Assignment 07 ON CARBONYL COMPOUNDS

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10042023 CHEMISTRY HOUSE Ranker’s Batch

Assignment # 07
ORGANIC CHEMISTRY
(Topic: Carbonyl Compounds)
(for JEE-Mains & Advanced 2024)
=============================================================================================================
Q.1 Among the following acids :
Me
(A) HCOOH (B) PhCOOH (C) Me COOH (D)
COOH

COOH Me
(E) Et3C – COOH (f) (G) COOH
Me
Me
(H) PhCH2COOH
‘n1’ no. of acids are not capable to perform HVZ reaction with Br2/red P
Consider the following reaction sequence

Me
N
1 eq. semicarbazide
CH=O (P)

1 eq. Borsch reagent


O
(Q)
The number of nitrogen atoms in (Q) are ‘n2’. The value of (n1 + n2) is :
(a) 11 (b) 12 (c) 13 (d) 14
COOH
Q.2 Heat Cl2 /red P
COOH   (A)   (B)
The structure of (B) is :

O
O
Cl
(a) O
O

O
O COOH
Cl
(b) O (c)
Cl
O

COOH + COOH
(d)
Cl Cl

page no # 1

Q.3 KCN
PhCH2Br  H3 O
 (A)   (B)
(B) on reaction with Br2/red P gives :

(a) Br CH2COOH (b) Br Ph


COOH

H
O
CH2COOH
(c) (d) Br C
Br pH

HOOC OH

Q.4 heat Product is :


Et Me

O O
O O O
O O O
(a) (b) (c) (d)
Et Me Et Et Me
Me Me Et

HOOC
COOH 
Q.5 OH Product is :
HO
O O COOH
(a) O (b)
HOOC O

O
HOOC O
HOOC
(c) (d) O
O

+
Q.6 n—BuCOOMe MeONa Product is :

O
OMe
(a) (b) OMe
O O O
O
O O
OMe
(c) O Me (d)
O
O
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