developer

    MSDS : D6000KAJ1W

    Page 3 of 6

    SECTION 7

    HANDLING AND STORAGE

    : Avoid dust, keep away from ignition sources. Handling Prevention of Fire and Explosion : This material is capable of creating a dust explosion. Keep away from heat, sparks & flame. : Keep container in cool and dry area. Storage : Avoid inhalation and ingestion. Avoid getting in eyes, on skin or clothing. Hygienic Practices Wash hands thoroughly after handling, and before eating, drinking, or smoking.

    SECTION 8

    EXPOSURE CONTROLS/PERSONAL PROTECTION


    : 15mg/m 3 (Total dust) 5mg/m 3 (Respirable fraction) : 3.5 mg/m 3 : Not listed : 10mg/m 3 (Total dust) 3mg/m 3 (Respirable fraction) : 3.5 mg/m 3 : Not listed : 4mg/m 3 (Inhalable fraction) 1.5mg/m 3 (Respirable fraction) : Not listed : : : : : Not listed Maintain adequate ventilation. Not required under intended use. Not required under intended use. Not required under intended use.

    Exposure Limits OSHA PELs (TWA) as the product Carbon black Other substances ACGIH TLVs (TWA) as the product Carbon black Other substances DFG-MAK (TWA) as the product All substances NOHSC (TWA) All substances Engineering Controls Eye Protection Skin Protection Respiratory Protection

    SECTION 9

    PHYSICAL AND CHEMICAL PROPERTIES


    : : : : : : : : : : Fine solid powder Black Odorless No data available 4.5 - 5.5 Not applicable Not applicable Not applicable Negligible Not a water-based product, therefore not applicable.

    Appearance Color Scent Melting Point Specific Gravity(H2O=1) Vapor Pressure Vapor Density (Air=1) : Evaporation Rate Solubility in Water pH Value

    MATERIAL SAFETY DATA SHEET


    Product Identity
    : D-6000

    Black Developer

    MSDS : D6000KAJ1W

    Page 4 of 6

    SECTION 10 STABILITY AND REACTIVITY


    Stability : Stable Incompatibility : Not identified. Hazardous Decomposition Products : Carbon monoxide and carbon dioxide. : Will not occur. Hazardous Polymerization:

    SECTION 11

    SUPPLEMENTAL HEALTH INFORMATION


    : LD50 is greater than 2,500mg/kg. (This was the highest attainable mass.) (Estimated from the constituent components.) : LC50(4H) is in excess of 5.18mg/l. (This was the highest attainable concentration.) (Estimated from the constituent components.) : Non-irritant. (Estimated from the constituent components.) (Estimated from the constituent components.) : Non-irritant. : Non-sensitiser. (Estimated from the constituent components.) : Negative in the Ames test. : In 1996, the IARC classified carbon black as a Group 2B carcinogen (possible human carcinogen). : In a study in rats by chronic inhalation exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92 % of the rats in the high concentration (16 mg/m 3)exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle (4 mg/m 3) exposure group. These findings are attributed to "lung overloading", a general response to excessive amounts of any dust retained in the lungs for a prolonged period.

    Acute oral toxicity

    Acute inhalation

    Eye irritation Skin irritation Skin sensitization Mutagenicity Carcinogenicity : Chronic Effects :

    SECTION 12

    ECOLOGICAL INFORMATION
    : LC50 is greater than limit of saturation (fish) : EC50 is greater than limit of saturation (daphnia) : Algal Growth Inhibition limit of saturation (This was the highest attainable mass.) (Estimated from the constituent components.)

    Aquatic environmennt

    SECTION 13

    DISPOSAL CONSIDERATION

    Dispose of in accordance with local, state and federal regulation. Empty plastic container may be recycled.

    SECTION 14

    TRANSPORTATION INFORMATION

    : None Special Precautions International Transport Information UN Classification Number : Not applicable DOT Identification Number : Not applicable : Not applicable Domestic Transportation : Not applicable Other Information

    MATERIAL SAFETY DATA SHEET


    Product Identity
    : D-6000

    Black Developer

    MSDS : D6000KAJ1W

    Page 5 of 6

    SECTION 15 REGULATORY INFORMATION


    : See section 11. IARC US/Canada Information OSHA Hazard Communication Standard, 29CFR 1910. 1200 : Not regulated. Toxic Substance Control Act (TSCA) : All chemical substances in this product comply with all applicable rules or orders under TSCA. : Product or components not listed. RCRA (40 CFR 261) CERCLA/SARA Information : Not regulated. NTP Annual Report on Carcinogens : Not listed as an NTP carcinogen. : Neither toner, or any of the components, are listed as chemicals known California Proposition 65 to the State of California to cause cancer or reproductive system effects. Controlled Products Regulations(Canada) : This product has been classified in accordance with the hazard criteria of the CPR. Workplace Hazardous Materials Information System(Canada) : No toxicology information available : Carbon black is listed in the New Jersey Right to Know List, Other State Regulations Pennsylvania Hazardous Substance List, and Massachusetts Substance List. U.S./Canada Label Statements : LOW HAZARD FOR RECOMMENDED HANDLING. Minimize dust generation and accumulation. Use with adequate ventilation. EU Information Label Information According to Directives 67/548 EEC & 88/379 EEC : Not required Symbol & Indication : Not required Risk Phrase : Not required Safety Advise Phrase EEC Directive(76/548 EEC, 79/831 EEC, 92/32 EEC) : All chemical substances in this product comply with all applicable rules or order under EEC Directive. The Subject of Specific Provisions in Relation to Protection of Man or the Environment.Directive 76/769/EEC : Not required : No specific regulations or restrictions. National requirement :

    SECTION 16 OTHER INFORMATION


    National Fire Protection Association (NFPA) Classification : : 0 Flammability : 0 Reactivity : 0 Health ( 0 = insignificant, 1 = slight ) Hazardous Materials Information Systems (HMIS) : : 0 Red (Flammability) : 0 Yellow (Reactivity) Blue (Acute Effects) : 0 ( 0 = insignificant, 1 = slight )

    MATERIAL SAFETY DATA SHEET


    Product Identity
    : D-6000

    Black Developer

    MSDS : D6000KAJ1W

    Page 6 of 6
    Notice : Judgments as to the suitability of information herein for purchaser's purposes are necessarily purchaser's responsibility. Therefore, although reasonable care has been taken in the preparation of such information, Toshiba Corporation extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or for consequences of its use. : IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risks of Chemicals to Humans, Vol. 65, Printing Processes and Printing Inks, Carbon Black and Some Nitro Compounds, Lyon, pp. 149-261. H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. MacKenzie, P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991). Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats, Fundamental and Applied Toxicology 17, pp. 280-299. : (1) OSHA PEL stands for Permissible Exposure Limit under Occupational Safety and Health Administration (USA). (2) ACGIH TLV stands for Threshold Limit Value under American Conference of Governmental Industrial Hygienists (USA). (3) DFG-MAK stands for Maximale Arbeitsplatzkonzentrationen under Deutsche Forschungsgemeinschaft. (4) TWA stands for Time Weighted Average. (5) IARC stands for International Agency for Research on Cancer. (6) NTP stands for National Toxicology Program (USA). (7) NIOSH stands for National Institute for Occupational Safety and Health (USA). (8) DOT stands for Department of Transportation (USA). (9) NOHSC stands for National Occupational Heath and Safety Commission (Australia). : Toshiba TEC Corporation Quality Assurance Department 6-78 Minami-cho, Mishima-shi, Shizuoka-ken,

    References

    Abbreviation

    Prepared by

    411-8520 Japan

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