02/11/2013 Revision:

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BHT
SAFETY DATA SHEET
Cayman Chemical Company
1180 E. Ellsworth Rd.
Ann Arbor, MI 48108
10/22/2007 Supercedes Revision:
1. Identification of the Substance/Mixture and of the Company/Undertaking
89910 Product Code:
BHT Product Name:
2,6-di-tert-butyl-4-hydroxytoluene; Butylated Hydroxy Toluene; Synonyms:
For research use only, not for human or veterinary use. Intended Use:
Manufacturer Information
Cayman Chemical Company Company Name:
CHEMTREC Within USA and Canada: +1 (800)424-9300 Emergency Contact:
CHEMTREC Outside USA and Canada: +1 (703)527-3887 Alternate Emergency Contact:
Cayman Chemical Company +1 (734)971-3335 Information:
www.caymanchem.com Web site address:
2. Hazards Identification
Harmful if swallowed
GHS Classification
Acute Toxicity: Oral, Category 4
Placard
Warning
Key word GHS Hazard
Exclamation
point
Causes skin irritation Skin Corrosion/Irritation, Category 2 Warning Exclamation
point
Causes serious eye irritation Serious Eye Damage/Eye Irritation, Category
2A
Warning Exclamation
point
Toxic to aquatic life with long lasting effects Aquatic Toxicity (Chronic), Category 2 Pollution
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation
H411: Toxic to aquatic life with long lasting effects.
GHS Hazard Phrases:
P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/clothing and eye/face protection as specified by the
manufacturer/supplier or the competent authority.
P273: Avoid release to the environment - if this is not the intended use.
GHS Precaution Phrases:
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P332+313: If skin irritation occurs, get medical advice/attention.
P362: Take off contaminated clothing and wash before re-use.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists, get medical advice/attention.
P391: Collect spillage.
GHS Response Phrases:
Please refer to Section 7 for Storage and Section 13 for Disposal information. GHS Storage and Disposal Phrases:
Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? Yes Other: Injection Route(s) of Entry:
Causes eye or skin irritation.
Harmful if swallowed.
Material may be irritating to the mucous membranes and upper respiratory tract.
May be harmful by inhalation or skin absorption.
May cause respiratory system irritation.
Potential Health Effects (Acute and Chronic):
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BHT
SAFETY DATA SHEET
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Eyes, Skin. Target Organs:
Please refer to Section 11. LD 50 / LC 50:
To the best of our knowledge, the toxicological properties have not been thoroughly investigated. Signs and Symptoms Of Exposure:
No data available. Medical Conditions Generally Aggravated By
Exposure:
3. Composition/Information on Ingredients
R22-51/53-36/38 204-881-4 GO7875000
Hazardous Components (Chemical Name)
BHT 128-37-0
CAS #
100.0 %
Concentration EC# Risk Phrases RTECS #
1.
4. First Aid Measures
Emergency and First Aid Procedures:
Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained
personnel. Get immediate medical attention.
In Case of Inhalation:
Immediately wash skin with soap and plenty of water for at least 20 minutes. Remove
contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse.
In Case of Skin Contact:
Hold eyelids apart and flush eyes with plenty of water for at least 20 minutes. Have eyes
examined and tested by medical personnel.
In Case of Eye Contact:
Wash out mouth with water provided person is conscious. Never give anything by mouth to an
unconscious person. Get medical attention. Do NOT induce vomiting unless directed to do so by
medical personnel.
In Case of Ingestion:
No data available. Indication of any immediate medical
attention and special treatment needed:
5. Fire Fighting Measures
Use alcohol-resistant foam, carbon dioxide, water, or dry chemical spray.
Use water spray to cool fire-exposed containers.
Suitable Extinguishing Media:
A solid water stream may be inefficient. Unsuitable Extinguishing Media:
No data available. Flammable Properties and Hazards:
No data. Flash Pt:
No data available. Autoignition Pt:
LEL: No data. UEL: No data. Explosive Limits:
No data available. Hazardous Combustion Products:
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent), and full protective gear to prevent contact with skin and eyes.
Fire Fighting Instructions:
6. Accidental Release Measures
Avoid raising and breathing dust, and provide adequate ventilation.
As conditions warrant, wear a NIOSH approved self-contained breathing apparatus, or respirator,
and appropriate personal protection (rubber boots, safety goggles, and heavy rubber gloves).
Protective Precautions, Protective
Equipment and Emergency Procedures:
Take steps to avoid release into the environment, if safe to do so. Environmental Precautions:
Contain spill and collect, as appropriate.
Transfer to a chemical waste container for disposal in accordance with local regulations.
Steps To Be Taken In Case Material Is
Released Or Spilled:
7. Handling and Storage
Avoid breathing dust/fume/gas/mist/vapours/spray.
Avoid prolonged or repeated exposure.
Precautions To Be Taken in Handling:
Keep container tightly closed.
Store in accordance with information listed on the product insert.
Precautions To Be Taken in Storing:
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SAFETY DATA SHEET
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Avoid contact with skin and eyes. Do not reuse this container. Use with adequate ventilation.
Wash thoroughly after handling.
Hazard Label Information:
8. Exposure Controls/Personal Protection
2 mg/m3 (Inhalation) No data. No data.
Hazardous Components (Chemical Name) ACGIH TLV
BHT 128-37-0
CAS # OSHA PEL Other Limits
1.
TWA: 10 mg/m3 TWA: 10 mg/m3 ()
STEL: ()
No data.
Hazardous Components (Chemical Name) France VL
BHT 128-37-0
CAS # Britain EH40 Europe
1.
Compatible chemical-resistant gloves Eye wash station in work area Lab coat Safety
glasses Safety shower in work area Vent Hood
Protective Equipment Summary - Hazard
Label Information:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits.
Engineering Controls (Ventilation etc.):
Safety glasses Eye Protection:
Compatible chemical-resistant gloves Protective Gloves:
Lab coat Other Protective Clothing:
NIOSH approved respirator, as conditions warrant. Respiratory Equipment (Specify Type):
Do not take internally.
Facilities storing or utilizing this material should be equipped with an eyewash and a safety
shower.
Wash thoroughly after handling.
Work/Hygienic/Maintenance Practices:
No data available. Environmental Exposure Controls:
9. Physical and Chemical Properties
Information on Basic Physical and Chemical Properties
[ ] Gas [ ] Liquid [ X ] Solid Physical States:
A crystalline solid Appearance and Odor:
No data. Melting Point:
No data. Boiling Point:
No data. Flash Pt:
No data. Evaporation Rate:
No data. Vapor Pressure (vs. Air or mm Hg):
No data. Vapor Density (vs. Air = 1):
No data. Specific Gravity (Water = 1):
No data. Solubility in Water:
~0.25 mg/ml in 1:3 EtOH:PBS (pH 7.2); ~30 mg/ml in EtOH, DMF, & DMSO; Solubility Notes:
No data. Autoignition Pt:
No data available. Explosive Properties:
No data available. Oxidizing Properties:
Other Information
No data. Percent Volatile:
C15H24O Formula:
220.40 Molecular Weight:
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SAFETY DATA SHEET
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10. Stability and Reactivity
No data available. Reactivity:
Unstable [ ] Stable [ X ] Stability:
Stable if stored in accordance with information listed on the product insert. Stability Note(s):
No data available. Conditions To Avoid:
Will occur [ ] Will not occur [ X ] Polymerization:
acid anhydrides
acid chlorides
bases
brass
copper
oxidizing agents
Incompatibility - Materials To Avoid:
carbon dioxide
carbon monoxide
Hazardous Decomposition Or Byproducts:
11. Toxicological Information
The toxicological effects of this product have not been thoroughly studied.
BHT - Toxicity Data: Oral LD50 (mouse): 650 mg/kg;
BHT - Irritation Data: Skin (rabbit): 500 mg (48h) moderate; Eyes (rabbit): 100 mg (24h)
moderate;
Toxicological Information:
BHT - Investigated as a mutagen, reproductive effector, and tumorigen.
Only select Registry of Toxic Effects of Chemical Substances (RTECS) data is presented here.
See actual entry in RTECS for complete information.
BHT RTECS Number: GO7875000
Chronic Toxicological Effects:
IARC: Group 3: Not classifiable as to its carcinogenicity to humans (BHT) Carcinogenicity/Other Information:
A4 3 n.a.
Hazardous Components (Chemical Name)
BHT 128-37-0
CAS #
n.a.
NTP IARC ACGIH OSHA
1.
12. Ecological Information
Avoid release into the environment - toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Runoff from fire control or dilution water may cause pollution.
General Ecological Information:
13. Disposal Considerations
Dispose in accordance with local, state, and federal regulations. Waste Disposal Method:
14. Transport Information
Globally Harmonized System of Classification and Labelling
Acute Toxicity: Oral, Category 4 - Warning! Harmful if swallowed
Skin Corrosion/Irritation, Category 2 - Warning! Causes skin irritation
Serious Eye Damage/Eye Irritation, Category 2A - Warning! Causes serious eye irritation
Aquatic Toxicity (Chronic), Category 2 - Toxic to aquatic life with long lasting effects
LAND TRANSPORT (US DOT)
Not dangerous goods. DOT Proper Shipping Name
LAND TRANSPORT (European ADR/RID)
Not dangerous goods. ADR/RID Shipping Name
AIR TRANSPORT (ICAO/IATA)
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SAFETY DATA SHEET
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Not dangerous goods. ICAO/IATA Shipping Name
Transport in accordance with local, state, and federal regulations. Additional Transport Information:
15. Regulatory Information
Xn: Harmful; N: Dangerous for the environment European Community Hazard Symbol codes
European Community Risk and Safety Phrases
R22 - Harmful if swallowed.
R36/38 - Irritating to eyes and skin.
R51/53 - Toxic to aquatic organisms, may cause long-termadverse effects in the aquatic environment.
S22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29 - Do not empty into drains.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S57 - Use appropriate container to avoid environmental contamination.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
US EPA SARA Title III
No No No
Hazardous Components (Chemical Name)
BHT 128-37-0
CAS #
No
Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110
1.
Other US EPA or State Lists
Inventory No No
Hazardous Components (Chemical Name)
BHT 128-37-0
CAS #
No
CAA HAP,ODC CWA NPDES TSCA CA PROP.65
1.
This SDS was prepared in accordance with 29 CFR 1910.1200, Regulation (EC) No.1272/2008,
and European Directive 67/548/EEC as amended.
Regulatory Information Statement:
16. Other Information
02/11/2013 Revision Date:
Company Policy or Disclaimer
For research use only, not for human or veterinary use.
DISCLAIMER: This information is believed to be accurate and represents the best information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting fromits use. Users should
make their own investigations to determine the suitability of the information for their particular purposes.
N.A.=Not available, N.P.=Not applicable, N.D.=Not determined, N.E.=Not established, N.R.=Not required
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